Documente Academic
Documente Profesional
Documente Cultură
Sl. No.
Name
Designation
1.
Principal,
G.B.S.S.S. No. 1,
Shakti Nagar, Delhi-110007
2.
Vice Principal,
Govt. Co-ed SSS, Shivpuri,
Delhi-110051
3.
Lecturer (Chemistry),
R.P.V.V., Narela
Delhi-110040
4.
Ravinder Malik
Member
Lecturer (Chemistry),
S.B.V., Narela, Delhi-110040
CONTENTS
S. No.
Chapter
Marks
Page
3-4
5-10
11-19
2. Solutions
20-30
3. Electrochemistry
23
31-41
4. Chemical Kinetics
42-51
5. Surface Chemistry
52-58
59-65
66-88
19
89-108
9. Co-ordination Compounds
109-116
117-136
137-150
151-172
13. Amines
28
173-185
14. Biomolecules
186-192
15. Polymers
193-197
198-205
206-247
Time : 3 hours
Sl.No. Typology of Questions
Max. Marks 70
VSA
(1M)
SA-I
(2M)
(LA)
(5M)
Total
Marks
10%
21
30%
21
30%
10
14%
11
10%
%
Weightage
100%
Total Marks
VSA
05
SA-I
10
SA-II
12
36
VBQ
04
LA
15
26
70
Total
1.
2.
The above template is only a sample. Suitable internal variations may be made for
generating similar templates keeping the overall weightage to different form of questions
and typology of questions same.
2.
Number of
particles per
Unit Cell
Relationship
between edge
length (a) and
radius (r) of
atom/ion
a = 2r
a =
a = 2 2 r
4
3
d=
ZM
a3NA
Where Z is rank of unit cell (no. of atoms per unit cell), M is molar mass/
atomic mass, a is edge length of the cube, a3 is volume of cubic unit cell
and NA is Avogadro constant.
Z
3.
Packing efficiency, PE
4 3
r
3
100
a3
Packing
efficiency
Rank of
Unit Cell (Z)
SC
52.4%
BCC
68.%
FCC
74%
Solution
1.
xA =
nA
nB
, and xB =
nA + nB
nA +nB
xA + xB = 1
2.
Molarity (M) =
Moles of solute
mol L1
Volume of solution in litres
3.
Molality (m) =
Moles of solute
mol kg1
Mass of solvent in kilograms
4.
5.
6.
pA pA
n
W MA
(for dilute solutions)
= ixB i B = i B
nA
MB WA
pA
Where xB is mole fraction of solute, i is vant Hoff factor and
pA pA
is
pA
7.
Tb = Tb Tb
Kb = molal boiling point elevation constant
m = molality of solution.
Tb = Boiling point of solution.
Tb = Boiling point of solvent.
8.
9.
= i CRT
i=
i=
11.
Tb
p
=i
MA 1000
pA
Kb
Here
p is lowering in vapour pressure, pA is vapour pressure of pure solvent,
i is van't Hoff factor, Tb is elevation in boiling point, Kb is molal elevation
constant and MA is molar mass of solvent
Electrochemistry
1.
Conductivity (k) :
k=
1 1 l
=
R A
m =
1000 k
c
m = + +
Here and are the limiting molar conductivities of cation and
anion respectively and + and are the number of cations and anions
furnished by one formula unit of the electrotype.
(b)
mc
om
cm
C
o
C 2
m
K=
=
1
m
1 o
m
3.
E = E
2.303 RT
1
0.059
1
log n+ E
V log n+
M
nF
[M ]
n
ne
cC + dD
is given by :
c
Ecell
= Ecell
4.
5.
C D
2.303RT
0.059
log QC E
V log
nF
n
Aa Bb
2.303RT
0.059V
log KC =
log KC
nF
n
G = nF Ecell
Where G = standard Gibbs energy change and nF is the number of
faradays of charge passed. Ecell is standard cell polential.
G = 2.303 RT log K c
9
Chemical Kinetics
1.
Integrated rate law equation for zero order reaction is given as below:
(a)
R Rt
k =
t1 =
2k
2.303
R
log
t
R t
k =
3.
t
1
2
0.693
k
Arrhenius equation
(a)
k=Ae
Ea
RT
log k log A
Ea
Ea
, Here
is slope of the straight line
2.303 RT
2.303 R
1
T
T T
a
2
2
1
log k = 2.303 R T T
1
1
2
Unit 1
HCP and CCP have equal efficiency i.e., 74% of space is occupied and
coordination no. is 12. CCP arrangement has FCC lattice.
2.
3.
4.
5.
tetrahedral void
(ii)
octahedral void
7.
8.
(b)
(c)
9.
Schottky defect arises due to missing of equal no. of cations and anions
from lattice sites in the crystalline solid of the type A + B and it lowers
and density of crystal of alkali metal halides, e.g., NaCl, KCl etc.
10.
11.
Non-stoichiometric defect
(a)
(b)
(c)
12.
13.
12
14.
Magnetic properties
2.
3.
4.
5.
What type of stochiometric defect is shown by (i) ZnS and (ii) CsCl?
6.
7.
an octahedral void?
(b)
a tetrahedral void?
8.
How many octahedral voids are there in 1 mol of a compound having cubic
closed packed structure?
9.
Arrange simple cubic, bcc and fcc lattice in decreasing order of the fraction
of the unoccupied space.
10.
11.
An element crystallises separately both in hcp and ccp structure. Will the
two structures have the same density? Justify your answer.
[Hint : Both crystal structures have same density because the percentage
of occupied space is same.]
13
12.
In Corundum, O2 ions from hcp and Al3+ occupy two third of octahedral
voids. Determine the formula of corundum.
13.
14.
15.
16.
Name the crystal defect which lowers the density of an ionic crystal.
17.
18.
Which point defect in ionic crystal does not alter the density of the
relevant solid?
19.
Name one solid in which both Frenkel and Schottky defects occur.
20.
21.
22.
23.
24.
25.
2.
(b)
3.
4.
(b)
Window glass panes of old buildings are thicker at the bottom than
at the top.
5.
6.
7.
8.
9.
10.
Density
(b)
Electrical conductivity.
(b)
Intrinsic semiconductor
(b)
Extrinsic semiconductor.
11.
Explain how vacancies are introduced in a solid NaCl crystal when divalent
cations (M2+) are added to molten NaCl.
12.
13.
Define the term point defects. Mention the main difference between
stoichiometric and non-stoichiometric point defects.
14.
15.
(b)
16.
17.
Ferromagnetism
(b)
15
12-16 compounds
[Class XII : Chemistry]
2.
Write the relationship between atomic radius (r) and edge length (a) of
cubic unit cell for
(a)
(b)
(c)
3.
*4.
5.
group 13 element,
(b)
group 15 element.
Ferrimagnetism
(c)
13-15 compounds
(b)
Antiferromagnetism
Examine the defective crystal lattice given below and answer the following
questions :
(a)
(b)
Out of AgCl and NaCl, which is most likely to show this type of defect
and why?
(c)
(a)
(b)
(c)
NUMERICALS
UNIT CELLS AND CRYSTAL LATTICES
1.
2.
3.
4.
6.
7.
A metallic element has a body centred cubic lattice. Edge length of unit cell
is 2.88 108 cm. The density of the metal is 7.20 gcm3. Calculate
(a)
(b)
(c)
[Ans. : (a) 2.39 1023 cm3 (b) 1.72 1022 g, (c) 1.162 1024 atoms]
8.
Molybednum has atomic mass 96 g mol1 with density 10.3 g/cm3. The
17
edge length of unit cell is 314 pm. Determine lattice structure whether
simple cubic, bcc or fcc.
(Given NA = 6.022 1023 mol1)
**9.
The density of copper metal is 8.95 g cm3. If the radius of copper atom
is 127 pm, find out whether the copper unit cell is a simple cubic, a bodycentred cubic or a face centred cubic?
(Given at. mass of Cu = 63.54 g mol1 and NA = 6.02 1023 mol1]
[Ans. : Z = 4, fcc type]
ZM
Z
[Hint : d = a3 N and calculate 3 by putting the values given in the
a
A
question.
z
Calculate packing efficiency by
Z
a3
4 3
r 100
3
a3
using value of
. The packing efficiency is 74% which shows that the lattice is fcc.
10.
A metal crystalises into two cubic lattices fcc and bcc, whose edge length
are 3.5 and 3.0 respectively. Calculate the ratio of the density of fcc
to bcc lattices.
11.
Tungsten crystallizes in body centred cubic unit cell. If the edge of the unit
cell is 316.5pm, calculate the radius of tungsten atom?
[Ans. : 137.04 pm]
12.
Iron has a body centred cubic unit cell with a cell dimension of 286.65 pm.
The density of iron is 7.874 g cm3. Use this information to calculate
Arogadro number.
(At. Mass of Fe = 55.845u).
[Ans. : 6.02 1023 mol1]
13.
Silver crystallizes in fcc unit cell. Each side of this unit cell has a length of
400 pm. Calculate radius of the silver atom.
14.
An element with density 11.2 g/cm3 forms a fcc lattice with edge length of
4108 cm. Calculate atomic mass of element.
IMPERFECTION IN SOLIDS
15.
AgCl is doped with 102 mol% of CdCl2, find the concentration of cation
vacancies.
[Ans. : 104 mol]
18
16.
17.
19.
Tina took Sheena to her ancestral house in a village. The house was more
than 100 years old. Both observed that glass panes fixed to windows were
thicker at the bottom than at the top. Also, they observed that some glass
objects were milky in appearance.
(a)
Why glass panes fixed to windows were slightly thicker at the bottom?
(b)
(c)
Two group of students were provided with 50 plastic balls each and a tray
by the teacher. They were asked to arrange them in an orderly manner in
minimum time. One group successfully arrnaged them while other group
was not able to arrange them.
(a)
(b)
(c)
(a)
(b)
21. (a)
(b)
Ferrimagnetic substances.
(ii)
Ferromagnetic substances.
(iii)
n-type semiconductors.
(1+1+1)
19
(2)
Unit - 2
SOLUTIONS
POINTS TO REMEMBER
1.
2.
3.
4.
5.
11.7% w/w Helium is added to air used by scuba divers due to its low
solubility in the blood.
6.
7.
Azeotropes having the same composition in liquid and vapour phase and
boil at a constant temperature and therefore cant be distilled.
8.
Azeotropes arise due to very large deviation from Raoults law. Maximum
boiling azeotropes form when solutions exhibit negative deviation from
Raoults law whereas minimum boiling azeotropes form when solutions
exhibit positive deviation from Raoults law.
9.
10.
vant Hoff factor (i ) is the ratio of the observed value of the colligative
property in solution to the theoretically calculated value of the colligative
property.
(a)
(b)
11.
12.
13.
2.
Which type of solid solution will result by mixing two solid components with
similar sizes of their molecules?
3.
4.
5.
6.
7.
8.
9.
10.
*11. N2 and O2 gases have KH values 76.48 kbar and 34.86 kbar respectively
at 293 K temperature. Which one of these will have more solubility in
water?
*12. Under what condition molality and molarity of a solution are identical.
Explain with suitable reason.
[Ans. : When solution is too dilute]
21
What will happen to the boiling point of the solution formed on mixing two
miscible liquids showing negative deviation from Raoults law?
15.
Liquid Y has higher vapour pressure than liquid X, which of them will
have higher boiling point?
*16. When 50 mL of ethanol and 50 mL of water are mixed, predict whether the
volume of the solution is equal to, greater than or less than 100 mL. Justify
your answer.
17.
18.
19.
20.
21.
If kf for water is 1.86 K kg mol1, what is the freezing point of 0.1 molal
solution of a substance which undergoes no dissociation or association of
solute?
22.
*23. What is the maximum value of vant Hoff factor (i) for Na2SO4 . 10H2O?
24.
What is the maximum value of vant Hoff factor (i) if solute molecules
undergo dimerisation.
25.
*26. The phase diagram for pure solvent and the solution containing nonvolatile
solute are recorded below. The quantity indicated by X in the figure is
known as :
1 atm
22
*27. AgNO3 on reaction with NaCl in aqueous solution gives white precipitate.
If the two solutions are separated by a semi-permeable membrane, will
there be appearance of a white ppt. in the side X due to osmosis?
2.
(b)
(b)
3.
4.
5.
Draw the total vapour pressure vs. mol fraction diagram for a binary solution
exhibiting non-ideal behaviour with negative deviation.
6.
The vapour pressure curve for three solutions having the same non-volatile
solute in the same solvent are shown. The curves are parallel to each
other and do not intersect. What is the correct order of the concentrations
of the solutions.
1 bar
23
7.
8.
9.
When 1 mole of NaCl is added to 1 litre water, the boiling point increases?
When 1 mole of C2H5OH is added to 1 litre water, the boiling point
decreases? Suggest reasons.
10.
11.
1 gram each of two solutes A and B (molar mass of A > molar mass of
B) are dissolved separately in 100 g each of the same solvent. Which
solute will show greater elevation in boiling point and Why?
12.
(a)
(b) Name the phenomenon involved in this experiment so that the level
of liquid in this the funnel has risen after some time.
13.
14.
15.
16.
17.
(a)
(b)
Solvent
(a)
Solution
Solution
(b)
(b)
(c)
2.
3.
(b)
(c)
4.
5.
RBC swell up and finally burst when placed in 0.1% NaCl solution.
(b)
When dried fruits and vegetables are placed in water, they slowly
swell and return to original form?
(c)
6.
(b)
(c)
[Elevation in b.pt.]
[Depression in f.pt.]
2.
(a)
(b)
(a)
(b)
3.
(a)
(b)
(c)
Calculate the amount of ice that will separate out on cooling solution
containing 50 g of ethylene glycol (molar mass = 62 g mol1) in 200
g H2O to 9.3C. (Kf for water = 1.86 K kg mol1)
[Ans. : 38.71g]
4.
(a)
(b)
(c)
26
NUMERICAL PROBLEMS
EXPRESSING CONCENTRATION OF SOLUTIONS
1.
2.
Calculate (a) molality (b) molarity and mole fraction of KI if the density of
20% (mass/mass) aqueous KI is 1.202 g/mL.
[Ans. : (a) = 1.5 m, (b) = 1.45m (c) = 0.0263]
3.
4.
by mass.
(a)
(b)
(c)
5.
6.
HENRYS LAW
7.
The solubility of oxygen in water is 1.35 103 mol L1 at 20C and 1 atm
pressure. Calculate the concentration of oxygen at 20C and 0.2 atm
pressure.
[Ans. : 2.7 104 mol L1]
8.
9.
Henrys Law constant for CO2 dissolving in water is 1.67 108 pa at 298
K. Calculate the quantity of CO2 in 1L of soda water when packed under
2.5 atm of CO2 pressure at 298K.
[Ans. 3.707 g]
27
RAOULTS LAW
10.
11.
The vapour pressure of pure liquids A and B are 450 and 750 mm Hg
respectively at 350K. Find out the composition of the liquid mixture if total
vapour pressure is 600 mm Hg. Also find the composition of the vapour
phase.
[Ans. : XA = 0.4, XB = 0.6, YA = 0.3, YB = 0.7]
12.
Two liquids X and Y on mixing form an ideal solution. The vapour pressure
of the solution containing 2 mol of X and 1 mol of Y is 550 mm Hg. But
when 4 mol of X and 1 mol of Y are mixed, the vapour pressure of solution
thus formed is 560 mm Hg. What will be the vapour pressure of pure X and
pure Y at this temperature?
[Ans. : px = 600 mm Hg; py = 400 mm Hg]
13.
(ii)
15.
16.
17.
Calculate the mass of a non-volatile solute (molar mass 40g mol1) which
should be dissolved in 114g octane to reduce its vapour pressure to 80%.
[Ans. : 8.0 g]
28
19.
20.
22.
23.
24.
Calculate the amount of NaCl which must added to one kg of water so that
the freezing point is depressed by 3K. Given Kf = 1.86 K kg mol1, Atomic
mass : Na = 23, Cl = 35.5).
[Ans. : 0.81 mol NaCl]
25.
29
26.
Two elements A and B from Compounds having formula AB2 and AB4.
When dissolved in 20.0 g benzene (C6H6), 1 g and AB2 lowers the freezing
point by 2.3 K whereas 1.0 g of AB4 lowers it by 1.3 K. The molar depression
constant for benzene is 5.1 K kg mol1. Calculate atomic masses of A
and B.
[Ans. : A = 25.584, B = 42.644]
27.
OSMOTIC PRESSURE
28.
29.
31.
Yaminis mother is preparing mango pickle. Yamini observed that her mother
cut mangoes into pieces and then kept them in salt water. She observed
that raw mangoes shrivel when pickled in salt water. She goes to her elder
sister and asks about this happening.
(a)
(b)
(c)
Parul has throat problem and was unable to answer teachers question
in the chemistry class. The teacher asked Parul to add pure NaCl to warm
water and gargle with it. After doing so she felt better. Then her friend
explained the chemistry behind this effect.
(a)
(b)
(c)
Write the associated values shown by Paruls friend and her teacher.
30
Unit - 3
ELECTROCHEMISTRY
POINTS TO REMEMBER
1.
2.
3.
H2
0.0V
4.
5.
For an electrochemical cell, if G < 0 then, cell will work and Ecell will
be > 0.
6.
7.
8.
9.
10.
11.
12.
A fuel cell is a voltaic cell that utilizes fuel such as H2, CH4, CH3OH etc.
in the cell reaction.
Anode : CH4 + 2H2O CO2 + 8H+ + 8e
Anode : CH3OH + H2O CO2 + 6H+ + 6e
Cathode : 4e + O2 + 4H+ 2H2O
13.
2.
3.
Give the condition for for a cell when there is no flow of electrons or current.
4.
Can you store zinc sulphate solution in a copper container? Give suitable
reason. (EZn2+/Zn = 0.76V, E Cu2+/Cu = 0.34V)
5.
6.
List the two factors that influence the value of cell potential of a galvaniccell.
7.
8.
Write the relation between Ecell and equilibrium constant (K) of a cell reaction.
9.
10.
11.
12.
13.
14.
15.
16.
32
17.
Two metals A and B have reduction potential values of 0.25V and 0.80V
respectively. Which of these will liberate hydrogen gas from dilute H2SO4?
18.
19.
20.
21.
22.
Galvanized iron does not corrode even if the coating of zinc is broken.
Explain why?
2+
2
Given : E Fe / Fe = 0.44V; E Zn / Zn = 0.76V
23.
How does tin plating prevent the corrosion of objects made of copper?
Cu2 Cu
0.34 V and E
0.14 V
Sn2 Sn
2.
Draw a diagram of the cell and mark anode and cathode as current
is drawn from the cell.
(ii)
Write the reactions taking place at the cathode and the anode during
the operation of Daniel cell.
3.
4.
5.
6.
Ionic mobility.
(b)
Over-voltage
Account for the fact that when chlorine is passed through a fluoride solution,
no reaction takes place.
Given E
F2
33
2F = 2.87V; E Cl2
2Cl
Cl2
2Cl = 1.36V
7.
Copper does not dissolve in HCl (aq) but dissolves in HNO3 (aq) producing
Cu2+ ions. Explain the difference in behaviour.
[Given E Cu2+
Cu
= 0.34V; E Cl2
NO (g) + 2H2 O, E NO 3
8.
NO
2Cl
= 1.36V and NO 3 4H + 3e
= 0.97V]
(b)
9.
Write the cell reaction which occurs in the lead storage battery (a) when
the battery is in use (b) when the battery is on charging.
10.
What are fuel cells? Describe the principle and overall reaction involved in
the working of hydrogenoxygen fuel cell or CH3OH O2 fuel cell.
11.
12.
(a)
(b)
(a)
(b)
34
13.
You are aquainted with the construction and working of a lead storage
battery. Give the plausible reason for the fact :
addition of water is necessary from time to time for maintenance
[Ans. If the recharging is too fast, the electrolysis of
H2O occurs to form H2 and O2(g)]
Formulate the galvanic cell in which the following reaction takes place :
Zn(s) + 2Ag+ (aq) Zn2+ (aq) + 2Ag(s)
State :
(a)
(b)
(c)
2.
3.
(b)
(c)
4.
5.
(a)
(b)
(a)
(b)
2.
(i)
3.
(a)
(b)
4.
(a)
(b)
Ce3+ + Fe3+
Given E Ce4
1.44V ; E
Ce3
Fe3
0.68V
Fe2
(a)
(b)
(ii)
Fuel cell.
6.
(a)
(b)
36
NUMERICAL PROBLEMS
NERNST EQUATION
1.
(a)
(b)
2.
A zinc rod is dipped in 0.1M solution of ZnSO4. The salt is 95% dissociated
at this dilution at 298K. Calculate the electrode potential
E
3.
Zn2+
0.76 V .
Zn
[Ans. : 0.7902V]
For the electrode Pt, H2 (g, 1 atm) | H+(aq) (x M), the reduction electrode
potential at 25C is 0.34V. Write the electrode reaction and calculate the
value of x. and the pH of solution.
[Ans. : x = 1.807 106, pH = 5.743]
4.
For what concentration of Ag+ (aq) will the emf of the given cell be zero
at 25C if concentration of Cu2+ (aq) is 0.1M?
Given E Ag+
Ag
0.80 V; E Cu2
0.34 V .
Cu
Write the Nernst equation and calculate the emf of the following cell at
298K.
Cu(s) | Cu2+ (0.130M) || Ag+ (102 M) | Ag(s)
Given E
6.
Cu2+
0.34 V; E
Cu
0.80 V
Ag
[Ans. : 0.37V]
Ag
Write the Nernst equation and emf of the following cell at 298K
Pt(s) | Br2(l) | Br (0.010M) || H+ (0.030 M) | H2 (g, 0.9 bar) | Pt(s)
Given E
[Ans. : 1.29 V]
37
7.
Given
0.34V ; E
Cu
2.375 V
Mg 2
Mg
[Ans. : 2.651 V]
8.
ECell 0.44 V
[Ans. : 0.5285V]
11.
Cu
0.34 V; E Fe2
0.44 V
Fe
Calculate the standard cell potential of a galvanic cell in which the following
reaction takes place :
2Cr(s) + 3Cd2+ (aq) 2Cr3+ (aq) + 3Cd(s)
Calculate rG and equilibrium constant, K of the above reaction at 25C.
[Given E
Cr 3 Cr
0.74V, E
Cd2 Cr
Calculate the cell emf and rG for the cell reaction at 25C
Zn(s) | Zn2+ (0.1M) || Cd2+ (0.01M) | Cd(s)
38
(Given
Zn2 2n
0.763V, E
Cd2 Cr
0.403V,
In the button cell widely used in watches and other derices, the following
reaction takes place :
Zn(s) + Ag2O (s) + H2O (l) Zn2+ (ag) + 2Ag(s) + 2OH(aq)
Zn2+/Zn
= 0.76V; E
Ag+/Ag
= 0.8V
2
2
Al O2 Al2O3 , f G 1050 kJ / mol
3
3
Calculate voltage applied to carry out electrolysis of Al2O3.
(F = 96500 C mol1]
[Ans. : 2.720 V]
[Hint :
2
4
Al O Al O2 , r G 1050 kJ / mol
3 2 3
3
rG = nE F and n = 4]
15.
17.
39
18.
KOHLRAUSCH LAW
19.
The molar conductivities of NH+4 ion and Cl ion are 73.5 S cm2 mol1 and
76.255 cm2 mol1 respectively. The specific conductivity of 0.1 M NH4Cl is
1.288 102 S cm1. Calculate the dissociation constant of NH4Cl.
[Ans. : 7.396 102]
20.
Molar conductivity at infinite dilution for NH4Cl, NaOH and NaCl solution at
298K are respectively 129.8, 218.4 and 108.9 S cm2 mol1 and cm for
102 M solution of NH4OH is 9.33 S cm2 mol1. Calculate the degree of
dissociation of NH4OH.
[Ans. : 0.039]
21.
[Ans. : 3 102]
23.
One afternoon when Preeti returned from her school she found that the
main gate of her house was painted in green. She was very happy to see
it. After about two months, she noticed a brown and brittle solid deposited
at a small portion of the gate. On looking minutely at it she found that there
was no paint on that portion of the gate. Immediately she thought of
its reason.
(a)
(b)
(c)
(d)
Manu and his father went to a shop to purchase a battery for inverter.
Shopkeeper showed them two types of batteries, one with lead plates and
other with cadmium plates. Manus father wanted to purchase lead battery
as it was cheaper but Manu suggested cadmium battery.
(a)
24.
(b)
(c)
(d)
The lead storage battery cannot be sealed whereas, the Ni-Cd battery
can be sealed. Explain why?
Hints :-
f G in kJ/mol for
Ag2O (s)
11.2
H2O (l)
237.13
Zn2+ (aq.) =
147.24
r G
f G (products) f G (reactants).
213.21 KJ/mol.
r G
n F E cell
E cell
1.1047 V.
41
Unit - 4
CHEMICAL KINETICS
POINTS TO REMEMBER
1.
mol L1 s1 or Ms1
s1
L mol1 s1 or M1 s1
2.
3.
4.
5.
When a reaction is first order w.r.t. each of the two reactants, it becomes
pseudo first order when one of the reactants is taken in excess.
H
For example, CH3 COOC2H5 H2O excess
CH3COOH C 2H5OH
6.
The half life (t1/2) of a reaction is the time in which the concentration of
a reactant is reduced to one half of its initial concentration.
t1 2
7.
R n1
0
8.
9.
k A e Ea
RT
10.
11.
Ea
denotes the fraction of effective collisions having kinetic energy
RT
activation energy (E a).
2.
3.
Express the rate of reaction in terms of Br (aq) as reactant and Br2 (aq)
as product for the reaction :
5 Br(aq) + Br(aq) + 6H+ (aq) 3 Br2(aq) + 3H2O(/)
4.
P
and negative sign () before
t
R
?
t
5.
6.
7.
Write the unit of first order rate constant of a gaseous reaction if the partial
pressure of gaseous reactant is given in bar.
8.
For a reaction :
R P, the change in concentration of reactant w.r.t. time is shown by
following graph :
43
Concentration [A]
[A]0
Time (t)
(i)
(ii)
9.
What will be the order of reaction, if the rate of reaction does not depend
on the concentration of any of the reactant.
10.
11.
12
13.
*14. Express the relation between the half-life period of a reactant and initial
concentration of a reaction of nth order.
[Ans. : t
R n01
*15. A reaction is 50% complete in 2 hours and 75% complete in 4 hours. What
is the order of reaction?
[Ans : First order]
16.
44
20.
For a chemical reaction, rate constant k = 5.3 104 mol L1 s1, what will
be the order of reaction?
[Ans. : Zero order]
List four factors which affect the rate of a chemical reaction. State how
each of these factors changes the reaction rate.
2.
Differentiate between
3.
(a)
(b)
A + B P is given by
4.
5.
6.
Show that time required for 99.9% completion of the first order reaction is
10 times of t1/2 for first order chemical reaction.
7.
8.
(a)
(b)
2.
(a)
(b)
3.
Room temperature
(b)
(c)
(a)
(b)
the following data were collected. All the measurements were taken
at 263K
Experiment
No.
Initial
Initial
[NO] / M
[Cl2] /M
Initial rate
of disapperance
of Cl2 [M / min]
0.15
0.15
0.60
0.15
0.30
1.20
0.30
0.15
2.40
0.25
0.25
(i)
(ii)
(iii)
2.
3.
(a)
(b)
(a)
Derive the equation for rate constant of a first order reaction. What
would be the units of the first order rate constant if the concentration
is expressed in moles per litre and time in seconds?
(b)
47
4.
The time required for 10% completion of first order reaction at 298K is
equal to that required for its 25%, completion at 308K. If the value of A is
41010s1. Calculate k at 318K and Ea.
NUMERICAL PROBLEMS
RATE OF REACTION
1.
2.
3.
[B2] mol/L1
0.5
0.5
1.6 104
0.5
1.0
3.2 104
1.0
1.0
3.2 104
[Ans : Rate = k [B2]
48
104
A first order reaction has a rate constant 1.15 103 s1. How long will 5g
of this reactant takes to reduce to 3g?
[Ans. : t = 444 s]
7.
Show that for a first order reaction, time required for 99% completion is
twice for the time required for the 90% completion of reaction.
8.
9.
360
720
Pressure (atm.)
35.0
54.0
63.0
The rate constant for a chemical reaction is 2.303 103 min1. If the
initial concentration of reactant is 0.02 mol L1, then calculate
(a)
(b)
20
2.303
2.303 10
0.02
log
x
Time/S1
1.
2.
0
100
0.4
0.7
49
ACTIVATION ENERGY
12.
13.
The rate of reaction triples when the temperature changes from 20C to
50C. Calculate the energy of activation. [R = 8.314 J K 1 mol 1,
and log 3 = 0.48]
[Ans. : 12.59 kJ]
15.
16.
The rate constant for the first order decomposition of H2O2 is given by the
following equation : log k = 14.34 1.25 104 K/T. Calculate Ea for this
reaction and at what temperature will its half-life be 256 minutes.
[Ans. : Ea = 239.34 kJ; T = 670K]
17.
18.
Ea 1
2.303 R T
1
,
T
a straight line with a slope of 4250 K is obtaioned. Calculate Ea for the
reaction. [R = 8.314 J k1 mol1].
[Ans. : 81.375 kJ mol1]
50
Reena and Meena were asked by the chemistry teacher to perform the
reaction between zinc and dilute H2SO4 in the laboratory. The teacher
provided zinc granules, zinc powder and dilute H2SO4. Reena choose zinc
powder and acid while meena choose zinc granules and acid.
(a)
(b)
(c)
(d)
Why does the rate of reaction increase with the increase in the
surface area?
51
Unit - 5
SURFACE CHEMISTRY
POINTS TO REMEMBER
1.
2.
3.
4.
5.
6.
Greater the surface area of the adsorbent, the more is the extent
adsorption.
7.
8.
9.
10.
, i.e.,
52
log
x
1
log k log P
m
n
The plot of log x/m vs log P gives a straight line with slope =
1
and y
n
intercept = log k.
11.
12.
13.
14.
15.
Enzymes are biological catalysts. Their main characteristics are their high
specificity, efficiency (even in traces) and activity at physiological
temperature of 37C and pH of 7.4.
16.
18.
19.
Lyophilic sols are formed by organic substances like gum, starch, protein
etc. These are reversible and more stable.
53
20.
21.
22.
23.
24.
25.
26.
The process of changing the colloidal particles in a sol into the insoluble
precipitate by the addition of some suitable electrolytes is known as
coagulation.
27.
28.
29.
30.
31.
32.
Why does a gas mixed with another gas not form a colloidal system?
2.
3.
4.
5.
6.
7.
Mention one shape selective catalyst used to convert alcohol directly into
gasoline.
8.
9.
(b)
10.
11.
12.
13.
14.
15.
What are the optimum temperature and pH at which enzymes are highly
active.
16.
What are the physical states of dispersed phase and dispersion medium
in foam rubber.
17.
18.
[Ans. : lactobacilli]
55
20.
21.
What happens when hydrated ferric oxide and arsenious sulphide sols are
mixed in almost equal proportions?
22.
23.
Mention the two conditions for the formation of micelles. [Hint.: CMC & Tk]
24.
25.
26.
State the purpose of impregnating the filter paper with colloidion solution.
27.
29.
30.
32.
Mention two examples of emulsifying agents for o/w type emulsions and
w/o type emulsions.
33.
34.
35.
36.
37.
In what way these are different : (a) a sol and a gel (b) a gel and an
emulsion.
38.
39.
40.
41.
(a)
(b)
Zeta potential.
(a)
(b)
42.
Mention the two necessary conditions for the observation of Tyndall Effect.
43.
44.
45.
(a)
(b)
(b)
46.
What are lyophilic and lyphobic colloids? Which of these sols can be easily
coaqulated on the addition of small amounts of electrolytes?
(b)
48.
49.
Mention the two important features of solid catalysts and explain with the
help of suitable examples.
50.
How are the following colloids different from each other in respect of
dispersion medium and dispersed phase? Give one example of each type.
(a)
An aerosol
(b)
A hydrosol
57
(c)
An emulsion.
[Class XII : Chemistry]
51.
What
(a)
(b)
(c)
happens :
by persistent dialysis of a sol.
when river water meets the sea water.
when alum is applied on cuts during bleeding.
52.
54.
While inserting a glass tube in a rubber cork, a student got a cut on his
finger and started bleeding. On sensing some trouble, the chemistry teacher
immediately rushed to the students and advised the student to apply ferric
chloride solution on the cut and then go to medical room of school. When
a few drops of ferric chloride were applied on the cut, the bleeding was
stopped.
(a) Why is ferric chloride used to stop bleeding?
(b) Define the process involved in above case.
(c)
What value can be associated to the above incidence.
(d) Can we use alum to stop bleeding in place of FeCl3. If yes, why?
A factory was situated very close to a residential area where Rahul lived.
The factory worked round the clock and smoke coming out of chimneys
was causing a lot of health problems to people living in the area. Rahul
and few others decided to meet factory officials and gave them an idea to
install an apparatus in chimney.
(a) Which apparatus should be installed in chimneys?
(b) What is the purpose of the apparatus?
(c)
On what principle, apparatus will work?
(d) What values do you attribute to Rahuls concern?
(a)
Define adsorption.
(b)
(c)
(i)
Specificity.
(ii)
Temperature dependence.
(iii)
Enthalpy change.
(iv)
Reversibility.
Unit - 6
Step 2.
Concentration
(i) Levigation
(ii) Forth Floatation,
(iii) Electromagnetic separation.
(iv) Electrostatic concentration.
(v) Leaching : Used for concentration
bauxite ore of Al :
Al2O3(s) + 2NaOH(aq) + 3H2O(l)
2Na [Al(OH)4](aq)
2Na[Al(OH)4](aq) + CO2(g)
Al2O3.xH2O(s) + NaHCO3(aq)
Heat
Al2O3.xH2O(s)
Al2O3(s) +
xH2O(g)
59
Concentrated Ore
Stem 3.
Step 4.
Conversion to metal
Calcination or Roasting
Note: Absence of air is not necessary
in calcination.
Metal oxide
Smelting, Autoreduction, Electrometallurgy,
Aluminothermic process, Hydromethyllurgy
Crude Metal
Step 5.
Purification of the metal
Distillation : Zn, Hg
Liquation : Sn
Electrolytic refining : Cu
Zone refining Ge, Si, B, Ga, ln
Vapour phase refining :
Monds process : Ni
Van Arkel Method : Zr, Ti.
6. Chromatographic method : Purification
of elements present in minute quantities.
VARIOUS TYPES OF STEEL
0.2 0.5%
1.
2.
3.
4.
5.
Properties
(i) It can be hardened by
heat treatment
Uses
(i) Lightly stressed machine
fittings, turbine, motors,
railway axels, crank
shafts, fish plates, cross
heads, etc.
0.5 0.7%
1.5 2% Cr
Extremely hard
Stainless steel
11.5% Cr.
2% Ni
Resists corrosion
Note: NaCN is used as Depressant when an ore contains both ZnS and PbS. It
selectively prevents ZnS from coming to the froth but allows Pbs to come with
the froth in froth floatation process.
60
2.
*3.
Give the names and formulas of three ores which are concentrated by froth
floatation process.
4.
5.
6.
Name the most important form of iron. Mention its one use.
[Ans. : Cast iron is used for making gutter pipes, castings, railway sleepers,
toys etc.]
7.
8.
9.
10.
11.
12.
13.
**14. Write the reaction involved in the extraction of copper from low grade ores.
[Ans. : First step is leaching of ore with acid or bacteria followed by
reduction : Cu2+ (aq) + H2 (g) Cu(s) + 2H+ (g)]
15.
16.
523K
Ti I4(g)
1700K
Ti(s) + 2I2(g)
Zinc but not copper is used for the recovery of metallic silver from the
61
18.
19.
20.
Why is the froth floatation method selected for the concentration of sulphide
ores?
21.
22.
23.
Name two metals which are used for reduction in metallurgical process.
2.
3.
4.
(b)
(c)
(d)
62
5.
Extraction of copper directly from sulphide ore is less favourable than from
its oxide through reduction. Explain.
[Ans. : 2CuS(s) + C(s) CS2 (l) + 2Cu(s)
CuO(s) + C(s) CO (g) + Cu(s)
G value is more ve in second case as compared with first case]
6.
7.
Write the chemical formulas of the following ores (a) Haematite (b) Magnetite
(c) Limonite (d) Siderite.
8.
9.
Name the elements present in anode mud during refining of copper. Why
does it contain such elements?
[Ans. : Au and Ag. They are not oxidised at anode. They are less
electropositive than copper.]
10.
Write the Chemical reactions taking place in different zones in the blast
furnace for the extraction of iron from its ore.
11.
How are impurities separated from bauxite ore to get pure alumina?
12.
13.
14.
15.
Hint : E
16.
(a)
Zn 2+
Zn
is ve, E Cu2
Cu
is + ve
(b)
17.
18.
2.
How is pure copper obtained from its chief ore? Write the chemical reactions
occurring during the extraction.
3.
Hg
(b)
Sn
(c)
Cu
(d)
Ge
(e)
Ni
(f)
Zr
The native silver forms a water soluble compound (B) with dilute aqueous
solution of NaCN in the presence of a gas (A). The silver metal is obtained
by the addition of a metal (C) to (B) and complex (D) is formed as a
byproduct. Write the structures of (C) and (D) and identify (A) and (B) in
the following sequence
Ag + NaCN + [A] + H2O [B] + OH + Na+.
[C] + [B] [D] + Ag.
[Ans. :
[A] = O2
[B] = Na [Ag(CN)2]
[C] = Zn
[D] = Na2 [Zn (CN)4].
**5.
Wrought iron is the purest form of iron. Write a reaction used for the
preparation of wrought iron from cast iron. How can the impurities of sulphur,
silicon and phosphorus be removed from cast iron?
(a)
Name the metals which are associated with the following terms in
their extraction from their ores.
(i)
Bessemers Convertor
(b)
2.
3.
(ii)
(iii)
CO and not Carbon is the main reducing agent in the blas furnace
for the reduction of Fe2O3 to iron.
(b)
(c)
(d)
(e)
(a)
(b)
(ii)
(iii)
65
Unit - 7
p-Block Elements
Anomalous behaviour of first element in the p-block elements is attributed to
small size, large (charge/radius) ratio, high ionization enthapy, high electronegativity
and unavailability of d-orbitals in its valance shell.
Consequences
1.
(2)
The first element in p-block element has four valence orbitals i.e. one 2s
and three 2p, Hence maximum covalency of the first element is limited to
four. The other elements of the p-block have vacant d-orbitals in their
valence shell, e.g. elements of the third period have nine (9) valece orbitals
one 3s, three 3p and five three 3d orbitals. Hence, these elements show
maximum covalence greater than four. Following questions can be
answered:
(i)
Nitrogen (N) does not from pentahalide while P froms PCl5, PF5, and
PF6 . Why?
(ii)
Sulphur (S) forms SF6 but oxygen does not form OF6. Why?
(iii)
(iv)
Fluorine forms only one oxoacid while other halogens form a number
of oxoacids. Why?
The first member of p-block elements displays greater ability to from pp bond (s) with itself, (e.g., C = C, C C, N = N, N N) and with the other
elements of second period, for example, C = O, C N, N = O compared
to the subsequent members of the group.
This is because p-orbitals of the heavier members are so large and diffuse
that they cannot have effective sideways overlapping. Heavier members
can form p d bonds with oxygen.
Nitrogen rarely forms pd bonds with heavier elements as in case of
trisilylamine (SiH3)3N.
66
SiH3
Now, the following questions can be explained using the above mentioned
reasoning :
3.
(i)
(ii)
(iii)
Due to small size and high electronegativity and presence of lone pair(s)
of electrons, elements N, O, F when bonded to hydrogen atom, forms
hydrogen bonds which are stronger than other intermolcular forces. This
results in exceptionally high m.p. and b.p. of the compounds having NH/
OH/FH bonds.
Isostructural species have same number of bond pairs and lone pairs if present
around the central atom in a molecule/ion. Thus, they have the same geometry/
shape/structure and the same hybridisation scheme. For example,
67
(a)
In case of HNO3, two nitrogenoxygen bonds are identical and smaller than the
third nitrogenoxygen bond. This is because the third NOH bond is not involved
in resonance.
Now the following questions can be expained on the basis of this concept.
(i)
(ii)
Bond angle : In regular structures (where no lone pairs are present in the
valence shell of the central atom in a molecule/ion), the bond angle does not
68
In presence of lone pair(s) on the central atom, the geometry is distorted and the
bond angle in changed.
+
N
109.5
(ii)
Boiling and melting points of hydrides depends upon the molar mass (or surface
area) of molecules. More the molar mass, the higher is the m.p. and b.p. Hydrides
forming intermolecular hydrogen bonds have exceptionally high m.p. and b.p.
since intermolecular hydrogen bonds are stronger than the van der Waals forces.
69
Increasing order of melting point and boiling point of hybrides is as given below :
PH3 < AsH3 < SbH3 < NH3
; Melting point
; Boiling point
; Boiling point
; Melting point
(i)
(ii)
H2O is liquid and H2S is gas or H2S is more volatile than H2O.
(ii)
(iii)
(iv)
NH3 is mild reducing agent while BiH3 is the strongest reducing agent
among the group-15 hydrides.
(v)
(ii)
(iii)
(HNO 3)
Stronger than HNO 3
H2SO3
(H3PO 3)
(H3PO 2)
H 2SO 4
(H3PO 4)
O
71
hyd H
will be oxidising property of the halogen and more positive will be standard
reduction potential Ered of the halogen.
Following questions can be explained on the basis of parameters, like diss H,
egH and hyd H.
(i)
(ii)
GROUP 15 ELEMENTS
VSA QUESTIONS (1-Mark Questions)
1.
2.
3.
4.
Nitrogen exists as a diatomic molecule with a triple bond between the two
atoms whereas the heavier elements of the group 15 do not exist as E2
at room temperature. Assign a reason.
[Hint : p p multiple bonds are formed by N due to its small size.]
5.
6.
7.
8.
9.
How does ammonia solution react with Ag + (aq)? Write the balanced
chemical equation.
10.
Why does NH3 form intermolecular hydrogen bonds whereas PH3 does
not?
[Hint : Due to high electronegativity, small size of nitrogen atom and
presence of lone pair of electrons on N atom]
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
In the structure of HNO3 molecule, the NO bond (121 pm) is shorter than
NOH bond (140 pm).
2.
3.
4.
heat
(i)
(NH4)2 Cr2O7
(ii)
(i)
NH2CONH2 + H2O
(ii)
(i)
Ca3 P2 + H2 O (l)
(ii)
I2 + HNO3 (conc.)
(i)
Ba(N3)2
heat
74
5.
6.
7.
8.
9.
10.
11.
12.
heat
(ii)
4H3PO3
(i)
PH4I + KOH
(ii)
HgCl2 + PH3
(i)
PCl3 + 3H2O
(ii)
PCl5 + H2O
(i)
NO3 + Fe2+ + H+
(ii)
Zn + HNO3 (dil)
(i)
Zn + HNO3 (conc)
(ii)
P4 + HNO3 (conc)
(i)
NH3 + O2
500K, 9 bar
(ii)
P4 + NaOH + H2O
(i)
(ii)
(i)
P4 + HNO3 (conc.)
(ii)
Cu + HNO3 (conc.)
Pt Rh
Why is red phosphorus denser and less chemically reactive than white
phosphorus?
75
13.
Give chemical reaction in support of the statement that all the bonds in
PCl5 molecule are not equivalent.
14.
15.
Arrange the following in the decreasing order of their basicity. Assign the
reason :
PH3, NH3, SbH3, AsH3, BiH3.
16.
Write the conditions that favour the formation of ammonia gas along with
the reactions involved in Habers Process.
17.
(i)
(ii)
(i)
(ii)
18.
19.
Draw the structures of white phosphorus and red phosphorus. Which one
of these two types of phosphorus is more reactive and why?
20.
Explain the Ostwalds process to manufacture nitric acid. Give any two
uses of HNO3.
21.
2.
(i)
(ii)
(iii)
An unknown salt X reacts with hot conc. H2SO4 to produce a brown coloured
gas which intensifies on addition on copper turnings. On adding dilute
ferrous sulphate solution to an aqueous solution of X and then carefully
adding conc. H2SO4 along the sides of the test tube, a brown complex Y
is formed at the interface between the solution and H2SO4. Identify X and
Y and write the chemical equation involved in the reaction.
[Hint : X is NO3 salt].
76
3.
(b)
Why does R3P = 0 exist but R3N = 0 does not ? (R = an alkyl group).
(c)
[Hint :
5.
6.
(a)
(b)
(b)
(c)
The bond angles (ONO) are not of the same value in NO2
and NO2 .
(b)
(c)
77
GROUP 16 ELEMENTS
[VSA QUESTIONS (1-Mark Questions)
1.
3.
Draw the structure of H2S2O8 and find the number of SS bond if any.
4.
Which one of the following is not oxidised by O3. State the reason.
Kl, FeSO4, K2MnO4, KMnO4
[Hint. : KMnO4, since Mn is showing maximum oxidation state of +7.]
5.
6.
7.
8.
9.
10.
11.
12.
The electron gain enthalpy with negative sign for oxygen (141 KJ Mol1)
is numerically less than that for sulphur (200 KJ mol1).Give reason.
13.
14.
Why are the two SO bonds in SO2 molecule have equal strength?
15.
16.
17.
78
2.
3.
4.
5.
(b)
PbS + O3
(ii)
Kl + H2O + O3
(i)
(ii)
S8 + H2SO4 (conc.)
Explain why?
(i)
(ii)
(i)
(ii)
6.
7.
8.
9.
(a)
H2SO5
(b)
SO32
(i)
(ii)
(iii)
2.
(ii)
(iii)
3.
4.
5.
2.
3.
6.
1.
B = SO2 (g)]
(a)
(b)
What happens when SO2 is passed through water and reacts with
NaOH.? Write balanced equation.
(c)
GROUP 17 ELEMENTS
VSA QUESTIONS (1-Mark Questions)
1.
2.
Ka (HI) = 7 1011
4.
5.
6.
7.
8.
9.
Fluorine exhibit only I oxidation state whereas other halogens exhibit +ve
oxidation states also. Explain why?
10.
11.
What happens when NaCl is heated with H2SO4 in the presence of MnO2.
12.
13.
14.
Despite lower value of its electron gain enthalpy with negative sign, fluorine
is a stronger oxidising agent than chlorine. Explain.
15.
Why does fluorine not play the role of a central atom in interhalogen
compounds?
16.
ClF3 molecule has a bent T-shaped structure and not a trigonal planar
structure. Explain.
2.
(i)
(ii)
(i)
(ii)
What happens when NaCl is heated with conc. H2SO4 in the presence
of MnO2. Write the chemical equation.
81
3.
4.
Which fluorinating agent are oftenly used instead of F2? Write chemical
equation showing their use as fluorinating agents.
[Hint : U(s) + 3ClF3(l) UF6(g) + 3ClF(g)
5.
6.
7.
8.
9.
10.
11.
(i)
(ii)
HCl + O2
(i)
Ca(OH)2 + Cl2
(ii)
N2 (Excess) + Cl2
(i)
(ii)
N2 + Cl2 (Excess)
(i)
(ii)
(i)
Fe + HCl
(ii)
Cl2 + F2 (Excess)
(i)
U + ClF3
(ii)
CuCl
82
(ii)
According to Fajans Rule, bigger ions more are polarised than the
smaller ion by a particular cation.
(ii)
(iii)
2.
3.
(b)
What are the products obtained when X2 reacts with H2O? Write
chemical equation.
(c)
What happens when X 2 reacts with hot and conc. NaOH? Give
equation.
Arrange the following in the order of the property indicated for each set :
(a)
(b)
(c)
[Hint :
(a)
4.
(b)
(c)
Hypochlorous acid
(b)
Chlorous acid
(d)
Perchloric acid
GROUP 18 ELEMENTS
1.
What inspired N. Bartlett for carrying out reactin between Xe and PtF6?
2.
Predict the shape and the asked angle (90 or mre or less) in the
following case:
XeF2 and the angle FXeF
3.
4.
Why do some noble gases form compounds with fluorine and oxygen only?
5.
6.
XeF2 has a straight linear structure and not a bent angular structure. Why?
7.
8.
Suggest reason why only known binary compounds of noble gases are
fluorides and oxides of Xenon and to a lesser extent of Kryton.
[Hint : F and O are most electronegative elements. Kr and Xe both have
low lonisation enthalpies as compared to He and Ne.]
2.
(a)
*(b)
84
4.
XeF2 is hydrolysed
(b)
XeF6 + H2O
Complete
hydrolysis
(ii)
XeF6 + H2O
Partial
hydrolysis
5.
6.
7.
(a)
(b)
XeF2(s) + H2O(l)
(b)
XeF4 + O2F2
143 K
2.
3.
(ii)
(iii)
(i)
How is XeO3 prepared from XeF6? Write the chemical equation for
the reaction.
(ii)
4.
XeOF4
(ii)
XeF6
(iii) XeO3
85
XeF2 + NaF
5.
(ii)
XeF4 + SbF5
(iii)
XeF4 + H2O
Give the formulas and describe the structures of noble gas species which
is isostructural with
(i)
ICl4
(ii)
IBr2
(iii)
BrO3
(b)
(c)
How is PH3 prepared in the laboratory? How is it purified? How does the
solution of PH3 in water react on irradiation with light and on absorption in
CuSO4? How can you prove that PH3 is basic in nature?
Write the chemical equations for all the reactions involved.
2.
86
4.
(b)
(c)
Complete the reactions of the above mentioned sequence and name the
process by which C is obtained.
[Hint. : A is NO and Ostwald process for the manufacture of HNO3].
5.
(b)
(c)
(d)
H3PO2 and H3PO3 act as reducing agents while H3PO4 does not.
(e)
87
6.
7.
(a)
How is XeF6 prepared from the XeF4? Write the chemical equation
for the reaction.
(b)
(c)
(d)
(e)
(a)
(b)
8.
oxygen
(b)
halogens
(c)
metals
(b)
(c)
(d)
(e)
88
Unit - 8
vap
M(l) M(vapour)
89
H
M(g)
M(s) a
(ii)
Metals of second (4d) and third (5d) transition series have greater
enthalpies of atomisation than corresponding elements of first transition series
on account of more frequent metal metal bonding due to greater spatial
extension of 4d and 5d orbitals than 3d orbitals.
(ii)
Why do Zr and Hf have very similar physical and chemical properties and
occur together in the same mineral?
(ii)
[iii)
+ aH
91
r G n EM/M
F nEM
F or
2 F n E 2
2
M /M
/M
EM
2
/M
rG
nF
the atomic number of the transition metal, therefore E M 2+ M value becomes less
and less negative.
EM 2+
values for Mn, Zn and Ni are more negative than expected trend. This
Mn3+ (d4)
Solution : Mn2+ (d5)
has much larger third ionisation energy due to disruption of extrastability of half
filled d5 configuration.
Cr3+ (d3)
Cr2+ (d4)
Cr3+ has half-filled t 2g level. Hence Cr2+ is oxidised easily to stable Cr 3+ ion.
Hence E value is compartively less.
Fe3+ (d5)
Fe2+ (d6)
Comparatively low value of E is also due to extra stability of d5 configuration
of Fe3+.
Example : Which is stronger reducing agent Cr 2+ or Fe2+ and why?
In water medium [Cr (H2O)6]3+ has more CFSE than [Fe (H2O)6]3+. Hence Cr2+
in a stronger reducing agent.
Cu2I2 + I2]
[Hint : 2Cu2+ + 4I
(ii)
(iii)
(iv)
(v)
Why is Cr2+ reducing and Mn3+ oxidising although both have d4 configuration?
[Hint :
(vi)
93
Calculation of CFSE : Each electron occupying t2g orbital results in the lowering
of energy by 0.40 0 and each electron occupying the eg orbital increases the
energy by 0.60 0. If x is the no. of electrons occupying t2g orbitals and y is
the no. of electrons occupying the e g orbitals, then CFSE is given by
CFSE
= (0.60 0y 0.40 0 x)
94
No d-d transition occurs if d-orbitals are empty or fully filled and therefore, such
ions may be colourless.
Exceptions : AgBr, Agl, have fully filled d-orbitals but are coloured due to
transference of electron cloud from Br or I to Ag+ (d10) when white light is
incident on AgBr / Agl. During this process, characteristic wave length of visible
light is absorbed. Similarly MnO4 (purple), CrO42 (yellow) and Cr2O72 (orange)
are coloured due to charge transfer from oxide ions to the central metal ions
although they have no d-electrons.
E = + 1.69 V
Mn2+ + 4H2O
MnO4 + 8H+ + 5e
E = + 1.52 V
2Cr3+ + 7H2O
Cr2O72 + 14H+ + 6e
E = + 1.33 V
Overall :
(b)
Overall :
MnO4 + 8H+ + 5e
Mn2+ + 4H2O] 2
2I
I2 + 2e] 2
2Mn4 + 10 I + 16 H+
MnO4 + 2H2O + 3e
MnO2 + 4OH] 2
I + 6 OH
IO3 + 3H2O + 6e
2MnO4 + H2O + I
95
How do acidified KMnO4 and acidified K2Cr2O7 reacts separately with (a)
SO2, (b) H2S (c) FeSO 4 (d) S2O3 in alkaline medium?
(ii)
Write the ionic equations of acidified KMnO4 with (a) oxalate ion (b) Mohr
salt (c) NO2 and (d) Iron (II) oxalate (e) Mn 2+ in alkaline medium?
[Hint : (d) Both Fe2+ and C2O42 are oxidised to Fe3+ and CO2 respectively.]
(ii)
2.
Explain CuSO4. 5H2O is blue while ZnSO4 and CuSO4 are colourless?
3.
4.
5.
Silver (Ag) has completely filled d-orbitals (4d10) in its ground state. How
can you say that it is a transition element.
[Hint : Ag2+ (d9)]
6.
In 3d series (Sc
Out of the following elements, identify the elements which do not exhibit
variable oxidation state?
Sc, Cr, Co, Zn.
8.
9.
10.
11.
Why Mn2+ compounds are more stable than Fe2+ compounds towards
oxidation to their +3 state?
12.
n (n + 2) B.M.]
13.
14.
15.
16.
The transition metals and their compounds are known for their catalytic
activity. Give two specific reasons to justify the statement.
17.
Write the chemical equation for the reaction of thiosulphate ions and alkaline
potassium permanganate.
18.
Mention the name and formula of the ore from which potassium dichromate
is prepared.
[Hint : FeCr2O4 (Chromite)].
19.
20.
(b)
Manufacture of polythene.
21.
22.
23.
24.
25.
98
26.
This is because extra stability is associated with half-filled t2g level and
half-filled d5 configuration.]
27.
How would you explain more odixising power of MnO4 than Cr2O72?
[Hint :
99
Write the chemical equation, when the yellow colour of aqueous solution
of Na2CrO4 changes to orange on passing CO2 gas.
2.
The stability of Cu2+ (aq) is more than that of Cu+ (aq). Why?
3.
4.
5.
6.
(a)
(b)
(b)
(b)
(a)
(b)
Out of Fe and Cu, which one would exhibit higher melting point?
[Hint. (i) Strong interatomic bonding arising from the participation of ns and
unpaired (n 1) d-electrons.
(ii) Fe has higher melting point due to presence of more unpaired electrons
3d-orbitals.
7.
8.
Describe giving reason which one of the following pairs has the property
indicated :
(a)
(b)
Of the ions Co2+, Sc3+, Cr3+ which one will give colourless aqueous solution
and how will each of them respond to magnetic field and why?
[Hint : Co2+ (3d7); Cr3+ (3d4); Sc3+ (3d)]
9.
MnO2 + KOH + O2
100
(b)
Na2Cr2O7 + KCl
10.
**11. For the first row transition metals the enthalpy of atomisation value are :
aH/kJ mol1
Sc
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
326
473
515
397
281
416
425
430
339
26
12.
(a)
(b)
Copper shows its inability to liberate hydrogen gas from the dilute
acids.
(b)
13.
14.
15.
(a)
MnO4 + NO2 + H+
(b)
513 K
KMnO4
Zn(NO3)2 + X + H2O
Zn + conc. HNO3
(b)
Zn(NO3)2 + Y + H2O
Zn + dil.HNO3
0.9V
Cr3+/Cr2+
Mn2+/Mn
1.2V
Mn3+/Mn2+
1.5V
Fe2+/Fe
0.4V
Fe3+/Fe2+
0.8V
101
0.04V
(ii)
[Hint : (i)
(ii)
Mn > Cr > Fe
**17. For the first row transition metals, the E values are :
E
(M+2/M) 1.18
Cr
Mn
Fe
Co
Ni
Cu
0.91
1.18
0.44
0.28
0.25
+0.34
19.
20.
(b)
(ii) Mn2+
(iii) Mn(OH)3
[Hint : 3, 5, 4, 1]
21.
102
2.
3.
*4.
(b)
(c)
Iodide ion
(c) H2S.
(a)
(b)
(c)
5.
(a)
(b)
(b)
(c)
Among TiCl4, VCl3 and FeCl2 which one will be drawn more strongly into
a magnetic field and why?
[Hint : Among these halides the transition metal ion having maximum
number of unpaired electrons will be drawn strongly into the magnetic field.
Ti4+ = 3d0
no. of unpaired e = 0
= 0
V3+ = 3d2
no. of unpaired e = 2
= 2.76 BM
Fe2+ = 3d6
no. of unpaired e = 4
= 4.9 BM]
103
7.
8.
(b)
Heat
KMnO4
(c)
(b)
(c)
2.
3.
(b)
(c)
(d)
(e)
(b)
(c)
*4.
**5.
(d)
(e)
(b)
(c)
(d)
(e)
Hg
O
H
N
Hg
*6.
7.
(C) Na2CrO4
I
H
(a)
(b)
Transition metals are less reactive than the alkali metals and alkaline
earth metals.
(b)
ECu2+ Cu has positive value but other 3d-elements have negative value.
105
8.
(c)
(d)
(a)
(b)
9.
(i)
electronic configuration
(ii)
oxidation states
(iii)
chemical reactivity.
(ii)
(a)
(b)
(b)
**10. (a)
(b)
106
[Hint :
(a)
(b)
A :
MnO2
Pyrolusite ore
B : K 2MnO 4
C : KMnO 4
Potassium
manganate
Potassium
permanganate
2MnO2
4 4H MnO 4 MnO2 2H2 O
Green
Purple
Black
**11. A mixed oxide of iron and chromium FeO.Cr2O3 is fused with sodium
carbonate in the presence of air to form a yellow coloured compound (A).
On acidification the compound (A) forms an orange coloured compound
(B), which is a strong oxidizing agent.
(i)
(ii)
[Hint :
(i)
(ii)
**12. When an oxide of manganese (A) is fused with KOH in the presence of
an oxidising agent and dissolved in water, it gives a dark solution of
compound (B). Compound (B) disproportionates in neutral or acidic solution
to give purple compound (C). An alkaline solution of compound (C) oxidizes
potassium iodide solution to a compound (D) and comound (A) is also
formed. Identify compounds A to D and also explain the reactions involved.
A = MnO2
13.
B = K2MnO4
C = KMnO4
D =KIO3
(ii)
(iii)
(iv)
The 4d and 5d series of transition metals have more frequent metalmetal bonding in their compounds than do the 3d metals.
(v)
(B). On heating compound (C) with conc. H2SO4 and NaCl, chlorine gas
is liberated and a compound (D) of manganese along with other products
is formed. Identify compounds A to D and also explain the reactions involved.
[Hint : A : KMnO4,
B : K2MnO4,
C : MnO2,
D : MnCl2]
One day a salesman selling cutlery knocked at the door of Rita. Rita is a
housewife. The salesman showed Rita some cutlery made of German
silver. He told her that German silver is a special silver based alloy made
in Germany and he will sell these pieces of cutlery for Rs 100 a piece only.
In the mean time Ritas next door friend Manju arrived. On enquiry, the
salesman explained everything to Manju also. Manju is a science graduate.
She stopped Rita from buying the cutlery and called police to catch the
salesman as he was cheating innocent people.
(a)
(b)
(c)
(d)
108
Unit - 9
COORDINATION COMPOUNDS
Points to Remember
Double salts like Mohrs salt [FeSO4 . (NH4)2 . 6H2O] dissociates completely
into simple constituent ions while complex compounds such as K4[Fe(CN)6]
does not dissociate into constituent ions like Fe2+ and CN ions.
4K+ + [Fe(CN)6]4
K4[Fe(CN)6]
Ligands are defined as the atoms or groups of atoms bound to the central
atom.
O
M
or M
or
NCS
O
M
SCN
110
2.
3.
4.
5.
6.
7.
8.
*9.
10.
How many geometrical isomers are possible for the tetrahedral complex
[Ni(CO)4].
[Ans. : No isomer, as the relative positions of the unidentate ligands attached
to the central metal atom are always the same with respect to each other].
*14. Write the formula and the name of the coordinate isomer of [Co(en)3]
[Cr(CN)6].
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
27.
28.
Define (a) homoleptic and (b) heteroleptic complexes with the help of one
example of each.
29.
[Co(NH3)4(H2O)Cl]Cl 2
(b)
[CrCl2(en)2]Cl; [en=ethane1,2diamine]
31.
32.
(a)
Co3+ ion is bound to one Cl, one NH3 molecule and two bidentate
ethylene diamine (en) molecules.
(b)
Ni2+ ion is bound to two water molecule and two oxalate ions. Write
the name and magnetic behaviour of each of the above coordination
entities. [Given atomic numer Co=26, Ni=27]
Terabromidocuprate (II)
(b)
PentaamminenitritoOCobalt (III)
(a)
(b)
[Co(NH3)5(NO3)] SO4
33.
34.
35.
(b)
36.
37.
**38. A complex is prepared by mixing CoCl3 and NH3 in the molar ratio of 1:4.
0.1 m solution of this complex was found to freeze at 0.372C. What is
the formula of the complex?
Kf of water = 1.86C/m
[Hint
: Tf = i Kf m = i 1.86 0.1
Tf(obs) = 0.373C
This means each molecule of complex dissociates into two ions.
Hence the formula is [CO(NH3)4Cl2] Cl
39.
40.
41.
(a)
(b)
spectrochemical series
42.
43.
[Ni(Co)4]
(b)
[Fe(Co)5]
44.
46.
(a)
(b)
(c)
(d)
(e)
(f)
cis-dichloridotetracyanochromate (II)
(b)
mer-triamminetrichloridocobalt (III)
(c)
fac-triaquatrinitritoNcobalt (III)
48.
(i)
(ii)
(iii)
[CoF6]3
(c)
[Fe(CN)6]4
(b) [Cr(NH3)6]3+
114
**49. A metal complex having composition Cr(NH3)4 Cl2Br has been isolated in
two forms A and B. The form A reacts with AgNO3 solution to give white
precipitate which is readily soluble in dilute aqueous ammonia, whereas B
gives a pale yellow precipitate which is partly soluble in concentrated
ammonia solution. Write the formula of A and B. Also mention the
isomerism which arises among A and B.
[Hint : A = [Cr(NH3)4 BrCl] Cl; B = [Cr(NH3)4Cl2] Br are ionisation isomers].
50.
(b)
[Co (en)3]3+
(c)
[Co(NH3)6] [Cr(CN)6]
51.
52.
53.
**54. A, B and C are three complexes of chromium (III) with the empirical formula
H12O6Cl3Cr. All the three complexes have water and chloride ion as ligands.
Complex A does not react with concentrated H2SO4, whereas complexes
B and C lose 6.75% and 13.5% of their original mass, respectively, treatment
with concentrated H 2SO4. Identify A, B and C. [Given Molar mass of
H12O6Cl3Cr = 266.5 g mol1]
Hints : A contains all water molecule as ligands so compound
A=[Cr.(H2O)6]Cl3
B loses 6.75% mass due to removal of water molecule, it means
6.75
266.5 = 17.98g; i.e. 1 mole of water..
100
Hence B = [Cr (H2O)5Cl]Cl2.H2O
Similarly, C = [Cr (H2O)4Cl2]Cl.2H2O.
(b)
(c)
Mention the reason for right and uniform electroplating when the
electrotype was change.
(d)
(a)
(b)
(ii)
57.
58.
1.
NiCl2 . 6H2O
2.
PtCl4 . 2HCl
3.
CoCl3 . 4NH3
(a)
(b)
(ii)
(iii)
(a)
(b)
(c)
Unit - 10
2.
3.
4.
5.
6.
Allylic substitution can be carried out using Cl2 or Br2 at high temperature.
7.
X
+ X2
8.
FeX3
+ HX ; X = Cl, Br
3 , 2 , 1 , CH3 X
For S 2
N
117
10.
For same alkyl group, boiling points of alkyl halides is in the order :
R I > RBr > RCl > RF.
11.
For same halogen, boiling points of halides increases with increase in the
size of alkyl group.
12.
13.
CX bond in aryl halides is shorter, stronger and less polar than in alkyl
halides.
14.
Aryl halides are much less reactive towards the nucleophilic substitution
(SN) reactions. Reactivity towards SN reactions increases if some EWG is
present at 0-and p-positions with respect to halogen.
15.
D.D.T. is 1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane.
16.
17.
18.
Aryl and vinyl halides do not give precipitate with AgNO3 solution.
1-Mark Questions
1.
Out of ethyl bromide and ethyl chloride which one has higher boiling point
and why?
2.
Which one of the two compounds CH3Br and CH3I will react faster in SN2
reaction with OH.
3.
CH3
H
Br
H
Write a chemical reaction in which the iodide ion replaces the diazonium
group in a diazonium salt.
H
4.
5.
Which one of the following reacts faster in SN1 reaction and why?
Cl
or
Cl
118
6.
7.
8.
CH3
H3C
H
Br
H
9.
10.
CH3
H3C
H
Br
H3C
11.
12.
13.
CH3
H 3C
CH2Cl
CH3
14.
15.
119
16.
17.
18.
19.
20.
21.
22.
23.
CH 2
CH 2 Br
CH 3
24.
Heat
+ Br2
UV light
25.
26.
Fe
+ Cl2
27.
Dark
CH 3
CH
CH2
CH
CH2
Cl
120
28.
CH3
CH3CH
CH
CH3
Br
29.
30.
CH3
CH3
CH
CH3
CH3 Cl
31.
CH3
CH
Br
CH2 CH
CH3
Cl
2-Mark Questions
1.
Explain as to why halogens are much less reactive than haloalkanes towards
nucleophilic substitution reactions.
2.
Which compound in each of the following pairs will react faster in SN2
reaction with OH and why?
3.
(i)
CH3Br or CH3I
(ii)
(i)
H3C
H
H
Br
H3CH2C
(ii)
4.
5.
121
6.
7.
8.
CH2Cl or
(ii)
I or
Cl
(ii)
Which one in the following pairs undergoes SN1 substitution reaction faster
and why?
Cl
(i)
Cl
or
I or
(ii)
9.
Cl
Cl
CH3
(i)
(ii)
10.
11.
+ HI
CH3CH2CH
CH2 + HBr
Explain why
(i)
(ii)
Explay as to why
(i)
(ii)
12.
13.
122
3-Mark Questions
1.
2.
(ii)
(iii)
CH3
(i)
+ HI
H + HBr
(ii)
H
(iii)
3.
(i)
(ii)
4.
How would you differentiate between SN1 and SN2 mechanism of substitution
reactions? Give one example of each.
5.
Explain why :
(i)
(ii)
(iii)
in the pair, (CH3)3CCl and CH3Cl, CH3Cl will react faster in SN2
reaction with OH?
123
6.
7.
(ii)
(iii)
(i)
CH3CHCH3 + OH
EtOH
CH3CH=CH2
Br
(ii)
8.
9.
(ii)
1-bromo-3-methylbutane, 2-bromo-2-methylbutane,3-Bromo-2methylbutane.
(iii)
(i)
(ii)
10.
Although chlorine is an electron withdrawing group, yet it is ortho-, paradirecting in electrophilic aromatic substitution reactions. Explain, why is
it so?
124
1.
(i)
(ii)
uv
or heat
125
2.
benzene to 3-bromonitrobenzene
(ii)
ethanol to but-1-yne
(iii)
1-bromopropane to 2-bromopropane
(iv)
benzene to 4-bromo-1-nitrobenzene
(v)
aniline to chlorobenzene
(vi)
2-methyl-1-propene to 2-chloro-2-methylpropane
(vii)
3.
(ix)
benzene to phenylchloromethane.
(x)
(i)
126
(viii) CH3Br
4.
5.
KCN
H3 O
Li Al H4
ether
Finkelstein reaction.
(ii)
Swarts reaction.
(iii)
Wurtz reaction.
(iv)
Wurtz-Fitting reaction
(v)
(vi)
(vii)
Sandmeyers reaction.
Write the major products and name the rule responsible for the formation
of the product.
127
6.
*7.
*8.
9.
(ii)
(iii)
(ii)
(iii)
(i)
(CH3)3 COH
(CH3)3CCl + O H
(ii)
CH3OH
CH3Cl + OH
Which compound in each of the following pairs will react faster in SN2
reaction with OH and why?
(i)
CH3Br or CH3I
(ii)
*10. In the following pairs, which halogen compound undergoes faster (i) SN1
and (ii) SN2 reaction?
128
(i)
(ii)
11.
(iii)
(iv)
(v)
(vi)
(vii)
(ii)
although alkyl halides are polar in nature but are not soluble in water.
(iii)
(iv)
(v)
(vi)
(vii)
(x)
129
12.
13.
(ii)
(iii)
(iv)
(v)
Write the different products and their number formed by the monochlorination
of following compounds :
(i)
CH3CH2CH2CH3
(ii)
(CH3)2CHCH 2CH3
(iii)
(CH3)2CHCH(CH 3)2
130
*14. (a)
(i)
(ii)
(iii)
(iv)
Freon-12
(ii)
DDT
(iii)
Carbon tetrachloride
(iv) Iodoform
131
+ Br
132
21.
(ii)
(iii)
4bromo-2, 4-dimethylhexane
, 2methyl3phenylpentane
(iv)
, 5oxohexanoic acid
**22. Primary alkyl halide (A) C4H9Br reacted with alc.KOH to give B. B when
reacted with HBr to give C, which is an isomer of A. When A reacted
with Na metal, it gave a compound D C8H18 that was different from the
compound, when n-butyl bromide was reacted with Na. Give the structural
formulas of A to D and write the chemical equations of reactions involved.
133
24.
Write the structures and names of the compounds formed when compound
A with molecular formula, C7H8 is treated with Cl2 in the presence of FeCl3.
CH3 CH2 CH = CH
Hint: A
CH3 CH2 CH
CH3 CH2
+
CH
CH3 + HCl
A+B
CH2 CH3
Cl
CH3 CH2CH2
CH CH3
Cl
+
CH3 CH2 CH2 CH CH3
CH2 CH3
Less Stable
(4 Hyperconjugative Structures)
More Stable
(5 Hyperconjugative Structures)
Which of the following compounds will have the highest melting point
and why?
CH3
CH3
Cl
CH3
Cl
Cl
Cl
Cl
Cl
CH3
CH3
CH3
(I)
(II)
(III)
Hint: (II) Most Symmetrical and therefore have highest melting point.
**27. A hydrocarbon of molecular mass 72 gmol-1 gives a single monochloro
derivative and two dichloro derivatives on photo chlorination. Give the
structure of the hydrocarbon.
Hint:
CH3
CH3
CH3
CH3
CH3
CH3
CH3
CH2 Cl
CH3
(Hydro Carbon)
CH3
(Monochloro Derivative)
Cl
CH3
CH2 Cl
CH3
CH3
CHCl2
CH3
(Dichloro Derivative)
(Dichloro Derivative)
134
28.
CH2
Hint:
29.
CH3
CH3
Cl
HCl
HCl
Which of the following haloalkanes reacts with aqueous KOH most easily?
Explain giving reason.
(i)
1-Bromobutane.
(ii)
2-Bromobutane
(iii)
3-Bromo-2-methylpropane
(iv)
2-Chlorobutane
30.
Why can aryl halides not be prepared by reaction of phenol with HCl in the
presence of ZnCl2?
31.
Which of the following compounds would undergo SN1 reaction faster and
why?
32.
33.
CH2Cl
CH2Cl
(A)
(B)
(i)
(ii)
135
34.
35
Cl
Cl
Cl
NO2
O2N
NO2
NO2
NO2
NO2
(I)
(II)
(III)
136
Unit - 11
2.
R.
3.
4.
5.
6.
7.
8.
In the reaction of alkyl aryl ether (anisole) with HI, the products are always
alkyl halide and phenol because OR bond is weaker than OAr bond
which has partial double character due to resonance.
9.
COC bond in ether is bent and hence the ether is always polar molecule
even if both alkyl groups are identical.
137
10.
11.
12.
13.
14.
O
CH3
or CH3
CH
1-Mark Questions
1.
2.
H3C
CH
CH2
CH3
3.
CH
CH
OH
CH3
CH2OH
Give reason:
Ethanol has higher boiling point than methoxymethane.
4.
H3C
CH
CH
CH2
CH2
CH3
OH
5.
6.
7.
Write the chemical equation for the preparation of phenol from benzene
using oleum and sodium hydroxide.
8.
9.
10.
11.
12.
138
13.
CH
CH
CH2
CH
CH3
OH
14.
CH2
CH
CH2OH and
(ii)
CH2 CH CH2 CH2OH , which one will react more easily with
concentrated HCI in the presence of anhydrous ZnCl2?
15.
H 3C
CH2OH
CH3 Br
2-Mark Questions
1.
2.
3.
4.
5.
propene to propan-1-ol
(ii)
Propene to propan-2-ol
(ii)
Propene to propan-2-ol
(ii)
Anisole to phenol
(ii)
The boiling points of ethers are much lower than those of the alcohols
of comparable molar masses?
(ii)
6.
(ii)
7.
8.
OH + SOCl2
(i)
CH2OH
+ HCl
(ii)
HO
9.
(ii)
10.
11.
12.
13.
14.
(i)
(ii)
(ii)
(ii)
140
15.
16.
Alcohols are more soluble in water than the hydrocarbons of comparable molecular masses.
(ii)
Propene to propan-2-ol?
(ii)
Phenol to 2, 4, 6-trinitrophenol?
3-Mark Questions
1.
2.
3.
4.
5.
(ii)
Butan-2-one to butan-2-ol
(iii)
Phenol to 2,4,6-tribromophenol.
(i)
(ii)
(ii)
(iii)
phenol to benzoquinone?
(ii)
propanone to 2-methylpropan-2-ol?
(iii)
Propene to propan-2-ol?
(a)
CH3
OH
CH3
141
6.
7.
8.
9.
(b)
(i)
(ii)
(ii)
(iii)
(ii)
(iii)
Phenyl methyl ether reacts with HI to give phenol and methyl iodide
and not iodobenzene and methyl alcohol.
(ii)
(iii)
(i)
(ii)
10.
11.
Draw the structure and name the product formed if the following alcohols
are oxidised. Assume that an excess of oxidizing agent is used.
(i)
CH3CH2CH2CH2OH
(ii)
Butan-2-ol
(iii)
Methylpropan-2-ol.
142
1.
2.
(ii)
(iii)
Williamson synthesis
(iv)
Reimer-Tiemann reaction.
(v)
Kolbes reaction
(vi)
(i) CH3MgBr
+
(ii) H /H2O
Cu/573K
143
(i) NaOH,
(ii) H
3.
4.
(ii)
(iii)
(iv)
propene to propan-l-ol.
(ii)
anisole to phenol
144
(iii)
butan-2-one to butan-2-ol
(iv)
ethanal to ethanol
(v)
phenol to ethoxybenzene
(vi)
1-phenylethene to 1-phenylethanol
(vii)
formaldehyde to cyclohexylmethanol
(x)
(xi)
(xii)
propene to propan-2-ol.
145
6.
7.
(ii)
CH3 CH2 OH
443 K
CH2 = CH2
(iii)
CH3CH2OH
CH3CH2OCH2CH3
413 K
8.
(iv)
CH3OH + CH3I
CH3OCH3 + HI
(v)
CH3OH + (CH3)3 CI
(CH3)3COCH3 + HI
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(a)
(b)
(x)
(xi)
(xii)
(ii)
(iii)
(iv)
10.
11.
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
What is the function of ZnCl2 (anhyd) in Lucas test for distinction between
1, 2 and 3 alcohols.
[A] : (CH3)2CHCH2OH
[B] : CH3CH(CH3)COOH
[D] : (CH3)3C OH
148
CH3CH2OH
(C)
CH3CHOHCH 3
(D)
CH3COOH
(E)
CH3COCH3
**15. Which of the following compounds gives fastest reaction with HBr and why?
(i)
(CH3)3COH
(ii)
CH3CH2CH2OH
**16. Phenol, C6H5OH when it first reacts with concentrated sulphuric acid, forms
Y The compound, Y is reacted with concentrated nitric acid to form Z.
Identify Y and Z and explain why phenol is not converted commercially to
Z by reacting it with conc. HNO3.
[Ans. :
NO2
Phenol is not reacted directly with conc. HNO3 because the yield of picric
acid is very poor]
149
17.
18.
Ethoxybenzene
(b)
2-methoxy-2-methylpropane
150
Unit - 12
2.
3.
4.
(ii)
(iii)
5.
6.
7.
8.
9.
11.
Monocarboxylic acids having (C12C18) carbon atoms, are called fatty acids.
12.
151
13.
Even membered carboxylic acids have higher melting point than odd
members preceeding or following it.
15.
O H
17.
The more is the Ka value, lesser is the pKa. A stronger acid always has
higher Ka but a lower pKa value.
18.
1-Mark Questions
1.
2.
3.
4.
H 3C
CH
CO
CH3
CH3
CH3
5.
CH
OH
OH
O
6.
7.
C
O
CH2
CH
CH3
Cl
152
8.
CH3
CH3
CH2COCH3
OH
9.
10.
11.
OC2 H5
Cl
12.
(CH3)2CH
CH2
CH(CH3)2
O
13.
14.
15.
CH3
O
16.
O
O2N
17.
CH2
CH3
CH3
C
O
CH
CH3
CH3
18.
19.
20.
O
OCCH3
H 3C
CH3
21.
22.
23.
24.
25.
O
CH3
CH2
CH
CH
26.
27.
28.
2-Mark Questions
29.
30.
31.
Propanal to butanone
(ii)
Benzaldehyde to benzophenone
Acetphenone to 2-phenyl-2-butanol
(ii)
Propene to acetone.
32.
(ii)
3-Mark Questions
33.
34.
+ C6H5COCl
(i)
Anhyd.AlCl3
CS2
2+
(ii)
H3C
Hg .H2SO4
CH3
(i) CrO 2Cl2
(ii) H2O
(iii)
NO2
35.
(i)
Descrie the mechanism of the addition of Grignard reagent to the
carbonyl group of a compound to form an adduct which on hydrolysis yield
an alcohol.
(ii)
36.
3-methylbutanal
(ii)
p-nitropropiophenone
(i)
(ii)
Ethanal to 3-hydroxybutanal
(b)
Benzaldehyde to benzophenone.
155
5-Mark Questions
37.
(i)
(a)
.............
O3
Zn/2HO
CH2
(b)
.......
CHO
CH2CH3
38.
(c)
KMnO4 ..........
KOH, heat
(ii)
(i)
(ii)
(a)
Cannizzaro reaction
(b)
(b)
(c)
(b)
39.
40.
(i)
How ill you prepare the following compounds starting with benzene?
(a)
(ii)
Benzaldehyde
(b)
Acetophenone
Propanone to propene.
(b)
Ethanol to 3-hydroxybutanal.
(c)
Benzaldehyde to benzophenone.
42.
43.
(i)
Conc. H SO
HBr
2 5
2
4
CHCHO
A
B
C
(ii) H O
(ii) H O
Peroxide
2
(ii)
44.
Conc. NaOH
(b)
(i)
(ii)
(a)
(b)
COCH3
CHO +
+ C2H5
Cl
OH
293K
Anhyd
AlCl3
157
45.
(i)
An organic compound with molecular formula C9H10O forms 2,4DNP derivative, reduces Tollens reagent and undergoes Cannizzaros
reaction. On vigorous oxidation, it gives 1,2-benzenedicarboxylic acid.
Identify the compound.
(ii)
(iii)
(a)
(b)
46.
(i)
(ii)
Propanone to propane
(b)
(c)
Ethanal to but-2-enal
CARBOXYLIC ACIDS
1-Mark Questions
1.
2.
3.
4.
O
CH3
5.
CH
CH
OH
COOH
Br
Cl
158
6.
7.
8.
9.
How would you complete the following conversion? Write the complete
equation.
Benzoic acid to m-nitrobenzyl alcohol.
2-Mark Questions
10.
11.
12.
13.
(ii)
Acetaldehyde to methane
(ii)
(ii)
KMnO4, H2SO4
(ii)
14.
COCH3
+
+CH3CH2NH2 H
(ii)
CH3CH2CH(Br)COOH, CH3CH(Br)CH2COH,
(CH3)2CHCOOH (acid strength)
159
3-Mark Questions
15.
16.
17.
18.
(ii)
(iii)
Cyclohexanol to cyclohexan-1-one.
(ii)
(iii)
(ii)
(iii)
SOCl2
Heat
(a)
COOH
(b)
(c)
19.
C6H5CHO
H2NCONHNH 2
CHO
CH2
CH2CH3
KMnO4
(a)
KOH, heat
COOH
SOClh
Heat
(b)
COOH
(c)
C6H5CONH2
H3O
Heat
160
20.
A Heat
+ NH3
COOH
5-Mark Questions
21.
22.
23.
(i)
(ii)
(b)
2
C6H5 COCl
...............
Pd BaSO
O
C
(b)
+ ........
CH3
Anhy.
AlCl3
O
C
(c)
+ ........
161
24.
(i)
(ii)
(a)
(b)
Propanone to propene
(b)
(c)
Bromobenzene to 1-phenylethanol.
25.
26.
COOH
Conc.HNO3
Conc.H3SO4
27.
(i)
(ii)
SOCl2
(i) NaBH4
(ii) H3O
SOCl2
Pd/H ,BaSO
4
D + S or2 quinoline
E
(b)
(b)
(c)
162
28.
(a)
(b)
30.
(a)
Propanone to propan-2-ol
(ii)
(iii)
(ii)
CH3
(i)
CH3
ZnHg
Conc. HCl
(ii)
CH3
Cl + H2
Pd-BaSO4
COOH
Br2/FeBr3
(iii)
(b)
Which of the each pair shown here would you expect to be stronger?
(i)
OH
(ii)
or CH3COOH
163
1.
(ii)
(iii)
Etard reaction
(iv)
Gatterman-Koch reaction
(v)
Aldol condensation
(vi)
(vii)
Cannizzaro reaction
2.
(ix)
Kolbes reaction
(x)
Hell-Volhard-Zelinsky reaction
(xi)
Clemmensen reduction
(xii)
Wolff-Kishner reduction
(xii)
Haloform reaction.
(ii)
benzene to benzaldehyde
(iii)
(iv)
propene to propanal
(v)
(vi)
(vii)
propanol to propene
(x)
(xi)
acetone to chloroform
(xii)
ethanal to but-2-enal
164
3.
conc. KOH
(iv)
2HCHO
(v)
2
CH3 COOH
(ii) H O
(i) Br P
2
CHO
(vi)
HNO3/H 2SO4
273283 K
(vii)
(viii)
(ix)
165
(x)
(xi)
(i)
(xii)
(ii) H2O
(xiii)
4.
5.
2,4-DNP derivative
(ii)
Schiffs base
(iii)
Oxime
(ii)
8.
6.
7.
(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)
C H 3CHO
(ix)
(x)
(xi)
and CH3COCH3
Cyclohexanone form cyanohydrin in good yield but 2,2,6 trimethylcyclohexanone does not.
(ii)
(iii)
(iv)
(v)
(vi)
For the formation of ethyl acetate from acetic acid and ethanol in
presence of sulphuric acid, the reaction mixture is heated to remove
water as fast as it is formed.
(vii)
(x)
(xi)
(xii)
NH2/OH in Glycol,
H2/Ni and NaBH4. Select one reagent for the following transformation and
give reasons to justify your answer.
Y ou are given four different reagents Z n-H g/H C l, N H 2
B : CHI3
C : CH3CH2CH2COONa
D : CH3CH2COOH
E : CH3COOH
**10. Formaldehyde and acetaldehyde on treatment with dil. NaOH form A which
on heating changes to B. When B is treated with HCN, it forms C. Reduction
of C with DIBAL- H yields D which on hydrolysis gives E. Identify A, B, C,
D and E.
[Ans. : A : HOCH2CH2CHO
B : CH2 = CH CHO
168
11.
12.
D+E
conc. NaOH
CH3
CHCOPh
PhC
*14
*15
(ii)
(iii)
16.
170
*17
**18. An aromatic compound X with molecular formula C9H10 gives the following
chemical tests :
(i)
(ii)
(iii)
(iv)
.
.
19.
20.
(ii)
Isopropyl alcohol
(iii)
3-methylbutan-2-one
(i)
(ii)
(iii)
[Ans : (iv)]
CH3
171
[C] = CH3 C
CH3
**22. An aromatic compound A (Molecular formula C8H8O) gives positive 2, 4DNP test. It gives a yellow precipitate of compound B on treatment with
iodine and sodium hydroxide solution. Compound A does not give Tollens
or Fehlings test. On drastic ooxidation with potassium permangnate it
forms a carboxylic acid C (Molecular formula C7H6O2), which is also formed
along with the yellow compound in the above reaction. Identify A, B and
C and write all the reactions involved.
COOH
COCH3
(A) =
(B) = CHI3
(C) =
CH3
R
(B) = Methyl Ketone
H3C
172
Unit - 13
AMINES
POINTS TO REMEMBER
1.
2.
NH2,
NH and
3.
4.
5.
6.
(i)
(ii)
In aqueous medium, the order is 2 > 1 > 3 (for CH3 group) and
2 > 3 > 1 for C2H5 group.
(iii)
(ii)
ERGs like CH3, OR, NH2 etc. increase basic strength while
EWGs like NO2, CN etc. decrease the basic strength. The effect
of substituents is more at para positions and less at meta-position.
7.
8.
9.
10.
11.
173
12.
Aliphatic diazonium salts are very unstable and do not exist while aromatic
salts are relatively stable.
13.
14.
Diazonium salts are important tools in the hands of organic chemists for
preparing a variety of aromatic compounds.
1-Mark Questions
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
2-Mark Questions
22.
23.
24.
25.
26.
(ii)
(ii)
(a)
(b)
(ii)
(iii)
(i)
27.
(ii)
175
28.
29.
30.
31.
32.
33.
34.
35.
36.
(ii)
Aniline to nitrobenzene
(ii)
Ethanamine to N-ethylethanamide.
(ii)
nitrobenzene to aniline.
(ii)
aniline to iodobenzene.
Sandmeyers reaction
(ii)
Coupling reaction
Convert:
(i)
nitrobenzene to phenol
(ii)
aniline to chlorobenzene
aniline to benzonitrile?
(ii)
Carbylamine reaction
(ii)
C 6H5N2+Cl
(b)
+ H3PO2 + H2O
176
3-Mark Questions
37.
38.
39.
40.
41.
42.
(ii)
(iii)
Nitrobenzene to aniline
(ii)
(iii)
Aniline to benzonitrile
(ii)
(iii)
State the reactions and reaction conditions for the following conversions.
(i)
(ii)
(iii)
Ethylamine to methylamine
C6H5NH2 + CH3COCl
(ii)
C2H5NH2 + C6H5SO2Cl
(iii)
C2H5NH2 + HNO2
C6H5N2+ Cl + C6H5NH2
(ii)
C6H5N2+ Cl + CH3CH2OH
(iii)
177
43.
44.
Carbylamine reaction
(ii)
Acetylation reaction
(iii)
NaCN
Reduction
CH3CH2Cl
A A
(ii)
Ni/H2
C6H5N2+Cl + H3PO2 + H2O
(iii)
C
O
45.
46.
NH2
LiAlH4
H2O
(ii)
(iii)
NH
(i)
CuCN
H2O/H
3
C
C6H5N2+Cl A
B
Heat
(ii)
NaNO 2 / HCl
H2 O / H
HCl
C6H5NO2 (i)Sn
A 273K
B
(ii) OH
47.
LiAlH
KCN
HNO
4
2
A
B
C
CH6CH5Br
NH
NaOH Br
3
3
2
A
B
C
(ii) CH3COOH
178
1.
(ii)
(iii)
Gatterman reaction
(iv)
Coupling reaction
(vi)
(vii)
Acetylation of aniline.
2.
3.
4.
5.
(i)
(ii)
(iii)
(iv)
(v)
(Boiling point)
373K
OH
(ii)
373K
OH
benzene to aniline
(ii)
aniline to benzene
(iii)
(iv)
p-toluidine to 2-bromo-4-methylaniline.
(v)
(vi)
(vii)
ethylamine to methylamine
hexanenitrile to 1-aminopentane.
(x)
aniline to 1,3,5-tribromobenzene.
(xi)
benzene to 3-bromophenol.
(xii)
aniline to 2,4,6-tribromofluoro-benzene.
Br /NaOH
NaCN
OH
2
CH CH l
A
C
Partial hydrolysis B
3 2
7.
180
8.
9.
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
HNO (conc.)
CHCl KOH
3
3
A
B C
H SO cons.
H Pt
2
D
E
C6H5NHCOCH3 CH3 COOH
10.
Identify A to F.
KOH Br
NaNO HCl
2
2
A
B
C
0 5 C
Cl Fe
H Pt
2
2
E
F
C6H5 CH2NH2
11.
Explain why :
(i)
(ii)
the quaternary ammonium salts having four different alkyl groups are
optically active.
(iii)
(iv)
(v)
(vi)
181
(vii)
(x)
(xi)
(xii)
12.
(xv)
diazonium salt of aromatic amines are more stable than the diazonium
salts of aliphatic amines.
(xvi)
**13. Three isomeric amines A, B and C have the molecular formula C3H9N.
Compound A on reaction with benzene sulphonyl chloride forms a product
which is soluble in NaOH. Compound B on reaction with benzene sulphonyl
chloride forms a product which is insoluble in NaOH and compound C
does not react with benzene sulphonyl chloride. Identify A, B and C.
[Ans. : (A) CH3CH2CH2NH2 (B) CH3CH2NHCH3 (C) (CH3)3N]
*14. An organic compound A (C2H3N) is used as a solvent of choice for many
organic reactions because it is not reactive in mild acidic and basic
conditions. Compound A on treatment with Ni/H 2 forms B. When B is
treated with nitrous acid at 273K, ethanol is obtained. When B is warmed
with chloroform and NaOH, a foul smelling compound C formed. Identify
A, B and C.
[Ans. : (A) CH3CN (B) CH3CH2NH2 (C) CH3CH2NC
182
16.
(A) CH3CH2COOH
(B) CH2CH2CONH2
(C) CH3CH2NH2
(D) CH3CH2NC.]
CH3
(i) NaNO2 + HCl, 273-278K
(ii) H3PO2
NO2
NH2
17.
18.
19.
Why does acetylation of NH2 group of aniline reduce its activating effect?
20.
21.
22.
23.
24.
25.
26.
183
27.
OH
+
ArN2Cl
OH
28.
29.
30.
CH3
O
Cl
KCN
H2/Pd
Cl
(C) = CH3 CH2 CH CH3
NH2
(D) = CH3 CH2 CH CH3
OH
**32. A colourless substance A (C6H7N) is sparingly soluble in water and gives
a water soluble compound B on treating with mineral acid. On reacting
with CHCl3 and alcoholic potash A produces an obnoxious smell due to
184
NH2
(A)
N2Cl
(B)
NC
(C)
NH
(D)
S
O
N2Cl
(E)
N=H
(F)
OH
**33. Predict the reagent or the product in the following reaction sequence.
CH3
CH3
CH3
1
NO2
(CH3CO)2O
(CH3CO)2O
Pyridine
Pyridine
NHCOCH3
NH2
CH3
CH3
5
NaNO2/HCl
NO2
NO2
NH2
Hint: 1:
Sn/HCl or Fe/HCl
NHCOCH3
2:
H3C
3:
NO2
H+/H2O or H3O+
N
4:
H 3C
NCl
NO 2
185
5: H3PO2/H2O
Unit - 14
BIOMOLECULES
POINTS TO REMEMBER
1.
2.
3.
4.
Glycocidic linkage : The oxide linkage which connects the monosaccharides units in oligosaccharides or polysaccharides.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
The purines bases in nucleic acids are adenine and guanine while pyrimidine
bases are thymine, uracil and cytosine. The base uracil is present only in
RNA while the base thymine is present only in DNA. RNA is of 3 types :
m-RNA, r-RNA, t-RNA.
15.
16.
17.
18.
Gene : The DNA sequence that codes for a specific protein or polypeptide
is called a gene.
19.
20.
21.
A, D, E, K
2.
3.
4.
5.
187
6.
7.
Glucose is an aldose sugar but it does not react with sodium hydrogen
sulphite. Give reason.
[Hint : The CHO group reacts with OH group at C5 to form a cyclic
hemiacetal].
8.
9.
10.
11.
12.
13.
Name the enzyme which catalyses the hydrolysis of maltose into glucose.
14.
15.
16.
Which forces are responsible for the stability of -helical structure of proteins.
17.
Which nucleic acid is responsible for carrying out protein synthesis in the cell.
18.
The two strands in DNA are not identical but complementary. Explain.
[Hint : H-bonding is present between specific pairs of bases present in
stands.]
19.
188
20.
What type of linkage holds together the monomers of DNA and RNA?
[Hint : Phosphodiester linkage]
21.
22.
23.
24.
25.
26.
Except vitamin B12, all other vitamins of group B, should be supplied regularly
in diet. Why?
27.
28.
29.
30.
2.
cellulose.
3.
4.
(i)
Acetylation of glucose with acetic anhydride gives glucose pentaacetate. Write the structure of the pentaacetate.
(ii)
6.
(i)
(ii)
7.
8.
189
9.
10.
(ii)
C6H5CH2CH(NH2) COOH
(iii)
H2N(CH2)4CH(NH 2)COOH
(iv)
HN = C(CH2)3CH(NH2)COOH
NH2
11.
What are essential and non-essential amino acids? Give one example of
each type.
12.
13.
14.
Keratin
(ii)
(iii)
Insulin
(iv) Haemoglobin.
15.
Myosin
denaturation of protein
(b)
specificity of an enzyme.
16.
17.
(i)
(ii)
190
18.
a peptide linkage
(ii)
a glycosidic linkage?
[Hint : (i) Peptide linkage refers to the CONH linkage formed by reaction
between COOH group of one amino acid with NH2 group of the other
amino acid.
(ii)
19.
Give the sources of vitamin A and E and name the deficiency diseases
resulting from lack of vitamin A and E in the diet.
20.
What are the main functions of DNA and RNA in human body.
How
(i)
(ii)
(iii)
3.
4.
(i)
(ii)
(iii)
Neetas mother fell ill and doctor diagnosed her with pernicious anemia.
She felt lethargic and did not have energy to do work. Neeta helped her
mother in household work till she recovered.
(a)
(b)
(c)
(d)
(i)
(ii)
(iii)
(iv)
192
1+1+1+2
Unit - 15
POLYMERS
Points to Remember
1.
2.
3.
4.
5.
6.
A condensation of two different unsaturated monomers exhibits copolymerisation. A copolymer like Buna-S contains multiple units of 1, 3-butadiene
and styrene.
7.
8.
9.
10.
1-Mark Questions
1.
Write the names of monomers of PMMA and state one use on it.
2.
3.
4.
5.
6.
What is the difference between the two notations Nylon-6 and Nylon 6, 6?
7.
8.
9.
10.
11.
12.
13.
14.
2-Mark Questions
16.
Nylon-6, 6
(ii)
PVC
17.
18.
19.
20.
What is the difference between elastomers and fibres? Give one example
of each.
194
21.
22.
23.
24.
(i)
(ii)
Dacron
(ii)
Neoprene
(iii)
Polyvinyl Chloride
(iv) Teflon
Bakelite
(ii)
Polypropene
26.
27.
3-Mark Questions
28.
Neoprene and
(ii)
Glyptal
30.
Nylon-6
(iii)
Polythene
(ii)
Nylon-6, 6
Terylene
(iii)
Teflon
(ii)
195
Neoprene
31.
32.
33.
Polythene
(iii)
Teflon
(ii)
PVC
Polythene
(ii)
PTFE
(iii)
Polybutadiene
(iv) Bakelite
Buna-S
(iii)
Glyptal
(ii)
Dacron
34.
35.
36.
Write the monomers which are used for the synthesis of following polymers?
(i)
Terylene
(iii)
Bakelite
(ii)
Polythene
38.
addition polymers
(ii)
condensation polymers
(iii)
Copolymers
(i)
(ii)
Which polymers is obtained when free radical polymerisation of
chloroprene occurs? Write the structure of the polymers thus obtained.
39.
Nylon-6
(iii)
Neoprene
(ii)
196
Teflon
40.
41.
Write the names and structures of the monomers of the following polymers:
42.
43.
(i)
Buna-S
(ii)
(iii)
Nylon 6, 6
Neoprene
Write the names and structures of the monomers and the following polymers:
(i)
Polystyrene
(iii)
Teflon
(ii)
Dacron
Write the names and structures of the monomers and the following polymers:
(i)
Bakelite
(ii)
(iii)
Polythene
Nylon-6
2.
3.
4.
5-Mark Question
1.
How are following polymers are obtained? Write the names of monomers
and the structures of the respective polymers.
(a) Dacron (b) Nylon-6 (c) Buna-N (d) Glyptal and (e) PHBV
197
Unit - 16
2.
3.
4.
Drugs are designed to interact with specific targets so that these have the
least chance of affecting other targets. This minimises the side effects and
localises the action of the drug.
5.
6.
7.
Chemicals are added to food for preservation, enhancing their appeal and
adding nutritive value in them.
8.
9.
These days detergents get preference over soaps because they work even
in hard water and acidic medium also.
10.
11.
12.
13.
(ii)
14.
15.
2.
3.
4.
5.
7.
8.
9.
10.
11.
13.
14.
15.
Name the derivative of sucrose which tastes like sugar and can be safely
used by weight conscious people.
16.
Why synthetic detergents are preferred over soaps for use in washing
machines?
[Hint : They work well even with hard water and acidic medium.]
[Hint : Compound (i) acts as a surface agent because its one end is
hydrophobic while the other end is hydrophillic in nature.]
20. What type of drug is chloramphenicol?
21. Name a chemical used as an antiseptic as well as disinfectant.
22. Give two examples of antidepressants.
23. Name the antioxidants commonly used to increase the storage of butter.
200
24.
25.
26.
27.
28.
29.
2.
What are narcotic and non-narcotic analgesics? Give one example of each.
3.
4.
target molecules
(ii)
enzyme inhibitors.
Equanil
(ii)
Morphine
5.
6.
(i)
(ii)
7.
(ii)
8.
Why should a drug not be taken without consulting a doctor? Give two
reasons.
9.
10.
11.
*12.
13.
14.
15.
Sulpha drugs work like antibiotics but they are not antibiotics? Is this a
valid statement and why? Give one example of sulpha drug and an antibiotic.
2.
(i)
(ii)
(iii)
Pick out the odd one amongst the following on the basis of their medicinal
properties. Give suitable reason.
(i)
(ii)
(iii)
[Hint :
3.
4.
(i)
(ii)
(iii)
enzymes
(ii)
receptor proteins
(iii)
neurotransmitter
chloramphenicol
(ii)
aspirin
(iii)
cimetidine or ranitidine
202
5.
6.
7.
analgesics
(ii)
tranquilizers
(iii)
antifertility drugs
typhoid
(ii)
(iii)
hypertension
bithional or bilthinol
(ii)
amoxycillin
(iii)
salvarsan
8.
9.
cationic detergents
(ii)
anionic detergents
(iii)
nonionic detergents
(ii)
(iii)
203
[Hint : (i)
anionic detergent.
(ii)
cationic detergent.
12.
(i)
(ii)
(a)
(b)
(c)
13.
What are detergents? How are they classified? Why are detergents usually
preferred to soaps for washing clothes? Give an example of detergents.
(ii)
(iii)
(iv)
204
(a)
(b)
205
SAMPLE PAPER-I
Chemistry (Theory)
Time allowed : 3 hours
Maximum Marks : 70
General Instruction
(i)
All questions are compulsory.
(ii)
Question numbers 1 to 5 are very short answer questions and carry 1
mark each.
(iii) Question numbers 6 to 10 are short answer questions and carry 2 markseach.
(iv) Question numbers 11 to 22 are short answer questions and carry 3
marks each.
(v)
Question number 23 is a value based question and carry 4 marks.
(vi) Question numbers 24 to 26 are long answer questions and carry 5 markseach.
(vii) Use log table, if necessary. Use of calculator is not permitted.
1.
2.
3.
H 3C
CH
CH
CH
CH2
CH3
1
OH
4.
5.
6.
7.
(b)
8.
9.
I2 + Conc. HNO3
(a)
HgCl2 + PH3
(b)
OR
Complete the following chemical equations:
10.
11.
(a)
(b)
CH2Cl or
(b)
I or
Cl
2
Cl
(b)
12.
13.
The rate of a reaction becomes four times when the temperature changes
from 300K to 320K. Calculate the energy of activation of the reaction,
assuming that it does not change with temperature.
(R=8.314 J K1mol1)
207
14.
15.
(b)
(c)
(b)
(c)
OR
Write the reactions involved in the following processes :
16.
17.
(a)
(b)
(c)
Recovery of gold after gold ore has been leached with NaCN
solution.
3
(b)
Scadium (z=21) does not exhibit variable oxidation states and yet it
is regarded as transition element.
(c)
CH3
(a)
+ HI
H + HBr
(b)
H
(c)
CH3CH2CH
H
3
CH2 + HBr
208
18.
19.
How will you bring about following conversions? Write complete equations
in each case.
(a)
Ethanal to 3hydroxybutanal
(b)
Benzaldehyde to benzophenone
(c)
Propanone to propene
CuCN
(i) NH , B
(a)
3
2
C6H5N2 Cl A
B
C
(ii)
(b)
NaNO2 / HCl
(i) Sn/HCl
C6H5NO2
A
B
(ii) OH
273K
H O / H
20.
21.
23.
HI
(b)
Br2 water
(c)
HNO3
22.
Buna-S
(b)
Neoprene
(c)
Nylon6, 6
Pick out the odd one amongst the following on the basis of their medicinal
properties. Give suitable reason.
(a)
(b)
(c)
Ravi a student of Class XII Chemistry wants to test the quality of water
samples in his locality. He took two samples of water, they are not forming
froths with soap, so he concluded that both water samples have hardness.
His friend Mohit suggested him to compare the hardness of water by
titrating it with Na4EDTA. The Ca2+ and Mg2+ ions from stable complexes
with EDTA4.
209
24.
(a)
(b)
(c)
(d)
(a)
What type of a battery is the lead storage battery? Write the anode
and the cathode reactions and the overall reaction occurring in a
lead storage battery when current is drawn from it.
(b)
OR
(a)
(b)
25.
(a)
(b)
= 349.1 S cm2mol1
(ii)
The electron gain enthalpy with negative sign for oxygen (141
KJ mol1) is numerically less than that for sulphur (200 KJ
mol1).
(iii)
(ii) ClF3
210
OR
(a)
(b)
26.
(a)
(ii)
(ii)
(iii)
(ii)
(b)
(c)
OR
(a)
(b)
Name the reagents and write the chemical equation for the preparation
of the following compounds by Williamsons synthesis.
(i)
Ethoxybenzene
(ii)
2Methyl2methoxypropane.
(i)
(ii)
(iii)
211
ANSWERS
1.
2.
H 0
S 0
3.
Hex4en3ol
4.
CH3
CH2
CH2
5.
6.
7.
8.
(a)
(b)
Hg3P2 + 6HCl
3HgCl2 + 2PH3
212
9.
(i)
OR
10.
11.
(i)
(ii)
(a)
[+]
(b)
(i)
4r
2
2 2r
Total Volume
V
3
Volume of one unit cell
a
1cm3
10 3
354 10
cm3
Tf
Tf 1.592 K
13.
Given k2 = 4 k1
T1 = 300 K, T2 = 320 K
R = 8.314 J K1 mol1
k
Ea T2 T1
log 2
2.303R T1T2
k1
4k
Ea
log 2
2.303 8.314
k1
log 4
320 300
300 320
Ea
20
Ea = 55.327 k J mol1
14.
15.
(a)
(b)
(c)
(a)
330 350 K
450 470 K
Ni+4CO
Ni(CO)4
Ni+4CO
1
214
(b)
2Ag + [Zn(CN)4]2
2[Ag(CN)2] + Zn
(c)
FeSiO3
SiO2 + FeO
Flux
Gangue
Slag
OR
(a)
Alumina
870K
ZrI4
2075K
(b)
Zr + 2I2
Impure
Zirconium
Zr + 2I2
Pure
Zirconium
(c)
4[Au(CN)2] + 4OH
4 Au(s) + 8 CN + 2H2O + O2
2Au + [Zn(CN)4]2
2[Au(CN)2] + Zn
16.
(a)
(b)
(c)
CH3
I
CH3
17.
(i)
+ HI
215
(ii)
(iii)
Br
+ HBr
H
H
CH3CH2CH
CH3
Br
18.
(i)
dil.NaoH
2 CH3CHO
CH3CH
CH2CHO
OH
CHO
COCl
COOH
C
HNO3
(ii)
SOCl2
C6H6
Anhy.AlCl3
1
(iii)
CH3
CH3
[H]
LiAH4
CH3
CH3
CH
Conc.H2SO4
CH3CH
CH2
OH
1
N2Cl
COOH
CN
+
CuCN
19.
(A)
NO2
20.
(a)
(B)
(C)
+
N2Cl
NH2
(i) Sn/HCl
(ii) OH
(b)
NH3
H2O/H
(a)
CONH2
OH
+
H2O/H
NaNO2/HCl
273-278K
Reaction with HI
CHO
(CHOH)4
RedP/HI
373K
CH3CH2CH2CH2CH2CH3
n-hexane
CH2OH
216
(b)
CHO
COOH
+ [O]
Br2water
(CHOH)4
(CHOH)4
CH2OH
Glucose
(c)
CH2OH
Glucose Acid
CHO
COOH
(CHOH)4
HNO3
Oxidation
(CHOH)4
CH2OH
Glucose
21.
(i)
COOH
Saccharic Acid
(ii)
2Chloro1, 3butadiene
CH2
CH
CH
CH2
1
Cl
(iii)
Nylon 6, 6
Hexamethyldiamine : H2N ((CH2)6 NH2
Adipic acid : HOOC (CH2)4COOH
22.
23.
(a)
(b)
(c)
(a)
Ethylenediaminetetraacetate ion
(b)
(c)
Complexometric titration
(d)
Scientific attitude, work for community, help for others [Any one] 1
217
24
(a)
(b)
Cu2+ +2Ag
Cu + 2Ag+
Cu | Cu2+ || Ag+ | Ag
Ecell
Cu2
0.059
log
=
2
n
Ag
0.1
0.059V
0.46V
log
2
0.0012
Ecell
Ecell = 0.3125V
OR
(a)
0(CH3COOH)
0CH
40.9 + 349.1
3COO
0H
218
1
[Class XII : Chemistry]
c
m
0
m
3 10 2
25.
(a)
(i)
(ii)
(iii)
(b)
F
Xe
(i)
F
1
F
F
Cl
(ii)
Cl
F
OR
(a)
(i)
(ii)
O
(b)
(i)
P
OH
OH
219
(iii)
(i)
(ii)
(b)
< pentan1ol
H 3O
H 2O + H
H
C=C
+ H
O H
..
+ H2O
..
(a)
H
Step II: Attack of nucleophile on carbocation
..
+ H2O
..
H
C
O
+
..
+ H2O
..
H
(c)
..
OH
..
26.
(ii)
C + H3O
Kolbes reaction
OH
O Na
OH
NaOH
(i) CO2
(ii) H
COOH
O Na
(a)
OCH2CH3
+ CH3CH2Br
Ethyl bromide
(i)
Sodium
phenoxide
+ NaBr
1
Ethoxybenezene
CH3
CH3
(ii)
(b)
(i)
O Na +CH3Br
CH3
CH3
OCH3+NaBr
CH3
2-Methyl-2-methoxypropane
O
R
(ii)
CH3
C6H5O + H+
C6H5OH
RO + H+
ROH
Phenol gives H+ ion easily because it forms phenoxide ion
which is resonance stablized while alcohols does not provide
H+ ion readily, because alkoxide ion (RO) is not stablised by
resonance, so phenol is more acidic than alcohols.
1
(iii)
221
Maximum Marks : 70
General Instruction
(i)
All questions are compulsory.
(ii)
Question numbers 1 to 5 are very short answer questions and carry 1
mark each.
(iii) Question numbers 6 to 10 are short answer questions and carry 2 markseach.
(iv) Question numbers 11 to 22 are short answer questions and carry 3
marks each.
(v)
Question number 23 is a value based question and carry 4 marks.
(vi) Question numbers 24 to 26 are long answer questions and carry 5 markseach.
(vii) Use log table, if necessary. Use of calculator is not allowed.
1.
2.
3.
4.
Ca3P2 + H2O
(ii)
Cu + H2SO4 (conc.)
222
OR
Arrange the following in the order of property indicated against each set :
(i)
(ii)
7.
8.
Outline the principles behind the refining of metals by the following methods:
(i)
(ii)
Chromatographic method
9.
State Raoults law for the solution containing volatile components. What is
the similarity between Raoults law and Henrys law?
2
10.
11.
(i)
(ii)
(a)
HBr
CH3CH2Br + H2O
CH3CH2OH
12.
(b)
(a)
(b)
13.
(i)
XeF4
(ii)
N2O5
KCN
HNO
(i)
4
2
A
B
C
CH3Br
273K
(ii)
3
3
2
A
B
C
CH3COOH
NH
Br KOH
CHCl NaOH
OR
223
(ii)
(iii)
14.
.15.
16.
17.
18.
(i)
(ii)
(iii)
(i)
(ii)
(iii)
(i)
(ii)
(iii)
(a)
(b)
(c)
The following data were obtained during the first order thermal
decomposition of SO2Cl2 at a constant volume:
3
SO2Cl2 (g) SO2 (g) + Cl2 (g)
Experiment
Time/s
Total pressure/atm
0.4
100
0.7
19.
20.
20.
[Ni(CN)4]2
(ii)
[NiCl4]2
(ii)
(iii)
The two O-O bond lengths in the ozone molecule are equal.
A+
A+
A+
A+
A+
A+
A+
A+
22.
23.
(i)
(ii)
(iii)
(i)
(ii)
After the ban on plastic bags, students of one school decided to make the
people aware of the harmful effects of plastic bags on environment and
Yamuna River. To make the awareness more impactful, they organized
rally by joining hands with other schools and distributed paper bags to
vegetable vendors, shopskeepers and departmental stores. All students
pledged not to use polythene bags in future to save Yamuna River.
After reading the above passage, answer the following questions :
(i)
225
24.
(ii)
(iii)
(iv)
(a)
(b)
(i)
(ii)
Fuel cll
KCl solution
is 100 .If the resistance of the same cell when filled with 0.02 mol
L1 KCl solution is 520 , calculate the conductivity and molar
conductivity of 0.02 mol L1 KCl solution. The conductivity of
0.1 M KCl solution is 1.29 102 1 cm1.
OR
(a)
(b)
25.
(a)
(b)
(ii)
(ii)
(iii)
(i)
(ii)
(iii)
Out of Cr3+ and Mn3+, which is a stronger oxidizing agent and why?
(iv)
(v)
26.
(i)
O + H2N OH
(ii)
(iii)
CH3COOH
(b)
Cl /P
(i)
(ii)
(a)
(b)
(ii)
Wolif-Kishner reduction
(ii)
Aldol condensation
(iii)
Cannizzaro reaction
227
MARKING SCHEME-2
1.
Lyophobic Sol : Metal Sol, metal sulphides/hydroxides (or any other, any
one example in each case)
2.
4-hydroxypentan-2-one
3.
Hydrogen bonding
4.
5.
6.
(i)
(ii)
+
1
OR
7.
(i)
(ii)
(i)
(ii)
8.
9.
(i)
Impurities are more soluble in the melt than in the solid state of the
metal.
1
(ii)
For the solution containing volatile components, the partial vapour pressure
of each component is directly proportional to its mole fraction.
1
In both cases, p x therefore, Henrys Law is a special case of Raoults
Law.
1
228
10.
Rate constant (k) is rate of the reaction when the concentration of each
reactant is unity. Half-life period of the reaction is the time in which the
concentration of the reactant is reduced to half of its initial concentration.1+1
11.
(a)
HBr H+ + Br
H
|+
CH3 CH2 O H + H CH3 CH2 O H
+
H
|+
+
CH3 CH2 O H CH3 CH2 + H2 O
CH3 CH2
(b)
Br
CH3 CH2 Br
+
Br CH2 + H2O
Br + CH2 OH2
|
|
(Where R = CH3)
R
R
OH
ONa
OH
|
| CHO
| CHO
|
|
+
CHCl3 + aq NaOH
H
salicylaldehyde
Xe
13.
F
(ii)
|| N O N
||
(b)
(i)
(a)
12.
White phosphorus
Red phosphorus
(a)
CH3 Br KCN CH3 CN LiAlH CH3 CH2 NH2 HNO2 CH3 CH2 OH
273K
A
B
C
(b)
CH3 COOH
NH3
NO2
|
(i)
(ii)
CH3 NH2
B
CHCI3 CH3 NC
NaOH
C
NO2
|
(i) Sn/HCI
(ii) OH
CH3 COOH
NH3
CH3 CONH2
229
Br2+KOH
CH3 NH2
[Class XII : Chemistry]
O
||
NH C CH3
|
NO2
|
(iii)
(CH3 CO)2O
15.
(i)
(ii)
Because of higher oxidation state (+4) high charge to size ratio, high
polarizing power.
1
(iii)
(i)
(ii)
(iii)
16.
17.
(a) Vitamin C
(b)
Peptide linkage
(c)
(a)
x
K p1/ n
m
(b)
(c)
230
18.
2.303
pi
log
t
2pt pt
2.303
0.4
log
t
0.8 0.7
2.303
0.4
log
100
0.1
2.303
x 0.6021 1.39 x 10 2 s 1
100
(a)
[Ni(CN)4]2
Ni28 [Ar]18 4s2 3d8
Ni(II) [Ar]18 3d8
4p
4s
3
sp hybridization
(Square Plannar)
(Diamegnetic)
1+
[NiCl4]2
Ni28 [Ar]18 4s2 3d8
Ni (II) [Ar]18 3d8
(b)
19.
1
4s
3
4p
sp hybridization,
tetrahedral
(paramagnetic)
231
1+
20.
(i)
(ii)
21.
(iii)
(i)
Schottky defect
(ii)
Decreases
Solutions which obey Raoaults law over the entire range of concentration
A-A or B-B ~ A-B interactions
1
Hmix= 0
Vmix= 0
(any one)
Tf
K f WB 1000
w A MB
0.48K 5.12Kkgmol1
wB
wB
1000
75 256
0.48 75 256
5.12 1000
wB = 1.8g
23.
(i)
(ii)
(iii)
Addition polymer.
(iv)
Thermoplastic polymer.
232
24.
G
129m1
= 20 mol m3
Concentration = m
=
K
C
248 10 3 Sm 1
20 mol m3
(b)
E cell = 2.71
0.059V
0.10
log
2
0.01
E cell = 2.71
0.059V
log10
2
233
25.
OR
(i) Mn, because of presence of 5 unpaired electrons in 3d subshell
+
(ii)
= n F (Ecu / Cu2+)
= n F ( Ecu / Cu2+/Cu)
(iv)
Eu2+
(v)
MnO4 + 8H+ + 5e
(iii)
N.OH
CH2OH
Mn2+
+ 4H2O
1
1
(ii)
||
(i)
26.
(iii)
Cl CH2 COOH
COONa
1
1
(b) (i) Add NaHCO3, benzoic acid will give brisk effervescence whereas
benzaldeyde will not give this test, (or any other test)
1
(ii) Add Tollens reagent, propanal will give silver mirror whereas
propanone will not respond to this test. (or any other test)
1
OR
234
(a)
(b)
O
NH2NH2
H2O
2 CH3 CHO
H
(iii)
dil. NaOH
NNH2
O +
O + Conc. KOH
CH2 + N2
H
C
H
|
C
|
H
(ii)
(i)
OH + H C
OK
235
SAMPLE PAPER-III
Chemistry (Theory)
Time allowed : 3 hours
Maximum Marks : 70
General Instruction
(i)
All questions are compulsory.
(ii)
Question numbers 1 to 5 are very short answer questions and carry 1
mark each.
(iii) Question numbers 6 to 10 are short answer questions and carry 2 markseach.
(iv) Question numbers 11 to 22 are short answer questions and carry 3
marks each.
(v)
Question number 23 is a value based question and carry 4 marks.
(vi) Question numbers 24 to 26 are long answer questions and carry 5 markseach.
(vii) Use log table, if necessary. Use of calculator is not permitted.
1.
2.
3.
Among octahedral and tetrahedral crystal fields, in which case the magnitude
of crystal field splitting is larger?
4.
5.
6.
7.
Classify each of the following as being either a p-type or an n-type semiconductor. Give reason.
(a)
(b)
236
8.
P4 8SOCl2
(b)
2 I O 2 H 2 O
9.
10.
(a)
(b)
11.
12.
(b)
SF4
(b)
XeO3
(c)
HOClO2
13.
14.
(a)
15.
(ii)
(b)
(a)
(b)
(c)
16.
17.
(b)
A non-ionic detergent.
(c)
A pain reliever used for relief from severe pains like post-operative
pain or pain due to terminal cancer.
(a)
(b)
(i)
(ii)
(a)
2
4
CH3 CH2 OH
CH2 CH2 H2 O
443K
(b)
19.
20.
Give reasons
(a)
(b)
(c)
(a)
(b)
238
(i)
(ii)
21.
22.
(a)
(b)
(c)
23.
24.
(i)
(ii)
Why was car driver stopped and asked to breath in the electronic
device?
(b)
(c)
(d)
(a)
(b)
(I)
(ii)
Give reason :
(i)
(ii)
(a)
(b)
(c)
In the button cell, widely used for watches and other devices, the
following reaction takes place :
Ag2O(s) H2O(l) 2e
2Ag(s) 2OH (aq)
(E = 0.344V)
Zn2 (aq) 2e
Zn(s)
(E = 0.76V)
25.
(b)
(c)
(d)
(e)
(a)
(b)
(c)
(i)
(ii)
Cr2O72 + 3Sn2+ + H+
(d)
Based on the following data, arrange Fe2+, Mn2+ and Cr2+ in the
increasing order of stability of +2 oxidation state
240
(a)
dil NaOH
heat
2
4
CH CH
A
B
C
HgSO
4
(b)
Give reasons
(i)
(ii)
(a)
(b)
(ii)
(A) reacts with hydrazine and is then heated with KOH and
ethylene glycol.
(iii)
241
Maximum Marks : 70
General Instruction
(i)
All questions are compulsory.
(ii)
Question numbers 1 to 5 are of 1 each. Answer these in one word or about
one sentence each.
(iii) Question numbers 6 to 10 are of 2 marks each. Answer these in about
30 words.
(iv) Question numbers 11 to 22 are of 3 marks each. Answer these in about 40
words.
(v)
Question number is of 23 4 mark. Answer thse in about 55 words.
(vi) Question numbers 24 to 26 are of 5 marks each. Answer these in about 70
words each.
(vii) Use log table, if necessary.
(viii) Use of calculator is not permitted.
1.
2.
3.
4.
5.
6.
7.
8.
Zone refining
(b)
Electrolytic refining
OR
How is copper extracted from copper pyrities? Write the equations of the
reactions involved.
9.
10.
(b)
Alc. KOH
Br 2
H2 O
2+
Hg /H2SO4
Br
11.
12.
13.
14.
(a)
(b)
(c)
(b)
KI O3 H2O
(c)
XeF4 H2 O
(b)
(c)
15.
(b)
(c)
Write the monomers of following polymers and mention one use of each
polymer.
16.
(a)
PAN
(b)
Nylon-6,6
(c)
Glyptal
17.
(b)
(c)
18.
(a)
19.
(b) Tranquilizers
HI
(b
(a)
NH2 and
CH2 NH2
244
(b)
20.
21.
22.
(a)
Sandmeyer reaction
(ii)
Ethanol to propan-2-ol
(ii)
Phenol to acetophenone
(b)
(a)
(b)
XeF2
(b)
ClF3
(c)
CH3
CH3CH2CH2
N
CH2CH3
23.
24.
Once at the weekend the students of a school along with the chemistry
teacher visited a coastal village. They noticed that most of people of that
village were having swollen neck. The villagers told that they are using the
salt prepared by evaporation of sea water.
(a)
(b)
(c)
Name the two salts which should be added to the common salt.
(d)
(a)
(b)
(b)
(ii)
(iii)
0
0
0
[Given : EO2 /H2O 1.23V, E Ag / Ag 0.80V, EH2O /H2 0.83V ]
25.
(a)
(b)
(ii)
(iii)
(a)
(b)
26.
(ii)
(iii)
(a)
Write structural formulas and names of four possible aldol condensation products obtained from propanal and ethanal. Indicate which
aldeyde acts as nucleophile and which as electrophile.
(b)
(ii)
(a)
O3
Zn H2O
O + HCHO
(i) NaBH4
(ii) H3O
CH2OH
(iii)
(b)
KMnO4
KOH, heat
(i)
Hell-Volhard-Zelinsky reaction
(ii)
Cannizzaro reaction
247