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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
: METHYLISOBUTYLCARBINOL
1.2 Relevant identified uses of the substance or mixture and uses advised against
Uses of the Substance/Mixture
: Specific use(s): Foaming agent, Additive for lubricants, Solvent for paints,
varnishes, thinners, strippers, adhesives, Intermediate for the synthesis of
organic chemicals
E-mail address
: information.fds@solvay.com
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
108-11-2
108-10-1
4-methylpentan-2-ol
4-methylpentan-2-one
Pictogram
Signal word
: Warning
Hazard statements
: H226
H335
Precautionary statements
: General:
None
Prevention:
P210
P233
P240
P241
P242
P243
P261
P271
P280
Response:
P303 + P361 +
P353
P304 + P340
P312
P370 + P378
Storage:
P403 + P233
P403 + P235
P405
Disposal:
P501
: 3 : serious
: 3 : serious
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
Instability or Reactivity
: 0 : minimal
: 108-11-2
Identification
number
KECI Number:
KE-24720
CAS-No.
4-methylpentan-2-ol
108-11-2
4-methylpentan-2-one
108-10-1
KECI Number:
KE-24725
GHS Classification
Flammable liquids , Category 3 ;
H226
Specific target organ toxicity - single
exposure , Category 3 ; H335
Flammable liquids , Category 2 ;
H225
Acute toxicity , Category 4 ; H332
Eye irritation , Category 2 ; H319
Specific target organ toxicity - single
exposure , Category 3 ; H335
Concentration
[%]
>= 95 - < 99
>= 1 - < 5
For the full text of the H-Statements mentioned in this Section, see Section 16.
3.2 Mixture
Not applicable, this product is a substance.
SECTION 4: First aid measures
4.1 Description of first aid measures
General advice
If inhaled
Skin contact
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes.
If eye irritation persists, consult a physician
Ingestion
4.2 Most important symptoms and effects, both acute and delayed
no data available
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
4.3 Indication of any immediate medical attention and special treatment needed
no data available
SECTION 5: Firefighting measures
Flash point
Auto-ignition temperature
no data available
Flammability/Explosive limit
Foam
Dry powder
Carbon dioxide (CO2)
Flammable liquid
Vapour/air mixtures are explosive.
Heating increases the inner pressure of the bottle, risk of explosion.
Further information
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
Dam up.
Prevent product from entering sewage system.
Try to prevent the material from entering drains or water courses.
Local authorities should be advised if significant spillages cannot be
contained.
Collect spillage.
Pick up and transfer to properly labelled containers.
Flammable product. Take all necessary precautions. Earth the containers and
the equipment.
Keep in suitable, closed containers for disposal.
Neutralization
Decontamination/cleaning
Collect spillage.
Pick up contaminated soil.
Clean contaminated floors and objects thoroughly while observing
environmental regulations.
Pick up and transfer to properly labelled containers.
Keep in suitable, closed containers for disposal.
Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for
disposal according to local / national regulations (see section 13).
Nonsparking tools should be used.
Disposal
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
Hygiene measures
: Ensure that eyewash stations and safety showers are close to the workstation
location.
Use clean, well-maintained personal protection equipment.
Wash hands before breaks and at the end of workday.
When using do not eat, drink or smoke.
The floor of the depot should be impermeable and designed to form a watertight basin.
Electrical installations / working materials must comply with the technological
safety standards.
Keep away from open flames, hot surfaces and sources of ignition.
Store in original container.
Keep away from heat.
Keep in a dry, cool and well-ventilated place.
Store contents under inert gas.
Keep under nitrogen.
Plastic materials.
no data available
Storage conditions
Recommended
Packaging Measures
Storage stability
Storage temperature
7.3 Specific end use(s)
no data available
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
Value type
TWA
Value
25 ppm
100 mg/m3
Basis
Occupational Exposure Limits Korea
STEL
40 ppm
165 mg/m3
TWA
50 ppm
205 mg/m3
4-methylpentan-2-one
STEL
75 ppm
300 mg/m3
Value
25 ppm
Basis
USA. ACGIH Threshold Limit Values (TLV)
Value type
TWA
Eye & Upper Respiratory Tract Irritation, Central Nervous System impairment, Danger of
cutaneous absorption
4-methylpentan-2-ol
STEL
40 ppm
Eye & Upper Respiratory Tract Irritation, Central Nervous System impairment, Danger of
cutaneous absorption
4-methylpentan-2-one
TWA
20 ppm
Upper Respiratory Tract irritation, Headache, Dizziness, 2010 Adoption, Substances for
which there is a Biological Exposure Index or Indices (see BEI section), Confirmed
animal carcinogen with unknown relevance to humans
4-methylpentan-2-one
STEL
75 ppm
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
Upper Respiratory Tract irritation, Headache, Dizziness, 2010 Adoption, Substances for
which there is a Biological Exposure Index or Indices (see BEI section), Confirmed
animal carcinogen with unknown relevance to humans
Value type
BEI
Value
1 mg/l
Methyl isobutyl
ketone (MIBK)
Urine
End of shift (As
soon as possible
after exposure
ceases)
Basis
ACGIH - Biological Exposure Indices (BEI)
Hand protection
Eye protection
Hygiene measures
: Ensure that eyewash stations and safety showers are close to the workstation
location.
Use clean, well-maintained personal protection equipment.
Wash hands before breaks and at the end of workday.
When using do not eat, drink or smoke.
Protective measures
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
: Dam up.
Prevent product from entering sewage system.
Try to prevent the material from entering drains or water courses.
Local authorities should be advised if significant spillages cannot be
contained.
Form : liquid
Physical state:
liquid
Colour: colourless
Odour
aromatic
Odour Threshold
no data available
pH
not applicable
Crystallization temperature
-90 C
Flash point
no data available
no data available
Flammability (liquids)
no data available
Flammability/Explosive limit
Auto-ignition temperature
no data available
Vapour pressure
4.95 hPa ( 20 C)
Vapour density
3.5
Density
0.807 g/cm3 ( 20 C)
Solubility
Water solubility :
7 g/l
partly miscible
Solubility in other solvents:
miscible with most organic solvents
POW: 1.43
Thermal decomposition
no data available
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
Viscosity
no data available
Explosive properties
no data available
Oxidizing properties
Henry's Constant
4.508962 Pa.m3/mol
(25 C)
Molecular Weight
102.17 g/mol
Acids
Strong oxidizing agents
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METHYLISOBUTYLCARBINOL
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no data available
no data available
Genotoxicity in vitro
no data available
Genotoxicity in vivo
no data available
Toxicity to reproduction/Fertility
no data available
Developmental Toxicity/Teratogenicity
no data available
Toxicology Assessment:
The substance or mixture is classified as specific target organ toxicant, single
exposure, category 3 with respiratory tract irritation.
no data available
Skin corrosion/irritation
Skin irritation
Serious eye damage/eye irritation
Eye irritation
Carcinogenicity
Carcinogenicity
STOT
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
Symptoms: Drowsiness
Local irritation
Dizziness
Vomiting
Diarrhoea.
no data available
Biodegradability
Ratio BOD/COD
Aspiration toxicity
Aspiration toxicity
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
Other data
UN 2053
III
3
F-E
S-D
NO
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
ADR
14.1 UN number
UN 2053
III
F1
30
3
(D/E)
NO
UN 2053
III
F1
30
3
NO
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
IMDG
14.1 UN number
UN 2053
III
3
F-E , S-D
NO
UN 2053
NO
III
3
366
220.00 L
355
60.00 L
CAS-No.
Threshold limits
108-10-1
>1
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
Flammable liquids
Type 2 petroleumsWater insoluble liquid
Threshold quantity : 1000 (litre)
Notification status
These data are not exhaustive but given for information. Contact your supplier for additional information
United States TSCA Inventory
: y (positive listing)
On TSCA Inventory
: y (positive listing)
All components of this product are on the
Canadian DSL.
: y (positive listing)
On the inventory, or in compliance with the
inventory
: y (positive listing)
On the inventory, or in compliance with the
inventory
: y (positive listing)
On the inventory, or in compliance with the
inventory
: y (positive listing)
On the inventory, or in compliance with the
inventory
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METHYLISOBUTYLCARBINOL
Revision: 2.00 KR ( EN )
Key or legend to abbreviations and acronyms used in the safety data sheet
Exposure controls/personal protection
STEL
TWA
Further information
Further information
: This sheet was updated (refer to the date at the top of this page).
Subheadings and text which have been modified since the previous version
are indicated with two vertical bars.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. Such information is only given as a guidance to help the user handle, use, process, store, transport,
dispose and release the product in satisfactory safety conditions and is not to be considered as a warranty or quality
specification. It should be used in conjunction with technical sheets but do not replace them. Thus, the information only
relates to the designated specific product and may not be applicable if such product is used in combination with other
materials or in an other manufacturing process, unless otherwise specifically indicated. It does not release the user from
ensuring he is in conformity with all regulations linked to its activity.
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