MSDS

Date : 10/09/2008

3X ENGINEERING

R3X1060 Part B

Page: 1/5

selon 91/155/CEE

1.0 Identification of the substance / preparation and society

1.1 Identification of the chemical:

R3X1060 Part B

1.2 Entity responsible for marketing:

3 X ENGINEERING S.A.M
9 avenue Albert II
98000 MONACO
Tl. : +377 92 05 79 81
1.3 Emergency number:

ORFILA : 01.45.42.59.59

2 .0 Composition / Information of components

Description of chemicals :

Mixed cycloaliphatic amines and alcohol.

Informations of hazardous components :

N CAS
100-1-6
2855-13-2
38294-64-3

Dsignation
Benzyl alcohol
Isophoronediamine
Cycloaliphatic amine adduct with BPA polymer

%
35-40
30-35
25-30

Ident.
Xn
C
C, N

Phrases R
R20/22
R21/22, R34, R43, R52/53
R21/22, R34, R43, R51/53

3.0 Hazard identification

Classification
Corrosive, Dangerous for the environment
Indications of risk to humans and the environment
Hazards to humans: Cause burns. Harmful by inhalation, skin contact and by ingestion. May cause
sensitization by skin contact.
Physical and chemical hazards: No Not classified as flammable but can burn.
Environmental Effects: Very toxic to aquatic organisms. May cause adverse long-term to the aquatic
environment.

4. 0 First aid
4.1 If inhaled : Move to fresh air. If the person does not recover quickly, consult a doctor or hospital.
4.2 In case of contact with skin : DO NOT WAIT. Remove immediately clothing and shoes. Rinse
immediately with plenty of water and soap if possible for at least 10 minutes. If symptoms persist, consult a
doctor or hospital.
4.3 In case of eye contact : DO NOT WAIT. Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes. Consult immediately a doctor.
4.4 If swallowed : DO NOT WAIT. Do not induce vomiting. If swallowed, immediately consult a doctor or
hospital.

5.0 Mesures against fire

5.1 Means of non-extinction appropriate :
Water jet.
5.2 Extinguishing media recommended :
Alcohol resistant foam, water spray or fog.
5.3 During the fight against fire :
Not classified as flammable but can burn. Clearance
possible carbon monoxide, nitrogen oxides if incomplete combustion. Coll containers nearby with water
spray.

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Date : 10/09/2008

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5.4 Protective equipment :

autonomously.

selon 91/155/CEE

Apparel comprehensive protection and breathing apparatus

6.0 Action accidental release

6.1 Precautions:
Avoid contact with skin, eyes, clothing. Completely ventilate the contaminated area.
Do not breathe vapors. Immediately remove all contaminated clothing.
6.2 Precautions for environmental protection :
Prevent contamination of soil and water. Prevent
any infiltration or runoff into sewers, gutters or rivers by using sand or soil or other suitable. If the product
reaches the sewers, it must be pumped in a shell not closed. You can call emergency services to assist in
the operation.
6.3 Methods of cleaning/recovering : Absorb or retain the liquid with sand, earth or limiting any subject
spraying. Recovering in a container labeled, closed, to proceed to a safe disposal. Scrub contaminated
surfaces with detergent solution Keep washing water as contaminated waste. Place containers prevarication
in a barrel or even an over-labeled
7.0 Storage and handling
7.1 Handling precautions :
Comply with local regulations. Avoid contact with skin, eyes and clothing. Do
not breathe mists, aerosols, vapors.
7.2 Criteria storage : Store according to local regulations. Keep container tightly closed and protected
from humidity. Keep only in original container. Keep container in a well ventilated. Keep away from direct
sunligth. Keep away from heat.
7.3 Storage : Ambient.
8.0 Monitoring the exposure of workers, personal protective equipment
8.1 Technical control : Use a local extraction ventilation air.
8.2 Components with limit values that require monitoring at work :
Components with limit
Updated
Term
values that require
Value
regulations
exposure
monitoring at work
Benzyl alcohol
ACGIH
Isophoronediamine
ACGIH
Cycloaliphatic amine
adduct with BPA
ACGIH
polymer
8.3 Personal protection measure :

Note
No established value
No established value
No established value

Respiratory: Having a self-contained breathing apparatus

ready for use if necessary. In the premises or the product
is pulverized, workers should avoid contact with aerosols
containing the agent treatment with control methods,
such as exhaust ventilation or suitable protective
equipment such as respirators mask full and air supply,
gloves and protective suits. Wear a respirator if
ventilation is inadequate. Hands: nitrile rubber. In an
emergency, wear waterproof gloves with cuffs to prevent
the spread of material to the area above the wrists.
Neoprene gloves. Butyl rubber. Nitrile rubber. The time
Waterproofing gloves chosen must be longer than the
period of use. Eyes: In places or treatment agent may
come into contact with eyes, workers should wear
goggles and a mask projections. People working near the
equipment, within range of potential exposure must also
wear goggles plastic. Workers should not touch their
eyes or skin with contaminated hands by the treatment
agent.

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8.4 Special protection measures and hygiene : Discard leather contaminated. Provide eye wash stations
and safety showers. Wash at the end of each work period
and before eating, smoking or using the toilet.
8.5 General protection measures and hygiene: Trying to prevent the penetration of material into sewers
or waterways. Keep out of surface water or sewage
systems. Build a retaining wall to prevent the dispersion
of liquids.

9.0 Proprits Physico-chimiques

9.1 Physical condition :

Yellow clear liquid

9.2 Odor :

Amine odor

9.3 Typical temperatures :

Flash point :
>100C.
Boiling point :
Ca.200C
Temperature self-flammability :

9.4 Solubility :

Ca. 567 mg/l at 25C

9.5 Gravity:

1,04 (at 25C)

9.6 Viscosity (mPa.s) :

500 - 700 (at 25C)

9.7 pH :

Ca. 12

250C.

10.0 Stability of product et reactivity :

10.1 Conditions to avoid :
Exposure to water vapor.
10.2 Hazardous reactions :
Stable under normal conditions of use. Reacts with strong oxidizing agents.
Strong acids. Hygroscopic.
10.3 Hazardous decomposition : Not to our knowledge.

11.0 Toxicologic informations

11.1 Acute :

Ingestion : Moderatly toxic, 200 <DL50< 2000 mg/kg

Contact with skin : Moderatly toxic, 200 <DL50< 2000
mg/kg

11.2 First irritation :

Of the skin : Corrosive.

Of the eye : Corrosive.

11.3 Additional toxicological information :

According to the method of calculating the latest current
version of the general directive of the EEC on the
classification of preparations, the product has the following
hazards: corrosive.
12.0 Ecological informations :
Eco toxicologic effects
Aquatic toxicity :

Fish : Slightly toxic, 10 <CL/CE/CI 50 <= 100 mg/l

Algae : Very toxic, CL/CE/CI 50 <= 1 mg/l
Invertebraties : Slightly toxic, 10 <CL/CE/CI 50 <= 100 mg/l

Toxicity to other agencies:

Non available data.

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Persistence et degradability :
Mobility
Sinks in water. The solvent dissipates in a day through evaporation and dissolution.
In the basement, the product is mobile and can contaminate water and groundwater.
Bioaccumulation
Contains components potentially bioaccumulative.
13.0 About the possibility of waste disposal :
13.1 Product :

Putting the collection of toxic waste or make to the dump

for hazardous waste

13.2 Packaging non cleaned :

Evacuation accordance with legal requirements.

14 .0 Transport details :

UN: 2735
Class: 8
Classification: C7
PG: III
No. Labeling:
No risk: 80
Shipping Name : AMINES, LIQUID, CORROSIVE, NOS (ISOPHORONEDIAMINE,
cycloaliphatic AMINES MODIFIED)
Marine Pollutant : Yes. Mark Marine pollutant required.
15.0 Regulatory informations
15.1 Labelling to EEC Directives
Symbol of danger :

C, Corrosive
N, Dangerous for the environment

15.2 Phrases R :

R20/21/22 Harmful by inhalation, contact with skin and if swallowed.

R43 May cause sensibilising after contact with skin.
R50/53 Very toxic to aquatic organisms, may cause adverse long term tothe
aquatic environment.

15.3 Phrases S :
26

In case of contact with eyes, rinse immediately and thoroughly with water
and consult a specialist.

28A

After contact with skin, wash immediately and thoroughly with soap and
water.

36/37/39

Wear suitable protective clothing, gloves and a protective equipment for eye
and face.

45

In case of accident or illness, consult a doctor immediately (where possible

the label).

57

Use appropriate container to avoid contamination of the environment.

61

Avoid release into the environment.

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Pays

List

Notification

USA

TSCA

Listed

EU

EINECS

Listed

Canada

DSL

Listed

Australia

AICS

Listed

Japan

ENCS

Listed

South Korea

ECL

Listed

China

SEPA

Listed

Philippines

PICCS

Listed

16.0 Other informations :

Ensure that all national or local regulations are respected.
Risk phrase
R20/22 Harmful by inhalation and ingestion.
Harmful in contact with skin and if swallowed.
Causes burns.
May cause sensitization by skin contact.
Toxic to aquatic organisms, may cause effects long term harmful to the aquatic environment.
Harmful to aquatic organisms, may cause effects long term harmful to the aquatic environment.
This Safety Data Sheet has been established according to European Directives in force and shall apply to all
countries that have translated the Directives into national law.
This profile is based on the current state of our knowledge, but does not guarantee about the properties of
the product and does not give rise to a legal contract.