Documente Academic
Documente Profesional
Documente Cultură
Promotional Examination
H2 CHEMISTRY
9746/03
Paper 3
26 September 2007
JC 1/2007
1 hour
Mark Scheme
1
(a)
[2]
(i)
O
CH3C
HO
CCH3
hydrogen bonding
OH
O
n
Ethanoic acid dimerises in the vapour phase by forming
hydrogen bonds between two molecules as shown above.
Therefore the Mr measured corresponds to 2 ethanoic acid
molecules and is 120 not 60.
(ii) Mr = mRT / PV
[3]
[2]
[1]
n
n
4
3
= (55.0 x 8.31 x 473) / (1.01 x 10 x 210 x 10 )
= 101.9 or 102 n
(b)
[4]
(ii) Hn = (47.3 x 4.2 x 8.4) / (0.025 x 1.20) n
1
1
= 55,600 J mol (or 55.6 kJ mol ) n
Hn for reaction between hydrochloric acid and sodium
1
hydroxide is about 57 kJ mol as it is the reaction:
+
H + OH H2O. n
A weak acid like ethanoic acid is not totally ionised in solution
and part of the heat liberated during neutralization is used
to further ionise the acid. n
Therefore the overall heat evolved is lesser in value or less
exothermic.
[Turn over
2
(c)
[3]
4.0 = x / (0.5 x)
Taking square roots: 2.0 = x / (0.5 x)
x = 0.333 (or 1/3) n
Amount of ethanoic acid is 0.5 0.333
= 0.167 mol (or 1/6) n
(d)
[1]
n
[4]
Initiation:
Cl
Cl
2Cl
n
Propagation:
Cl + CH3CO2H HCl + CH2CO2H
CH2CO2H + Cl2 Cl + CH2ClCO2H
Termination:
Cl + Cl Cl2
CH2CO2H + CH2CO2H HO2CCH2CH2CO2H
CH2CO2H + Cl CH2ClCO2H (any two) n
Total [20]
3
2
(a)
(b)
(i) The ClCl bond energy is the energy required to break one
mole of ClCl covalent bonds in the gaseous state. [1]
or
Bond energy is the energy required break one mole of covalent
bond between two atoms in the gaseous state.
ClCl(g) 2Cl(g);
H = BE(ClCl) [1]
[1]
[1]
(iii)
[3]
1
(+579) = +193 kJ mol1 [1]
3
H = [1 E(NN) + 1 E(ClCl)] [2 E(NCl)] [1]
= [(+78) + (+244)] [2 (+193)]
= 64 kJ mol1 [1]
E(NCl) =
(i)
F
F
[1]
[1]
[7]
(ii)
F B F
F
F N F
F
[1]
[1]
F
F N F
F
[1]
B
F
120
shape [1]
F
107
F
F
shape [1]
109
F
F
shape [1]
[Turn over
4
(iii)
F
N
[1]
N
F
correct representation of the two isomers [1]
(c)
(i)
n(MnO 4 )
n(C 2 O 4 2 )
c (MnO 4 )
25.40
1000
25.0
0.0498
1000
2
=
5
[2]
2
25.0
0.0498
[1]
5
25.40
= 0.0196 mol dm3 [1]
c(MnO 4 ) =
(ii)
[4]
21.80
= 2.137 103 mol
1000
25.0
n(NH2OH) reacted = 0.0427
= 1.068 103 mol
1000
both steps or correct ratio n(Fe3+) : n(NH2OH) [1]
2.137 10 3
= 2 units [1]
Increase in oxidation state of N =
1.068 10 3
Initial oxidation state of N in NH2OH = 1
Final oxidation state of N in R = 1 + 2 = +1 [1]
R is N2O [1]
If value of c(MnO4) wrong in (i), allow TE [1] for calculating
n(Fe3+) and n(NH2OH) reacted and TE [1] if method for next
two steps correct. Hence max mark is [2] for TE.
n(Fe3+) reacted = 5 0.0196
Total [20]