Documente Academic
Documente Profesional
Documente Cultură
College
2University of California Irvine
3NASA Langley Research Center
Ozone
&
Par8culate
Ma?er
1-hour
CA
standard
Sources
of
NOx:
vehicles
fuel
combus8on
industry
Sources
of
VOCs:
Urban
areas
Oil
and
natural
gas
sites
Agricultural
areas
Forests
Mixing
ra4o
(ppt)
1.99
106
1137
66
97
627
17
40
80
1.2
106
78
Mixing
ra4o
(ppt)
n-hexane
14.2
n-heptane
7.6
isoprene
29
benzene
26
toluene
30
xylene
13
acetaldehyde
1684.25
butanal
79.6
acetone
2042.2
butanone
190
methanol
3819.2
ethanol
704.6
VOC
La8tude
Urban inuence
Longitude
Gilman,
J.B.
et
al.
Environ.
Sci.
Technol.
2013
Contribu8on
of
gases
to
factors
Contribu8on
of
factors
to
cans
Conc. of Species
CO
Propane
Ethane
Ethyne
i-pentane/n-pentane
=
0.91
%
of
Species
Urban:
CO
CO2
Ethane
Ethene
Ethyne
Propane
Ethyltoluene
Propane
Butane
Pentane
Hexane
Biogenics/Agriculture:
Methane
DMS
Isoprene
Alpha-pinene
Beta-pinene
biogenics/agriculture
0.5
0.4
urban
0.3
0.2
0.1
0
48%
31%
Sample
2
28%
46%
Sample
3
27%
24%
30%
13%
59%
28%
Sample 4
34%
Sample
5
33%
34%
21%
45%
33%
urban
biogenics/agriculture
Sample 4
Sample 5
urban
oil
&
natural
gas
biogenics/agriculture
28%
27%
45%
46%
24%
33%
30%
33%
34%
Sample
2
28%
13%
59%
Sample
1
48%
21%
31%
i-pentane/n-pentane propane/ethyne
Acknowledgments
Dr.
Jason
Schroeder
Sean
Freeman
Dr.
Donald
R.
Blake
Rowland-Blake
Lab
Dr.
Emily
Schaller
Rick
She?er
DC-8
Flight
Crew
UND
&
NSERC
THANK YOU!
References
American
Lung
Associa8on.
State
of
the
Air:
Health
Eects
of
Ozone
and
Par8cle
Pollu8on.
h?p://www.stateosheair.org/2014/health-risks/?referrer=h?p://www.stateosheair.org/2014/
msas/bakerseld-ca-metropolitan-sta8s8cal-area.html
(accessed
Aug
1,
2015).
California
Environmental
Protec8on
Agency.
Air
Resources
Board:
Quality
Assurance
Air
Monitoring
Site
Informa8on.
h?p://www.arb.ca.gov/qaweb/site.php?s_arb_code=15257
(accessed
Aug
3,
2015).
Finlayson-Pi?s,
B.
J.
and
Pi?s,
J.
N.
Chemistry
of
the
Upper
and
Lower
Atmosphere:
Theory,
Experiments,
and
Applica?ons;
Academic
Press:
San
Diego,
2000.
Gilman,
J.
B.;
Lerner,
B.
M.;
Kuster,
W.
C.;
Gouw,
J.
A.
Source
signature
of
vola8le
organic
compounds
from
oil
and
natural
gas
opera8ons
in
northeastern
Colorado.
Environ.
Sci.
Technol.
2013,
47,
1297-1305,
DOI:
10.1021/es304119a
Russo,
R.
S.;
Zhou,
Y.;
White,
M.
L.;
Mao,
H.;
Talbot,
R.;
Sive,
B.
C.
Mul8-year
(20042008)
record
of
nonmethane
hydrocarbons
and
halocarbons
in
New
England:
seasonal
varia8ons
and
regional
sources.
Atmos.
Chem.
Phys.
2010,
10,
49094929,
DOI:
10.5194/acp-10-4909-2010
United
States
Environmental
Protec8on
Agency.
Human
Exposure
and
Atmospheric
Sciences:
EPA
Posi8ve
Matrix
Factoriza8on
Model.
h?p://www.epa.gov/heasd/research/pmf.html
(accessed
Aug
3,
2015).
Ques8ons?
k (10-12 cm3/molecule s)
methane
0.00618
ethane
0.254
propane
1.12
n-butane
2.44
n-pentane
4.0
n-hexane
5.45
n-heptane
7.0
Methane is 42 8mes less reac8ve than ethane and 187 8mes less reac8ve than propane