Documente Academic
Documente Profesional
Documente Cultură
Thus H=ve=exothermic
o
H=+ ve=endothermic
Thermochemical equations
Show the energy released or absorbed during a chemical
reaction.
o 6CO2(g) + 6H2O(l) C6H12O6(aq) + 6O2(g); H = +2803
kJ mol1
C6H12O6(aq) + 6O2(g) 6CO2(g) + 6H2O(l); H = 2803
kJ mol1
Activation energy
is the energy required to break the bonds of reactants
so that a chemical reaction can proceed.
Process: Energy absorbed bonds between atoms
break new bonds form energy is released
product
Energy profile (diagram on side)
Collision theory
For a chemical reaction to occur, the particles must collide with each other
with sufficient energy to overcome the activation energy barrier to the
reaction.
YIELD
Chemical equilibrium is the stage when the quantities of reactants and
products in the reaction remain unchanged
Reaction yield is how far the reaction will go/ the extent of conversion of
reactants into products
Reversible reactions
o Some physical and chemical changes can be reversed.
o Forward and reverse reactions occur simultaneously
o N2(g) + 3H2(g) 2NH3(g)
Equilibrium
Dynamic equilibrium
o Equilibrium is a dynamic state, Forward and back reactions have not
ceased
o Amounts and concentrations of chemical substance remain constant
o Total gas pressure is constant
o Temperature is constant
o Reaction is incomplete
General process: Reactants start reacting to form product (forward
reaction) some of the products formed, reactant to form the reactants
(reverse reactions) eventually forward and backward reactions perform
at the same rate the amount of reactants and products remains
constant
Different reactions proceed to different extents have different
equilibrium constants
Equilibrium Law
aA + bBcC + dD
o
o
[C] [D]
a
b
[ A ] [ B]
1
K
K <104
4
10 < K <10
reactants
104 < K
Q<K
Proceed right (faster rate of forward
reaction)
Q=K
Has reached equilibrium
Q>K
Proceed left (faster rate of reverse reaction)
Effects on the equilibria
Le Chateliers law
o
Pressure
o Changes the equilibrium position (the relative amount of products
and reactants)
o Does not change K
o GASES ONLY
o To change pressure, need to change volume
Increase Volume, Decrease pressure, system partially
opposes change by favouring the direction that produces
more particles
Decrease Volume, Increase pressure, system partially
opposes change by favouring the direction that produces less
particles
o Adding inert gas
No effect with the position of equilibrium
o Aqueous solution adding water
Increases volume, system partially opposes change by
favouring the direction that produces more molecules
Concentration
o Changes the equilibrium position (the relative amount of products
and reactants)
o Does not change K
Adding reactants
Pushes the reaction forward.
o Adding products
Pushes the reaction backward
o Reducing reactants
Pushes the reaction backward
o Reducing products
Pushes the reaction forward
Temperature
o Changes K
o Exothermic reaction (T opposite effect on K)
As temperature increases products decrease decrease K
value
As temperature decrease products increase increase K
value
o Endothermic reaction (T same effect on K)
As temperature increase products increase increase K
As temperature decrease products decrease decrease K
Catalyst
o Does not change K
o Increases rate of reaction via an alternate pathway.
o Only speeds up the time it reaches equilibrium does not change
position of equilibrium
Some reactions dont reach equilibrium
o Reaction will produce products that leave the system forwards
reaction until completion
o
E.g.
system.
o Reaction where minute quantities of reactants are present
Acid-base equilibria
At equilibrium water is
o
o
Kw
H 3O
OH
K w =
+
H 3 O
O H
K =
H3 O
pH=log 10
Kw
increases
Acidity constant
o
Kw
decreases