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V
R
So phase difference, =
6.
= radian
mv 2
R
2m(kE)
qB
mV 2
qB
q2
m
2
q2
=
= 1 MeV
m
4
(d) From circuit diagram
7.
45
20
>
1.414
A
480
(d)
V 2 V1
V2 V1
40.8
A rA/B
E = 30V
480 20
= 19.2 .
480 20
Total resistance R = 40.8 + 19.2 = 60
r1 r2
Resistance of ammeter =
r1 r2
V1
V2
A
A
5.
V
R
30
= 0.5A
40.8 19.2
(a) From question,
Rise in temperature t = 40C
8.
=?
0
2
Coefficient of volume expansion
= 5 104K1
= 0 (1 t)
2
KEmax = 2.48 2.28 = 0.2 ev
=
0
9.
(d)
min =
2 9 10 31 0.2 1.6 10 19
25
109
9
= 2.80 109 nm
min =
Adiabatic
Isothermal
h
2m KE max
20
10 34
3
h
=
p
Isobaric
2.8 109 m
10.
Zc =
1
C
R2
Req =
l
1A
l
leq
l
2A
eq A eq
Xc = 1/c
R
2l
l
=
A
eq A
eq =
V
=
Zc
Vc = iXc =
Vc =
11.
1
C
R2
1
C
R2
i=
f=
1
C
1 2
V 15
=
r 0.45
i+
100
3
=0
100
= 6.66 kgm2s2
45
(a) Here, original frequency of sound, f0 = 100 Hz
Speed of source Vs = 19.4 cos 60 = 9.7
= (I) ( ) = 3
KEmax =
100
100
+ ( ) (15)
=
3
45
Average torque transmitted by brakes to the wheel
(RC )2 1
hc
1 2
0=
KEmax =
AC Source
Current i =
14.
19.4
6.6 10
34
5 10
3 108
7
60
2.82
O
19.4 cos 60 = 9.7
3
From Doppler's formula
16.
(c)
V V0
V Vs
f1 = f0
1 2
I
2
Work is minimum when I is minimum.
I is minimum about the centre of mass
So, (m1) (x) = (m2) (L x)
or, m1x = m2L m2x
K.E. =
V 0
V ( 9.7)
f1 = 100
f1 = 100
9.7
V
V 1
m 2L
x= m m
1
2
17.
9.7
= 103Hz
330
Apparent frequency f1 = 103 Hz
1
f1 = 100
(a)
V1 =
V
;
3
V2 = ?
V1=V/3
M1
u2=0
u1=V
M1
M2
M2
KEf
KEi
V2=?
Vf
or V
i
2
and u1
V2 =
V
3
or, V2
V2
V
3
V22
u1
V and V1
18.
= V22
8 2
V
9
V2 =
2 2
V
3
2gh
2gh
V0
(d) In an explosion a body breaks up into two pieces of
unequal masses both part will have numerically equal
momentum and lighter part will have more velocity.
U Th + He
P2
P2
KETh =
, KEHe =
2m Th
2m He
V
3
19.
V02
1
2
= 20ms1
V12 V22
2
1
2
= 90
V2
= V22
9
or V22 =
or,
1
mVf2
2
1
mVi2
2
2gh
1
1
1
1
M1u12
M 2 u 22
M1V12
M 2 V22
2
2
2
2
...(iii)
Putting M1 = M2 and u2 = 0 in equation (i), (ii) and (iii)
we get
+ =
1
2
4
20.
1
a(4)2
2
a = gsin
k=
T=
21.
2
T
25. (c)
1
(given)
25
A max
A min
22.
A 22
A1 A 2
A1 A 2
2
A max
Imax
Imin
A 2min
5
1
A1
25
or A
2
1
5 1
5 1
3
2
6
4
electric field is E =
V
i
x
V
j
y
3
2
22
32
(a)
dV
dx
V
k
z
Here
q = CV
24.
(a)
q
2dK
V (3.5 0.5)
=
A
R
100
[ Barrier potential VB = 0.5V]
3
= 30mA
100
27. (c) The gravitational force on the satellite will be aiming
towards the centre of the earth so acceleration of the
satellite will also be aiming towards the centre of the
earth.
28. (d) From Newton's second law for rotational motion,
dL
, if L = constant then
dt
So, = r F = 0
2i 6j 12k
q
2dK
K=
C2 V 2
F=
2dK 0
1 2
at
2
1
= 0.577 0.6
3
= 1
30. (d)
V
potential gradient
L
V iR
E0r l
=
=
L
L
r r1 L
S = ut +
=0
0
( i 3j 6k)
So, E = Kl =
s = tan 30 =
n 22
(6i 5j 2k)
n12
5
27
Solving we get
23.
Re
9
4
E (1,1,0)
Re
E =
Re
A12
s = 4m and t = 4s given]
0.9
= 0.5
3
As we know,
I1
I2
A2
a=
I1
25
I2 = 1
I
1
= 0.5 [
2
k(g) cos
4=
E 0 rl
(r r1 )L
RT
m
= 1.6 =
952 =
6
10
3.3 273
4 10
8
5
CP
Also, = C
V
So, CP =
8
5
8 5
= 8JK1mol1 [CV = 5.0 JK1 given]
5
35.
(a)
36.
mv12 2mv 22
or, V12
r
(r / 2)
So, V1 = 2V2 i.e., n = 2
V0 =
MA
So, M
B
37.
W1
Y1
RT
3
2
3
4
W l
.
A l
W2
Y2
[
R2
.
R 2 (R h)
GM
l, A, l
Y1
Steel
A, l, l
Y2
BMB
and PB
RT
From question,
PA
A MA 2 MA
PB
MB
B MB
4V22
32. (d) Given: Height of the satellite from the earth's surface h
= 0.25 106m
Radius of the earth R = 6.38 106m
Acceleration due to gravity g = 9.8 m/s2
Orbital velocity, V0 = ?
GM
(R h)
A MA
PA =
6.63 106
Brass
GM
= 7.76 km/s
R2
75 cm
W1
W2
38.
Y1
Y2
[Ysteel/Ybrass = 2 given]
; V0 = ?
V0
Using formula, AV = V
i
V0 = AV Vi
5=
T2
T1 T2
273 20
T1 (273 20)
253
T1 253
39.
4
3
T1 =
d=f0+fe
6
Magnification by eye piece
f
m=
f u
I
L
fe
fe
[ (f 0 f e )]
fe
I
or,
f0
L
f0
Magnification, M = f
e
40.
t
t
A.B = 0 = cos t.cos 2 + sin t.sin 2
= cos
fe
f0
t
2
t
2
cos
t
t=
2 2
45. (a) Here, number of turns of coil, N = 50
Current through the coil I = 2A
Area A = l b = 0.12 0.1m2
So,
L
I
ghAV
F
and P
gh
A
= 13.6 103 10 150 103 0.5 103/60
102
= 1.70 watt
60
(d) Applying dimensional method :
VC = x yrz
[M0LT1] = [ML1T1]x [ML3T0]y [M0LT0]z
Equating powers both sides
x + y = 0; x = 1 x = 1
1 + y = 0 y = 1
x 3y + z = 1
1 3(1) + z = 1
1 + 3 + z = 1
z = 1
(d) Photoelectric equations
hc
hc
Ek1max =
...(i)and Ek2max =
/2
=
41.
42.
EK2max =
2hc
30
60
M
Torque required to keep the coil in stable equilibrium.
M B = MB sin 60
= Ni AB sin 60
= 12 3 10
...(ii)
= 0.20784 Nm
CHEMISTRY
46. (d)
hc
...(iii)
CHCl3 + NaOH
: CCl3 + H 2 O
: CCl3
: CCl2 + Cl
3
2
= 5 0 2 0 .1 2 0 . 1 0. 2
2hc
Cl
C
Cl
43.
R2V = n r2(v)
44.
v=
R V
n r
VR
+ :C
hc
(work function) =
2
(a) Inflow rate of volume of the liquid = Outflow rate of
volume of the liquid
Cl
Cl + H O
2
OH
O
C=O
H
OH
2HCl
nr 2
A = cos ti sin tj
t
t
B = cos i sin j
2
2
For two vectors A and B to be orthogonal A.B = 0
K=
2NO(g)
[NO]2
[N 2 ][O 2 ]
1
1
N 2 + O2
2
2
NO
CCl2
H
7
K =
48. (d)
[NO]
[N 2 ]1 2 [O 2 ]1 2
53.
= K1 2
Bond order
MgCO3
MgO + CO 2
1
(10 5) 2.5
2
= 9.52 g of MgO
Since 8.0 g of MgO is formed
1
(10 6)
2
1
(10 7) 1.5
2
Purity of sample =
8
100 = 84.0%
9.52
2
Bond order for O2
n
V(kg)
1
(10 8) 1.0
2
54.
O2
O2
O 2
2
O
||
O C CH3
..
W
1
51. (d) Molality =
M V(kg)
=
1.00 m =
n
i.e., 1 mole in 1 kg of water
V(kg)
Moles of 1 kg H2O
=
55.
1000g
= 55.55 mole
18g / mol
56.
Moles of solute = 1
Mole fraction
=
57.
nsolute
1
=
n solute + n water (1 + 55.55)
= 0.01768 = 0.0177
52. (d) Rate constant k = 0.6 10-3 mole per second.
mole per second shows zero order reaction)
For a zero order reaction
[A] = [A]0 kt
and[A0] [A] = [B] = kt
= 0.6 103 20 60 = 0.72 M
(un it
58.
8
59.
(c) 1-chloro-1-methylcyclohexane.
O
O
OH
+ CH3 C Cl
CH3
Cl
O C CH3
Acetylation Reaction
NH2
Cl
+
CH2
CH3
Cl
CH3
+ H Cl
+ Cl
NaOH
O
Schotten-Baumen Reaction
NH C
CH3
CH3
H
+ Cl
+ H Cl
60.
CH3 C
(b)
O
H
CH3
CH3
Cl
CH3
CH3
2,3-Dimethyl-2-butene
(CH3)2CH CH CH = CH2 contain 7 carbon atoms
|
CH3
CH3
ZnCl 2
R O ZnCl 2
|
CH3
CH3 C CH = CH2 + H
CH3 C CH CH3
CH3
(R
H
(I)
CH3 CH 2 )
CH3
Rearrangement
CH3
CH3
C=C
CH3
CH3
CH3
(Stable 3 carbocation)
CH3
(Friedel Crafts Reaction)
CH3Cl
C=O
O
O
+
R
Base
CH3
O
OH + HO
CH3 C CH3
Perkin Reaction
Ar
[HOZnCl 2 ]
H
(I)
CH3
(d)
AlCl3
R O ZnCl2
|
CH3 C C
CH3
2, 3 - dimethyl 2 - butene
61.
62. (c)
CH3 C CH3
|
H2O
CH3
9
70.
from (CH3 ) 2 C OH
(a)
Ni2
is oxidised by KMnO 4 .
dsp hybridization
71.
( 6)
16.9
50 = 8.45 g of Ag NO
3
100
SO2
4 in which sulphur is in highest oxidation state
cannot be oxidised.
Fe 2 SO32
Fe 2
(+4)
2
SO3
(+6)
nmole =
Fe 2
NaCl =
5.8
50
100
nNaCl =
2.9g
= 0.0495 moles
(23 35.5) g/ mol
Fe(NO 2 )2
Fe
(+3)
+ 2NO2
2NO3 + 2e
8.45g
(107.8 14 16 3) g / mol
8.45 g
= 0.0497 moles
169.8g / mol
SO4 + 2e
In FeC2 O4
4p
4s
3d
AgNO3 + NaCl
1 mole
1 mole
0.049 mole 0.049 mole
Nitrogen can be
oxidised to (+V)
state
n=
(+5)
68. (d) XeF4, XeO4
w
M
2.9 g
AgCl + Na + Cl
1 mole
0.049 mole of AgCl
72.
73.
(b)
O
F
Xe
Xe
F
F
(Square planar)
O
[Tetrahedral]
OH
+H
OH
H
H
O
H
NH
69. (a)
(Caprolactum)
H
N
Nylon6
74.
75.
10
76.
77.
78.
0.09
= 0.045 = 4.5 102
2
79.
r=
3a
4
4 3
r
3
Packing Fraction (P.F.) =
(4r / 3)3
2
80.
Cl
N
N
N
Co
N
N
Cl
trans
(I)
N
and
N
Co
Cl
N
Cl
cis
(II)
81.
CH3
Nu
NH2
R3
R2
CH3 CH CH 3 , CH 3 N CH 3
|
Nu
3
8
= 0.68
2C6 H6(g)
9O2(g)
V2O5
410 C
Co
N
CHC
Cl
(d) (n + l) rule can be used. Titanium is a multi electron system
(n + l) 3s < 3p <
4s
< 3d
(3 + 0) (3 + 1)
(4 + 0)
(3 + 2)
||
||
||
||
3
4
4
5
If (n + l) values are same, than value of "n" has to be
considered.
O + 4CO2(g) + 4H2O(g)
CHC
O
O
||
87. (b)
R C R
Maleic anhydride
NH 2 NH 2
11
NH2
N
OH
1
H2O
Elimination
RCR
RCR
NHNH2
(Addition)
While in all other case no elimination take place.
88. (d) Because arylhalides does not undergoes nucleophilic
substitution easily.
H
89. (c)
COOH
CH3
OH
Four different Substituent, only one chiral centre. Hence
only enantiomers arc possible.
+
A
90. (c)
B
+
A
A+
A
+
A
+
+ Frenkel defect is
dislocation effect
BIOLOGY
91. (a) Mendel did not use pod length for his experiment.
92. (c) Chargaff's rule is not applicable to RNA
93. (d) Two sperms and a vegetative cell are produced by male
gametophyte in angiosperms.
94. (a) Ribosomes are not membrance-bound cell organelle.
95. (b) The chitinous exoskeleton of arthropods is formed by
the polymerisation of N-acetyl glucosamine.
96. (a) Superior ovary is found in china rose, mustard brinjal,
potato, onion and tulip. Guava and cucumber have
inferior ovary.
97. (a) The function of the gap junction is to facilitate
communication between adjoining cells by connecting
the cytoplasm for rapid transfer of ions, small molecules
and some large molecules.
98. (b) Colostrum contains high levels of lgA, which gives
passive immunity to foetus.
99. (d) Fovea centralis is the most sensitive part of retina. It
has high density of cones, but rods are not found.
100. (b) The second sound heard by doctors using stethoscope
occurs when semilunar valves close down after the
blood flows into vesels from ventricles.
101. (a) Coconut water is the free nuclear endosperm which is
used by us.
102. (d) Restriction enzymes are used to cut DNA at specific
locations.
103. (d) Nuclear envelope is not found in a prokaryotic cell.
12
123. (a)
124. (c)
125. (c)
126. (b)
127. (c)
128. (c)
129. (b)
130. (a)
131. (c)
132. (b)
133. (c)
134. (d)
135. (d)
136. (a)
144. (c) Detritivores are the organisms which feed on dead plants
and animal residues.
145. (b) Babesiosis is malaria like disease caused by protozoonBabesia. In this desease haemoglobinuric fever takes
place.
146. (d) Competition occurs for light, food and space among
organisms in which all partners are adversely affected
in an ecosystom.
147. (b) Genome > chromosomes > gene > nucleotide.
148. (c) XX
XcY
Normal women Colourblind man
Xc
x XX c
x XX c
OO
XY
Normal women
Normal man
vitamin-A.
Outbreeding is useful in the problem of inbreeding
depression.
In codominance both alleles are independently
expressed in the heterozygote.
ADH (Antidiuretic hormone) and oxytocin are produced
by hypothalamus and stored in posterior pituitary.
Biomagnification means an increase in concentration of
toxins through the trophic levels of a food chain.
Industrial melanism occured in England due to industrial
revolution. It caused black coating of moths for the
adaptation in the present environment.
OO
x
xc
149. (c)
150. (d)
151. (d)
152. (a)
2102
, so premolars
2102
Y
XY
XY
153. (d)
154. (c)
155. (c)
156. (b)
157. (d)
158. (a)
X
Y
XX XY
XX X c Y
13
159. (a) GIFT (Gamete Intra Fallopian Transfer) is a technique
helping to have a child.
160. (a) In poliomyelitis, anterior horn cells of spinal cord are
destructed which causes loss of motor activities of limbs.
161. (d) Leghemoglobin prevents oxygen poisoning which
causes inactivation of nitrogenase.
162. (a) Biotic community is an association of individuals of
different species living in the same habitat and showing
functional interactions.
163. (a) In the disease, emphysema, alveolar surface area is
reduced due to destruction of alveolar walls.
164. (c) RNA and protein synthesis occur in Balbiani rings.
165. (a) (a)
(iii), (b)
(iv), (c)
(i), (d)
(ii)
166. (c) Lysosomes, golgi apparatus and mitochondria are the
cell organelles which have membranes.
167. (d) Avena coleoptile curvature is used for the bioassay of
auxin.
168. (c) Zona pellucida is formed as a new membrane by
secondary oocyte around itself.
169. (a) Satellite DNA displays high degree of polymorphism in
population and also the same degree of polymorphism
in an individual, which is inherited from parents to
children (offsprings).
170. (b) Mycoplasma lacks cell wall.