Safety Data Sheet according to (EC) No 1907/2006

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sds no. : 115282
V010.1

BONDERITE L-AD P known as MULTAN P

Revision: 20.11.2012
printing date: 12.05.2014

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
BONDERITE L-AD P known as MULTAN P
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use:
Water Soluble Cooling Lubricants for Metal Working
ua-productsafety.de@henkel.com

1.4. Emergency telephone number

The Henkel information service also provides an around-the-clock telephone service on phone no.+49-(0)211-797-3350 for
exceptional cases.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification (CLP):
No data available.
Classification (DPD):
N - Dangerous for the
environment
R50 Very toxic to aquatic organisms.
Xi - Irritant
R36/38 Irritating to eyes and skin.
2.2. Label elements
Label elements (CLP):
No data available.

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Label elements (DPD):

N - Dangerous for the
environment

Xi - Irritant

Risk phrases:
R50 Very toxic to aquatic organisms.
R36/38 Irritating to eyes and skin.
Safety phrases:
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37 Wear suitable gloves.
2.3. Other hazards
None if used properly.

SECTION 3: Composition/information on ingredients

Declaration of the ingredients according to CLP (EC) No 1272/2008:
Hazardous components
CAS-No.
3-Iodo-2-propynyl butylcarbamate
55406-53-6

EC Number
REACH-Reg No.
259-627-5

content
5- 10 %

Classification
Acute toxicity 4; Oral
H302
Serious eye damage/eye irritation 1
H318
Acute toxicity 4; Inhalation
H332
Acute hazards to the aquatic environment 1
H400

For full text of the H - statements and other abbreviations see section 16 "Other information".
Substances without classification may have community workplace exposure limits available.
Declaration of ingredients according to DPD (EC) No 1999/45:
Hazardous components
CAS-No.
3-Iodo-2-propynyl butylcarbamate
55406-53-6

EC Number
REACH-Reg No.
259-627-5

content
5 - 10 %

Classification
Xn - Harmful; R20/22
Xi - Irritant; R41
N - Dangerous for the environment; R50

For full text of the R-Phrases indicated by codes see section 16 'Other Information'.
Substances without classification may have community workplace exposure limits available.

SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation:
Move to fresh air.
In case of adverse health effects seek medical advice.

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Skin contact:
Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing.
In case of adverse health effects seek medical advice.
Eye contact:
Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If pains remains (intensive smarting,
sensivity to light, visual disturbance) continue flushing and contact/seek doctor or hospital.
Ingestion:
Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor.
4.2. Most important symptoms and effects, both acute and delayed
EYE: Irritation, conjunctivitis.
SKIN: Redness, inflammation.

4.3. Indication of any immediate medical attention and special treatment needed
See section: Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media:
Carbon dioxide, foam, powder
Fine water spray
Extinguishing media which must not be used for safety reasons:
Water jet (solvent-containing product).
5.2. Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in fires.
5.3. Advice for firefighters
Wear self-contained breathing apparatus.
Additional information:
Cool endangered containers with water spray jet.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes.
6.2. Environmental precautions
Do not empty into drains / surface water / ground water.
6.3. Methods and material for containment and cleaning up
Remove with liquid-absorbing material (sand, peat, sawdust).
Dispose of contaminated material as waste according to Chapter 13.
6.4. Reference to other sections
See advice in chapter 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Avoid skin and eye contact.
Ensure that workrooms are adequately ventilated.
Avoid spraying/aerosol generation.
See advice in chapter 8
Take measures to prevent the build-up of electrostatic charges.

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Hygiene measures:
Wash hands before work breaks and after finishing work.
Do not eat, drink or smoke while working.
7.2. Conditions for safe storage, including any incompatibilities
Store in sealed original container.
Store frost-free.
Store in sealed original container.
Do not store together with oxidants.
7.3. Specific end use(s)
Water Soluble Cooling Lubricants for Metal Working

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational Exposure Limits
Valid for
Germany
Ingredient
Oxydipropanol
25265-71-8

ppm

mg/m3
67

Oxydipropanol
25265-71-8

Type
AGW:

Short Term Exposure

Classification:

Category
8
If the AGW and BGW values
are complied with, there
should be no risk of
reproductive damage (see
Number 2.7).
Category II: substances with a
resorptive effect.

Remarks
TRGS 900

TRGS 900

Biological Exposure Indices:

None
8.2. Exposure controls:
Engineering controls:
Ensure good ventilation/suction at the workplace.
Respiratory protection:
In case of aerosol formation, we recommend wearing of appropriate respiratory protection equipment with ABEK P2 filter.
This recommendation should be matched to local conditions.
Hand protection:
Chemical-resistant protective gloves (EN 374).
Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30
minutes permeation time as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation
time as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
This information is based on literature references and on information provided by glove manufacturers, or is derived by
analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be
considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing
factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced.

Eye protection:
Protective goggles
Skin protection:
Suitable protective clothing

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SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
liquid
clear
Amber
Odor
characteristic

pH
Initial boiling point
Flash point

not applicable
No data available / Not applicable
> 100 C (> 212 F); Flash Point, Pensky-Martens
No flash point up to 100 C
No data available / Not applicable
No data available / Not applicable
1,025 - 1,065 g/cm3

Decomposition temperature
Vapour pressure
Density
(20 C (68 F))
Bulk density
Viscosity
Viscosity (kinematic)
Explosive properties
Solubility (qualitative)
(Solvent: Water)
Solidification temperature
Melting point
Flammability
Auto-ignition temperature
Explosive limits
Partition coefficient: n-octanol/water
Evaporation rate
Vapor density
Oxidising properties

No data available / Not applicable

No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
of high solubility
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable

9.2. Other information

No data available / Not applicable

SECTION 10: Stability and reactivity

10.1. Reactivity
Reaction with oxidants.
10.2. Chemical stability
Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
See section reactivity
10.4. Conditions to avoid
No decomposition if used according to specifications.
10.5. Incompatible materials
None if used properly.
10.6. Hazardous decomposition products
None if used for intended purpose.
In case of fire toxic gases can be released.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
General toxicological information:
The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant
available health/ecological information for the substances listed under Section 3 is provided in the following.

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Skin irritation:
Irritating to the skin.
OECD 404
Eye irritation:
Irritating to eyes.
OECD 405
Sensitizing:
Sensibilization test: no findings (not sensitizing).
OECD 406

SECTION 12: Ecological information

General ecological information:
The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant
available health/ecological information for the substances listed under Section 3 is provided in the following.
Do not empty into drains / surface water / ground water.
Ecotoxicity:
Very toxic to aquatic organisms.
Persistence and degradability:
Ultimate biodegradation:
The product contains both "readily biodegradable" components as well as compounds which do not fulfil the OECD's criteria
for "ready biodegradability".

12.1. Toxicity
Exposure
time

Species

Method

0,067 mg/l

Acute
Toxicity
Study
Fish

96 h

Oncorhynchus mykiss

OECD Guideline
203 (Fish, Acute
Toxicity Test)

NOEC
EC50

0,0084 mg/l
0,65 mg/l

Fish
Daphnia

35 d
48 h

Pimephales promelas
Daphnia magna

EC50

0,053 mg/l

Algae

72 h

Hazardous components
CAS-No.

Value
type

Value

3-Iodo-2-propynyl
butylcarbamate
55406-53-6

LC50

3-Iodo-2-propynyl
butylcarbamate
55406-53-6

3-Iodo-2-propynyl
butylcarbamate
55406-53-6

OECD Guideline
202 (Daphnia sp.
Acute
Immobilisation
Test)
Scenedesmus subspicatus (new OECD Guideline
name: Desmodesmus
201 (Alga, Growth
subspicatus)
Inhibition Test)

12.2. Persistence and degradability

Hazardous components
CAS-No.
3-Iodo-2-propynyl
butylcarbamate
55406-53-6

Result

Route of
application

Degradability

Method

25 %

OECD Guideline 301 F (Ready

Biodegradability: Manometric
Respirometry Test)

12.3. Bioaccumulative potential / 12.4. Mobility in soil

Hazardous components
CAS-No.
3-Iodo-2-propynyl
butylcarbamate
55406-53-6
3-Iodo-2-propynyl
butylcarbamate
55406-53-6

LogKow Bioconcentration Exposure

factor (BCF)
time
3,3 - 4,5

2,81

Species
Carassius sp.

Temperature

Method

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SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product disposal:
In consultation with the responsible local authority, must be subjected to special treatment.
Recommended cleaning agents
Water, if necessary with added cleaning agent.
Waste code
120108
The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes
for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We
will be happy to advise you.

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SECTION 14: Transport information

14.1.

UN number
ADR
RID
ADNR
IMDG
IATA

14.2.

UN proper shipping name

ADR
RID
ADNR
IMDG
IATA

14.3.

RID
ADNR
IMDG
IATA

not applicable
not applicable
not applicable
Marine pollutant
not applicable

Special precautions for user

ADR
RID
ADNR
IMDG
IATA

14.7.

III
III
III
III
III

Environmental hazards
ADR
RID
ADNR
IMDG
IATA

14.6.

9
9
9
9
9
9
9
9
9
9

Packaging group
ADR
RID
ADNR
IMDG
IATA

14.5.

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iodine

carbamate)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iodine
carbamate)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iodine
carbamate)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iodine
carbamate)
Environmentally hazardous substance, liquid, n.o.s. (Iodine carbamate)

Transport hazard class(es)

ADR

14.4.

3082
3082
3082
3082
3082

not applicable
Tunnelcode: (E)
not applicable
not applicable
not applicable
not applicable

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
not applicable

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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
VOC content
0%
(1999/13/EC)

15.2. Chemical safety assessment

A chemical safety assessment has not been carried out.
National regulations/information (Germany):

WGK:

WGK = 3, highly water endangering product. Classification according to the

mixture rules in German VwVwS regulation annex 4 from 27 July 2005.

Storage class according to TRGS 510:

10

SECTION 16: Other information

The labelling of the product is indicated in Section 2. The full text
of all abbreviations indicated by codes in this safety data sheet are as follows:
R20/22 Harmful by inhalation and if swallowed.
R41 Risk of serious damage to eyes.
R50 Very toxic to aquatic organisms.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H400 Very toxic to aquatic life.

Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any
particular properties.