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l ~ l i n n s l a ~ r - l ~ ~ ~ ~ ~ f i e l ~ lOil
- ~ ICi' Oa lI I~I IvI ~~ I~I yT , Fello\\-s l ' ; ~ l i f .
Honolulu C t ~ ~ ~ a v l i t l n tVil
e d ~ n r ~ , o r ; c t i v i lT. n f t , ~ i l i f .
General
There a r e now about 900 producing oil wells in
Michigan, of which number about 700 a r e producing
from limestone formations considered favorable for the
stimulation of production by the use of acid. During
the past year and one-half over 450 wells have been
given more than 1,000 acid treatments, using approximately 1,000,000 gal. of hydrochloric acid. The net
result of these treatments has been the stimulation and
the conservation of oil production t h a t might have
otherwise been delayed or never produced because of
the economics of operating small wells.
While acid treatment of wells has been in progress,
laboratory research and field, tests have been continued
with a view of obtaining better results by the use of
a n acid suited to the formation to be treated, the determination of the am'ounts of acid to .use, the time for
initial and successive treatments, and the analysis of
the increase o r early recovery in oil production.
TABLE 2
Depth
From
(Feet)
To
(Feet)
3,629
3,635
3,644
3,652
3,635
3,639
3,649.5
3,654
,.
Well
From
(Feet)
'
,
To
(Feet)
, --
Acid B
(Per
Cent)
sample of the producing formation to be treated, particularly if the treatment is to be made on a well in a
new area where the pay for~nationmay be dolomitic
68.4
83.8
97.5
73.7
87.0
85.7
97.6
60.6
TABLE 3
Solubility In :
-4c1d A
(Per
Cent)
Acid "A"
( P e r Cent)
TABLE 1
Depth
Solubility I n :
A
B
C
D
E
F
(Hours)
................. 24
................. 96
.................. 96
................. 96
................. 24
................. 24
'
Solubility
( P e r Cent)
3.9
27.4
31.0
23.6
61.7
32.4
Technique
The technique of treating wells with acid3 requires
the use of equipment such a s illustrated by Fig. 1, and
FIG. 1
treatment, while a n equal strength of uninhibited or
raw acid dissolves a s much a s 0.286 lb. of steel per
square foot per day. Hydrochloric acid has no reaction
with oil or natural gas.
Acids now can be furnished having various reaction
speeds and intensities, and research work on the part
of the chemical company has developed a blend of acid
with which the reaction, when introduced into the formation, can be delayed for the most part until pressure
is relieved in the well bore. This acid is as yet too costly
for general use. Another interesting project being
introduced is the development of a non'-aqueous base
acid which, with the limestone, forms a resultant solu-
Effect of Successive Acid Treatments in Well " B "Producing Formation, Dundee Limestone.
FIG. 3
While Fig.4, for well " C," shows a high accunlulated
return a s a result of acid treatment immediately following the completion of the well, it is probable that even
better results might have been obtained if the first
treatment ha'd been delayed 10 days, giving the well
a chance to clean itself and establish movement of oil
Effect of Successive Acid Treatments i n Well " C "Producing Formation, Dundee Limestone.
FIG. 4
towards the hole. I t may be noted that the second treatment of 12 bbl. of acid did not materially increase the
accumulated production, and i t is believed t h a t a second
treatment of 24 bbl. to 36 bbl. of acid about 90 days
after the first treatment would have netted higher returns. The fourth treatment, a s shown by Fig. 4, was
profitable.
Conclusions
'
'
.so
at4
7w
720
7.0
7m
.ca
820
U O
rm
szo
FIG. 5
prospect of only 1,216 bbl. f o r a nine months' period,
was increased by t h e use of a 12-bbl. and a 48-bbl.
acid treatment to produce about 8,700 bbl. more than
2 350
Z
300
?j
2,o
A
.
0 I00
P0
B. A . C u ~ ~ n i u g h n m"Aci~l
.
Trentlnellt of Linie F o r n i a t i o ~ ~ s . "
preselited a t s p r i n g ~lleetirlg. Auler. , l ' c t . Illst.. Div. o f . Prod.,
I-Iouston. T e s . , April 7-8, 1933.
R. B. Ka\vcolnbe, "Acid Treatlllent f o r Incrensilig Oil F r o d~lctiou." Oil I l ' e c P l ~ ,69, no. 11, 1:) I 1'J:jH ) .
" S . A. Best. " T r e a t i n g Li111er;toneFormation," etc.. Oil G n s J.,
'30
,.,
FIG. 6
could be reasonably estimated by the normal decline
curve. Although this well had a n initial of 420 bhl. per
day, t h e production might have declined in three more
years to a point where i t would not be economical to
operate-necessitating
t h e abandonment of the well
without the recovery of oil a s stimulated by acid
treatment.
Another example illustrating t h e effect of acid treatment on settled production is shown.by Fig. 6 f o r well
" E," which had a n initial production of about 615 bbl.
per day, and was producing about 35 bbl. per day
almost three years after completion. A 12-bbl. and a
24-bbl. acid treatment show a n increase in accumulated
production of 12,460 bbl. over a period of eight months,
and i t is estimated t h a t t h e well would have produced
DISCUSSION
Don Knowlton (Phillips Petroleuln Corporation) :
W h a t a r e t h e effects on gas-oil ratios of these various
treatments with acids?
H. J. Lowe (The P u r e Oil Company) : Initially, there
is a decrease in gas-oil ratio; but within a reasonable
time a f t e r t h e acid treatment, i t gradually works u p to
about the same a s i t was before.
Mr. Knowlton: Do you think t h a t in most instances
i t will actually increase the ultimate recovery to a n y
g r e a t extent?
Mr. Lowe: T h a t is a n open question. I think i t can
be said t h a t where we open up new lenses, we undoubtedly increase t h e oil recovery. A s I see t h e thing, the
only advantage t h a t we a r e sure of at the present time
is t h a t we get w h a t would be called a normal ultinlate
recovery in a shorter period of time.
Mr. Knowlton: Does t h a t depend upon t h e type of
reservoir, on the type of sedimentation, whether i t is
more or less continuous, o r in streaks?
'
Mr. Lowe: The limestone is very spotty. For instance, we have drilled wells with widely varying initials
practically offsetting each other, and the effects will undoubtedly vary with the reservoir conditions.
Mr. Pierce: We have made microscopic studies in
the laboratory on cores from a certain lime formation,
before and after treating the core with acid, which
demonstrated that some sections of the core were opened
up, disclosing new oil sources that were not apparent
before treating with acid. Not only were the original
openings increased in size, but new openings were made.
Member: I n which case you would increase the
amount of oil available to production from the well.
Chairman Robinson: Do you have a n average figure
of what i t costs per barrel for treating?
Mr. Lowe: ~ s s u m i nthat
~ the treatment would cost
$200 or $300, and resulted in 12,000 bbl. recovery, a s
indicated on the production curves shown, the resultant
cost per barrel would be but a fraction of a cent for the
use of the acid.
Chairman Robinson: I wondered whether i t was average, or whether those were usual conditions.
Mr. Lowe: We have had very phenomenal results in
acid-treating some wells in Michigan. The production
graphs submitted with this paper a r e from representative wells where average results have been obtained.
Norman E. Maswell (Crew-Levick Company) : I s
-this limestone, or has i t a porosity?
Mr. Lowe: I t is filled with small holes which -vary
from the size of a pinhead to the size of a pea or larger.
As f a r a s I know, the drilling has not disclosed any
large caverns.
Mr. Maxwell : Can the limestone be said to be porous?
Is it similar to sandstone?
Mr. Lowe: Not a t all. Some is very tight. The limestone is porous, but not in the sense that sand is porous.
The pores a r e much larger. I t could be compared to a
sponge in its general characteristic.
C. E. Burt (Baker Oil Tools, Inc.) : I n the old wells,
where the cores may have been lost, how a r e the formations sampled in order to make the analysis?
Mr. Lowe: In the first place, there a r e no old wells
in this pool; i t was developed initially some seven or
eight years ago. There, hasn't been a great deal of
coring done.
The Dundee limestone is more or less blanket formation. Cores have been taken in selected wells which
seem-to give the desired information.
Mr. Burt: I s pressure applied from the casinghead,
or i s pressure used a t all?
Mr. Lowe: The well is filled with oil, balancing the
column inside and outside the tubing. After installing
suitable casinghead connections, the acid is introduced
in the tubing. A volume of oil equal to the volume of
acid is permitted to escape through the casinghead,
which is then closed. A volume of oil equivalent to the
volume of the acid is then introduced into the tubing
under pressure, which forces the acid back into the formation to be treated. Of course, this is a n ,ideal situation subject to change t o meet individual conditions.
The well is then shut in f o r a period necessary t o complete chemical reactions, which is from a few hours t o
a s much a s three days.
.
,
,
ACIDTREATMENT
OF
In the laboratory tests the acid treatment opened up
a core from this well so that, using the same pressure,
i t was four times more permeable after the acid treatment than before.
George Wittmer, Jr. (American Natural Gas Cornpany) : I understand that practically all of the Dundee
wells in Michigan a r e wet. I s i t your thought or experience that acid treatment is practical and recommended for wells that a r e producing a s much a s 25
per cent water?
J. Bennett (The Pure Oil Company) : I have seen
acid put in wells t h a t were producing a small amount
of water, and they produced a greater amount of water
afterwards.
Mr. Lowe: I would be inclined t o think where wells
were making a considerable amount of water, you might
have to use more concentrated acid to take care of possible dilution a s a result of the presence pf the water;
but I think the results would be just a s satisfactory.
The usual procedure is to plug off the water before acid
treatment.