Aieee Model Test Paper 2010 Solution

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SOLUTIONS
MODEL TEST PAPER
AIEEE–2010
BOOKLET CODE (A)
Note: (i) The test is of 3 hours duration.

(ii) The test consists of 90 questions. The maximum marks are 432.
(iii) There are three parts in the question paper. The distribution of marks
subjectwise in each part is as under for each correct response.
Part A − Physics (144 marks) − Question No. 1 to 2 and 9 to 30 consists FOUR
(4) marks each and Question No. 3 to 8 consists EIGHT (8) marks each for each
correct response.
Part B − Chemistry (144 marks) − Question No. 31 to 39 and 46 to 60 consists
FOUR (4) marks each and Question No. 40 to 45 consists EIGHT (8) marks
each for each correct response.
Part C − Mathematics(144 marks) − Question No. 61 to 82 and 89 to 90 consists
FOUR (4) marks each and Question No. 83 to 88 consists EIGHT (8) marks
each for each correct response.
(iv) Candidates will be awarded marks as stated above for correct response of each
question. 1/4th marks will be deducted for indicating incorrect response of each
question. No deduction from the total score will be made if no response is indicated
for an
item in the answer sheet.
PHYSICS
PART − A
1. According to Bohr’s theory, the radius of the m th orbit of an atom of atomic

number Z is given by
0m2h 2 m2
rn =  (0.53 ) Å
Me 2 Z Z
According to the problem,
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m 2 (0.53) Å
(rn)Fm =  (0.53 Å)  n
100
For Z = 100, m = 5
25 1
 n =   (d)
100 4
is correct
2. The decay can be represented as

M220  M216 + 4
Here Atomic Number of parent metal = A = 220
Applying conservation of energy,
(A  4)
(K.E.) = Q
A
216
  5.5 = 5.4 MeV  (b) is correct
220
3. Heat lost by ice = Heat gained by water

Heat gained by water to come from 20°C to 0°C
= 5  1  20 = 100 kcal
Amount of heat lost by ice to come from  20°C to 0°C
= 2  20  0.5 = 20 kcal
This 20 kcal will be utilized to bring down the temperature of a part of water from
20°C to 0°C. The remaining amount of heat will come from melting of ice.
Amount of heat from melting of ice = 100  20 = 80 kcal
80 80
Mass of ice melted =   1 kg
Lf 80
Final mass of water = 5 + 1 = 6 kg  (b) is correct
4. Using Snell’s law,

n1sin r = n2 sin i
i.e. 1 sin 90° = glass sin i
 glass = 1 / sin i  (b) is correct

5. AB is isothermal process and BC is isobaric process. In process AC, pressure

decreases and temperature increases, which means volume increases more rapidly.
Keeping the above facts in mind (a) is the most suitable P-V diagram.
 (a) is correct
6. Electric lines of force emerge radially outwards from the charge and are not
present inside the conductor, as field is zero there.
 (b) is correct
7. Potential energy is
U =  MB cos  =  i AB cos 
 U1 =  i AB cos 180° = + i AB
U2 =  i AB cos 90° = 0
i AB
U3 =  i AB cos 135° =
2
i AB
and U4 =  i AB cos ( 45°) =
2
Thus 1 > 3 > 2 > 4  (b) is correct

8. To verify Ohm’s Law, voltmeter is connected in parallel and ammeter in series.
 (d) is correct
9. Increase in length of aluminium rod,
lA = l1 At
Increase in length of steel rod
lS = l2 St
According to given condition,
lA = lS
 l1At = l2St
l1 
or  A
l2 S
l1 A
or =
l1  l2  A  S
 (d) is correct
10. c

11. Power dissipated  Requivalent

(I) Req = R + R + R = 3R
(II) Req = 2R/3
(III) Req = R/3
(IV) Req = 3R/2
Thus increasing order of power dissipation is
I > IV > II > III  (a) is
correct
12. Since the gravitational field is conservative in nature, therefore work done is path
independent. Thus work done in the three cases will be equal
i.e. W1 = W 2 = W 3  (a) is correct
13. (a) is correct

14. When radius of the wire is changed, it will not change the ratio of the resistance of
two arms. Since the null deflection point depends upon the ratio of resistances and
not upon the resistance itself, hence null deflection point will not change and will
remain x.
 (d) is correct
15. Since, Mass = volume  density
and density of nucleus is constant
 V  Mass  (b) is correct
16. From the adjoining figure,

N
N = F sin 60° + 3g 60°
…….(i) F
F cos 60°
60°
and F cos 60° = N …….(ii) M =
From equations (i) and (ii), we get N
F sin 60° g
1
F cos 60° = (F sin 60  3 g)
2 3
1  
= F 3  3  10  
F
 5
2 3 
 2 
 4

F F
   5
2 4
F
  5
4
 F = 20 N  (b) is correct
17. The loop will expand due to radially outward magnetic force.  (d) is correct
18. For simple harmonic motion,

x = A cos t
On differentiating twice with respect to t, we get
d2x
  2 t
dt 2
Restoring force =  m2x
1
Work done =  P.E. = m 2 x 2
2
So when x = 0, P.E. = 0 (minimum)
1
and when x = A, P.E. = m 2 A 2 (maximum)
2
Thus I and III represent the correct graph.  (a) is correct
19. As angular velocity  is given constant, so angular momentum L will be constant

if moment of inertia I is constant, which is about an axis passing through centre.
 (a) is correct
20. For convex lens,
26 cm
1 1 1
 
f v u
1 1 1
  
30 v 
 v = 30 cm
This image acts as object for concave lens. Therefore the distance of object from
concave lens
= 30  26 = 4 cm

For concave lens,

1 1 1
   v  5 cm
v 4  20
v h2
Also, m = 
u h1
5
 h2 = 2  = 2.5 cm  (a) is
4
correct
21. The given situation can be represented as
v 22 m/s
Sound Source Thief Police

(165 Hz)
Let f1 = frequency of the police car heard by motorcyclist

and f2 = frequency of the siren heard by motorcyclist
300  v
 f1 =  176
330  22
330  v
and f2 =  165
330
 f1  f2 = 0
 v = 22 m/s  (b) is correct
22. Plane of motion must be perpendicular to at least one of the component of the
magnetic field, and since it is non-circular hence electric field must be there along
x-axis.
 
Only E  a î , B  ck̂  a î fulfill these two conditions.
 (b) is correct
23. Applying conservation of angular momentum about centre of the rod,

Jl
= Icm 
2
l   l 2 
 Mv = 2 M    
2   2  

vl l4
or  2 
2 4
v
    (b)
l
is correct

24. Since, L + e =
4

 0.1 + e =
4
3
 0.35 + e =
4
3 L
 0.35 + e = (4 + 4e)
4
 0.35 + e = 0.3 + 3e
(i) (ii)
 0.05 = 2e
 e = 0.025  (a) is
correct
25. Young’s modulus [Y] is

Stress F/A

Strain l / L
20  1
= 6 4
 2  1011 N/m 2  (c)
10  10
is correct
26. As rate of heat transfer,

dQ dT
  ms  eAT 4
dt dt
dQ
or   eAT 4
dt
 Emissive power, E  A
or Ex < Ey  Ax < Ay
Thus, Ex < Ey ; Ax < Ay is the correct relation.  (d) is correct
27. Here, v = l3 = (1.2  102 m)3

= 1.728  106 m3
Since l has two significant figures, hence v will also have two significant figures
i.e. v = 1.7  106 m3 .
 (a) is correct
28. (b ) i  E / R  (a) is correct
29. 2R  (c) is correct
30. i1  i0 e t / 3 RC
i2  i0 e  t / RC
2t
i1
 e 3 RC i.e. increasing with (t)  (b) is correct
i2
CHEMISTRY
PART − B
31. Number of atoms on 24 g of C (12)

24
=  6.023  1023 = 2  6.023  1023 atoms
12
Number of atoms in 56 g of Fe (56)
56
=  6.023  1023 = 6.023  1023 atoms
56
Number of atoms in 27 g of Al (27)
27
=  6.023  1023 = 6.023  1023 atoms
27
Number of atoms in 108 g of Ag (108)

108
=  6.023  1023 = 6.023  1023 atoms  (a) is
108
correct
32. Freezing point of a liquid substance is defined as the temperature at which the
vapour pressure of its liquid is equal to the vapour pressure of the corresponding
solid. The addition of non-volatile solute always lowers the freezing point. At the
freezing point, liquid and solid are in equilibrium. On cooling a solution of a non-
volatile solute below the freezing point of solution, some of liquid will separate as a
solid solvent.
 (a) is correct
33. Me2SiCl2 on hydrolysis will produce Me 2Si(OH)2 which ultimately, upon loss of
water, will form Me2Si=O. But silicon atom, because of its very large size in
comparison to oxygen, is unable to form -bond. Thus, the product of hydrolysis is
polymeric in nature.
Me Me
MeSiOSi
Me2SiCl2 + 2H2O  Me2Si(OH)2  O O
MeSiOSi
Me Me
 (c) is correct
34. When optically active acid reacts with racemic mixture of an alcohol, it forms two
types of isomeric esters. In each the configuration of the chiral centre of acid will
remain the same. So the mixture will be optically active.
 (a) is correct
35. SO2 and H2S are both reducing agents. H2S is obtained by the action of acid upon
sulphide while SO2 is obtained by the action of acid upon sulphite. The option (d) is
correct because SO2 is a colourless gas with irritating smell. However H 2S has
rotten egg like smell. The reactions involved are
SO 32  + H2SO4  SO2 + H2O + SO 24 
[A] [B]
3SO2 + K2Cr2O7 + H2SO4  K2SO4 + Cr2(SO4)3 + H2O
 (d) is correct
36. The given reaction can be completed as
H3C
(CH3)2NH
N NO2
DMF , 
H3C

F NO2
(A)
H3C
(i) NaNO2 + HCl / 0  5C
N NH2
(ii) H2 / Ni
H3C
(B)
 (a) is correct
37. When MnO2 is oxidised to K2MnO4 in alkaline medium, it acquires a stable

oxidation state, i.e., +6 and forms K2MnO4 which is purple green in colour
2MnO2 + 4KOH + O2  2K2MnO4 + 2H2O  (b) is correct
38. Number of electrons in NO 3 = 7 + 24 + 1 = 32
Number of electrons in CO 32  = 6 + 24 + 2 = 32
Both have same number of electrons. So they are isoelectronic.
Total number of valence electrons in NO 3 = 5 + 6  3 + 1 = 24
Total number of valence electrons in CO 32  = 4 + 6  3 + 2 = 24

24
Now, = 3 (Q1) + 0 (R1)
8
Thus type of hybridisation is sp2
Central atom in each being sp2 hybridised, thus they are isostructural also.
 (a) is correct
39. The desired reaction can be expressed as
CHO OHC
OH  / 100 o C
     
Intramolecular
Cannizzaro’s reaction
CHO OHC
COO HOH2C COOH HOH2C

H+ / H2O

CH2OH OOC CH2OH HOOC
 (d) is correct

40. The reaction of Ethyl exter with CH3MgBr is excess, can be expressed as
O :O OC2H5
CH3 + CH3MgBr
OC2H5 CH3 CH3
O XMgO CH3
CH3MgX
CH3 + C2H5O
CH3 CH3 CH3
HO CH3
HOH / H+
CH3 CH3  (a) is

correct
41. Heat of formation is the amount of heat evolved or absorbed when one mole of the
compound is formed from its elements. When all the substances are taken in their
standard state i.e. 298 K and 1 atm pressure, it is called standard heat of formation
( H of ) .
Thus in given thermochemical equations, (b) represents the standard heat of
formation of HF.
1 1
H2(g) + F2(g)  HF(g) ; H of , standard heat of formation of HF(g)
2 2
 (b) is correct
42. The dipole moment of a polar molecule depends on its geometry and shape. A
symmetrical molecule is non-polar even though it contains polar bonds. CH 4 being
symmetrical has zero resultant dipole moment. The bond dipole moment of C H
bond and that of CCl bond reinforce one-another.
Cl Cl Cl H
C Resultant C Resultant
Cl H Cl H

CHCl3 (1.03 D) CH2Cl2 (1.62 D)
Cl H
C Resultant
H H
CH3Cl (1.86 D)
In CHCl3, the resultant of CH and CCl dipoles opposes the resultant of two CCl
dipoles while in CH2Cl2, the resultant of CH dipoles adds to the resultant of two
CCl dipoles. In case of CH3Cl, the resultant of two CH dipoles adds to the
resultant of CH and CCl dipoles . Thus dipole moment of CH3Cl is highest among
the given compounds. The molecule (CCl 4) again becomes symmetrical and dipole
moment reduces to zero.
 (c) is correct
43. The acidic strength of the attached groups are in the following order.
NO2
COOH > OH > OH > HCCH
Two moles of amide ions will attract two moles of most acidic hydrogen and the
obtained product will be

OOC
OH
O2N
CH
 (a) is correct
O
44. The physical adsorption occurs readily at low temperature and increases with
decreasing temperature as the adsorption process is exothermic (Le-Chatelier’s
principle). Since the activation energy in the physical adsorption is more or less
zero, the rate of adsorption is not affected even at low temperature.
 (b) is correct
45. Acid hydrolysis of P and Q can be expressed as
OCOCH3 OH O
H2O / H+
CH3 CH3 CH3

H2C H2C  H3C
(P)
H3C
H3C
H2O / H+
OH
OCOCH5
(Q)
H3C
CHO
Ketone (non-reducing) and aldehyde (reducing) can be distinguished by Fehling’s

solution as we know that ketone does not react with Fehling’s solution.
 (c) is correct
46. The rate constant of the first order reaction

2.303 N
K= log 0
t N
From the given data, we can write
2.303 800
K= 4
log = 1.386  104 s1  (c) is
2  10 50
correct
24 23
47. 21 N decays into 11 Na via radioactive decay. The decay reactions are
11 Na24  11 Na23 + 0n1

0 n1  1p1 + 1e0 or 
Thus the reaction involves  emission.  (a) is
correct
48. The salt with lower value of K sp precipitates first. Here HgS has the lowest value of
Ksp hence it will precipitate first.
 (c) is correct
49. The desired reaction is

CH3 CH3 CH3 CH3 CH3 CH2

H+ + +
H2O
H3C OH CH3
Cis-Butene-2 Trans-Butene-2 Butene-1
(1) (2) (3)
Major
Hence only three structures shown above and possible.
 (d) is correct
50. The molecular structure of H3PO3 is as shown below
H P OH
OH
There are only two OH groups which means that at the most two hydrogen atoms
can be replaced and hence it is dibasic. Here the oxidation number of P is +3. P
may also have +5 oxidation state in some compounds. Increase in oxidation number
represents that H3PO3 can be oxidised and hence it is a reducing agent.
 (c) is correct
51. After examining the four given structures we can easily see that only (a) has the
desired hybridization.
H 2C CH C N
(from left to right)
sp2 sp2 sp sp
 (a) is correct
52. C2H5O will abstract proton from phenol, converting the phenol into phenoxide ion.
This would then make nucleophilic attack on the methylene carbon of alkyl iodide.
But C2H5O is in excess. C2H5O is better nucleophile than C6H5O (phenoxide) ion,
since in the former the negative charge is localised over oxygen and in the latter it is
delocalised over the whole molecular framework. So it is C 2H5O ion that would
make nucleophilic attack at ethyl iodide to give diethyl ether (Williamson’s
synthesis).
H 3C H3C
+ I  H3C O CH3 + :I

O
Thus the product is C2H5OC2H5  (b) is correct

53. The extent of deviation of a real gas from an ideal behaviour is expressed in terms of
compressibility factor, Z, defined as
PV
Z=
nRT
For positive deviation, Z > 1.  (a) is
correct
54. The AgNO3 and BaCl2 in excess releases Ag+ and Ba++ respectively, in solution in
excess and the two salts of mixture release Br  and SO 4  respectively. The
reaction can be represented as
Ag+ + Br  AgBr
Excess 0.01 mole 0.01 mole
Ba2+ + SO 24   BaSO4
Excess 0.01 mole 0.01 mole  (d) is correct
55. The desired reaction can be written as
+
Ph 
PhC
H H O
 2
CH3 CH3
H3C +
OCH3 OH O
Ph Ph  Ph
H3C H3C H3C

(A)
 (a) is correct
56. The central boron atom in H3BO3 is electron-deficient. Therefore it accepts a pair of
electrons, hence weak Lewis acid. There is no d-orbital of suitable energy in boron
atom. So, it can accommodate only one additional electron pair in its outermost
shell. Thus it is monobasic weak Lewis acid.
B(OH)3 + H2O  [B(OH)4] + H+  (c) is correct
57. The complete set of reactions of gold extraction can be written as

1
2Au + 4CN + H2O + O 2  2[Au(CN)2] + 2OH
2
2[Au(CN)2] + Zn  [Zn(CN)4]2 + 2Au

Hence on comparison we find

X = [Au(CN)2], Y = [Zn(CN)4]2  (a) is
correct
58. In an electrolytic cell, electrolysis of an electrolyte takes place by passage of electric

current through its aqueous solution or molten state. Current flows by the migration
of ions towards oppositely charged electrodes. In electrolytic cell, flow of electrons
takes place from cathode to anode through internal supply.
 (c) is correct
59. ( d ) is correct
60. (d ) is correct
MATHEMATICS
PART − C
61. Here 4x + x + x = 180

 6x = 180
 x = 30
From sine rule,
sin 120 sin 30 sin 30
 
a b c
 a : a + b + c = (sin 120) : (sin 120 + sin 30 + sin 30)
3 32
= :
2 2
= 3 : 3 +2  (c) is
correct
62. The given function I (m, n) is defined as

1
I (m, n) =  t m (1  t ) n dt
0
1
 t m 1  n 1
= (1  t ) n .  
m  1 0 
m 1 0
(1  t ) n  1 t m  1


2n n
 I (m, n) =  I [(n  1), (m + 1)]  (c)
m 1 m 1
is correct
63. Given parabola is
x2 y2
 =1
cos 2 α sin 2 α
Eccentricity = 1  tan 2 α = sec 
Vertex = (a, 0) = ( cos , 0)

Focus = (ae, 0) = (1, 0)
a
Directrix = x = 
e
 x =  cos2
Thus only abcissa of foci is independent of   (b) is correct
64. Equation of the line AB can be written as

x + y = 21 A (0, 21)
The number of integral solutions to the equation

x + y < 21
i.e. x < 21  y O (0, 0)
B (21, 0)
Thus, number of integral coordinate

= 19 + 18 + ……. + 1
19  20
= = 190  (a) is
2
correct
65. Volume of parallelopiped formed by vectors
1 a 1
= 0 1 a = 1  a + a3
a 0 1
dV
 0  3a 2  1
da
1
 a = 
3

1
Thus V will be minimum at a =  (c) is
3
correct
66. Equation of the tangent to the given ellipse can be written as

(3 3 cos ) sin 
x  y 1
27 1
x cos  y sin 
   1
3 3 1
Sum of intercepts,
3 3 1
l = 
cos  sin 
dl
  3 3 sec  tan   cot  cosec   0
d
3 3 sin  cos 
or 2
  0
cos  sin 2 
 3 3 tan3  1 = 0
1
or tan2 =
3 3/2
1
 tan  =
3

  =
6
 (a) is correct
67. Let A (0, 0), B (4, 0) and C (3, 4) be the triangle.
AE and BD are perpendiculars on BC and AC respectively. A (0, 0)
Since BD  AC
D
3
 Slope of BD = 
4
B (4, 0) C (3, 4)
Equation of BD is 3x + 4y  12 = 0 E

Similarly AE  BC ……(i)
1
 Slope of AE =
4
Equation of AE is x  4y = 0 ……..(ii)
By equations (i) and (ii),
3
x = 3, y =
4
 3
Thus the orthocentre of the triangle is  3,   (d) is correct
 4
68. Since we know that
1
x +  2;  x>0
x
1
x 
or x  1
2
tan 2 α
x2  x 
 x2  x
 tan 2 α
2
tan 2 α
 x2  x   2 tan   (c) is correct
x2  x
69. Since A2 = B
 0  0  2 0 1 0
 A =2          

1 1
 
1 1
 
  1 1
 
5 1

Comparing, we get
2 = 1 or =  1 ………(i)
and +1=5 or =4 ………(ii)
Since the two values of  do not match, thus no real value of  exists
 (d) is correct
70. Let the equation of the chord be
y = m (x  4)
Length of perpendicular dropped from (6, 0) = 2

(4, 0)
2

m ( 6  4)  0
  2
1 m2
( 2m) 2 4m 2
  2 or =2
1  m2 1  m2
 2m2 = 2
 m = 1  (a) is
correct
71. Point must lie on both line and plane

 2(4)  4(2) + k  7 = 0
or k = 7
But a1a2 + b1b2 + c1c2 = 0
 2(1)  1(4) + 2(1) = 0
Thus k = 7 satisfies  (a) is
correct
72. Since P (B  C) = P (B) 

P (A  B  C )  P (A  B  C )
3 1 1
 P (B  C) =    
4  3 3 A B
9  8 1
=  C
12 12
 (a) is correct
73. Eliminating x between the two given equations, we get
(9, 3)
y= 2y  3
 y  2y  3 = 0
2
 (y  3) (y + 1) = 0
(0, 0) (3, 0)
Area bounded by the curve
9
=  x dx
0

9
x 3/2 2
=   9 3/2
3/ 2 0
3
2
  27  18  (b)
3
is correct
x2  1
2
74. Given function f (x) = 2 e  t dt
x
On differentiation, we get
f  (x) = 2x e 
 (x 2  1) 2 2 )2
 e  (x


(x 4  1  2x 2 ) 2  1
= 2x e  (1  e 2 x )
 f  (x) > 0, for x  (, 0)  (b) is correct
75. Let the range of the function be y

x2  x  2
Hence y =
x2  x  1
 y (x2 + x + 1) = x2 + x + 2
(1  y)  ( y  1) 2  4 ( y  1) ( y  2)
 x=
2 ( y  1)
or (y  1)2  4 (y  1) (y  2) > 0
7
 y > 1, y 
3
 7
Thus the range of f (x) is 1,  (d) is correct
 3

76. If a function obeys mean value theorem then it must be differentiable in the interval
on which it is defined.
The function (a) is not differentiable at x = 1/2 (a) is
correct
77. The given differential equation is

dy
(t + 1)  ty = 1
dt

dy t 1
  y 
dt t 1 t 1
t 11
 I.F. = e   t 1
dt
 e t  log e ( t  1)
 e  t . ( t  1)
Thus the solution is
 y (et) (t + 1) =  e 1 dt  c
 e t  c
or y = t
e ( t  1)
Since y (0) =  1 (given)

1 c
  1 = 1 (1)
or c=0
e t
Thus y=
e  t ( t  1)
1
or y=
t 1
1
 y (1) =   (b) is correct
2
78. Given pair of straight lines is
y2  14y + 45 = 0 y=9

 (y  5) (y  9) = 0 (4, 7)
y=5
and x2  8x + 12 = 0
 (x  6) (x  2) = 0
The given square is shown in figure. x=2 x=6
Thus centre is (4, 7)  (b) is correct
79. For each value of x, there is one value of

f (x) and range  [0, 1]
Thus f (x) is one-one not onto, which is O (0, 0)
also evident from the adjoining figure.
 (b) is correct
80. Desired limit is

f ( 2  2 h  h 2 )  f ( 2)
Lim
h 0 f (1  h  h 2 )  f (1)
f ( 2) ( h  2) 6
 Lim  .2 = 3  (c) is
h 0 f (1) (1  h ) 4
correct
81. Since, (1 + t2)12 (1 + t12) (1 + t24) = (1 + t2)12 (1 + t12 + t24 + t36 )
Hence required coefficient is 12
C6 + 2  (d) is correct
  z 1 z 1
82. Re () =  
2 z 1 z 1
| z |2  1
= =0  (d)
| z  1 |2
is correct
83. The coefficient determinant equation gives

1 a 0
0 1 a = 0
a 0 1
 1 + a3 = 0
 a = 1  (c) is
correct
84. Number of ways of selecting two numbers, such that both numbers are greater than
4 is 3C2 .
6
Total number of ways of selection of two numbers is C2
3
C2 4
 Required probability = 1  6
  (a) is
C2 5
correct
85. Given ellipse is
x2 y2
+ = 1
9 5
The equation of tangent at (x1, y1) can be written as
xx 1 yy1
2
  1 Q
a b2
( ae, b2/a) (ae, b2/a)
R O
P
(ae,  b2/a) (ae,  b2/a)
For More Sample Paper and Their Answer Key S

5 4
e2 = 1  
9 9
2
 e =
3
one end point of latus rectum
(2, 5/3)
Equation of the tangent at (2, 5/3) is
2x y
 = 1
9 3
1 9 27
Area of triangle OPQ =     3 
2 2 4
Area of quadrilateral PQRS
27
= 4  Area of triangle OPQ = 4  = 27 sq. units.
4
 (a) is correct
86. The given limit is
sin nx [(a  n ) nx  tan x ]
Lim = 0
x 0 x2
sin nx  tan x 
or Lim
nx ( a  n ) n  x  n = 0
x 0  
 an  n2  1 = 0
1
 a = n+  (d) is correct
n
87.(d) is correct
88. (c) is correct
89. (b) is correct
90.(a) is correct



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Note: (i) The test is of 3 hours duration.

1. According to Bohr’s theory, the radius of the m th orbit of an atom of atomic

According to the problem,

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2. The decay can be represented as

3. Heat lost by ice = Heat gained by water

4. Using Snell’s law,

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5. AB is isothermal process and BC is isobaric process. In process AC, pressure

Thus 1 > 3 > 2 > 4  (b) is correct

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11. Power dissipated  Requivalent

13. (a) is correct

16. From the adjoining figure,

From equations (i) and (ii), we get N

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18. For simple harmonic motion,

19. As angular velocity  is given constant, so angular momentum L will be constant

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For concave lens,

Sound Source Thief Police

Let f1 = frequency of the police car heard by motorcyclist

23. Applying conservation of angular momentum about centre of the rod,

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25. Young’s modulus [Y] is

26. As rate of heat transfer,

27. Here, v = l3 = (1.2  102 m)3

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31. Number of atoms on 24 g of C (12)

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Me2SiCl2 + 2H2O  Me2Si(OH)2  O O

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37. When MnO2 is oxidised to K2MnO4 in alkaline medium, it acquires a stable

38. Number of electrons in NO 3 = 7 + 24 + 1 = 32

Total number of valence electrons in CO 32  = 4 + 6  3 + 2 = 24

COO HOH2C COOH HOH2C

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CH3 CH3  (a) is

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CHCl3 (1.03 D) CH2Cl2 (1.62 D)

COOH > OH > OH > HCCH

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H2C H2C  H3C

Ketone (non-reducing) and aldehyde (reducing) can be distinguished by Fehling’s

46. The rate constant of the first order reaction

11 Na24  11 Na23 + 0n1

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CH3 CH3 CH3 CH3 CH3 CH2

Thus the product is C2H5OC2H5  (b) is correct

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55. The desired reaction can be written as

H3C H3C H3C

57. The complete set of reactions of gold extraction can be written as

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Hence on comparison we find

58. In an electrolytic cell, electrolysis of an electrolyte takes place by passage of electric

61. Here 4x + x + x = 180

62. The given function I (m, n) is defined as

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Vertex = (a, 0) = ( cos , 0)

64. Equation of the line AB can be written as

The number of integral solutions to the equation

Thus, number of integral coordinate