Documente Academic
Documente Profesional
Documente Cultură
US 7,943,102 B2
(58)
FORMALDEHYDE
(75) Inventor:
References Cited
( * ) Notice:
2,462,413 A
21949 Meath
2,504,402 A
4/1950 Field
2,519,788 A
8/1950 Payne
3,959,383 A *
(21)
.
Appl' NO" 11/463388
(22)
Flledl
4,358,623 A
4,404,414 A *
4,450,301 A *
Aug- 9, 2006
(65)
(62)
(30)
(51)
(52)
Int. Cl.
B01] 8/04
B01] 19/30
B01] 8/18
B01] 8/00
B01] 10/00
B01] 19/00
US. Cl.
(2006.01)
(2006.01)
(2006.01)
(2006.01)
(2006.01)
(2006.01)
422/631; 422/139; 422/129; 422/187;
422/211; 422/600; 422/630
5/1976
5,997,826 A
6,147,263 A
2/1977
_
Primary Examiner * Walter D Gn?in
(57)
ABSTRACT
A method for formaldehyde production through catalytic oxi
dation of methanol, comprising the steps of feeding to a ?rst
oxidation catalytic bed (2) a gas ?oW comprising methanol
and oxygen at a predetermined crossing linear ?oW rate,
obtaining at the outlet of said ?rst catalytic bed (2) a How of
tion catalytic bed (6) is distinguished by the fact that the How
of gaseous reaction products comprising unreacted methanol
is fed to the second catalytic bed (6) With a crossing linear
?oW rate substantially equal to said predetermined ?rst cata
US. Patent
Sheet 1 015
Fig.1
US 7,943,102 B2
US. Patent
Sheet 2 015
Fig.2
US 7,943,102 B2
US. Patent
Sheet 3 015
mE
NNrm
O
mm_,
US 7,943,102 B2
NN
ifW91
mm"N
US. Patent
Sheet 4 015
Fig.6
US 7,943,102 B2
US. Patent
Sheet 5 015
US 7,943,102 B2
Fig.7
40
US 7,943,102 B2
1
CROSS-REFERENCE TO RELATED
APPLICATIONS
dehyde.
20
times) With respect to the ?rst catalytic bed feeding ?oW rate.
lytic bed.
Further on, in such second bed no heat removal takes place,
so that this operates in an adiabatic Way.
PRIOR ART
40
hot spots.
50
place.
Beside the continuous heat removal, it is in fact thanks to
the suitable predetermined linear ?oW rate of such reactants in
the tubes that it is possible to carry out said reaction in
into formaldehyde
SUMMARY OF THE INVENTION
life.
Sometimes, further on, the gas exiting from the reactor
tubes in Which the ?rst oxidation occurs has substantial non
catalytic bed.
proceeds.
aforesaid catalytic bed, said bed being of the pseudo-isother
mal type.
The expression pseudo-isothermal catalytic bed is meant
65
US 7,943,102 B2
4
3
comprising unreacted methanol; feeding the ?oW of gaseous
of predetermined amplitude.
20
oxidation temperature.
BRIEF DESCRIPTION OF THE DRAWINGS
25
30
35
native embodiment;
FIG. 7 schematically shoWs a reactor according to a further
alternative embodiment.
40
this is the reason Why they are fed into a second catalytic bed
6 and further reacted by means of an additional oxidation, as
45
50
55
formaldehyde.
As used herein, the expression crossing transverse sec
tion means the internal section of a duct or a catalytic bed,
respectively.
Such section is measured perpendicularly to the ?oW direc
tion inside the duct or the catalytic bed, respectively.
60
the opening 9.
US 7,943,102 B2
5
tion.
Such catalytic bed 2 is so structured so as to de?ne a
reactor 5.
part to the reaction and in its loWer part by the bed bottom 16,
such bottom being impermeable to gases.
The bed 2 is inserted in a cage structure externally delim
20
35
The residence time and the crossing linear ?oW rate are in
crossing ?oW rate With respect to those of the prior art, thus
distributing the thermal load Which is sometimes localiZed as
a hot spot to Which the catalyst is subject, that can reduce its
effectiveness With time.
perature.
Such ?oW rate value is obtained through the speci?c siZing
45
sure.
55
60
US 7,943,102 B2
7
verted methanol.
The same reactor is equipped With a second catalytic bed of
particles.
Differently from the previous ones, the apparatus obtained
20
25
35
40
45
50
Example 1
60
neath.
The reactor is fed With 8500 Nm3/h of gas thus reaching a
65
US 7,943,102 B2
10
In the preferred embodiment of the invention shown in
FIG. 2, the secondary reactor is designed in such a Way that
a Width of 10 mm.
20
predetermined amplitude;
a second catalytic bed With a crossing transverse section of
predetermined amplitude;
duct.
4. The apparatus according to claim 3, Wherein a heat
30