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Scientia Horticulturae
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Department of Food Agriculture and Chemical Technology, Karakoram International University, Gilgit, Pakistan
Department of Food Technology, Pir Mehr Ali Shah, Arid Agriculture University, Rawalpindi, Pakistan
a r t i c l e
i n f o
Article history:
Received 31 December 2010
Received in revised form 9 May 2011
Accepted 31 May 2011
Keywords:
Apricot varieties
Proximate composition
Functional properties
a b s t r a c t
In order to ascertain physico-chemical, functional and geometrical traits of apricot fruit from Northern Areas of Pakistan, six predominantly grown varieties namely, Alman, Habi, Khakhas, Mirmalik,
Neeli and Shai were selected in this study. Proximate composition as crude fat (2.13%), crude protein
(6.188.7%), crude ber (11.8513.6%), ash (9.4512.1%) and total sugars (56.864.9%) were determined
on dry weight basis. The data showed variations among the investigated parameters in all varieties. Functional properties of apricot fruit viz. ascorbic acid (67.3990.94 mg/100 g), total phenolic compounds
(45907310 mgGAE/100 g), total carotenoids (10.0918.13 mg/100 g -carotene) and antioxidant activity (56.8482.33%) were also recorded. The data pertaining to mineral contents (mg/100 g) revealed K as
the predominant element (20403000) followed by P, Mg, Ca, Na and Fe among all the tested samples.
Furthermore, geometrical characters of apricot varieties were also determined as important sensory and
technological attributes on fresh weight basis. The result from the present study showed that all the
tested varieties are highly nutritious and rich in functional components.
2011 Elsevier B.V. All rights reserved.
1. Introduction
Apricot, Prunus armeniaca L., a member of the Rosaceae family;
is one of the most important stone fruit of South East Asia. Pakistan
is the 3rd major producer of apricot with an annual production
of 0.5 million Mt (FAO, 2008; DOA, 2008). The major ecological
zones in Pakistan for apricot production are the Northern Areas
(Gilgit-Baltistan), Malakand division of NWFP and upper parts of
Balochistan province (Jasra and Ra, 2002).
Apricot is the major fruit crop of the Northern Areas, having
1.8 million fruit bearing trees with an annual production of 0.11
million Mt. It contributes to 62% share of total fruit production
of the area. Nearly 60 varieties are grown in this region. Among
them, Alman, Habi, Halman, Shakanda and Khakhas are the most
important in terms of bulk production and general acceptance. The
apricots presently grown in this region are known for their unique
characteristic color, avor, taste and overall quality (MFC, 2005;
DOA, 2008).
Apricot to the Northern Areas could be what Banana is to the
banana republics. Apricot is synonym to the area and has remained
as traditional part of diets of the people and an important economic crop for centuries. Favorable environmental conditions of
this region enable the production of quality apricots with high dry
matter and sugar contents (MFC, 2005). Owing to the perishable
nature of this fruit and limited marketing opportunities, a large
proportion of the fruit is wasted during glut season and the losses
are as higher as 44% of total fresh produce (FAO and DOA, 2007).
Nutritionally, it is a rich source of sugars, bers, minerals, bioactive phytochemicals and vitamins like A, C, thiamine, riboavin,
niacin and pantothenic acid (Leccese et al., 2007). Among the phytochemicals, phenolics, carotenoids and antioxidants are important
for their biological value (Lichou et al., 2003).
During the ripening of fruits a series of complex biochemical
reactions take place which leads to production of phenolic compounds, carotenoids and the formation of volatile compounds.
Among these natural compounds, carotenoids are the prevalent
group of pigments in nature, and present in all photosynthetic
organisms, which are responsible for most of yellow to red colors
of fruits and owers.
In the recent years, there is an increasing interest in polyphenols
and carotenoids for their antioxidant properties and ability to ght
against chronic diseases (Dragovic-Uzelac et al., 2007). It has been
shown that dietary antioxidants may provide effective protection
from oxidative damage in living systems (Lila, 2004). Apart from
its nutritional characteristics, apricot fruit also has some pharmacological signicance due to having high amounts of antioxidant.
It is used as cleansing agent and mild laxative, antipyretic, antiseptic, emetic and ophthalmic properties. A recent study by Enomoto
387
Ablank Asample
Ablank
100
Dg = (LWT )0.333
10.45
10.92
11.61
12.10
9.25
9.61
0.27E
0.40CD
0.33BC
0.30A
0.66D
0.18B
6.18
6.54
6.18
7.61
8.25
8.70
80.60 0.14D
78.80 0.13E
79.00 0.24E
85.30 0.12A
85.00 0.16B
84.50 0.17C
19.00
20.00
18.00
12.67
12.73
14.60
0.61B
0.56A
0.43C
0.50E
0.42E
0.33D
19.40
21.20
21.00
14.70
15.00
15.50
0.13B
0.15A
0.24A
0.12E
0.16D
0.17C
2.47
2.54
2.18
2.10
3.00
2.25
0.010C
0.011B
0.032E
0.012F
0.100A
0.040D
CP (%)a
CF (%)a
DM (%)
TSS ( Brix)
MC (%)
Parameter
Varieties
Table 1
Proximate composition of apricot commonly grown in Northern Areas.a
0.073E
0.047D
0.024E
0.135C
0.143B
0.245A
MC, moisture content; DM, dry matter; C Fib., crude ber; CF, crude fat; CP, crude protein; RS, reducing sugars; NRS, non reducing sugars; TS, total sugars.
All the values are means of three replications +SD.
Values with same letters are not statistically different at alpha 0.05.
a
Results for CF, CP, C Fib., Ash, RS, NRS, And TS were expressed on dry weight basis.
3. Results
C Fib. (%)a
11.38
11.96
12.23
13.60
11.85
12.57
Ash (%)a
0.013D
0.026C
0.018B
0.015A
0.024F
0.017E
Dg
100
L
16.73
21.38
14.95
15.96
15.32
15.10
RS (%)a
0.30B
0.38A
0.0.49D
0.30C
0.27D
0.38D
47.13
43.55
47.54
40.82
45.95
41.98
NRS (%)a
0.67B
0.53D
0.47A
0.50F
0.40C
0.34E
S = Dg2
63.86
64.90
62.49
56.78
61.27
57.08
TS (%)a
0.66B
0.73A
0.51C
0.47E
0.33D
0.45E
Alman
Habi
Khakhas
Mirmalik
Neeli
Shai
388
389
Table 2
Some chemical and functional properties of apricot commonly grown in Northern Areas.
Varieties
Parameters
pH
Alman
Habi
Khakhas
Mirmalik
Neeli
Shai
4.70
5.20
4.10
4.00
3.80
4.51
TA (% Malic acid)
0.012B
0.020A
0.024D
0.037E
0.050F
0.020C
0.61
0.54
0.67
0.70
0.86
0.45
0.04C
0.03D
0.03B
0.01B
0.03A
0.01E
AA (mg/100 g)a
77.76
79.27
86.26
86.60
90.94
67.39
0.27D
0.40C
0.33B
0.30B
0.66A
0.18E
TC (mg/100 g -carotene)a
312B
390A
280C
250D
210F
175E
17.03
18.13
16.12
14.50
12.23
10.12
0.32B
0.34A
0.31C
0.3D
0.27E
0.21F
AoA (%)a
64.50
82.33
62.19
58.42
55.70
56.77
1.10B
2.06A
1.30C
0.44D
1.01E
0.78E
TA, titratable acidity; AA, ascorbic acid; TPC, total phenolic compounds; TC, total carotenoids; AoA, antioxidant activity.
All the values are means of three replications +SD.
Values with same letters are not statistically different at alpha 0.05.
a
Results were expressed on dry weight basis.
R2 = 0.9916
69
67
65
63
61
59
57
55
4500
5500
6500
7500
390
Table 3
Mineral composition of Apricot commonly grown in Northern Areas (mg/100 g DW).
Varieties
Minerals
Na
Alman
Habi
Khakhas
Mirmalik
Neeli
Shai
19.42
22.49
13.30
15.89
17.71
16.31
0.42B
0.39A
0.17E
0.25D
0.41C
0.31D
Ca
2340.0
2120.0
2040.0
2918.0
3000.0
2340.0
54.13C
43.84D
43.72E
58.05B
61.48A
53.39C
124.80
120.50
109.10
104.20
112.20
102.50
1.60A
2.74B
1.50D
1.55E
2.58C
1.72E
Mg
143.58
265.63
203.00
175.04
179.78
213.91
5.65E
6.69A
8.85C
3.96D
4.36D
8.48B
128.00
147.60
152.10
113.24
139.70
129.80
Fe
3.93C
2.13A
3.95A
1.88D
5.05B
1.65C
Zn
12.20
10.40
7.24
5.14
8.82
6.52
0.93A
0.78B
0.42D
0.58E
0.62C
0.46D
1.95
3.53
2.14
3.18
3.46
0.82
Mn
0.26B
0.39A
0.17B
0.25A
0.30A
0.13C
0.51
1.18
0.70
0.82
1.07
0.64
Ni
0.03E
0.08A
0.06D
0.07C
0.07B
0.02D
Cu
0.41
0.21
0.32
0.31
0.36
0.70
0.04B
0.02D
0.02C
0.01C
0.03BC
0.04A
0.14
0.84
0.36
0.23
0.86
0.17
0.01D
0.04A
0.01B
0.03C
0.03A
0.01D
Table 4
Some physical and geometrical properties of Apricot commonly grown in Northern Area.
Varieties
Parameters
FL (mm)
Alman
Habi
Khakhas
Mirmalik
Neeli
Shai
35.73
40.00
32.95
45.49
29.55
29.42
FW (mm)
0.40C
0.73B
0.39D
0.55A
0.40E
0.26E
37.00
37.60
24.91
38.90
26.62
28.46
0.41B
0.53B
0.30E
0.55A
0.36D
0.39C
FT (mm)
33.28
35.11
29.32
37.50
24.85
27.63
GMD (mm)
0.04C
0.04B
0.03D
0.06A
0.03F
0.03E
35.29
37.43
29.02
40.60
26.97
28.37
0.37C
0.45B
0.48D
0.48A
0.41F
0.44E
FV (cm3 )
21.60
25.03
18.30
30.00
16.60
17.20
SA (mm2 )
0.36C
0.35B
0.24D
0.48A
0.24F
0.25E
3946.2
4423.2
2644.7
5176.2
2284.2
2527.5
Sph. (%)
62.78C
147.55B
89.07D
125.11A
70.67E
78.71D
98.88
94.00
88.07
89.25
91.26
96.43
F Wt. (g F Wt.)
0.04A
0.03C
0.03F
0.05E
0.03D
0.02B
23.91
28.38
15.85
35.91
14.00
12.50
0.29C
0.36B
0.19D
0.50A
0.25E
0.14F
FL, fruit length; FW, fruit width, FT, fruit thickness; GMD, geometric mean diameter; Sph., sphericity; F Wt., fruit weight; P Wt., pulp weight; Pit Wt., pit weight.
All the values are means of three replications +SD on fresh weight basis.
Values with same letters are not statistically different at alpha 0.05.
P Wt. (g F Wt)
21.75
25.99
14.49
33.54
12.94
11.21
0.22C
0.28B
0.11D
0.41A
0.18E
0.11F
0.07B
0.09A
0.07C
0.08A
0.07D
0.11C
Pulp/Pit Ratio
10.07
10.92
10.66
14.15
12.22
8.71
0.23D
0.32C
0.48CD
0.32A
0.65B
0.70E
391
basis. Similarly, Ruiz et al. (2005), found the amount of total phenolic compounds from 326 to 1600 mg/100 g on fresh weights basis
in Spanish apricot varieties. Akbulut and Artik (2002) and Scalzo
et al. (2005) observed the range of total phenolic content from 769
to 1283 mg GAE/kg and 214 to 266 mg/L respectively in different
apricot cultivars on fresh weight basis. In comparison to previous
ndings regarding total phenolics, it is evident that all the apricot
varieties evaluated in this study have signicant amounts of phenolic compounds. Differences however exist those might be due to
the variety, geography, climatic conditions and stage of ripening
(Akbulut and Artik, 2002).
The ndings of present study showed considerable amounts
of carotenoids in the tested genotypes. Previous literature shows
that apricot is a rich source of carotenoids especially -carotene,
which represents 50% of total carotenoid in this fruit (Radi et al.,
2004). Akin et al. (2008) have reported -carotene contents of
Maltaya apricots in the range of 14.8391.89 mg of -carotene
equiv./100 g, which supports the ndings of the present study.
The signicant variations among all tested varieties were also in
line with the earlier studies of Dragovic-Uzelac et al. (2007) on
carotenoids and phenolic compounds in three apricot cultivars of
Croatia. The carotenoids of fruit act as antioxidants and protect the
cell membrane from oxidative damage. However, variations among
carotenoid contents are attributed to climate, variety, geographical origin, harvest year and the methods of cultivation (Akinci et al.,
2004).
Apricots contain a wide variety of phytochemicals that function as antioxidant. They are attributed to scavenge free radicals
and thus quench a certain amount of DPPH in the experimental
essay. Food quality analysis regarding antioxidant components of
produce is fast becoming an accepted prole that primarily highlights the antioxidant capacity as a quality index for many fruits and
vegetable (Leccese et al., 2007). High phenolic contents in the investigated varieties demonstrated an increased antioxidant activity.
The results pertaining to antioxidant activity in the current study
were in conrmation with previous ndings on apricot and other
fruits. Andlauer and Furst (1998) and Vinson et al. (1998) observed
that foods with a wide variety of phytonutrients demonstrated high
antioxidant activity. These ndings were also in line with those
of Durmaz and Alpaslan (2007), that high phenolic contents contribute to increased antioxidant capacity.
A good correlation (R2 = 0.9916) was established between phenolic compounds and antioxidant activity in this study which is
supported by previous reports. Drogoudi et al. (2008) found a better correlation between antioxidant capacity (R2 = 0.9542) and the
total phenolic content in 29 apricot cultivars while weak correlation was observed with reference to total carotenoids. It was
suggested that phenolics have more signicant contribution to the
total antioxidant capacity in apricot.
All the varieties under investigation demonstrated varying
amounts of minerals and Habi was found comparatively rich
regarding overall mineral composition followed by Neeli. Habi was
especially rich in Na, Ca, P, Mg, Fe and Zinc, which are the most
frequently needed minerals by the human body. Haciseferogullari
et al. (2007) studied the mineral content of Turkish apricots and
reported Al, Ca, Fe, K, Mg, Na and P as major minerals of the apricot fruits. They also established K levels between 20,791 ppm and
33,364 ppm. The importance of the minerals cannot be neglected
in the body systems. Calcium and phosphorus serve as important part of the skeleton and assists in teeth and bone formation
(Brody, 1994). Na, K, Ca, and Mg are involved in neural conduction and muscle contraction. Further more calcium, phosphorus,
sodium, potassium, magnesium, chlorine and sulfur make up the
dietary macro elements which are required at levels of more than
100 mg/day by the adults and play important roles in the biological
systems (Nielsen, 1994).
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