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Mario Paredes, PE
State Corrosion Engineer
June 17, 2013
Florida Department of Transportation
Anchor Cap
Pier
Pier
Deviators
Parsons
Brinckerhoff
Parsons
Brinckerhoff
405-9L
9/20/2011
Segregated
Chalky Grout
Corrosion
Product
Moisture Content
100 100
40
20
30
Ca2+ Ca2+
K+
K+
20
10
NO32-NO32SO42- SO42-
Moisture
Content
Moisture
Content
NO3220
SO42-
NEW
Na+ Na+
Cl- Cl-
40210L V
ClCa2+
70 70
NO32K+
SO42- 60
60
Na+
Moisture Content
Cl50 50
NO32Ca2+
SO42- 40
40 K+
Moisture Content
Na+
30 Cl-30
NEW
NEW
40210L V
40
10theory:
Content
Current
10 Moisture
30
0 prevent
Sulfates
0
20
passivation
10
40210L V
10
80
40210L IV
0
20
50
40210L II
Moisture Content %
50
I %
Content
Moisture40210L
10
30
80
Na+
90
Moisture Content %
40210L III
60
80
4000
10
100
50
70
03000 90
40
60
2000 80
30
50
1000 70
20
40
0 60
40210L IV
Ca2+
90
K+
60
II
0.14 mgCl/gdry
pH 12.7
55% moisture
4300 ppm SO42-
III
0.18 mgCl/gdry
pH 12.7
44% moisture
1900 ppm SO42-
Ca2+
K+
Na+
ClNO32SO42Moisture Content
IV
0.09 mgCl/gdry
pH 12.7
14% moisture
310 ppm SO42-
80
100
6000
30
70
90
5000
20
70
SO42-
I
0.25 mgCl/gdry
pH 11.9
7100 ppm SO42-
Corrosion
13
12
11
0.1
10
9
8
0.01
pH
NO32-
40210L V
90
7000
40
80
Cl-
0.47 mgCl/gdry
pH 9.8
7800 ppm SO42-
40210L IV
Na+
40210L III
100
8000
50
90
Estimated
40210L II
K+
Moisture Content %
9000
60
Content %
Moisture
%
Moisture Content
Concentration (ppm)
Moisture Content %
Ca2+
NEW
NEW
Task 1
100
40210L I
10000
70
30 deg.
100%
Soft grout
Moisture content
80%
60%
No soft grout
40%
20%
0%
PT4-2
PT1
PT2
PT3
PT4-2
100%
Soft grout
Moisture content
80%
No soft grout
60%
40%
20%
0%
PT2
PT3
PT1
PT4-1
PT4-2
100%
Soft grout
Moisture content
80%
60%
40%
20%
0%
No soft grout
Moisture content
100%
80%
60%
40%
20%
0%
Soft grout
Data acquisition
Raw data
Non destructive
No holes needed
Fast
Can be done while grout is
still fluid (to allow for instant
QC).
Produces image of cross
section
Task 3
2
Steven Schein
System (SS System)
Reference Scan
Scale
Dtotal = in.
Dstrand = .1660 in.
Cut Defect
Break Defect
Drill Defect
Buried Damage
QUESTIONS?