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Definition:
IUPAC: Azane
chemical compound made of molecules which each contain one atom of
nitrogen and three atoms of hydrogen
Molecular structure: NH3
PROPERTIES OF AMMONIA
a. PHYSICAL PROPERTIES
MM: 17.031 g/mole
Color: Colorless
Odor: Sharp, pungent odor
BP: 33.35 C (28.03 F)
FP: 77.7 C (107.8 F)
b. CHEMICAL PROPERTIES
Chemical Formula: NH3
Type of Base: Weak
Affinity(water): High
Corrosiveness: To some metals
Oxidation Power: Strong
Reactive: Quite
Volatility: Increases w/ pH
USES OF AMMONIA
Fertilizer
- applied in the form of either its salt or its solution form. These are Ammonium
Nitrate and Ammonium Sulfate.
Ammonium Nitrate (NH4NO3)
- used in high-nitrate fertilizers
Acid-Base reaction:
HNO3(aq) + NH3(g) NH4NO3(aq)
Ammonium Sulphate ((NH4)2SO4 )
- used mainly in fertilizer in the reduction of pH of the soil.
2 NH3 + H2SO4 (NH4)2SO4
Cleaner
- generally streak free
- used mainly in the cleaning of glass stainless steel and occasionally a stove
- usually contain 5 to 10% ammonia
Manufacture of Commercial Explosives
- e.g., trinitrotoluene (TNT), nitroglycerin, and nitrocellulose
Precursor to Nitrogenous Compounds
- Nitric Acid (HNO3)
Ostwald Process
- Urea ((NH2)2CO)
HABER BOSCH
PROCESS
Nitrogen Sources: Pre Haber-Bosch Process
Manures (barnyard and other)
Guano (solidified bird excrement accumulated on subtrop/tropical
islands)
Chilean Nitrate (sodium nitrate)
CokeOven Gas (byproduct) Ammonium Sulfate
Coke oven gases produced primarily in the steel industry
Produced by reacting recovered coke oven ammonia with sulfuric acid
Nitrogen Fixation Processes:
Electric Arc Process
- Uses electrical current to combine N and oxygen in the air to form
nitric oxide (NO)
(NO) Nitric Acid Calcium Nitrate/Sodium Nitrate
Cyanamide Process
Limestone burned to form calcium oxide; fused with coke in electric furnace Calcium
carbide (CaC2) reacted with N at high temperature to form Calcium cyanamide (CaCN2)
ammonia; ammonium phosphates; nitric acid; ammonium nitrate
Haber-Bosch Process
N2 + 3 H2 2 NH3 (H = 92.4 kJmol1)
medium temperature (~500oC)
very high pressure (~250 atmospheres, ~351kPa)
a catalyst (a porous iron catalyst prepared by reducing magnetite, Fe3O4)
FLOWCHART
References:
http://www.firt.org/sites/default/files/2Vroomen.pdf
http://www.ias.ac.in/resonance/Volumes/16/12/1159-1167.pdf
https://en.wikipedia.org/wiki/Ammonia
http://www.britannica.com/science/ammonia
http://www.eoearth.org/view/article/170573/
http://www.nawabi.de/chemical/ammonia.asp
http://www.ch.ic.ac.uk/rzepa/mim/environmental/html/ammonia_text.htm
http://www.slideshare.net/brandonhardwicke/properties-of-ammonia
http://www.slideshare.net/brandonhardwicke/production-of-ammonia
http://www.slideshare.net/brandonhardwicke/ammonia
https://en.wikipedia.org/wiki/Haber_process
http://www.chm.bris.ac.uk/motm/ammonia/Ammonia%20MOTM.htm