Sunteți pe pagina 1din 159

ME 2034 NUCLEAR ENGINEERING

7th semester
B.E, Mechanical Engineering
June 2014 Nov 2014
Prepared by
Mr. W. Aju Wilber
Assistant professor
EEE Department

12/6/2014

ME 2034 NUCLEAR ENGINEERING

UNIT I NUCLEAR PHYSICS


Nuclear model of an atom-Equivalence
of mass and energy-binding- radio
activity-half life-neutron interactionscross sections
12/6/2014

ME 2034 NUCLEAR ENGINEERING

Nuclear model of an atom


The Rutherford model is a model of the atom devised
by Ernest Rutherford. Rutherford directed the
famous GeigerMarsden experiment in 1909
Based on the experimental results, contained the new
features of a relatively high central charge
concentrated into a very small volume in comparison
to the rest of the atom and with this central volume
also containing the bulk of the atomic mass of the
atom. This region would be named the "nucleus" of
the atom in later years
12/6/2014

ME 2034 NUCLEAR ENGINEERING

Definition of NUCLEAR ATOM


a conceptual model of the atom developed by
Ernest Rutherford in which a small positively
charged nucleus is surrounded
by planetary electrons

12/6/2014

ME 2034 NUCLEAR ENGINEERING

Equivalence of mass and energy binding


Massenergy equivalence is the concept that
the mass of an object or system is a measure of
its energy content
The equivalence of energy E and mass m is reliant on
the speed of light c and is described by the famous
equation
E = mc2
This equation tells us that matter and energy are
really two forms of the same thing.
12/6/2014

ME 2034 NUCLEAR ENGINEERING

E = mc2
E = total energy of a system
M = total mass of the system
C = speed of light
If an object is not moving then:
Eo = moc2
Eo is the rest energy and mo is the rest mass
12/6/2014

ME 2034 NUCLEAR ENGINEERING

Mass-Energy Equivalence
The law of conservation of energy
becomes a law of mass-energy
conservation.

12/6/2014

ME 2034 NUCLEAR ENGINEERING

Nuclear reactions also obey the energy


conservation laws.
The total amount of energy before the reaction
has to equal the total amount of energy after the
reaction.
Energy stored as mass must be included in order
to apply the law of conservation of energy to a
nuclear reaction.
12/6/2014

ME 2034 NUCLEAR ENGINEERING

A fission reaction splits up a large nucleus into


smaller pieces.

A fission reaction typically happens when a neutron hits a nucleus with enough energy to
make the nucleus unstable.
Fission breaks the nucleus into two smaller pieces and often releases one or more extra
neutrons.
Some of the energy released by the reaction appears as gamma rays and some as kinetic
12/6/2014
ME 2034 NUCLEAR ENGINEERING
energy of the smaller nuclei and the extra neutrons.

A nuclear chain reaction occurs when the fission of


one nucleus triggers fission of many other nuclei.

In a chain reaction, the first fission reaction releases two or more


neutrons. The two neutrons can hit two other nuclei and cause fission
reactions that release four neutrons. The four neutrons hit four new nuclei
and cause fission reactions that release eight neutrons. The number of
neutrons increases rapidly. The increasing number of neutrons causes
12/6/2014
ME 2034 NUCLEAR ENGINEERING
10
more nuclei to have fission reactions and enormous energy is released.

Binding Energy
The mass of a nucleus is generally less than the
sum of the masses of the nucleons.
This difference is called the mass-defect. Such a
phenomenon is observed in atomic or subatomic
levels, and not with ordinary materials that we
handle, where the total mass has to be the sum
of the component masses.
The mass-defect is responsible for the binding
together of the nucleons.
The energy equivalent of the mass-defect is
called the binding-energy of the nucleus.
12/6/2014

ME 2034 NUCLEAR ENGINEERING

11

illustrative picture of binding energy

when individual nucleons pack themselves together to form


a system, which we call nucleus, they liberate some energy in
the form of photons (gamma rays).
The liberated energy manifests as a reduction in the net mass
of the nucleus, as per Einsteins relation. I
t may also be said that the nucleus could be split into
nucleons by supplying external energy equal to the binding
12/6/2014
ME 2034 NUCLEAR ENGINEERING
energy

12

Radioactivity
The emission of ionizing radiation or particles
caused by the spontaneous disintegration of
atomic nuclei.
Radioactive substances, or the radiation emitted
by these

12/6/2014

ME 2034 NUCLEAR ENGINEERING

13

Half life
Half-life (t12) is the amount of time required for a
quantity to fall to half its value as measured at
the beginning of the time period. While the term
"half-life" can be used to describe any quantity
which follows an exponential decay, it is most
often used within the context of nuclear
physics and nuclear chemistrythat is, the time
required, probabilistically, for half of the
unstable, radioactive atoms in a sample to
undergo radioactive decay.
12/6/2014

ME 2034 NUCLEAR ENGINEERING

14

12/6/2014

ME 2034 NUCLEAR ENGINEERING

15

12/6/2014

ME 2034 NUCLEAR ENGINEERING

16

Neutron interactions and cross section


Neutrons essentially interact only with the
atomic nucleus
Cross-sections can vary dramatically and
erratically based on complex interactions
between all the nucleons in the nucleus and the
incident neutron
Huge effort and money has been spent to
measure these cross-sections for many materials
and a wide range of neutron energies
12/6/2014

ME 2034 NUCLEAR ENGINEERING

17

12/6/2014

ME 2034 NUCLEAR ENGINEERING

18

12/6/2014

ME 2034 NUCLEAR ENGINEERING

19

12/6/2014

ME 2034 NUCLEAR ENGINEERING

20

The end
12/6/2014

ME 2034 NUCLEAR ENGINEERING

21

UNIT II NUCLEAR REACTIONS


AND REACTION MATERIALS
Mechanism of nuclear fission and fusion- radio
activity- chain reactions-critical mass and
composition-nuclear fuel cycles and its
characteristics-uranium production and
purification-Zirconium, thorium, beryllium.
12/6/2014

ME 2034 NUCLEAR ENGINEERING

22

Mechanism of nuclear fission and fusion

12/6/2014

ME 2034 NUCLEAR ENGINEERING

23

Nuclear Fusion
Nuclear fusion is the process by which
multiple nuclei join together to form a heavier
nucleus.
It is accompanied by the release or absorption
of energy depending on the masses of the
nuclei involved.
Iron and nickel nuclei have the largest binding
energies per nucleon of all nuclei and therefore are
the most stable.
12/6/2014

ME 2034 NUCLEAR ENGINEERING

24

DEUTERIUM

FUSION

HELIUM

TRITIUM

12/6/2014

NEUTRON

ME 2034 NUCLEAR ENGINEERING

25

Nuclear Fusion
The fusion of two nuclei lighter than iron or
nickel generally releases energy.
The fusion of nuclei heavier than them
absorbs energy.

12/6/2014

ME 2034 NUCLEAR ENGINEERING

26

NUCLEAR FISSION
A reaction in which an atomic nucleus of a
radioactive element splits by bombardment
from an external source, with simultaneous
release of large amounts of energy, used for
electric power generation

12/6/2014

ME 2034 NUCLEAR ENGINEERING

27

Nuclear Fission
Neutron induced in
U235

Fission is Exothermic

The sum of the masses of


the resulting nuclei is less
than the original mass (about 0.1%
less)
The missing mass is converted to
energy
according to E=mc2 ME 2034 NUCLEAR ENGINEERING
12/6/2014

28

Neutrons may!
1 - Cause another fission by colliding with a U235 nucleus
Creates two smaller nuclides and free neutrons
The free neutrons potentially collide with nearby U235 nuclei
May cause the nuclide to split as well
Each split (fission) is
accompanied by a large
quantity of E-N-E-R-G-Y

2 - Be absorbed in other material


3 - Lost in the system
12/6/2014

ME 2034 NUCLEAR ENGINEERING

If sufficient neutrons are present, we may achieve a chain reaction

29

Chain reaction
Nuclear fission releases more neutrons which
trigger more fission reactions
The number of neutron released determines the
success of a chain reaction
One of the products of nuclear fission reactions are
neutrons. But these are free to hit other nuclei of U235 nearby, causing these to fission as well as
releasing additional neutrons. As this process carries
on, a huge amount energy is released. In fact, each
generation of fission neutrons takes only a fraction of
second to be produced. This is what happens in an
uncontrolled chain reaction such as the nuclear bomb.
12/6/2014

ME 2034 NUCLEAR ENGINEERING

30

12/6/2014

ME 2034 NUCLEAR ENGINEERING

31

Controlling chain reactions


We can use control rods inserted into the uranium to slow the chain
reaction down. These absorber rods contain atoms of Boron or
Cadmium that can absorb the fission neutrons without undergoing a
fission reaction themselves.
These rods ensure that an average of one further fission occurs
after every nucleus that splits. So, only one of the 2-3 neutrons
produced in the fission of a nucleus will hit another U-235 nucleus.
The other(s) will be absorbed by atoms in the rods.

12/6/2014

ME 2034 NUCLEAR ENGINEERING

32

Control rods

12/6/2014

ME 2034 NUCLEAR ENGINEERING

33

NUCLEAR FUEL CYCLE


The nuclear fuel cycle, also called nuclear
fuel chain, is the progression of nuclear
fuel through a series of differing stages.

12/6/2014

ME 2034 NUCLEAR ENGINEERING

34

Stages or Steps
It consists of steps in the front end
-which are the preparation of the fuel
steps in the service period
-in which the fuel is used during reactor
operation
steps in the back end
-In which are necessary to safely manage,
contain, and either reprocess or dispose
12/6/2014

ME 2034 NUCLEAR ENGINEERING

35

Stages or
Steps

12/6/2014

ME 2034 NUCLEAR ENGINEERING

36

Uranium Mining and Milling

12/6/2014

ME 2034 NUCLEAR ENGINEERING

37

Uranium mining
Excavation Technique
-In-situ Technique
-Open Pit
-Underground Mining

12/6/2014

ME 2034 NUCLEAR ENGINEERING

Recover uranium
ore

38

ISL in situ leaching

In-situ
12/6/2014

ISL
Oxygenated ground water
with slight acid or alkaline
Leaching agent oxygen with
sodium carbonate
Ion exchange separates the
uranium
After purification and drying
the yellow cake contains 80
percentage uranium is
obtained

ME 2034 NUCLEAR ENGINEERING

39

Uranium milling
The process extracting uranium from mined ore
Crushed and leached
Leaching is the process of
Leaching agent is
extracting minerals from a
solid by dissolving them in
- mostly sulfuric acid
a liquid
- alkaline can be used
These leaching agent not only extracts uranium and
also extracts some materials like vanadium,
selenium, iron, lead and arsenic.

12/6/2014

ME 2034 NUCLEAR ENGINEERING

40

Yellow cake

a drum of yellow cake

Final Product of Milling Step 70 to 80 % uranium


12/6/2014

ME 2034 NUCLEAR ENGINEERING

41

Enrichment and fabrication

12/6/2014

ME 2034 NUCLEAR ENGINEERING

42

Natural Uranium

235U
12/6/2014

only fissile nuclide only


1 atom of 235U in 140 atoms of 238U
ME 2034 NUCLEAR ENGINEERING

43

Enrichment
Process of increasing the amount of U-235
UF6 uranium hexafluoride is the feed

12/6/2014

ME 2034 NUCLEAR ENGINEERING

44

Methods
Gaseous diffusion
Gas centrifuge
Thermal diffusion

12/6/2014

ME 2034 NUCLEAR ENGINEERING

45

Gas centrifuge
Common enrichment method
High speed spinning cylindrical chamber

12/6/2014

ME 2034 NUCLEAR ENGINEERING

46

12/6/2014

ME 2034 NUCLEAR ENGINEERING

47

12/6/2014

ME 2034 NUCLEAR ENGINEERING

48

Thermal diffusion
Uses heat transfer across thin layer of liquid or
gas
Cooling a vertical film on one side and cooling on
other surface
It produces convection current
Flows upwards on hot downwards on cool surface
Lighter molecule U235 diffuse towards warm
surface
Heavier molecule U238 towards cooler surface
12/6/2014

ME 2034 NUCLEAR ENGINEERING

49

The combination of this diffusion and convection current


causes the lighter u235 molecule to concentrate on top
12/6/2014

ME 2034 NUCLEAR ENGINEERING

50

Fuel fabrication

into

UF6
UO2 powder then processed
into ceramic pellet of enriched uranium

Grinding process
to get uniform
pellet size

12/6/2014

ME 2034 NUCLEAR ENGINEERING

51

Pellets and Fuel Assembly

12/6/2014

ME 2034 NUCLEAR ENGINEERING

52

12/6/2014

ME 2034 NUCLEAR ENGINEERING

53

Fuel Rods

12/6/2014

ME 2034 NUCLEAR ENGINEERING

54

Fuel Assembly

12/6/2014

ME 2034 NUCLEAR ENGINEERING

55

BACK END
Storage
reactor shut down
Spent fuel
cooled aged fuel in modular
dry storage
ISFSI - Independent Spent
Fuel Storage Installation
Usually stored in water or boric acid
To protect the environment from ionizing
radiation
12/6/2014

ME 2034 NUCLEAR ENGINEERING

56

Spent Fuel

12/6/2014

ME 2034 NUCLEAR ENGINEERING

57

Spent
Storage pool

12/6/2014

ME 2034 NUCLEAR ENGINEERING

58

12/6/2014

ME 2034 NUCLEAR ENGINEERING

59

Reprocessing
Chemical operation separates useful fuel for recycling
from waste
Used fuel contains
95% of U238 but it contains
1% U235, 3% fission product which are highly
radioactive.
Hot nitric acid
dissolving metallic outer case
Reprocessing enables recycling of uranium and
plutonium into fresh fuel
12/6/2014

ME 2034 NUCLEAR ENGINEERING

60

Recycling
Uranium
direct
Plutonium
MOX
MOX
mixed oxide fuel in which uranium
and plutonium combined

12/6/2014

ME 2034 NUCLEAR ENGINEERING

61

Disposal
Radioactive waste is hazardous to most forms
of life and the environment
Radioactive waste has to be isolated and
confined in appropriate disposal facilities
There are no proper disposal facilities for the
used fuel

12/6/2014

ME 2034 NUCLEAR ENGINEERING

62

12/6/2014

ME 2034 NUCLEAR ENGINEERING

63

12/6/2014

ME 2034 NUCLEAR ENGINEERING

64

12/6/2014

ME 2034 NUCLEAR ENGINEERING

65

Zirconium
Zr
atomic number
used in nuclear reactors
Low

neutron

zirconium
High corrosion resistant
12/6/2014

40

Obtained
mainly from
the mineral
Zircon

Lustrous shiny, glossy


Grayish-white metal
Solid in room temp.
Highly flammable in power form

alkalis, acids, salt water .etc.

ME 2034 NUCLEAR ENGINEERING

66

12/6/2014

ME 2034 NUCLEAR ENGINEERING

67

12/6/2014

ME 2034 NUCLEAR ENGINEERING

68

Properties
Name

Zirconium

Symbol
Atomic number
Atomic Weight
Density
Melting Point
Boiling Point

Zr
40
91.224
6.511 g/cm3
1855 C
4409 C
solid

Phase

12/6/2014

ME 2034 NUCLEAR ENGINEERING

69

Occurrence
130 mg/kg
0.026 g/L
Source

within Earths crust


in sea water
zircon

Australia, Brazil, India, Malaysia, Russia and US.

Difficult to separate chemically


The annual production of Zirconium is 900,000
metric tone aprox.
12/6/2014

ME 2034 NUCLEAR ENGINEERING

70

Isotopes
Natural isotopes
5 isotopes 90Zr, 91Zr, 92Zr, 94Zr, 96Zr
Stable

Artificial isotopes
28 isotopes range from 78 to 110
12/6/2014

ME 2034 NUCLEAR ENGINEERING

71

a substance enclosed
under pressure and
released as a fine spray

Precautions

Inhalation
skin and lung Granulomas
Aerosols
pulmonary Granulomas
Persistent exposure
morality in rat
guinea pig and decrease of hemoglobin in dog
cells
Ingestion
causes cancer
12/6/2014

ME 2034 NUCLEAR ENGINEERING

72

Applications
Nuclear energy
low absorption cross
section for thermal neutron
Materials for rockets and other flying
machines
Manufacture super conductivity device
winding
Cut into Gemstones for use in jewelry
Zirconium carbonate is used in lotions to treat
poison
12/6/2014

ME 2034 NUCLEAR ENGINEERING

73

Beryllium
Rare element in earth
Be
atomic number
Beryllium
grey steel

Strong
Light weight

Used as hardening agent in alloys, like beryllium


copper
12/6/2014

ME 2034 NUCLEAR ENGINEERING

74

12/6/2014

ME 2034 NUCLEAR ENGINEERING

75

Properties
Highest melting point of the light metal
Elasticity is 3 times greater than steel
Low density
fastest sound conducting
speed
Excellent thermal conductivity
Nonmagnetic
12/6/2014

ME 2034 NUCLEAR ENGINEERING

76

Applications
Stiffness, light weight,
defense and aerospace
High speed aircraft
Alloying agent
Missiles
Space vehicles
Be-copper
Communication satellites

Electrical spring contact


Telescope
beryllium mirrors
12/6/2014

ME 2034 NUCLEAR ENGINEERING

77

Radiation applications
Nuclear applications
Compounds application

12/6/2014

ME 2034 NUCLEAR ENGINEERING

78

Thorium
Th
atomic number
90
Source
thorite and thorianite
India, US, Australia, Canada, Brazil, Malaysia,
south africa
Atomic number : 90
Discovered
: 1828
Melting point : 1,755 C
Boiling point
: 4,787 C
12/6/2014

ME 2034 NUCLEAR ENGINEERING

79

12/6/2014

ME 2034 NUCLEAR ENGINEERING

80

12/6/2014

ME 2034 NUCLEAR ENGINEERING

81

Precautions
Cancer
Lung diseases
Skin problem

12/6/2014

ME 2034 NUCLEAR ENGINEERING

82

END

12/6/2014

ME 2034 NUCLEAR ENGINEERING

83

Unit 3
Reprocessing
Nuclear fuel cycle spent fuel
characteristics role of solvent
extraction in reprocessing solvent
extraction equipment

12/6/2014

ME 2034 NUCLEAR ENGINEERING

84

Nuclear reprocessing
Separates any unstable elements from fission
products and other materiel used in nuclear
reactors fuels
Uranium
Plutonium
Thorium , etc,.
Fission products (waste)
Other materials
12/6/2014

ME 2034 NUCLEAR ENGINEERING

85

Spent nuclear fuel characteristics


Used fuel
Contains used waste materials and other
materials
Waste material
Fission product

Other material
Uranium
Plutonium
12/6/2014

ME 2034 NUCLEAR ENGINEERING

86

Spent fuel

12/6/2014

ME 2034 NUCLEAR ENGINEERING

87

Nuclear reprocessing methods


1. PUREX Plutonium and Uranium Recovery
EXtraction
2. UREX URanium EXtraction
3. TRUEX TRansuranic EXtraction
4. MOX Mixed Oxide
5. PYRO Pyrometallurgical processing
6. FLOUREX
12/6/2014

ME 2034 NUCLEAR ENGINEERING

88

PUREX
PUREX Plutonium and Uranium Recovery
EXtraction
Used to reprocess spent fuel only U and Pu
Irradiated fuel dissolved in nitric acid
Further by filtering, scrubbing, partitioning
and stripping process the U and Pu is
separated from the fission material
Results in a pure stream of plutonium
12/6/2014

ME 2034 NUCLEAR ENGINEERING

89

UREX
UREX URanium EXtraction
Used in high level nuclear waste reprocessing
It process 99.9 % of Uranium and 95 % of Technetium
are separated
AHA - Acetohydroxamic acid is used in scrubbing
section
AHA reduces the content of plutonium and Neptunium
Hence the clear form of uranium is obtained
Results in pure uranium stream
The plutonium remains mixed with the fission products
and minor actinides

12/6/2014

ME 2034 NUCLEAR ENGINEERING

90

TRUEX
TRUEX TRansuranic EXtraction
Designed to remove transplutonium metals
from waste
It uses second extraction agent
N-octyl ( phenyl) N
N- diisobutyl afbamoylmethylphosphine oxide in
combination with tributylphosphate (CMPO)

PUREX process can be turned into TRUEX


process using the second agent
12/6/2014

ME 2034 NUCLEAR ENGINEERING

91

MOX
MOX Mixed Oxide
Combination or bended form of uranium and
plutonium
MOX fuel is an alternative to low enriched
uranium fuel used in light water reactors
MOX is done in France and England
Lesser extent in Russia, India, Japan, China
To develop fast breeder reactors and reprocessing
12/6/2014

ME 2034 NUCLEAR ENGINEERING

92

PYRO Pyrometallurgical processing


chemical elements with atomic numbers from 89 to 103
Separating Actinides elements within the actinides
family
Spent fuel

heated

Mixed with molten salt


An electrical
current is applied
Actinides condense on the cathode

12/6/2014

Non actinides waste


ME
2034 NUCLEAR
remains
inENGINEERING
the salt

93

Advantages
Does not use water
Since water is problematic in nuclear chemistry

It tends to serve as moderator


Accelerate nuclear reactions
Easily contaminated
Not easily cleaned up
It tends to evaporate and takes away Tritium with it

Separates all actinides


More efficient and compact than PUREX
12/6/2014

ME 2034 NUCLEAR ENGINEERING

94

FLUOREX

It is a hybrid process involving


Fluoride volatility
Solvent extraction

Cost effective reprocessing of spent fuel


Separates Uranium in simple process
FLUOREX process is developed where fluoride
volatility process is used to purify Uranium
Extremely pure U and MOX fuels are recovered in
FLUOREX
It is also coast effective
12/6/2014

ME 2034 NUCLEAR ENGINEERING

95

Nuclear fuel cycle or chain


1. Front end
2. Service period
3. Back end
Two types of fuel cycle
Open fuel cycle (once - through fuel cycle)
Closed fuel cycle

12/6/2014

ME 2034 NUCLEAR ENGINEERING

96

once - through fuel cycle


Fuel is used once
sent to storage with out
processing
Method favored by six countries
US
Canada
Sweden
Finland
Spain
South Africa
12/6/2014

ME 2034 NUCLEAR ENGINEERING

97

once - through fuel cycle


Enrichment

Ore processing

Fuel
production

Fuel used for


disposal

Uranium mine

12/6/2014

Starts

Power reactor

ME 2034 NUCLEAR ENGINEERING

Ends

98

Plutonium Cycle
PU (+ U)

Enrichment

Ore processing

Fuel
production

Power reactor

Fuel used for


disposal

Uranium mine
Starts
12/6/2014

Reprocessing

Ends
ME 2034 NUCLEAR ENGINEERING

99

Several countries are using this process


offered by BNFL
COGEMA

Reprocessed uranium and plutonium are


fabricated as MOX fuel

12/6/2014

ME 2034 NUCLEAR ENGINEERING

100

Minor Actinides Recycling


Actinides
chemical elements with atomic numbers from 89 to 103
All actinides are radioactive, paramagnetic

Minor Actinides
Neptunium
Americium
Curium
Berkelium
Californium
Einsteinium
12/6/2014
Fermium

Major Actinides
U-92, Pu-94, ect..

ME 2034 NUCLEAR ENGINEERING

101

Minor Actinides Recycling

12/6/2014

ME 2034 NUCLEAR ENGINEERING

102

With a careful reactor design all the actinides


in the fuel can be consumed

12/6/2014

ME 2034 NUCLEAR ENGINEERING

103

Extraction
Liquid liquid extraction
Is a mass transfer operation
Liquid solution
the feed
Liquid solvent
to extract

Extract
The desired
extracted
solute
12/6/2014

ME 2034 NUCLEAR ENGINEERING

Liquid liquid

Raffinate
The residual feed
solution contains
little solute
(impurities)104

Solvent requirements

Feed

Raffinate

Extract

12/6/2014

Solvent

stageENGINEERING
extractor
MESingle
2034 NUCLEAR

105

F = Feed
R = Raffinate
S = Solvent
E = Extract

12/6/2014

Quantity in rate , mass

ME 2034 NUCLEAR ENGINEERING

106

Extraction in increased number of stages

F1 Xf

X1

1
Y1

12/6/2014

X2

2
Y2

Xn

3
Y3

ME 2034 NUCLEAR ENGINEERING

S Ys

107

Commercial Extractors
1. Mixer Settlers
o
o
o

Series of static mixer with settling stages


Mostly used in metal industry
Looks like vessel where feed and solvent are mixed and
settled

2. Centrifugal devices
o
o

High speed rotary machine


Mostly used in pharmaceutical or cosmetic industry

3. Column contractors
o
o
o
12/6/2014

Mostly used in chemical industry


Static or agitated
Examples are, static column, spray column, packed and
agitated column, rotating disc . Etc.
ME 2034 NUCLEAR ENGINEERING

108

Mixer - Settler
Mixing
The physical properties and viscosity determines
the amount of mixing
a very small drop of a liquid
Less mixing causes large droplets and decreases
interfacial area when two material are brought to contact, so the space
where they made contact is called interfacial area,
It is usually considered in heat transfer calculation

This reduces mass transfer and efficiency


Higher agitation more mixing, makes difficult to settle
droplets
12/6/2014

ME 2034 NUCLEAR ENGINEERING

109

Settling
Depends on the fluid properties and the amount of
mixing
Settling in agitated batch vessels is carried out by
stopping it.
Emulsions are formed due to agitation, in such cases it
takes extended period to settle
Emulsion can also form through inherent chemical
compounds
Some times coagulants are added to prevent emulsion
12/6/2014

Coagulation process which


suspends particles blood clot
ME 2034 NUCLEAR ENGINEERING

110

Mixer - Settler

12/6/2014

Extraction equipment
usedENGINEERING
in nuclear pre-processing
ME 2034 NUCLEAR

111

Mixer - Settler

12/6/2014

Uranium extractor
mixer
settler extractor
ME 2034 NUCLEAR
ENGINEERING

112

Mixer - Settler
recycling

Settler tank

--light liquid--

12/6/2014

Uranium extractor
mixer
settler extractor
ME 2034 NUCLEAR
ENGINEERING

113

Each stage consist of at least a mixer and a


settler
The liquid are pumped from one stage to the
next, but occasionally gravity flow can be
arranged if sufficient headroom is available
Light liquid flows by air lift and recycling of
settled lift liquid to the mixer is accomplished
by overflow

12/6/2014

ME 2034 NUCLEAR ENGINEERING

114

Advantages and disadvantage


Advantages

Efficient
Flexible
Offers wide range of capacities
Short shutdown

Disadvantage
large in size
Time
Cause solvent dehydration as a result of radiolysis and
hydrolysis
Maintenance
12/6/2014

ME 2034 NUCLEAR ENGINEERING

115

Pulsed columns
It is a solvent extractor
There is no individual extraction stages
They are continuous working
Modes of operation
First operation
Organic continuous mode

Second operation
Aqueous continuous mode

NUCLEAR ENGINEERING
Both are continuousME 2034
working
mode

12/6/2014

116

Operating principle
Solvent
light phase
Circulates bottom to top of a cylindrical tube
With a Aqueous
heavy phase
Disperses - Spreads in droplets
Immiscible with solvent
not forming a homogeneous mixture when mixed

Aqueous
continuou
s mode
12/6/2014

To generate and maintain this emulsion


the liquid are moved front and back
along the tube
expand and contract
Dispersing the organic phase in the aqueous phase
A pulsating motion is given on the light liquid by a flexible Diaphragm
ME 2034 NUCLEAR ENGINEERING

117

Pulsed column

12/6/2014

ME 2034 NUCLEAR ENGINEERING

118

The pulsating motion forces light and heavy liquids


alternatively through Perforation hole which is 1mm
in diameter
Advantages
No need of maintenance
Geometrically safe, even for high flow rates
Low sensitivity to interfacial crud

Drawbacks
Height
Limited flexibility

12/6/2014

ME 2034 NUCLEAR ENGINEERING

119

Centrifugal Extractor
Advantages
Compactness
Low in time
Minimizes solvent degradation
Offers wide range of capacities
Safe to use
They also reach equilibrium very quickly
12/6/2014

ME 2034 NUCLEAR ENGINEERING

120

Disadvantages
Very sensitive to process disturbances
Sensitive to the presence of crud or particles
Particle may settle and cause clogging
blocking

12/6/2014

ME 2034 NUCLEAR ENGINEERING

121

UNIT - IV
Nuclear Reactors
Nuclear reactors, types of fast breeding reactordesign and construction of fast breeding reactorsheat transfer techniques in nuclear reactorsreactor shielding. Fusion reactors

12/6/2014

ME 2034 NUCLEAR ENGINEERING

122

Nuclear reactor
Is similar to furnace of a steam power plant or combustion
chamber of a gas turbine
In this heat is produced due to nuclear fission chain reaction
The nuclear reactor consist of

12/6/2014

Reactor core
Moderator
Control rods
Cooling system
Reactor Vessel
Biological shielding

ME 2034 NUCLEAR ENGINEERING

123

Reactor core

12/6/2014

ME 2034 NUCLEAR ENGINEERING

124

12/6/2014

Prototype
type fast breeder reactor
ME 2034 NUCLEAR ENGINEERING
125

Fast breeder reactor

12/6/2014

ME 2034 NUCLEAR ENGINEERING

126

12/6/2014

ME 2034 NUCLEAR
Liquid metal
fastENGINEERING
breeder reactor

127

Gas cooled reactor

12/6/2014

ME 2034 NUCLEAR ENGINEERING

128

Lead cooled fast breeder

12/6/2014

ME 2034 NUCLEAR ENGINEERING

129

Pool layout sodium


cooled fast Reactor

12/6/2014

ME 2034 NUCLEAR ENGINEERING

130

12/6/2014

Compact layout sodium


cooled fast breeder

ME 2034 NUCLEAR ENGINEERING

131

12/6/2014

Super critical water reactor

ME 2034 NUCLEAR ENGINEERING

132

Molten Salt Reactor

12/6/2014

ME 2034 NUCLEAR ENGINEERING

133

12/6/2014

Molten salt reactor with multi-reheat


helium Brayton cycle
ME 2034 NUCLEAR ENGINEERING

134

12/6/2014

Very high
temperature reactor

ME 2034 NUCLEAR ENGINEERING

135

Heat transfer issue


for SCWR concept

12/6/2014

ME 2034 NUCLEAR ENGINEERING

136

Boiling water Reactor

12/6/2014

ME 2034 NUCLEAR ENGINEERING

137

CANDU
Reactor

12/6/2014

ME 2034 NUCLEAR ENGINEERING

138

12/6/2014

ME 2034 NUCLEAR ENGINEERING

139

UNIT V SAFETY AND DISPOSAL


Safety and disposal: Nuclear plant safety-safety
systems-changes and consequences of accidentcriteria for safety-nuclear waste-types of waste
and its disposal-radiation hazards and their
12/6/2014
ME 2034 NUCLEAR ENGINEERING
prevention-weapons
proliferation.

140

DISPOSAL
Radioactive waste is hazardous to most forms
of life and the environment
Radioactive waste has to be isolated and
confined in appropriate disposal facilities
There are no proper disposal facilities for the
used fuel

12/6/2014

ME 2034 NUCLEAR ENGINEERING

141

Nuclear Waste
Recently nuclear power has entered many discussions as world
energy needs rise and oil reserves diminish.

Most opponents of nuclear power point to two main arguments:


meltdowns and nuclear waste.
Nuclear waste is any form of byproduct or end product that

releases radioactivity.
How to safely dispose of nuclear waste is pivotal for the
continued operation of nuclear power plants, safety of people
living around dump sites, and prevention of proliferation of
nuclear materials to non-nuclear states.
12/6/2014

ME 2034 NUCLEAR ENGINEERING

142

Low Level Waste


LLW

Low level waste is any waste that could be


from a high activity area.
90% volume of waste
It does not necessarily carry any
radioactivity.
Split into four catagories: A, B, C, and GTCC.
12/6/2014

ME 2034 NUCLEAR ENGINEERING

143

Intermediate Level Waste


ILW

Intermediate level waste requires shielding


when being handled.
7% volume of waste
Dependent on the amount of activity it can
be buried in shallow repositories.
Not recognized in the United States.
12/6/2014

ME 2034 NUCLEAR ENGINEERING

144

High Level Waste


HLW

High level waste has a large amount of


radioactive activity and is thermally hot.
3% volume of waste
95% of radioactivity
Current levels of HLW are increasing about
12,000 metric tons per year.
Most HLW consists of Pu-238, 239, 240,
241, 242, Np-237, U-236
12/6/2014

ME 2034 NUCLEAR ENGINEERING

145

Front End Waste


Front end waste consists mostly of LLW and
ILW.
The primary front end waste is depleted
uranium and radium.
DU has several uses due to its high density
(19,050 kg/m3).
Mix with uranium to form reactor fuel
12/6/2014

ME 2034 NUCLEAR ENGINEERING

146

Service Period Waste


Consists of mostly ILW.
Mostly waste produced at the plant during
normal operation.
Spent fuel rods are the most dangerous
waste produced during the service period.

12/6/2014

ME 2034 NUCLEAR ENGINEERING

147

Launch it into Space


Near infinite storage
space
Completely removes
waste from biosphere
Technical risks and
problems
Political
entanglements
12/6/2014

ME 2034 NUCLEAR ENGINEERING

148

Importance of Nuclear Waste Management


Nuclear power carbon free energy source
Currently limited by economics, safety, and
technology
Clear limiting factor, lack of permanent disposal
Growth of nuclear capacity will require development
of permanent disposal options
Critical considerations
Safety
Security
12/6/2014

ME 2034 NUCLEAR ENGINEERING

149

Nuclear Waste

Composed of radionuclides
Low, Medium, and High-level waste
High-level waste produced in nuclear reactors
Consists of
Fission products (short-half lives)
Actinides (long-half lives)

Of note: 99Tc, 129I, 239Pu, 240Pu, 235U, 238U


12/6/2014

ME 2034 NUCLEAR ENGINEERING

150

Health Risks
Somatic Effects
Cancer

Genetic Effects
Hereditary Genetic Damage

Teratogenic Effects
Birth defects
Prenatal death
12/6/2014

ME 2034 NUCLEAR ENGINEERING

151

Important characteristics of
Radiation

Wavelength
Frequency
Intensity
Velocity
Straight line propagation
Spectrum
Inverse square law

12/6/2014

ME 2034 NUCLEAR ENGINEERING

152

Ultraviolet radiation hazards


Common sources: sun, UV lamps (black lights),
welders arc
Some devices may emit only a small amount of
visible light while emitting intense UV radiation
Especially dangerous to the eyes since they do not
dilate readily in response to UV -- retinal burns
Photosensitization to UV can occur from certain
dermal chemicals and oral drugs (e.g. antibiotics)
12/6/2014

ME 2034 NUCLEAR ENGINEERING

153

Types of UV Radiation
Type

Wavelength

Effect

UV-A

315-400 nm

Little effect

UV-B

280-315 nm

Skin cancer
possible

UV-C

100-280 nm

Cornea damage

Black light Region

12/6/2014

ME 2034 NUCLEAR ENGINEERING

154

Ionizing Radiation Characteristics

12/6/2014

Mass

Charge

Stopped by

Alpha

+2

4 cm air

Beta

-1

X-ray

6-300 cm
air
Lowered
10% by
15-30 cm
tissue

Gamma

0
ME 2034 NUCLEAR ENGINEERING

50 cm
tissue
155

Human radiation dose-effect data


DOSE (rems)

PROBABLE EFFECT

0-25
25-100
100-200

No noticeable effect
Slight blood changes
Vomiting, fatigue (recovery
in weeks)
Vomiting, severe blood
changes, hemmorhage
(recovery in 1-12 mo.)
Survival unlikely

200-600

600-1000
12/6/2014

ME 2034 NUCLEAR ENGINEERING

156

Ionizing radiation
General precautions
Confine radioactive chemicals to small areas
which are posted
Cover bench tops with plastic-backed absorbent
material
Use trays to catch spills
Wear gloves to protect hands and lab coat to
catch splatters
Dispose of contaminated clothes appropriately
12/6/2014

ME 2034 NUCLEAR ENGINEERING

157

Radiation monitoring devices


Film badges after the fact measurement,
developed weekly or monthly
Geiger counter best for high energy beta,
gamma
Scintillation counter used for wipe
surveys
12/6/2014

ME 2034 NUCLEAR ENGINEERING

158

End

12/6/2014

ME 2034 NUCLEAR ENGINEERING

159

S-ar putea să vă placă și