Documente Academic
Documente Profesional
Documente Cultură
7th semester
B.E, Mechanical Engineering
June 2014 Nov 2014
Prepared by
Mr. W. Aju Wilber
Assistant professor
EEE Department
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E = mc2
E = total energy of a system
M = total mass of the system
C = speed of light
If an object is not moving then:
Eo = moc2
Eo is the rest energy and mo is the rest mass
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Mass-Energy Equivalence
The law of conservation of energy
becomes a law of mass-energy
conservation.
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A fission reaction typically happens when a neutron hits a nucleus with enough energy to
make the nucleus unstable.
Fission breaks the nucleus into two smaller pieces and often releases one or more extra
neutrons.
Some of the energy released by the reaction appears as gamma rays and some as kinetic
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energy of the smaller nuclei and the extra neutrons.
Binding Energy
The mass of a nucleus is generally less than the
sum of the masses of the nucleons.
This difference is called the mass-defect. Such a
phenomenon is observed in atomic or subatomic
levels, and not with ordinary materials that we
handle, where the total mass has to be the sum
of the component masses.
The mass-defect is responsible for the binding
together of the nucleons.
The energy equivalent of the mass-defect is
called the binding-energy of the nucleus.
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Radioactivity
The emission of ionizing radiation or particles
caused by the spontaneous disintegration of
atomic nuclei.
Radioactive substances, or the radiation emitted
by these
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Half life
Half-life (t12) is the amount of time required for a
quantity to fall to half its value as measured at
the beginning of the time period. While the term
"half-life" can be used to describe any quantity
which follows an exponential decay, it is most
often used within the context of nuclear
physics and nuclear chemistrythat is, the time
required, probabilistically, for half of the
unstable, radioactive atoms in a sample to
undergo radioactive decay.
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The end
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Nuclear Fusion
Nuclear fusion is the process by which
multiple nuclei join together to form a heavier
nucleus.
It is accompanied by the release or absorption
of energy depending on the masses of the
nuclei involved.
Iron and nickel nuclei have the largest binding
energies per nucleon of all nuclei and therefore are
the most stable.
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DEUTERIUM
FUSION
HELIUM
TRITIUM
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NEUTRON
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Nuclear Fusion
The fusion of two nuclei lighter than iron or
nickel generally releases energy.
The fusion of nuclei heavier than them
absorbs energy.
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NUCLEAR FISSION
A reaction in which an atomic nucleus of a
radioactive element splits by bombardment
from an external source, with simultaneous
release of large amounts of energy, used for
electric power generation
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Nuclear Fission
Neutron induced in
U235
Fission is Exothermic
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Neutrons may!
1 - Cause another fission by colliding with a U235 nucleus
Creates two smaller nuclides and free neutrons
The free neutrons potentially collide with nearby U235 nuclei
May cause the nuclide to split as well
Each split (fission) is
accompanied by a large
quantity of E-N-E-R-G-Y
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Chain reaction
Nuclear fission releases more neutrons which
trigger more fission reactions
The number of neutron released determines the
success of a chain reaction
One of the products of nuclear fission reactions are
neutrons. But these are free to hit other nuclei of U235 nearby, causing these to fission as well as
releasing additional neutrons. As this process carries
on, a huge amount energy is released. In fact, each
generation of fission neutrons takes only a fraction of
second to be produced. This is what happens in an
uncontrolled chain reaction such as the nuclear bomb.
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Control rods
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Stages or Steps
It consists of steps in the front end
-which are the preparation of the fuel
steps in the service period
-in which the fuel is used during reactor
operation
steps in the back end
-In which are necessary to safely manage,
contain, and either reprocess or dispose
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Stages or
Steps
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Uranium mining
Excavation Technique
-In-situ Technique
-Open Pit
-Underground Mining
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Recover uranium
ore
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In-situ
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ISL
Oxygenated ground water
with slight acid or alkaline
Leaching agent oxygen with
sodium carbonate
Ion exchange separates the
uranium
After purification and drying
the yellow cake contains 80
percentage uranium is
obtained
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Uranium milling
The process extracting uranium from mined ore
Crushed and leached
Leaching is the process of
Leaching agent is
extracting minerals from a
solid by dissolving them in
- mostly sulfuric acid
a liquid
- alkaline can be used
These leaching agent not only extracts uranium and
also extracts some materials like vanadium,
selenium, iron, lead and arsenic.
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Yellow cake
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Natural Uranium
235U
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Enrichment
Process of increasing the amount of U-235
UF6 uranium hexafluoride is the feed
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Methods
Gaseous diffusion
Gas centrifuge
Thermal diffusion
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Gas centrifuge
Common enrichment method
High speed spinning cylindrical chamber
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Thermal diffusion
Uses heat transfer across thin layer of liquid or
gas
Cooling a vertical film on one side and cooling on
other surface
It produces convection current
Flows upwards on hot downwards on cool surface
Lighter molecule U235 diffuse towards warm
surface
Heavier molecule U238 towards cooler surface
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Fuel fabrication
into
UF6
UO2 powder then processed
into ceramic pellet of enriched uranium
Grinding process
to get uniform
pellet size
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Fuel Rods
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Fuel Assembly
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BACK END
Storage
reactor shut down
Spent fuel
cooled aged fuel in modular
dry storage
ISFSI - Independent Spent
Fuel Storage Installation
Usually stored in water or boric acid
To protect the environment from ionizing
radiation
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Spent Fuel
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Spent
Storage pool
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Reprocessing
Chemical operation separates useful fuel for recycling
from waste
Used fuel contains
95% of U238 but it contains
1% U235, 3% fission product which are highly
radioactive.
Hot nitric acid
dissolving metallic outer case
Reprocessing enables recycling of uranium and
plutonium into fresh fuel
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Recycling
Uranium
direct
Plutonium
MOX
MOX
mixed oxide fuel in which uranium
and plutonium combined
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Disposal
Radioactive waste is hazardous to most forms
of life and the environment
Radioactive waste has to be isolated and
confined in appropriate disposal facilities
There are no proper disposal facilities for the
used fuel
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Zirconium
Zr
atomic number
used in nuclear reactors
Low
neutron
zirconium
High corrosion resistant
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Obtained
mainly from
the mineral
Zircon
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Properties
Name
Zirconium
Symbol
Atomic number
Atomic Weight
Density
Melting Point
Boiling Point
Zr
40
91.224
6.511 g/cm3
1855 C
4409 C
solid
Phase
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Occurrence
130 mg/kg
0.026 g/L
Source
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Isotopes
Natural isotopes
5 isotopes 90Zr, 91Zr, 92Zr, 94Zr, 96Zr
Stable
Artificial isotopes
28 isotopes range from 78 to 110
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a substance enclosed
under pressure and
released as a fine spray
Precautions
Inhalation
skin and lung Granulomas
Aerosols
pulmonary Granulomas
Persistent exposure
morality in rat
guinea pig and decrease of hemoglobin in dog
cells
Ingestion
causes cancer
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Applications
Nuclear energy
low absorption cross
section for thermal neutron
Materials for rockets and other flying
machines
Manufacture super conductivity device
winding
Cut into Gemstones for use in jewelry
Zirconium carbonate is used in lotions to treat
poison
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Beryllium
Rare element in earth
Be
atomic number
Beryllium
grey steel
Strong
Light weight
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Properties
Highest melting point of the light metal
Elasticity is 3 times greater than steel
Low density
fastest sound conducting
speed
Excellent thermal conductivity
Nonmagnetic
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Applications
Stiffness, light weight,
defense and aerospace
High speed aircraft
Alloying agent
Missiles
Space vehicles
Be-copper
Communication satellites
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Radiation applications
Nuclear applications
Compounds application
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Thorium
Th
atomic number
90
Source
thorite and thorianite
India, US, Australia, Canada, Brazil, Malaysia,
south africa
Atomic number : 90
Discovered
: 1828
Melting point : 1,755 C
Boiling point
: 4,787 C
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Precautions
Cancer
Lung diseases
Skin problem
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END
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Unit 3
Reprocessing
Nuclear fuel cycle spent fuel
characteristics role of solvent
extraction in reprocessing solvent
extraction equipment
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Nuclear reprocessing
Separates any unstable elements from fission
products and other materiel used in nuclear
reactors fuels
Uranium
Plutonium
Thorium , etc,.
Fission products (waste)
Other materials
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Other material
Uranium
Plutonium
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Spent fuel
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PUREX
PUREX Plutonium and Uranium Recovery
EXtraction
Used to reprocess spent fuel only U and Pu
Irradiated fuel dissolved in nitric acid
Further by filtering, scrubbing, partitioning
and stripping process the U and Pu is
separated from the fission material
Results in a pure stream of plutonium
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UREX
UREX URanium EXtraction
Used in high level nuclear waste reprocessing
It process 99.9 % of Uranium and 95 % of Technetium
are separated
AHA - Acetohydroxamic acid is used in scrubbing
section
AHA reduces the content of plutonium and Neptunium
Hence the clear form of uranium is obtained
Results in pure uranium stream
The plutonium remains mixed with the fission products
and minor actinides
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TRUEX
TRUEX TRansuranic EXtraction
Designed to remove transplutonium metals
from waste
It uses second extraction agent
N-octyl ( phenyl) N
N- diisobutyl afbamoylmethylphosphine oxide in
combination with tributylphosphate (CMPO)
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MOX
MOX Mixed Oxide
Combination or bended form of uranium and
plutonium
MOX fuel is an alternative to low enriched
uranium fuel used in light water reactors
MOX is done in France and England
Lesser extent in Russia, India, Japan, China
To develop fast breeder reactors and reprocessing
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heated
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Advantages
Does not use water
Since water is problematic in nuclear chemistry
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FLUOREX
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Ore processing
Fuel
production
Uranium mine
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Starts
Power reactor
Ends
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Plutonium Cycle
PU (+ U)
Enrichment
Ore processing
Fuel
production
Power reactor
Uranium mine
Starts
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Reprocessing
Ends
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Minor Actinides
Neptunium
Americium
Curium
Berkelium
Californium
Einsteinium
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Fermium
Major Actinides
U-92, Pu-94, ect..
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Extraction
Liquid liquid extraction
Is a mass transfer operation
Liquid solution
the feed
Liquid solvent
to extract
Extract
The desired
extracted
solute
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Liquid liquid
Raffinate
The residual feed
solution contains
little solute
(impurities)104
Solvent requirements
Feed
Raffinate
Extract
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Solvent
stageENGINEERING
extractor
MESingle
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F = Feed
R = Raffinate
S = Solvent
E = Extract
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F1 Xf
X1
1
Y1
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X2
2
Y2
Xn
3
Y3
S Ys
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Commercial Extractors
1. Mixer Settlers
o
o
o
2. Centrifugal devices
o
o
3. Column contractors
o
o
o
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Mixer - Settler
Mixing
The physical properties and viscosity determines
the amount of mixing
a very small drop of a liquid
Less mixing causes large droplets and decreases
interfacial area when two material are brought to contact, so the space
where they made contact is called interfacial area,
It is usually considered in heat transfer calculation
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Settling
Depends on the fluid properties and the amount of
mixing
Settling in agitated batch vessels is carried out by
stopping it.
Emulsions are formed due to agitation, in such cases it
takes extended period to settle
Emulsion can also form through inherent chemical
compounds
Some times coagulants are added to prevent emulsion
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Mixer - Settler
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Extraction equipment
usedENGINEERING
in nuclear pre-processing
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Mixer - Settler
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Uranium extractor
mixer
settler extractor
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ENGINEERING
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Mixer - Settler
recycling
Settler tank
--light liquid--
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Uranium extractor
mixer
settler extractor
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Efficient
Flexible
Offers wide range of capacities
Short shutdown
Disadvantage
large in size
Time
Cause solvent dehydration as a result of radiolysis and
hydrolysis
Maintenance
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Pulsed columns
It is a solvent extractor
There is no individual extraction stages
They are continuous working
Modes of operation
First operation
Organic continuous mode
Second operation
Aqueous continuous mode
NUCLEAR ENGINEERING
Both are continuousME 2034
working
mode
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Operating principle
Solvent
light phase
Circulates bottom to top of a cylindrical tube
With a Aqueous
heavy phase
Disperses - Spreads in droplets
Immiscible with solvent
not forming a homogeneous mixture when mixed
Aqueous
continuou
s mode
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Pulsed column
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Drawbacks
Height
Limited flexibility
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Centrifugal Extractor
Advantages
Compactness
Low in time
Minimizes solvent degradation
Offers wide range of capacities
Safe to use
They also reach equilibrium very quickly
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Disadvantages
Very sensitive to process disturbances
Sensitive to the presence of crud or particles
Particle may settle and cause clogging
blocking
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UNIT - IV
Nuclear Reactors
Nuclear reactors, types of fast breeding reactordesign and construction of fast breeding reactorsheat transfer techniques in nuclear reactorsreactor shielding. Fusion reactors
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Nuclear reactor
Is similar to furnace of a steam power plant or combustion
chamber of a gas turbine
In this heat is produced due to nuclear fission chain reaction
The nuclear reactor consist of
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Reactor core
Moderator
Control rods
Cooling system
Reactor Vessel
Biological shielding
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Reactor core
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Prototype
type fast breeder reactor
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ME 2034 NUCLEAR
Liquid metal
fastENGINEERING
breeder reactor
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Very high
temperature reactor
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CANDU
Reactor
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DISPOSAL
Radioactive waste is hazardous to most forms
of life and the environment
Radioactive waste has to be isolated and
confined in appropriate disposal facilities
There are no proper disposal facilities for the
used fuel
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Nuclear Waste
Recently nuclear power has entered many discussions as world
energy needs rise and oil reserves diminish.
releases radioactivity.
How to safely dispose of nuclear waste is pivotal for the
continued operation of nuclear power plants, safety of people
living around dump sites, and prevention of proliferation of
nuclear materials to non-nuclear states.
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145
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Nuclear Waste
Composed of radionuclides
Low, Medium, and High-level waste
High-level waste produced in nuclear reactors
Consists of
Fission products (short-half lives)
Actinides (long-half lives)
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Health Risks
Somatic Effects
Cancer
Genetic Effects
Hereditary Genetic Damage
Teratogenic Effects
Birth defects
Prenatal death
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Important characteristics of
Radiation
Wavelength
Frequency
Intensity
Velocity
Straight line propagation
Spectrum
Inverse square law
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Types of UV Radiation
Type
Wavelength
Effect
UV-A
315-400 nm
Little effect
UV-B
280-315 nm
Skin cancer
possible
UV-C
100-280 nm
Cornea damage
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Mass
Charge
Stopped by
Alpha
+2
4 cm air
Beta
-1
X-ray
6-300 cm
air
Lowered
10% by
15-30 cm
tissue
Gamma
0
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50 cm
tissue
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PROBABLE EFFECT
0-25
25-100
100-200
No noticeable effect
Slight blood changes
Vomiting, fatigue (recovery
in weeks)
Vomiting, severe blood
changes, hemmorhage
(recovery in 1-12 mo.)
Survival unlikely
200-600
600-1000
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Ionizing radiation
General precautions
Confine radioactive chemicals to small areas
which are posted
Cover bench tops with plastic-backed absorbent
material
Use trays to catch spills
Wear gloves to protect hands and lab coat to
catch splatters
Dispose of contaminated clothes appropriately
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End
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