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Part 1
Straight Objective Type
This section contains 8 multiple choice questions numbered 1 to 8. Each question has 4 choices (A), (B),
(C) and (D), outt of which ONLY ONE is correct.
1. A disc of radius R is rolling without slipping on a fixed
circular track of radius 2R. Line joining the centre of the disc
and centre (O) of circular track is rotating with constant
angular velocity in clockwise sense. A rod AB whose end
A is attached to a small ring which can move only along a
fixed horizontal rod and other end of rod B is pivoted at B,
R/2 distance above centre of disc as shown. Find the angular
velocity of rod AB at the instant when rod AB is making an
angle 30 with horizontal and centre of the disc is directly
above the centre (O) of the track as shown in figure.(Assume
rod can rotate freely about hinge point B)
(A) Zero
(B)
(C)
(D)
2. Two blocks A and B of masses m and 2m respectively are connected together by a light spring of
stiffness
fness k and then placed on a smooth horizontal surface. The blocks are pushed towards each
other the block A by the spring, by the time the spring acquires its natural length, is
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
!
"# !
!
"# !
$
$
%
$
&
&$
)3*+',-.' / 01,' 2 1
(
)*+',-.' / 01,' 2 1
(
)*+',-.' / 01,' 2 1
(
)6*+',-.' / 01,' 2 1
(
5 /
9
(D) 15N(-7
10. In the previous problem initial elongation in the spring is
(A)
(B)
(C)
(D)
m
=
(D)
?
?
12. The angular speed of A with respect to D is (when string become taut)
(A)
(B)
(C)
(D)
?
?
?
&
?
?
?
?
?
14. Find the angular velocity of disc A at the instant of maximum compression in the spring
(A)
(B)
(C)
(D)
?
?
?
?
horizontal
zontal axis coinciding with the diameter passing through open ends. First the wire is taken
aside such that its plane becomes horizontal and then it is released from rest. Choose the
(B) Vertical component of force exerted by the axis on the wire is 552 N
F
(B) The tension in the string at the bottom most position equals to m G / 5*,-.'
*,-.'!.
F
(C) The tension in the string as the sphere passes the 90 position B equals to m G / 2*,-.'!.
F
(D) The tension in the string at the bottom most position equals to m G 2 5*,-.'
*,-.'!.
18. In the adjacent figure, a uniform disc of mass 2m and radius l/2
and radius l/2
/2 is lying at rest on a smooth horizontal surface. A
particle A of mass m is connected to a light string of length l ,
whose other end is attached to the circumference of the disc.
Initially string is just taut and tangential to the disc, particle A is
at rest. In the same horizontal plane another particle B of same
mass m moving with velocity > perpendicular to string collides
elastically with A. just after impact which of the following
statements will be true
(A) Tension in the string is
?
=G
(B) Acceleration
leration of the centre of the disc is
(C) Tension in the string is
?
=G
?
=G
?
=G
19. In the adjacent figure a block A of mass m is hanging vertically with the help of a light
inextensible string which is passi
passing
ng over massless and frictionless pulley its other end is attached
to block C of mass 2M as shown in the figure
figure. Pulley is fixed
to the block B of mass 2M as shown. Then, (ignore any
friction)
(A) Tension in the string immediately after system is
I$
I$
I$
JI
I
$
(C) The acceleration of block of mass m immediately after system is released from rest is JI
$
(D) The acceleration of block of mass m immediately after system is released from rest is J I
?
Chemistry
Part 2
Straight Objective Type
This section contains 8 multiple choice questions numbered 1 to 8. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.
1. Which observation did not contribute to the development of Bohrs model of the atom?
(A) Photons have specific frequency and wavelength
(B) Electrons have dual nature (wave
(wave-particle duality)
(C) Light is emitted by K gas at low pressure when electricity is passed through it
(D) The nuclear model proposed by
Rutherford
2. What wavelength of light is required to
convert
Given bond enthalpies: N=N (711 kj/mole)
N-N
N (163 kj/mole)
(A) 218 nm
(B) 310 nm
(C) 425 nm
(D) 612 nm
3. Boron nitride is reffered to as white graphite because it is lubricious material with the same
platy hexagonal structure as black graphite (Carbon graphite).
Which of the following properties of hBN is untrue?
(A) Hcp unit cell
(B) High thermal conductivity
(C) High electrical resistance
(D) Chemically inert
4. Lanthanum (III) chloride is a white hygroscopic powder which attains the following equilibrium
in a sealed vessel:
LaCL (s)+ K M (g) LaCIO (s)+ 2HCI(g)
More water vapour is added and the equilibrium is allowed to re-establish. If at new
equilibrium, OP Q has doubled, OPRS increases:
(A) 2 times
(B) 2 times
(C) 3 times
(D) 3 times
5. Electron capture accomplishes the same end result for the nucleus as:
(A) emission
(B) T C emission
(C) T J emission
(D) U emission
6. If the reaction A + B P is exothermic to the extent of 30 kcal/mole and V for the forward
reaction is 294 kj/mole, V for the backward reaction in kcal/mole is:
(A) 324
(B) 264
(C) 100
(D) 40
7. Which physical constant for K M has higher magnitude than W M:
(A) Boiling point
is Z . x+y is
(A)
(B)
(C)
(D)
6
7
8
9
Comprehensive Type
This section contains 3 groups of questions. Each group has 2 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
correct.
[\ = 10C
K OM
C K J + K OM
C
[ = 10C]
K OM
C K J + K OM
C
[^ = 10C
9. If 1,2,3,4 moles of K OM
, NaK OM
, N KOM
and N OM
respectively are mixed together to
form an aqueous solution, resulting pH is:
(A) 8
(B) 9
(C) 10
(D) 12
10. If 2.5 mole each of K OM
, NaK OM
, N KOM
and N OM
are mixed together to form an
aqueous solution, resulting pH is
(A) 5
(B) 7
(C) 9
(D) 11
Paragraph for questions Nos. 11 to 12
The isomerisation of cyclopropane K% to propene is believed to occur by the following mechanism:
Step-1: K% + K% K% + K%
Step-1: K% CK - CH = CK
11. At low pressure, step-1 unindirectional and slow whereas step-2 is bidirectional and fast. Order
of the reaction is:
(A) 0
(B) 1
(C) 2
(D) 3
12. At high pressure, step-1 is bidirectional and fast whereas step-2 is unidirectional and slow. Order
of the reaction is:
(A) 0
(B) 1
(C) 2
(D) 3
Paragraph for Question Nos. 13 to 14
Redox reaction involves transfer of electrons between 2 chemical species. An unbalanced and
incomplete example is shown below:
` + K OM H` + O
M%
13. If the above reaction were possible in either direction, maximum equivalent weight would
belong to:
(A) `
(B) K OM
(C) K`
(D) O
M%
14. If the above reaction were unidirectional towards right, what fraction of O
M% would be left
unreacted if reaction were started with stoichiometric amount of reactants.
(A)
(B)
(C)
(D)
(B) `K aK
(C) K
(D) baK
16. If equatorial plane in PCL= molecule is the X-Y plane, the orbitals hybridizing to produce axial
bonds will be:
(A) cd
(B) e
Cf
(C) cf
(D) ed
17. Which of the following anions is/are bigger than hydride ion(K C )
(A) g C
(B) L C
(C) ah C
(D) L C
18. Which of the following changes can be experimentally realized in the laboratory:
(A) Combustion of Mg ribbon in CM
(B) Reduction of FeCL (aq.) on adding Zn granules
(C) Dry heating of hydrated MgCL to get anhydrous MgCL
(D) Evolution of brown gas on heating LiNM
19. Which digits would appear as stoichiometric coefficient of either reactant or product when the
following skeletal redox reaction is balanced:
ib.M
+ K j + K jM
iKjM
+ b.jM
+ b.jM
+ j + K M
(A) 2
(B) 4
(C) 6
(D) 8
20. Identify the correct sequencing of hydrides based on the parameter specified in bracket:
(A) NK > OK > l,K > jmK (bond angle)
(B) SbK > `K > l,K > OK (boiling point)
(C) NK > OK > l,K > jmK (dipole moment)
(D) NK > OK > l,K > jmK (basic nature)
Mathematics
Part 3
Straight Objective Type
This section contains 8 multiple choice questions numbered 1 to 8. Each question has 4 choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.
(B)
(C)
(D)
(C) Is equal to 0
(D) Does not exist
3. Let f be a differentiable function such that |y| 1 }1,1 and g(x) = |y|, g(0) = 4,
then choose the correct statement
(A) There is no point x in the interval (-1,0) at which g(x) 2
(B) g(x) > 2 (0,1)
(C) there is a point of local maxima of g(x) in (-1,1)
(D) x=0 is a point of local maxima of g(x)
4. v
"# J
J
J !J
;
J !
^
^
;
(A)
(B)
J ;
J !
^
;
(C)
J ; J !
J ;
J !
dx, is
+0
+0
+0
=
^ C
f C
, is
fCf ^
f C
C
B.C
C ! = 0
f C
C
B.C
C ! = 0
f C
C
2B.C
C ! = 0
(B) In|
4 + 5
+ 2 + 2| +
(C) In|
4 + 5
+ 2 + 2| +
(D) In|
4 + 5
+ 2 + 2| 2B.C
6. The value of v
(A) )22
J ^/
e, is
f C
C
!
C
=0
(B) )32
(C) )23
(D) )33
=
,. .-B,.
,. .-B,.
&
,. .-B,.
&
,. .-B,.
Comprehension type
This section contains three groups of questions. Each group has two multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which only one is
correct.
Paragraph for question Nos. 9 and 10
Read the following write up carefully and answer the following questions:
Let y =
,
9. If A is the area of the region bounded by = *, x axis, the line = x and the line = x,
then the value of A lies in the interval
(A) 0, %!
(B) % , !
(C) , !
(D) , 1!
10. The slope of tangent to the curve = *, 0, @ at the point where it meets the curve
= 1, is
x
x
x
x
(A)
(B)
(C)
(D)
(D) 6
+ C = 2, (where k is a parameter)
+
, (where k is a parameter)
C
f
+ C = 1, (where k is a parameter)
(C) =
(D)
Y C
.
Y J
The graphs of y = f(x) and y = f(4x) are symmetrical about the points (a1, 0)
(B) a1 = 2, a2 =
(C) v y2e = 1
(D) v y2e = 0
16. Let g(x) = f(x) + f(1-x) where f(x) = sin@ , 0,1 then
(A) g(x) = y ! y
C
!
(D)
/ ;x
< v
C
e < 2
Cx
17. Let f(x) = 5x tan x + 8sin(tan x) + 5ln(cos x), then in the interval
, 0!
(A)
(B)
(C)
(D)
F(x) is increasing
F(x) has a point of local maxima
F(x) has a root
F(x) is always negative
Cx x
Cx
Cx x
19. Let f be any twice differentiable function x + and x = b be its points of local maxima and local
minima respectively then
(A) y = [f(x)], ([.] denotes the G.I.F) must be continuous at x = a
(B) y = [f(x)], ([.] denotes the G.I.F) must be continuous at x = b
(C) f(a) must be negative
(D) f(b) must be negative
/
2 ! dx, then
/
v
1
e
v 1
e
20. let | = v
(A) | =
(B) | =
x/
(C) | = v
(D) | = %
ANSWER KEY
Q. No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Physics
A
D
B
C
B
C
D
A
C
A
B
A
C
A
A,B,D
C,D
B,C
A,B
A,C
B,C
Chemistry
B
A
A
B
C
C
C
C
C
B
C
B
C
D
A,B,C
A,D
B,C,D
A,B,D
A,B,D
A,B,C,D
Mathematics
A
C
C
C
D
B
A
A
B
B
B
B
A
C
B,D
A,B,C,D
A,D
A,B,C
B,D
A,B,C,D