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EXPERIMENT
DATE PERFORMED
SEMESTER
PROGRAM
SUBMIT TO
No.
Title
1
2
3
4
Procedure
Process Flow Diagram (PFD)
Workbook/Stream Summary
Questions & Discussions
10
20
30
40
TOTAL MARKS
Remarks:
Checked by:
100
Marks
TABLE OF CONTENT
Objective
Procedure
2-3
Workbook/stream summary
5-6
Discussion
Conclusion
Reference
OBJECTIVE
1. To install and converge a plug flow reactor
2. To simulate a process involving reaction
PROCEDURE
1.
Firstly ,a new iCON project is started by selecting the New Project Button.
2.
In the window , All Property package from the Chemical System Categories is
selected.
3.
Add
all
the
chemicals
being
used
which
are
Acetone(C2H6O),
In the Visio PFD flowsheet, all the equipments involved in production of acetic
anhydride were put in correct order.
5.
The stream was chosen and labeled FEED then the Plug Flow Reactor(PFR) is added
and connected to the outlet stream Stream_out.
6.
7.
Pressure
: 150 kPa
Mass flow
: 8000 kg/hr
In order to adjust the composition of the feed stream, click the Composition button:
Acetone : 1.00
Ketene : 0.00
Methane: 0.00
2
6.
All the information given is being key in the streams and reactors.
Hint:
Qout = 0 W, P = 50 kPa
Assume :
Length: 30 m
Inner diameter: 0.5 m
Kinetics :
Forward: A = 8.2 x 1014 , E = 2.85 x 105 kJ/mol
Reverse: A = 0, E = 0
The length and inner diameter can be changed to achieve specific goal.
8. The simulation is run by clicking the run button and the result are obtained which will
be discussed in the discussion section and to answer the question given.
Based on the figure above, it shows the PFD for the production of acetic anhydride. Vapour
phase cracking of acetone is used in order to produce ketene and methane.
C2H6O
C2H2O+ CH4
This reaction is first order with respect to acetone. The energy out is Q(out)=0 W
STREAM SUMMARY
Name
Feed
Stream_out
Description
Upstream Op
PFR-1.Out
Downstream Op
VapFrac
T [C]
P [kPa]
MoleFlow/Composition
PFR-1.In
1.00
1.00
760.0
642.0
150.00
100.00
Fraction
kmol/h
Fraction
kmol/h
ACETONE
1.00000
137.74
0.66637
110.17
KETENE
0.00000
0.00
0.16681
27.58
METHANE
0.00000
0.00
0.16681
27.58
1.00
137.74
1.00
165.32
Total
Mass Flow [kg/h]
Volume Flow [m3/h]
Std Liq Volume Flow [m3/h]
Std Gas Volume Flow [Sm3/d]
8000.00
8000.00
7888.098
12579.257
10.044
11.216
7.8317E+4
9.3996E+4
Energy [W]
4.182E+6
3.456E+6
H [kJ/kmol]
109297.0
75254.4
381.335
302.483
S [kJ/kmol-K]
MW
Mass Density [kg/m3]
Cp [kJ/kmol-K]
Thermal Conductivity [W/m-K]
Viscosity [Pa-s]
58.08
48.39
1.0142
0.6360
166.152
129.756
0.1223
0.0984
2.6609E-5
2.4650E-5
57.267
76.090
Z Factor
1.0000
1.0000
Surface Tension
Speed of Sound
The diagram shows the volume for the volume of PFR to achieve at least 20% conversion of
acetone is 0.044m3 which the length is 13.01m and the inner diameter is 6.550cm.
QUESTIONS
What is the volume of PFR to achieve at least 20% conversion of acetone?
Based from the result, to achieve at least 20% conversion of acetone the volume of PFR is
0.044 m3. The flow rate of the feed is 137.74 kgmole/hr and the stream out is 110.19
kgmole/hr. The length and diameter was adjusted until the conversion is 20%. From the table,
the length is 13.01m and the diameter is 6.55cm.
DISCUSSION
The objective of this experiment is to determine the volume, length, and diameter of the PFR
for desired conversion of product. In this experiment, the desired conversion of acetone is
20%. In order to get the 20% conversion, the length and diameter are adjusted. When the
length and diameter were adjust, the flow of the feed and stream out of the product will
change significantly. Thus, the conversion can be determine from the flow of the feed and
product by using equation. In this experiment, to get the 20% conversion, the length is
13.01m and the diameter of the PFR is 6.55cm. The result also show the volume of the PFR
which is 0.044m3. In real situation, to build a PFR reactor, a certain specification shoud be
follow. An ICON software is a theoretically calculation in order to get the 1 st idea of
manufacture of the reactor.
A plug flow reactor (PFR) is a type of chemical reactor where the influent is pumped into the
pipe. Chemical reactions occur through the length of the PFR and the reaction rate is not a
constant. A conversion factor is a ratio (or fraction) which represents the relationship between
two different units. A conversion factor is always equal to 1.
CONCLUSION
As conclusion, a desired conversion of a product can be achieve by adjusting the length and
diameter of the PFR reactor.
REFRENCE
1. Springer Production, 2007, Chemical Reactor Development: from Laboratory
Synthesis to Industrial Production By D. Thoenes.
2. Plug Flow Reactor,
http://www.umich.edu/~elements/5e/asyLearn/bits/pfrfinal/index.htm
3. Mann, U. (2009) Plug-Flow Reactor, in Principles of Chemical Reactor Analysis and
Design: New Tools for Industrial Chemical Reactor Operations, Second Edition, John
Wiley & Sons, Inc.,
4. Held, H., Rengstl, A. and Mayer, D. 2000. Acetic Anhydride and Mixed Fatty Acid
Anhydrides. Ullmann's Encyclopedia of Industrial Chemistry. .