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Gaseous Fuels:
Vs Diesel: Cetane # of 0.
Types of coal:
1.
Low rank coals 47%:
lignite 17% Power Generation
Sub-bituminous 30% Power Generation,
Cement Manufacture, Industrial uses. (*)
2.
Hard coal 53% :
Bituminous 52%
Challenges:
Equilibrium
Gibbs free energy: At equilibrium, the Gibbs function, G,
is at a minimum for an isothermal, isobaric fixed-mass
system.
Alkanes (CnH2n+2):
Conservation of Mass
Combustion: exothermic process where fuels are rapidly
oxidized.
Flame:
For T>3000K
1)
Add the specie NO
2)
NO N2 + O2
3)
NO important as a pollutant above 1700K
For T>3500K
1)
Add the specie N
2)
N2 2N CO and
m+n denotes
overall
reaction order.
Global reactions are only accurate close to
conditions used to determine their constants.
Global Reaction: A single reaction containing
initial reactants and final products,
representing an entire combustion process.
e.g. 2H2 + O2 2H2O
Elementary Reaction: A chemical reaction in
which species react directly to form products in
At equilibrium:
From before:
As xi P = [ ]i RT:
Types of reactions:
CH3 + O CH2O + H
HCO + M H + CO + M
CO + OH CO2 + H
Alkane oxidation:
Chain Initiation:
RH R + H where RH is an alkane
H Abstraction:
RH + OH R + H2O
CO + OH CO2 + H.
Thermal Oxidation:
2.
Temperature (added fuel)
3.
Turbulent Mixing with Oxygen (added air)
T99: Temperature needed to destroy 99% of a
compound in 1 second.
NOX Emissions
Ground Level Ozone:
NOx Formation:
1.
Thermal NO (N2 from air)
2.
Fuel NO (N from fuel)
3.
Prompt NO (N2 reacting with HCs)
Thermal NO:
Control:
1.
Reduce Peak Temperature. Exhaust Gas
Recirculation (or Flue Gas Recirculation).
Lowers temperature in cylinder and thus NOx
but also reduces output power.
2.
Reduce time. Quick quench.
3.
Reduce oxygen concentration at highest
temperature zone. Low excess air.
4.
Reduce nitrogen concentration. Oxy-fuel
burners.
CxHyNz + mO2 NO + .
Mechanism:
1.
Fuel N HCN
2.
Then, NO formation similar to Prompt NOx
Staging Methods:
1.
Overfire Air. Separate air injection. NOx
Reduction by 40 to 60 percent.
2.
Low NOx burners. Staging within burner.
NOx Reduction of 30 to 55 percent
Catalytic Converter:
Application: Gasoline (SI) engines Engine
Modifications: fuel air ratio controlled to near
stoichiometric (equivalence ratio of approx. 1),
need oxygen sensor, computer control & air/fuel
control Fuel Change
Lead and sulfur eliminated Problems
Poor performance at low startup temperature
Selective Catalytic Reduction:
NO converted to N2 by NH3 (ammonia) and a
platinum catalyst in the presence of oxygen:
4 NO + 4 NH3 +O2 4 N2 + 6 H2O
T from 500-800K
Over 90% removal can be achieved
Catalysts can become fouled by aluminum
sulfates from fuel sulfur.
Applications:
Gasoline (S.I.) engines:
Conditions: Premixed Combustion, =1, high
pressure.
NOx formation. Mostly thermal NOx with
equilibrium O. Some prompt NO and thermal
NOx with super equilibrium O.
NOx Control: EGR (5-15%), Catalytic converter.