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Basics in Welding and Weldability

HGRS/MTC

Objective
Outline the most important concepts and rules of

welding in the cement industry


Create awareness around the main key success

factors of high quality welding


Provide examples from the cement industry

Maintenance training

"Basics in Welding and Weldability"

Agenda
Welding process
Weldability of steels
Welding techniques
Welding defects
Practical examples



Kiln shell crack repair


Hydrogen induced cracks

Conclusions

Maintenance training

"Basics in Welding and Weldability"

Welding process
The process of welding employs the heat of an

external source (usually electrical arc) to bring metals


to be welded to a molten state. The metals fusing
takes place almost instantaneously
From this point of view, welding has many similarities

with steel heat treatments, especially Quenching and


this has to be taken in consideration

Maintenance training

"Basics in Welding and Weldability"

Welding process
Carbon Iron Diagram

. Quenching is a heat
treatment which
objective is to form a
very hard and resistant
(but brittle) martensite
structure: The material
is heated until it
reaches its austenitic
structure and then
directly cooled down to
the ambient
temperature

"Basics in Welding and Weldability"

Maintenance training

Welding process
200C
600C
900C
1000C
1400C

In a welding process, there are 2


main operations :
1. Melting and fusing in the zone
under the arc
2. Heat treatment in the area around
The higher the cooling speed is,

Heat Affected
Zone : HAZ

the higher is the amount of


martensite structure formed
Martensite is a very hard, resistant

but brittle steel structure


Preheating is used to reduce the
cooling rate (speed) after welding
3mm
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Maintenance training

"Basics in Welding and Weldability"

Welding process

Maintenance training

"Basics in Welding and Weldability"

Welding process
In general molten steels have a strong affinity for

oxygen, nitrogen and hydrogen : if the welding


atmosphere is not controlled, the molten metal will
pick-up some oxygen or/and hydrogen, forming
oxides/nitrides or/and other structures as the weld
solidifies. These are impurities which will embrittle
the weld and weaken it
For this last reason shielded welding techniques (or

welding under controlled atmospheres) were


developed : SAW (Submerged Arc Welding), MIG
(Metal Inert Gas),

Maintenance training

"Basics in Welding and Weldability"

Weldability of steels
The term weldability is relative : practically all

metals are weldable. Some however require special


welding procedures in order to preserve the
properties and characteristics designed for
The quality of welding may be affected by any one

of the following factors :









Oxidation
Non metallic inclusions
Change of structure
Gas solubility of metal
Coefficient of thermal expansion
Operator, welding current/voltage,
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Maintenance training

"Basics in Welding and Weldability"

Classification of steels
The classification used in this document is based

on the chemical composition (DIN & AFNOR),


Examples from the Cement industry :

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Maintenance training

"Basics in Welding and Weldability"

Ordinary Steels
Iron/Carbon alloys (C<1.2% in general), with small

quantities of Mn (<0.8%) and Si (<0.5%) and other


impurities (S and P)
Tensile Strength Yield Strength Elongation
Brinell Hardness
2
kg/mm2
%
kg/mm

%C
Low Carbon

< 0.15

35 - 42

20

28 - 30

< 120

Mild

0.15 - 0.3

40 - 45

20 - 25

22 - 25

120 - 140

Medium Carbon

0.3 - 0.6

45- 65

22 - 35

22 - 15

140 - 180

High Carbon

0.6 - > 0.8

65 - > 85

40 - > 50

14 - 6

180 - > 220

< 0.25% Carbon, there are no precautions to be

taken for welding


Classification according to DIN and AFNOR (based on Chemical composition)
Maintenance training

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"Basics in Welding and Weldability"

Ordinary Steels
0.25 0.4% Carbon, Preheating is needed

because the critical cooling speed which forms the


martensite might be exceeded
Above 0.4% Carbon, preheating is a must. The

temperature of preheating is around 75 350C


depending on the thickness (see low alloy steels)
For welding casehardened steels, the

casehardened layer must be removed even with


preheating
For quenched steels, preheating, maintaining at

stable temperature during welding and slow cooling


process are needed
Classification according to DIN and AFNOR (based on Chemical composition)
Maintenance training

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"Basics in Welding and Weldability"

Low Alloy Steels


At least one alloy element is added in a quantity

< 5% to improve the steel properties (Mechanical


Resistance, Corrosion and Abrasion)
Mn
Ni
Cr
V
Si
Mo
Co, Ti, Al, Cu, W

Minimal Content
in %
1.2
0.5
0.25
0.05
1
0.1
0.3

The Carbon content is not sufficient to predict the

weldability, some alloy elements participate also in


the process of martensite formation : the Carbon
Equivalent % has to be considered
Classification according to DIN and AFNOR (based on Chemical composition)
Maintenance training

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"Basics in Welding and Weldability"

Low Alloy Steels


Actually, it is the cooling velocity around the

welding seam which must be controled :







Preheating which objective is to reduce the cooling


rate after welding
Covering the area welded for slow cooling
In some special cases (steels with high quenching
aptitude), the cooling is controled in a furnace (50C
per hour)

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Maintenance training

"Basics in Welding and Weldability"

Low Alloy Steels


The preheating level depends on :
The material composition : Carbon equivalent (%CE)
The thickness
Sfrian Diagram (Thickness, %CE, preheating T)




400
carbon equivalent

0.2

300
temperature in C

%CE =
C+Mn/6+(Ni+Cu)/15
+(Cr+Mo+V)/5

350
0.25

250

0.3
0.4

200

0.5

150

0.6

100

0.7

50

0.8

0
0

50

100

150

thickness in mm

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Maintenance training

"Basics in Welding and Weldability"

High Alloy Steels


The content of at least one alloy element exceeds

5%
Ni
Cr
Mn
Si
W
Mo
V
Cu
Al
Co
Ti

Maximal content
in %
30
30
14
4
20
8
5
2
12
18
1.6

The weldability of such steels has to be analyzed

case by case
Classification according to DIN and AFNOR (based on Chemical composition)
Maintenance training

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"Basics in Welding and Weldability"

High Alloy Steels


Example

13% Mn Steels : Abrasion/Impact resistant steels

very sensitive to precipitation of carbides around


250C, the welding sequences must be controlled
in order to limit the temperature increase
Application : Hardfacing of crusher hammers and

impact bars

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Maintenance training

"Basics in Welding and Weldability"

High Alloy Steels


Example

Chromium, Molybdenum materials : Usually >1%C,

2-30% Cr, and 0-3% Mo.The carbides formed


(Mainly C + Cr, 10 40%) are very hard and
resistant but very fragile (notch effect due to
carbides)
The structure of the matrix (martensite, austenite,

), and the form and dimensions of carbides


depend on the heat treatment (especially the
solidification speed) and has a large influence on
the behavior under wear and impact
In most of the cases, welding is not recommended

or should be performed by specialized third parties


Application : liners and inlet wall for ball mills
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Maintenance training

"Basics in Welding and Weldability"

Welding techniques
The common techniques used in cement are :




Manual Arc welding


Submerged arc welding : SAW
MIG/TIG

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Maintenance training

"Basics in Welding and Weldability"

Manual Arc Welding


Most common technique
Deposition rate around 1.5 kg/h
Better control of post-welding deformation
Less sensitive to lack of fusion defects
The welding electrode coating role is :
. Stabilizing the arc
. shielding the arc: prevent from
atmospheric contamination (O2, N2)
. Scavenging and deoxidizing :
produce a slag blanket to protect the
molten crater (and reduce its cooling)
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Maintenance training

"Basics in Welding and Weldability"

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Manual Arc Welding


For special works (I.e. kiln shell replacement), the

welder must be qualified and certified according to


DIN/EN 287-1, ASME9 or equivalent

5 -10

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Maintenance training

"Basics in Welding and Weldability"

Manual Arc Welding


The deposition rate can be increased by using

more welders (place restrictions may apply)


The oscillating welding technique is unfavorable for

residual stresses, the straight line technique gives


better results
To avoid thermal distortions, the welding sequence

must be determined carefully

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Maintenance training

"Basics in Welding and Weldability"

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Manual Arc Welding


For special works (i.e. kiln shell replacement), the

electrodes have to be heated (dried) 2 hours at


200-350C and must be kept at this temperature
while welding
It is very important

To define and stick to


The welding
Procedure rules

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Maintenance training

"Basics in Welding and Weldability"

Semi automatic / Automatic Arc Welding


In the semi-automatic arc welding, the electrode is

mechanically fed through a welding gun into the arc


from a continuously wound coil. The operation still
needs an operator
In the fully automatic arc welding, the electrode is

fed through welding jaws into the arc from a


continuously wound coil. The welding doesnt need
an operator
These 2 techniques increase welding speed,

reduce welding time and thus allow lower welding


cost

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Maintenance training

"Basics in Welding and Weldability"

12

Submerged Arc Welding


Very high deposition rates : 10kg/h, the welding

velocity is around 80cm/mn


Semi-automated process

Very high quality of weld with

specialized operator

Wire and flux must

correspond to the material


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Maintenance training

"Basics in Welding and Weldability"

Submerged Arc Welding


Commonly used for welding kiln shells external and

internal

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Maintenance training

"Basics in Welding and Weldability"

13

Metal Inert Gas (MIG) Welding


Semi automated process with Gas protecting the

weld pool
This Welding process is sensitive to lack of side-

wall fusion and cold lapping defects


Defect occurs in case of

lack of gas
Certified people
Deposition rate: 2.5 kg/h

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Maintenance training

"Basics in Welding and Weldability"

Welding defects
The most common welding defects are :








Cold cracking, or hydrogen induced cracking


Solid inclusions
Porosities
Lack of fusion
Shape defects (design related defects)
Lamellar tearing
Hot cracking

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Maintenance training

"Basics in Welding and Weldability"

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Hydrogen induced cracking : Cold cracking


Hydrogen induced cold cracking : occurs at low

temperatures (< 150C), usually originates from the


weld toe, and it is caused by the diffusion of
hydrogen from the weld deposit to embrittle the
existing martensite structure
The hydrogen comes mostly from moisture

associated with fluxes :




Usage of low hydrogen consumables. TIG and MIG


prcessess, being fluxless, give lower levels of
hydrogen
Usage of austenitic electrodes (I.e. 2222) : the
hydrogen diffusion rate is lower in austenite structure
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Maintenance training

"Basics in Welding and Weldability"

Hydrogen induced cracking : Cold cracking

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Maintenance training

"Basics in Welding and Weldability"

15

Solid inclusions
The most important is slag Inclusion which arises

because it is difficult to ensure that all pockets of


slag are removed from the weld surface
(particularly when access is difficult). Slag deposits
are produced by the welding flux
Oxide inclusions usually result from inadequate

precleaning of the joint surface

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Maintenance training

"Basics in Welding and Weldability"

Porosities
Porosity occurs when a weld is saturated with a

particular gas (hydrogen, nitrogen, CO) which


forms bubbles on discontinuities in the metal
Gases originate from air entrainment in the arc

atmosphere (hydrogen, nitrogen), grease and


moisture on joint faces or welding consumables
(hydrogen) or chemical reaction in the weld (CO)
Factors of influence : instability of the arc, inefficient

cleaning of the surface, and bad control of the arc


at stops and starts

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Maintenance training

"Basics in Welding and Weldability"

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Lack of fusion and lack of penetration


The welding arc is not sufficiently penetrating to

wet the edge, or does not completely fill the joint


Generally depend on the electrode manipulation,

joint design, arc current and surface preparation


Example : shell joining section

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Maintenance training

"Basics in Welding and Weldability"

Shape defects
Example : undercut, poor profile, misalignment
Consequence of poor electrode manipulation, bad

fit-up, or/and incorrect procedure (current, voltage,


speed, )


Undercut is caused by too high current or too low


speed
Too low current can cause excessive spatter

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Maintenance training

"Basics in Welding and Weldability"

17

Lamellar tearing
Development of cracks in the base metal in parallel

with the seam surface : The bonding between the


inclusions and the matrix in the base metal is weak
and some inclusions will brittle, therefore strains in
the thickness direction will cause de-cohesion and
fracture of inclusions

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Maintenance training

"Basics in Welding and Weldability"

Lamellar tearing
Preventing measures :


Modification of welding procedure and joint design to


reduce strains in the thickness direction

Usage of low inclusion levels (I.e. low sulphur steels)

Special heat treatments that modify the shape of


porosities

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Maintenance training

"Basics in Welding and Weldability"

18

Hot cracking
Occurs during or just after solidification below

1200C
Due to the presence of low melting point

components such as iron sulphides or phosphide


which mechanical resistance is lowered under
temperature
It is admitted to be due to shrinkage strains before

cohesion
Inter-granular

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Maintenance training

"Basics in Welding and Weldability"

Weld seam design


The weld design

Fatigue Strength

has a direct impact


on its resistance :

Load
cycles
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Maintenance training

"Basics in Welding and Weldability"

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Weld seam design

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Maintenance training

"Basics in Welding and Weldability"

Welding Material
The most special electrodes commonly used in the

cement industry are :





2222 of Castolin : kiln tires, rollers


E7018 : kiln shell

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"Basics in Welding and Weldability"

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Welding with 2222


Electrode that provides an optimum combination of

strength and ductility


Factors to consider :




Linear Coefficient of thermal expansion


Effects of dilution
Sigma phase precipitation
Eutectic 2222

Tensile strength N/mm2


Yield strength N/mm2

650 - 690
390

Elongation %

40 - 45

Hardness HB

170 - 210

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Maintenance training

"Basics in Welding and Weldability"

Welding with 2222


Linear Coefficient of Thermal Expansion (TEC)
 The Thermal Expansion Coefficient increases with
temperature
 At 300C, the TEC of the following materials are :


Austenitic steel (stainless) : 17.2 10-6/C


Eutectic 2222 : 14.4 10-6/C
0.2% Carbon steel : 13.4 10-6/C
Chromium Iron : 10 10-6/C

The stainless steel welding will expand and contract


significantly, this will increase the residual stresses
whilst distorting the joint
Eutectic 2222 has a TEC very close to the Carbon
steel, in operation, this results in maximum safety
margin against cracks
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Maintenance training

"Basics in Welding and Weldability"

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Welding with 2222


Effect of dilution


Dilution is expressed as the amount of parent metal


ingressed in the weld deposit
When conventional stainless steel electrodes are
used to weld carbon steels, the weld metal will
inevitably be diluted with the parent metal by at least
20 30%, this creates a weld deposit which may be
embrittled due to martensite formation
The 2222 weld is capable of dissolving a high
proportion of steel (~50%) whilst retaining its natural
austenitic structure
Reference : Schaeffler diagram Cr equivalent vs. Ni
equivalent
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Maintenance training

"Basics in Welding and Weldability"

Welding with 2222


Sigma phase precipitation


Brittle Iron-Chromium intermetallic which is very


dependent on temperature and time kinetics. It can
form at 900C within minutes and after several days
at 500C
It often occurs when welding thick carbon steel
section with with 309 or 310 based electrodes
Eutectic 2222, even when diluted can not reach the
sigma zones and is therefore resistant to
embrittlement
Reference : ternary diagram Nickel/Chromium/Iron

Example of application : kiln tires and rollers

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Maintenance training

"Basics in Welding and Weldability"

22

Welding with E7018


E7018 : American Welding Society numbering

system






E : Metal arc welding electrode


70 : Minimum allowable tensile strength of deposits
expressed in 000 pounds / inch2
1 : All welding positions
8 : arc characteristics and polarity (ac and dc)

Iron powder low hydrogen electrode : rimmed

steel core wire upon which a lime covering is


applied
Yield strength: 470 MPa, Tensile strength: 540

MPa, Elongation: 30%

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Maintenance training

"Basics in Welding and Weldability"

Welding with E7018


Because this covering is slightly thicker than

normal, the arc is shorter and moderately


penetrating, the slag is heavy and friable and the
deposited metal lies in a flat bead providing a very
reduced tendency for underbead cracking (cold
cracking)
E7018 belongs to the Low Moisture Absorption

electrodes family

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"Basics in Welding and Weldability"

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Welding with E7018


Preheat is generally not required to prevent

hydrogen induced cracking


Preheat should be used with hardenable steels to

prevent the formation of hard heat-affected zones


and eliminate tendencies toward quench cracking
on cooling
Preheat may be required in welding heavy sections

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Maintenance training

"Basics in Welding and Weldability"

Basics in Welding and weldability


Practical example 1
kiln shell crack repair

24

Fatigue and Crack formation


Kilns are exposed to dynamic loads : fluctuating

stresses that can be bending, torsion, tensile,


compression or combinations of these
Stresses like these can lead to crack formation and

fracture without any kind of deformation and real


overload

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Maintenance training

"Basics in Welding and Weldability"

Fatigue and Crack formation


The load and stress changes are higher because of

heat deformations and possible incorrect


adjustment (typical case : crank in the tube)
Examples of areas where cracks can start : shell

welding joints, toe of welds between shell and


supports, manholes, satellite cooler supports,

Circumferential welds
Loose tires pads
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"Basics in Welding and Weldability"

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Crack repair

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Maintenance training

"Basics in Welding and Weldability"

Crack repair

When a crack is detected, the first actions are :


1.
2.

Finding the length of the crack


Finding the depth of the crack

This is done with NDT

methods as UT, MP or DP

If the crack is throughgoing,

it is necessary to work from both


inside and outside

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Maintenance training

"Basics in Welding and Weldability"

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Crack repair procedure

The normal procedure is the following :


1.

Gouging from one side to about 2/3 of the thickness

2.

The gouging must start a little away from the crack


ends in sound material, gouging towards the crack,
to avoid crack propagation
Smooth transition
radius

Crack end

Gouging direction

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Maintenance training

"Basics in Welding and Weldability"

Crack repair procedure


3.

Careful cleaning by grinding

4.

Preheating : If the result of the Carbon equivalent is


higher than 0.41 it is necessary to preheat. It must
be pointed out that even if the result is lower than
this, it does not harm to preheat, especially with
heavy sections and if the weather is cold

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Maintenance training

"Basics in Welding and Weldability"

27

Crack repair procedure


5.

Welding with a normal basic electrode as AWS E


7016 or E 7018 (The electrodes have to be dry)

Each run should be overpeened


to reduce stresses, and carefully
cleaned from slags

6.

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Maintenance training

"Basics in Welding and Weldability"

Crack repair procedure


7.

Grinding down the surface of the weld : Root weld

8.

The process has to be repeated from the other side


controlling that the root is completely clean

9.

Control with UT, MP and/or DP

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Crack repair procedure


After the repair, in the case of long cracks, the shell

can be reinforced by adding some joining plates :

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Maintenance training

"Basics in Welding and Weldability"

Basics in Welding and Weldability


Practical example 2
Hydrogen-induced cracking - kiln shell welding
December 2003

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Situation
Welding joint NA between a 75mm thick new shell

and a 60mm thick old section


Root weld and outside welding completed, internal

gouging and DP done


While welding internally, a loud bang was heard : A

crack was found inside the partially welded area

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Maintenance training

"Basics in Welding and Weldability"

Situation
A 3.5m long crack was found in the HAZ in the old

shell during the UT of the outside completed


welding
The crack was not fully removed after gouging and

grinding 20mm
A 1.6m long crack was also found in the partially

welded groove on the inside of the kiln


MP was carried out and cracks were found also in

the root weld

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Investigation : External consultant


Preliminary finding was that the dye penetrant

residue was probably not fully removed




A hydrogen-induced crack (HIC) could have been


developed due to welding over the DP residue
A Hydrogen removal heat treatment (HRHT) should be
carried out before continuing

Excess hydrogen in parent base metal


 Many repairs were done successfully in the past
 The joint at the other end of the 60mm thick old shell
was welded to a new section without problem
 Hypothesis not probable

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Investigation : External consultant

HIC (or Cold cracking)

Occurs after welding has been completed

4 main Conditions :

1. Hydrogen is introduced by diffusion during the

welding to the weld or HAZ :


. Moisture in the coating of the electrodes
. Oil, grease, dirt, paint, water in the surface
. Degreasing fluids used to clean surfaces, DP or wet
MP powder residues
. Hydrogen in the parent metal : original casting
process, heat treatment, or corrosion (example H2S)
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Investigation : External consultant


2. Low preheating temperatures (<150C)
3. Hard HAZ microstructure : Soft microstructures

tolerate more hydrogen before cracking occurs.


The E9018 weld metal is susceptible to HIC
4. Existence of tensile stresses on the weld seam

originating from thermal contraction of the cooling


or from external efforts

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"Basics in Welding and Weldability"

Investigation : External consultant


Some indications :
1. Position and morphology :

very fine and some times


interrupted cracks, usually
develop internally, at the toe
of the adjacent weld passes
and on the root weld metal
2. HIC propagate
3. More HIC develop and

propagate during attempts to


repair without HRHT
4. No cracking occur after the

HRHT and other precautions

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Investigation : Contractor
Crack only in the 60mm thick old shell
Steel : 0.24%C, 1.01%Mn,
The crack was propagating
Cracks had not been found in any of the other kiln

joints (other sections thinner !)


All cracks are hydrogen-induced and a HRHT must

be carried out before any repair


It is not a standard practice to remove the DP

lacquer before gouging and welding (Not


acceptable statement)
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"Basics in Welding and Weldability"

Information from the DP supplier


The product is a paint that contains an organic

resin that incorporates hydrogen in its formulation


Welding over this product must be avoided to

prevent hydrogen-induced cracking


The product datasheet does not permit gouging

and welding over the lacquer

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33

Repair
Before the HRHT, for safety reasons, the contractor

recommended :
Complete welding of the 3.5m long and 20mm deep
groove on the external
 Installation of strong backs to prevent further cracking
HRHT : 450C 20 hours (december 23)


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Repair
After the HRHT :


In some areas the lacquer was not


completely removed
The 1.6m and 3.5m cracks propagated
and others were created

It was reported afterwards that the

contractor didnt perform UT on the


entire section : difficulty to know the
history of the defects !
UT on the entire section :




2 lack of fusions : 380mm and 190mm


3 cracks : 35mm, 1200mm and 1500mm
Laminations : 1200mm long
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34

Repair
No additional cracks were developed after :







HRHT
Strict storage and handling of the E9018 welding
electrodes
Proper cleaning of the joints before welding
Repair welding
DP was replaced by MP

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Welding procedure
Welding Procedure Specification WPS :


The ASME WPS applied by the contractor was qualified for


a thickness range of 4.8mm to 56mm :
- E9018-D1 electrodes (min tensile strength of 90kpsi),
preheating at 150C, 3.2mm for the root and 5mm for the filler

The FOX EV 51 (E9018-D1) standard low hydrogen


electrodes (lime covered) were used for the root and filler
passes, This electrode when well prepared (backing at
300C for 2 hours) has a diffusible hydrogen of <10ml/100g

The electrodes to be used in such applications are the


special extra-low hydrogen content ESAB OK 74.78 or
E7018 with a diffusible hydrogen of < 5ml/100g

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Maintenance training

"Basics in Welding and Weldability"

35

Welding procedure
Welding Procedure Specification WPS :


According to the hydrogen Control Method, the


minimum preheating temperature should have been
180C for diffusible hydrogen less than 9.5ml/100g to
prevent HIC

The risk of HIC increased substantially when FLS


replaced the low strength E7018 electrodes with the
higher strength E9018-D1

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Welding procedure
Drying and holding ovens :


A temperature of 130C was measured in the large


oven that contained many electrodes
The drying and main holding oven was stored outside
and directly exposed to rain
It is possible that some electrodes which were used
were not baked (dried) : information from welding
registers

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36

Learning from the practical case 2


The WPS has to be prepared including all details

prior to the welding


Selection of an extra low diffusible hydrogen

electrode <5ml/100g : Equivalent to E7018


Preheating the shell sections at the right

temperature depending on the C equivalent and


thickness in all the areas between 100 and
+100mm of the joint
Proper drying and storage of the electrodes has to

be checked : 300 to 350C during 2 hours

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Maintenance training

"Basics in Welding and Weldability"

Conclusions
Welding is an important Maintenance activity

performed in cement plants


Welding is not as simple as we imagine, special

care must be given when welding alloyed materials


The welding efficiency (quality and time) impacts

directly the equipment availability


The main welding parameters have to be known

and prepared in advance :






Material to weld
Welding technique and electrode to be used
Welding procedure : preheating temperature, cooling
speed, preparation of the electrodes
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37

Conclusions
Once developed, the Welding procedure has to be

strictly followed
The contractors involved in special welding jobs

must have the right experience


The NDT method to be applied has to be checked

in advance
Other HGRS complementary documents :




Kiln shell replacement


Girth gear repair procedure
Mill end repair procedure

75

Maintenance training

"Basics in Welding and Weldability"

38

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