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CHEMISTRY 4 (SNP20304)
TUTORIAL 1- HOW FAST? RATES
1. For the reaction: 4NH3(g) + 3O2(g)
decrease of NH3 is 0.82 mol dm-3 s-1. What is the rate of decrease of O2 and
the rate of formation of N2 and H2O?
2. In the reaction X
s is 2.15 mol dm-3 and 1.08 mol dm-3 respectively. What is the average rate of
the reaction during this time interval?
3. In the reaction W
reaction has started is 1.00 mol dm-3. If the rate of dissociation of W at this
point is 8.6 x 10-3 mol dm-3 min-1 and assuming that the rate remains constant,
what is the concentration of W at 25.0 min after the reaction has started?
4. In the reaction 2NH3 (g)
PQ
P3Q
Rate = k[Q]
Rate = k[P][Q]
Rate = k[X2][C2]2
At temperature T, the rate of reaction is r. how does the reaction rate change
if
a) Only the partial pressure of X2 is doubled?
b) The partial pressure of X2 is halved and C2 is doubled?
2AX(g) is
Experiment
1
2
3
I2 + 2H2O
Experiment
1
2
3
4
compounds. The initial rate data are given in the following table.
Experiment
Initial [A]
(mol dm-3)
1
2
1.8 x 10-2
3.0 x 10-2
Initial rate of
decomposition of A
(mol dm-3 s-1)
9.0 x 10-4
1.5 x 10-3
2NO(g) + O2(g)
If the rate constant, k at T K is 0.033 mol-1 dm3 min-1 and the initial
concentration of NO2 is 8.00 mol dm-3,
a) What is the concentration after the reaction time of 30 mins?
b) What is the time when the concentration of A is 0.08 mol dm -3?
14. The rate constants at different temperatures for the decomposition of an
organic compound X are as shown.
Temperature
320
385
(K)
k (s-1)
5.70 x 10-6
2.15 x 10-3
a) Calculate the activation energy for the reaction.
b) Determine the rate constant at 500 K.
15.The first order reaction X2
and 63.6 min at 520 K. Calculate the activation energy of this reaction.