Scribd Logo
Încărcați

Bine ați venit la Scribd!

  • Magnesium Carbonate

    Încărcat de

    Alyana Dizon
    597 vizualizări26 pagini
    The document describes the preparation of two varieties of magnesium carbonate: light variety and heavy variety. It provides the procedures, reactants, equipment used, and equations for both varieties. The light variety is prepared by slowly mixing solutions of magnesium sulfate and sodium carbonate in cold water, boiling the mixture, filtering, washing with boiling water, and drying. The heavy variety involves evaporating hot solutions of the reactants to dryness and then boiling the dried mixture in water. Key differences between the varieties are also summarized.

    Descriere originală:

    Phar chem 1

    Drepturi de autor

    © © All Rights Reserved

    Formate disponibile

    PDF, TXT sau citiți online pe Scribd

    Vi se pare util acest document?

    Este necorespunzător acest conținut?

    Raportați acest document
    The document describes the preparation of two varieties of magnesium carbonate: light variety and heavy variety. It provides the procedures, reactants, equipment used, and equations for both varieties. The light variety is prepared by slowly mixing solutions of magnesium sulfate and sodium carbonate in cold water, boiling the mixture, filtering, washing with boiling water, and drying. The heavy variety involves evaporating hot solutions of the reactants to dryness and then boiling the dried mixture in water. Key differences between the varieties are also summarized.

    Drepturi de autor:

    © All Rights Reserved
    Descărcați ca PDF, TXT sau citiți online pe Scribd
    Indicator pentru conținut neadecvat
    597 vizualizări26 pagini

    Magnesium Carbonate

    Încărcat de

    Alyana Dizon
    The document describes the preparation of two varieties of magnesium carbonate: light variety and heavy variety. It provides the procedures, reactants, equipment used, and equations for both varieties. The light variety is prepared by slowly mixing solutions of magnesium sulfate and sodium carbonate in cold water, boiling the mixture, filtering, washing with boiling water, and drying. The heavy variety involves evaporating hot solutions of the reactants to dryness and then boiling the dried mixture in water. Key differences between the varieties are also summarized.

    Drepturi de autor:

    © All Rights Reserved
    Descărcați ca PDF, TXT sau citiți online pe Scribd
    Indicator pentru conținut neadecvat
    din 26

    Preparation

    of Magnesium Carbonate USP


    Pharmaceu*cal Chemistry 1 Laboratory

    Therapeutic Uses of
    Magnesium Carbonate
    Antacid
    Laxa*ve
    An*dote to acid poisoning

    Therapeutic Uses of
    Magnesium Carbonate
    Externally as absorbent or drying powder.
    In large doses are cathar*c and ingredient of

    the popular cathar*c lemonade purga*ves


    (dose is 8 grams).

    Source of Magnesia (MgO)

    Forms of Magnesium Carbonate


    1. Light variety
    2. Heavy variety

    Forms of Magnesium Carbonate USP:


    Light Variety
    Heavy Variety

    Temperature of water
    Amount of water
    Boiling *me
    Drying

    Light Variety
    Cold water
    125 mL
    15 minutes
    Not exceeding
    100oC

    Heavy Variety
    Boiling water
    25 mL
    30 minutes
    Air-dry

    LIGHT VARIETY

    Procedure for the preparation

    MgSO4.7H2O (15 grams) / Na2CO3.H2O (7.6 grams)


    (Separate beaker containers)

    Both in 125mL of cold dist. water


    Filter if necessary

    2
    3

    Sodium Carbonate solu*on


    (+) Mg2+ soluAon slowly
    with constant s*rring

    Test the mixture (litmus paper)

    LIGHT VARIETY

    Procedure for the preparation

    If not alkaline
    (+) Na2CO3. H2O
    Un*l it is denitely so

    5
    6

    Mark the volume. Boil the mixture gently (15 minutes)

    (+) water from Ame to Ame.


    to maintain the original mixtures volume

    Transfer to Buchner funnel; allow to drain


    completely.

    KEEP!

    HEAVY VARIETY

    Procedure for the preparation


    MgSO4.7H2O (15 grams) / Na2CO3.H2O (7.6 grams)
    (Separate containers)

    Both in 25mL of boiling d . water



    Filter if necessary before mixing the hot solu*ons

    Evaporate the mixture to dryness

    HEAVY VARIETY

    Procedure for the preparation


    (+) 50 mL of dis*lled water

    Heat to boiling for 30 minutes (maintain original volume)

    4
    5

    HEAVY VARIETY

    Procedure for the preparation


    Transfer to Buchner funnel

    NEXT MEETING

    Buchner Funnel
    Rapid ltra*on of voluminous substance.

    LIGHT VARIETY

    Procedure for the preparation

    7
    8

    Filtrate
    To test the by-product

    Wash the residue on the lter paper


    (+) boiling water
    Un*l the washings is free from sulfate ions

    9
    10

    Dry the product (not exceeding 100oC)

    WEIGH!

    Reserve 1/3 of the product (For MgO and iden*ca*on tests)

    HEAVY VARIETY

    Procedure for the preparation


    Use the ltrate to test the by-product

    Wash the residue with boiling water (small por*ons)

    UnAl the last porAon of washings is free for sulfate

    Dry (without hea*ng) and weigh

    Reserve 1/3 of the product


    (For MgO and iden*ca*on tests)

    10

    Physical Properties
    Color&
    Taste
    Odor
    White and Slightly
    odorless earthy
    taste

    RelaAve
    Bulk
    Bulk

    Test for identity


    Results
    EquaAons
    1. Eervescence (MgCO3)4.Mg(OH)2.5H2O + 10HCl 5MgCl2 +
    4CO2 + H2O
    2. White
    crystalline
    precipitate

    MgCl2 + NH4Cl + Na2HPO4 MgNH4PO4 + HCl +


    2NaCl

    Ions

    Reagent

    Result

    Ion Present

    Na+

    KH2SbO4 / K2H2Sb2O7

    NaH2SbO4 (white precipitate) Na+

    SO42-

    BaCl2

    BaSO4 (white precipitate)

    SO42-

    Eervescence
    Bubbling of a gas through liquid. This is

    produced when acid is added to CO32- + HCO3-.

    Libera*on of CO2 (gas)

    Equation in Light Variety


    EquaAon (1):
    6MgSO4.7H2O + 6Na2CO3.H2O
    (MgCO3)4.Mg(OH)2.5H2O + Mg(HCO3)2 + 6Na2SO4 +
    41H2O
    EquaAon (2):
    5Mg(HCO3)2 + H2O (MgCO3)4.Mg(OH)2.5H2O + 6CO2

    Equation in Light Variety


    EquaAon (1):
    306MgSO4.7H2O + 306Na2CO3.H2O
    5(MgCO3)4.Mg(OH)2.5H2O + 5Mg(HCO3)4 + 306Na2SO4
    + 205 41H2O
    EquaAon (2):
    5Mg(HCO3)2 + H2O (MgCO3)4.Mg(OH)2.5H2O + 6CO2

    Equation in Light Variety


    EquaAon (1):
    30MgSO4.7H2O + 30Na2CO3.H2O
    5(MgCO3)4.Mg(OH)2.5H2O + 5Mg(HCO3)4 + 30Na2SO4 +
    205H2O
    EquaAon (2):
    5Mg(HCO3)2 + H2O (MgCO3)4.Mg(OH)2.5H2O + 6CO2

    Equation in Heavy Variety


    5MgSO4.7H2O + 5Na2CO3.H2O
    (MgCO3)4.Mg(OH)2.5H2O + 5Na2SO4 + CO2
    + 34 H2O


    Factors that determine the variety of


    Magnesium Carbonate:
    Factors
    Light Variety Heavy Variety
    A. Temperature and concentra*on Cold water
    Boiling water
    of the reac*ng solu*on
    B. Temperature at which the
    precipitate is dried.

    100O C

    Air dry

    C. Amount of water

    125 mL

    25 mL

    Theoretical and Actual Yield

    485.64 g

    15g MgSO4.7H2O x 1 mole ES x 1 mole (MgCO3)4.Mg(OH)2.5H2O (MgCO3)4.Mg(OH)2.5H2O


    x
    ES

    246.50 g ES

    5 moles ES

    1 mole
    (MgCO3)4.Mg(OH)2.5H2O

    = 5.911 g (MgCO3)4.Mg(OH)2.5H2O

    S-ar putea să vă placă și