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Minerals Engineering
journal homepage: www.elsevier.com/locate/mineng
a r t i c l e
i n f o
Article history:
Received 4 February 2014
Accepted 7 April 2014
Available online 4 May 2014
Keywords:
Heavy minerals
Geometallurgy
Ore characterisation
Quantitative mineralogy
Mineral processing
a b s t r a c t
The original geometallurgical model for the Namakwa Sands deposit was modied to accommodate ore
blends in addition to the various single ore types. A process mineralogy approach was followed in a structured and systematic manner to evaluate the integrity of the adjusted model, particularly for ilmenite and
zircon, the minerals of highest intrinsic value. This study reproduced recovery relationships predicted by
the geometallurgical model for each of the key process functions, and as a result the integrity of the geometallurgical model is validated. Overall, the recovery potential determined for ilmenite and zircon are
well adjusted to model estimates. Poor mineral liberation, an anomalously high abundance of garnet
and pyroxene and variation in particle chemistry are recognized as the key recovery penalties. The gangue content is the most signicant constraint to ilmenite recovery, whereas zircon chemistry is the most
important negative factor in the production of a premium quality zircon product. Results of this study
contributed to the renement of the current geometallurgical model and also identied opportunities
to optimise mineral resource utilisation in the future.
2014 Elsevier Ltd. All rights reserved.
1. Introduction
Tronox Mineral Sands is presently operating the world-class
Namakwa Sands heavy minerals deposit which is located along
the west coast of South Africa. Estimated pre-mining mineral
resources are in excess of 1 100 Mt of ore with in situ grades of
7.9 wt.% total heavy minerals, 3.16 wt.% ilmenite, 0.85 wt.% zircon,
0.50 wt.% leucoxene and 0.21 wt.% rutile. The bulk of this megadeposit represents cemented high-grade ore that hosts a diverse
heavy mineral suite.
Geometallurgical challenges related to the heterogeneity of the
ore prompted systematic intervention, endeavouring to improve
mineral resource intelligence (Philander and Rozendaal, 2008,
2009, 2011). As a result, a geometallurgical template model was
developed for the Namakwa Sands deposit (Philander and
Rozendaal, 2013). This model demonstrated a promising ability
to predict the valuable mineral recovery potential for the seven
ore types individually, but was not previously evaluated for ore
blends. Since then Namakwa Sands abandoned ore-type campaigning in favour of consistent blending, which provides a greater
10
11
Fig. 1. A simplied illustration of the Namakwa Sands processing ow sheet. The average mineralogical composition of the total heavy mineral fraction at each sampling
point is depicted as pie charts. IRMS = induced roll magnetic separator, HAL = hot acid leach; Zirkwa = secondary zircon product; Tiokwa = secondary rutile product.
12
Fig. 2. Actual zircon grade-recovery data as a data density plot, which is draped
onto modelled grade-recovery feed curves for the two primary concentrator plants.
PCP East displays consistent recoveries across a wide feed grade range, whereas PCP
West recoveries are notably scattered for a xed feed grade.
Ilmenite
Garnet
Pyroxene
Zircon
116
124
124
144
132
143
83
82
120
108
114
100
126
118
137
120
114
121
108
98
105
111
115
103
136
127
133
113
145
142
124
113
127
151
63
105
105
99
102
130
113
95
102
61
109
109
143
168
114
106
114
31
12
117
158
164
129
108
78
84
36
112
115
124
107
102
primary concentrate blends into magnetic and non-magnetic concentrates. Both concentrates are subjected to mechanical attritioning to reduce surface related contamination such as duricrust
cement, ferruginous and siliceous coatings as well as clays. A
reclaim route serves the re-treatment of reject material (Fig. 1).
The geometallurgical model predicted that feed grade and particle size affect zircon recovery the most, whereas magnetic susceptibility is less important (Philander and Rozendaal, 2013).
Actual zircon recoveries average around 90%. Zircon losses to magnetic concentrate amount to approximately 3% of total feed. Trace
quantities of this particular zircon population either have ironbearing inclusions or are highly coloured, a zircon type known
for containing elevated amounts of iron, which increases its
magnetic susceptibility (Philander and Rozendaal, 2008). The bulk
Fig. 3. Heavy mineral density proles for the two concentrator plants PCP West and PCP East in relation to the densities of key heavy minerals. Note that a density cut-point
of 3.4 g/cm3 is used at the primary concentrator plants.
13
Fig. 4. Actual data straddle the modelled liberated total zircon recovery trend
line, illustrating the important effect of liberation on PCP West recovery.
Fig. 5. The inverse relationship between pyroxene feed grade and ilmenite and
zircon recoveries.
of the zircon reporting to magnetic concentrate however is represented by ner particles that were probably entrained by coarser
ilmenite or garnet (Table 1). Particle overcrowding in the middling
section of the WHIMS circuit was found to occur frequently due to
a high abundance of garnet in the feed, causing signicant entrainment of zircon to magnetic concentrate. This type of entrainment
highlights the inherent weakness of conventional WHIMS to
recover ne non-magnetic rutile and zircon in the presence of high
quantities of magnetic minerals (Dobbins et al., 2009).
The majority of zircon not recovered to non-magnetic concentrate, register in the reclaim. These zircon particles are slightly
coarser than those in the non-magnetic concentrate (Table 1).
Coarser garnet is suspected to entrain the bulk of the zircon to
reclaim. The garnet content of the spiral feed, which is inversely
related to the zircon abundance, emerged as an important zircon
recovery driver (Fig. 6). Garnet, the most abundant gangue constituent in the feed has the ability to complicate the secondary concentration sub-processes, degrade both the magnetic and nonmagnetic concentrates and contribute to valuable mineral losses.
Almandine (Fe2+
3 Al2[SiO4]3), the chief garnet-type identied, has
the problematic tendency to respond positively across a range of
magnetic eld strengths due to variable iron and manganese content (Fig. 7). Nearly a third of total garnet fed to SCP reports as a
non-magnetic, whereas the rest contains sufcient iron and manganese and behaves magnetically similar to ilmenite. The heavy
mineral concentrate produced by PCP East usually contains less
than 2 wt.% garnet, whereas the ore treated by PCP West is highly
garnetiferous by comparison, and as a result heavy mineral concentrate could contain up to 30 wt.% garnet. Therefore, a 180 lm
vibrating screen is used to remove coarse garnet from PCP West
concentrate at the SCP. Less than 20% of garnet, however, is
removed in this process, whereas corresponding losses of ilmenite
and zircon are usually less than 3%.
Ilmenite recoveries to magnetic concentrate usually reach 80%.
Approximately 14% of ilmenite not recovered reports to reclaim
and another 4% ends up in the non-magnetic concentrate (NMC),
of which nearly 40% is altered, or is intimately associated with
other low iron bearing phases (Fig. 8). The magnetic susceptibility
of these particles is considered insufcient to be recovered by
WHIMS. A signicant proportion of the ilmenite in the non-magnetic concentrate is noticeably coarser, a known disadvantage of
WHIMS to recover coarse magnetic mineral particles (Table 1;
Dobbins et al., 2009). Similarly, a considerable proportion of the
ilmenite reporting to reclaim is coarse and an almost equal quantity is unaltered (Fig. 8). The recovery of ilmenite in the presence
of almandine, which exhibits similar magnetic behaviour, occurs
with a substantial penalty (Table 2).
In summary, ilmenite and zircon recoveries in the secondary
concentration process are essentially inuenced by the quantity
of garnet in the feed and not the ilmenite or zircon feed grades
as the geometallurgical model predicted. Other recovery penalties
such as magnetic susceptibility and particle size are conrmed to
be subordinate. The latest ndings highlight the difculty of conventional WHIMS to effectively separate heavy minerals that display extreme differences in magnetic behaviour due to variations
in chemical composition.
Table 2
Ilmenite and zircon recovery penalties determined for the four process areas. Values are expressed as percentages.
Recovery Penalties
PCP East
PCP West
SCP
MSP
Zircon
Ilmenite
Zircon
Ilmenite
Zircon
Ilmenite
Zircon
Ilmenite
0.2
0.5
0.0
0.2
2.0
0.0
12.2
4.6
0.0
10.9
7.5
0.0
3.1
0.3
2.9
9.4
3.0
4.3
2.1
12.7
4.2
Recovery potential
99.3
97.8
83.2
81.6
93.7
83.3
85.2
95.8
14
Fig. 6. The inverse relationship between garnet feed grade and zircon recovery in
the spiral circuit of the Secondary Concentration Plant.
Fig. 7. Single grain chemistry of garnet particles illustrating that the magnetic
susceptibility of garnet is related to its iron and manganese content.
15
Fig. 9. The deportment of key penalty elements for the ilmenite and zircon products.
Fig. 10. Ilmenite grains showing common siliceous surface coatings and silicate mineral inclusions.
Fig. 11. Negative relationship between locked SiO2 content of ilmenite and
recovery.
Fig. 12. Average iron content of the two varieties of zircon sampled from different
MSP streams in relation to the zircon product specication.
16
Table 3
Observed and model recovery penalties for ilmenite and zircon in the overall context.
Values are expressed as average percentages. npd = not previously determined.
Recovery penalties
Feed grade
Gangue content
Mineral liberation
Magnetic susceptibility
Particle size
Particle chemistry
Recovery potential
Zircon
Ilmenite
Model
Observed
Model
Observed
11
npd
3
2
2
8
74
9
3
1
3
9
76
20
npd
7
5
3
14
51
17
6
3
5
3
66
is well aligned with model estimates. The impact of particle chemistry on ilmenite recovery, however has been overestimated in the
model, and as a result the recovery potential for ilmenite proved
higher than previously determined. The ndings of the current
study present substantial incentives to further rene the geometallurgical model, which could nd application in the broader mineral
sands industry.
Mineral liberation, gangue content and particle chemistry are
conrmed as the key recovery penalties. Several proposals to
address these constraints are mainly directed to better align mineral resource characteristics, processing technology and market
dynamics. Geometallurgy remains integral to Namakwa Sands
mine planning strategies that endeavour to optimise mineral
resource utilisation that is sustainable across life of mine. Currently, there is a methodical focus to investigate alternative technologies and research the latest developments in heavy mineral
separation to help narrow the gap between actual mineral recoveries and determined recovery potential.
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