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PERATURAN PEMARKAHAN
KIMIA KERTAS 2
MODUL PENINGKATAN PRESTASI 2014
SEKOLAH-SEKOLAH MENENGAH ZON B KUCHING
SECTION A

No
1

Answer

Sub
Mark
1+1

Total
Mark
2

(b) 27-13// 14

(c) Q and R

(d) Group 1 and Period 4

(e) P and T

(f)(i) Ionic bond

TOTAL

(a) R: 2.6; S: 2.8.3

(ii) S2Q3
(iii) state any one of physical properties of ionic compounds.
ex: high melting and boiling points; soluble in water but insoluble in organic
solvents

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No
2

Answer
(a)

to dry the hydrogen gas

(b)(i)

to avoid oxygen in air react with hydrogen gas//to prevent explosion

(ii)

Sub
Mark
1

Total
Mark
1

to prevent the hot copper react with oxygen in the combustion tube from

1
1

reform copper(II) oxide

(c)
Element

Cu

Mass (g)

3.2

0.8

3.2/64 = 0.05

0.8/16 = 0.05

Number of mole
Mole ratio

Empirical formula : CuO

1+1

(d)
CuO + H2 Cu + H2O
(correct chemical formulae of reactants and products 1M)
(correct balance chemical equation 1M)

(e)

The heating, cooling and weighing processes are repeated until a constant

1
1

value is obtained
TOTAL 9

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No
3

Answer

Sub
Mark
1

Total
Mark

(ii) Copper metal

(iii) Insert a glowing splinter into the test tube containing the gas.

TOTAL

10

(a)(i) Cu2+, H+
(ii)

SO42 , OH-

(b)(i) Cu Cu2+
(ii) Cu2+

+ 2e-

+ 2e- Cu

(c)(i) Remain unchanged

(ii) The rate of dissociation/ionization of Cu2+ ions at anode is the same as the
rate of discharged of Cu2+ at the cathode
(d)(i) Oxygen gas

The glowing splinter will be rekindled / relighted.

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No
4

Answer

Sub
Mark

Total
Mark

1+1

(a)
Mg + 2HCl MgCl2 + H2
(correct chemical formulae of reactants and products 1M)
(correct balance chemical equation 1M)

(b)

(c)

(d)(i)
(ii)

Size of particle//magnesium//total surface area

Concentration of hydrogen ion, H+

Average rate of reaction =

Rate of reaction Experiment C is higher than Experiment B

H2SO4 is diprotic acid //dissociate completely in water

to/ produce higher concentration of hydrogen ion, H+

The number of particles/H+ per unit volume is higher

The frequency of collision between hydrogen ion/H+ and Magnesium

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60
// 1.2 cm3s-1
50

atom is higher

The frequency of effective collision is higher

TOTAL

10

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No
5

Answer
(a) Chemical reaction involves oxidation and reduction occurring simultaneously
(b) To detect the current flow//produced
(c)(i) Oxidising agent : bromine water
Reducing agent : iron(II) ion// iron(II) sulphate

Sub
Mark
1

Total
Mark
1

1
1

(ii) Electrode X : Fe2+ Fe3+ + e-

Electrode Y : Br2 + 2 e- 2 Br-

(e) Potassium iodide solution

(f) 0 -1

(g) Add sodium hydroxide, NaOH, solution/ ammonia solution, NH3(aq)

(d)

electron flow

brown precipitate

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TOTAL

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No
6

Answer
(a) Heat change/release when one mole of a metal is displaced from its salt

Sub
Mark
1

Total
Mark
1

1+1

solution by a more electropositive metal

(b) state any one of the observation

Brown solid is deposited/ formed/
Blue solution becomes colourless
Zinc metal dissolves

(c) Zn + Cu2+ Zn2+ + Cu

(correct reactants and products 1M)
(correct balance chemical equation 1M)

(d)(i) H = mC
= (50)(4.2)(8)
= 1680 J// 1.68 kJ
(ii)
Mole of CuSO4 =

50x0.2
1000

= 0.01 mol
(iii)

Heat of displacement of copper =

1.68
0.01

= 168 kJmol-1
H= - 168 kJmol-1

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(e)

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Energy
Zn + Cu2+
H= - 168 kJmol-1
Cu + Zn2+

y-axis with label of energy

Two different energy levels + correct chemical/ionic equation

H= - 168 kJmol-1

(f) Magnesium /Aluminium

TOTAL

11

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SECTION B

No.

Sample answer

Sub
Total
Marks Marks

7(a)(i) Continuous variation

1

7(a)(ii) Height of precipitate (cm)

Tinggi mendakan (cm)
P1 - axes and label(paksi dan label)

P2 unit(unit)

P3 - shape of the graph(bentuk graf)

Volume of barium chloride (cm3)

Isipadu larutan barium klorida (cm3)
7(a)(iii) Volume of 0.5 mol dm-3 barium chloride solution needed to react completely
with 5.0 cm3, 0.5 mol dm-3 potassium chromate(VI) solution = 5 cm3

Isipadu larutan barium klorida 0.5 mol dm-3 yang diperlukan untuk bertindak
balas lengkap dengan 5 cm3 larutan kalium kromat(VI) 0.5 mol dm-3 = 5 cm3
Number of mole of barium chloride
(Bilangan mol barium klorida)

=
=
=

MV
1000
(0.5)(5)
1000
0.0025 mol

1
1

1+1

P1 Volume of BaCl2 (Isipadu BaCl2)

P2 Calculation/steps (Langkah pengiraan)
P3 Answer with unit (Jawapan dengan unit)
7(a)(vi) Ba2+ + CrO42- BaCrO4
P1 reactants (bahan)
P2 product (hasil)
7(b)(i) P1 - Nitrate ion
P2 - Add 2 cm3 dilute sulphuric acid to 2 cm3 salt x solution in a test tube.

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P3 - Add 2 cm3 iron(II) sulphate solution to the solution and mix well.
P4 - Add a few drops concentrated sulphuric acid from the side of slanted test
tube.
P5 A brown ring is produced.
7(b)(ii) P1 + P2 Lead(II) ion and Aluminium ion maybe present.
P3 Pour 2 cm3 potassium iodide solution to a test tube containing 2 cm3 salt
x solution.
P4 Shake well.
P5 If yellow precipitate is formed,
P6 lead(II) ion is confirmed present.

1
1
1
1+1
1
1
1
1
TOTAL

No.

Sample answer

8(a)(i) Polymer is a long-chained molecules,

which is consists of repeating units of monomers.

6
20

Sub
Total
Marks Marks

1
1

1+1

Polimer adalah molekul berantai panjang,

yang terdiri daripada mengulangi unit monomer.
8(a)(ii)

CH3

8(a)iii) Propene

Propena
8(a)(vi) To manufacture piping / bottle crates / carpets / car batteries / ropes

Untuk pembuatan paip / peti botol / permaidani / bateri kereta / tali

8(b)(i)

Able to state any two uses of polymer

Detergent dissolved in water and reduces the surface tension of water
Detergen larut dalam air dan mengurangkan ketegangan permukaan
air

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It ionises in water to form sodium ions, Na+ and detergent anions

Ia mengion dalam air untuk membentuk ion natrium, Na+ dan anion
detergen

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8(b)(ii)

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Detergent anions consist of hydrophobic and hydrophilic parts

Anion detergen terdiri daripada bahagian-bahagian hidrofobik dan
hidrofilik

Hydrophilic part dissolved in water and hydrophobic part dissolved in

grease.
Bahagian hidrofilik larut dalam air dan sebahagian hidrofobik larut
dalam gris.

The movement of water lifts the grease off the surface

Pergerakan air mengangkat gris di luar permukaan

The grease is broken into smaller droplets that are suspended in water
forming an emulsion
Gris dibahagikan kepada titisan kecil yang terampai di dalam air
membentuk emulsi

The greasy droplets which carry the same charge repel one another
Titisan gris yang membawa cas yang sama menolak antara satu sama
lain

When the cloth is rinsed with water, the greasy droplets will be
removed
Apabila kain itu dibilas dengan air, titisan gris akan dikeluarkan

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8

Strength : Able to cleanse in hard water and acidic water

Kelebihan : Dapat membersih dalam air liat dan berasid.

Weakness : Non-biodegredable
Kelemahan: Tidak terbiodegredasi

8(c)

Tradisional medicine
Ubat tradisional

Modern medicine
Ubat moden

Example : Aloe Vera

Contoh: Aloe Vera

Example : Aspirin
Contoh : Aspirin

1+1

Uses : To treat skin wounds

Kegunaan: Merawat luka
kulit

Uses : To relive pain

Kegunaan : Mengurangkan
kesakitan

1+1

TOTAL

20

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SECTION C

No.

Sample answer

Sub
Total
Marks Marks

9(a)(i)
1

9(a)(ii) Q Propane /Propana

P Propanol /Propanol

1
1

OR / ATAU
Q Etane /Etana
P Ethanol /Etanol
9(a)(iii) Compound R:
1. Burnt in excess oxygen to produce carbon dioxide and water.
Terbakar dalam oksigen berlebihan untuk menghasilkan karbon
dioksida dan air.

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1

2. Can be oxidised to carboxylic asid.

Boleh dioksidakan kepada asid karboksilik.
Compound S:
Has a fragrant/fruity smell // insoluble in water // volatile // having dense than

1+1

water// soluble in organic solvents // a colourless liquid

Berbau harum/buah // tidak larut air // meruap // lebih tumpat dari air // larut

dalam pelarut organic // cecair tidak bewarna

State correctly any two of the above statement

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9(b)

C3H8

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+ 502 3 CO2 + 4 H2O

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Correct formula of reactants of reactants & products: 1M

Correct balanced chemical equation: 1M
1 mol of C3H8 produce 3 moles of CO2
1 mol C3H8 menghasilkan 3 mol CO2
Therefore, the number of mol of CO2 produced
Maka, bilangan mol CO2 terhasil
= 0.05 X 3
= 0.15 mol
The volume of CO2 produced
Isi padu CO2 yang terhasil
= 0.15 X 24.0
= 3.6 dm3

1
1
5

ATAU / OR
C2H6 +

7
02 2CO2 + 3H2O /
2

2C2H6 + 702 4CO2 + 6H2O

1 mol of C2H6 produce 2 moles of CO2
1 mol C2H6 menghasilkan 2 mol CO2
Therefore, the number of mol of CO2 produced
Maka, bilangan mol CO2 terhasil
= 0.05 mol X 2
= 0.1 mol
The volume of CO2 produced
Isi padu CO2 yang terhasil
= 0.1 X 24.0
= 2.4 dm3
9(c) A few drops of acidified potassium manganate(VII) solution is added to
compound Q and R.
Beberapa titis larutan kalium manganat(VII) berasid ditambahkan ke dalam
sebatian Q dan R.
Compound Q does not show any changes.
Sebatian Q tidak akan menunjukkan perubahan.

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Compound R decolourise the purple color of acidified potassium

manganate(VII) solution.
Sebatian R akan menyahwarnakan warna ungu kalium manganat(VII)
berasid.

OR /ATAU
A few drops of bromine water are added to compound Q and R.
Beberapa titis air bromin ditambahkan ke dalam sebatian Q dan R.
Compound Q does not show any changes.
Sebatian Q tidak akan menunjukkan perubahan.
Compound R decolourise the brown color of bromine water.
Sebatian R akan menyahwarnakan warna perang air bromin.
9(d)(i) The number of double bonds reduces thus vulcanized rubber is not easily
spoiled by oxygen in air, ultraviolet rays or chemicals.
Bilangan ikatan dubel/ganda dua berkurangan maka getah tervulkan
tidak mudah dirosakkan oleh oksigen dalam udara, sinaran ultraungu atau
bahan kimia.
9(d)(ii) The sulphur cross-link will pull the chains back to their original arrangement.
Rangkai silang sulfur akan menarik rantai polimer kembali kepada susunan
asalnya.
9(d)(iii) When the molecular size increases, the Van der Waals attractive forces
between molecules increases.
Apabila saiz molekul bertambah, daya tarikan Van der Waals antara molekul
bertambah.
More energy needed to overcome the attractive force.
Lebih banyak tenaga diperlukan bagi mengatasi daya tarikan tersebut.

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TOTAL

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No.

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Sample answer

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Total
Marks Marks

10(a) Any one type of strong acid :

Hydrochloric acid // Nitric acid // Sulphuric acid,
Acid reacts with a base / alkali to produce salt and water //
Hydrochloric acid reacts with sodium hydroxide / (any base/alkali) to produce
sodium chloride and water.
HCl + NaOH NaCl + H2O

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1

Acid reacts with a reactive metal to produce salt and hydrogen //

Hydrochloric acids react with Magnesium / Zinc to produce magnesium
chloride / zinc chloride and hydrogen.

Mg + 2HCl MgCl2 + H2

Acid reacts with a carbonate metal to produce salt, carbon dioxide and water
// Hydrochloric acids reacts with calcium carbonate / (any metal carbonate) to
produce calcium chloride, carbon dioxide and water
CaCO3 + 2HCl CaCl2 + CO2 + H2O
10(b) Solution A:
Ethanoic acid partially ionizes/dissociate in water to produce hydrogen ions,
The presence of freely moving hydrogen/ions cause solution A / ethanoic acid
to show its acidic properties.
Solution B:
Without water / in propanone ethanoic acid still exists as molecule,
No freely moving hydrogen/ions present, hence it does not shows its acidic
properties.

1
1

1
1
1
1

10(c) The material and apparatus needed

The calculation involve
The step involve in preparation
Materials :
Solid sodium hydroxide and distilled water.
Apparatus :
50 cm3 beaker, 250 cm3 volumetric flask, electronic balance, glass rod, filter
funnel.

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Determine the mass of sodium hydroxide, NaOH:

No. of moles of NaOH = 1 x 250 = 0.25 mol

1000
Mass of NaOH needed = No. of moles x Molar mass of NaOH
= 0.25 x 40
= 10 g
1. Using an electronic balance, 10 g of sodium hydroxide is exactly

1+1

weighed and placed into a beaker.

2. Distilled water is added to the beaker to dissolve all the solid sodium
hydroxide.

1
1

3. Then the solution is poured into 250 cm3 volumetric flask.

4. The beaker is rinsed with distilled water and the solution is poured

into the volumetric flask.

5. The solution in the volumetric flask is topped up with distilled water

until its calibration mark.

10
TOTAL

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