Global Crude Assay Report 15-4019 Doba Crude Rev2

Intertek Crude Assay
Global Crude Assay Report
Crude Oil Assay Report

For
Cameroon Oil Transportation Company
(COTCO)
15-004019-0-RDAM
Document Reference:
Doba Blend Crude Oil
Crude Oil Assay Report No:
15-004019-0-RDAM
Date of Issue:
11-May-2015
Table of Contents
Job Reference Information
Project Overview ..
4-5
Whole Crude Characteristics
TBP Yield Distribution .
7-8
Assay Summary Table
Detailed Hydrocarbon Analysis of IBP 15 C ..
10
Naphtha Characteristics . 11-12

Kerosene / Distillate Fuel Characteristics ..
13
Distillate Fuels Characteristics .
14
Vacuum Gas Oil Characteristics ..
15
Residue Characteristics ..
16
15-004019-0-RDAM
Job Reference Information
Client Ref:
MT Suez Vasilis - Doba Blend Crude Oil
Date:
11-May-2015
Crude Oil Assay Report No: 15-004019-0-RDAM
Cameroon Oil Transportation Company (COTCO)
FOR THE ATTENTION OF
SAMPLE DETAILS
: 5 Samples received on 30-Mar-2015
SOURCE
: Submitted Samples
DESCRIPTION
: See next page Label description
CONTAINERS
: 5 x 5 litres containers
SEALS
: Intertek 026628
RESULTS
: See attached
Intertek 026621; Intertek 026622; Intertek 026623; Intertek 026625;
Reported by:
Approved by:
Mozes Hitharie Sr.Chemical Analyst
G.Erdogan-Operational Laboratory Manager
Intertek Nederland B.V.

Leerlooierstraat 135
3194 AB Hoogvliet Rotterdam, The Netrherlands
Telephone: +31 10 4902702 Fax: +31 10 4723225
15-004019-0-RDAM

Intertek Nederland B.V.
Leerlooierstraat 135
3194 AB Hoogvliet Rotterdam, The
Netherlands
Telephone: +31 10 4902702

Fax: +31 10 4723225
Client:
Cameroon Oil Transportation Company
Client Contact:
Laurice F Chamago Daouda
Client Reference:
Intertek Reference:
15-004019-0-RDAM
Sample ID:
2397672
Date Received:
30-Mar-2015
Date Start Distillation:
16-Apr-2015
Date Completed:
11-May-2015
Subject:
This report details the assay characterization analysis performed on the Doba
Blend Crude Oil sample submitted by Cotco
Project Overview
Label of Intertek West Africa SARL Caleb Brett
Linesample during loading
Vessel
:Suez Vasilis
Product
:Doba Blend C.O.
Installation
:Cotco
Port
:Kribi Cameroun
Berth
:FSO Kome Kribi 1
Date
:23/03/2014
17-mrt-15
Description Label
Samples Receipt:
Sample submission consisted of five 5 liters containers with all the same label description representing
duplicate aliquots of Doba Blend Crude Oil. No exceptions encountered and no abnormal conditions
observed.
15-004019-0-RDAM
Laboratory Procedures:
Preliminary Analysis-Whole Crude:
The individual crude oil sample segregated for testing was analyzed for the parameters listed in the following
Whole Crude Characteristics table.
The density and water-content were performed. Since the water content is >0.3 % vol , the dehydration step
had to be performed prior the fractional distillation.
Distillation:
Distillation was carried out by ASTM D2892 (15/5) fractionating tower and ASTM D5236 vacuum potstill to
generate the extended true boiling point curve presented within this report.
In consultation with the client the distillations were performed twice to get sufficient product per fraction, so
that all the requested tests could be performed (excluded the RON/MON on the Naphtha fraction).
Characterization Analysis:
The characterization of the crude oil and distillate/residue fractions as generated by the above distillation
procedures were analyzed by the relevant international standards and/or in-house methods in accordance
with client requirements. Where a requested method has proven unsuitable for the sample due to nature or
properties the laboratory may have selected the most appropriate alternative.
Laboratory Observations / Test Method Modifications and Exception Details:
Whole Crude Characteristics
Wax content - UOP 46
Not applicable per method due to the matrix of the crude sample. The wax couldn't be separated from the
original material.
Wax Appearance Temperature/Wax Dissolution Temperature
The sample was submitted to an external laboratory (Intertek Norway) to perform the test.
Naphtha Characteristics
Fractions 3 & 4 RON ASTM D2699 and MON ASTM D 2700
Because of insufficient product yielded during distillation, the tests couldnt be performed according to the
requested methods, therefore the octane numbers were calculated via GC-MS.
Residue Characteristics
Fractions 13 & 14 - Wax content - UOP 46
Not applicable per method due to the matrix of the fractions. The wax couldn't be separated from the original
material.
At 557 C (AET) the distillation was discontinued because signs of incipient cracking were observed.
15-004019-0-RDAM
PROPERTIES OF WHOLE CRUDE

TEST
METHOD
UNIT
RESULTS
Dens ity @ 15C
ASTM D 5002
kg/L
0.9037
Spec. Gravi ty @60/60 F
Cal cul ated
API gravi ty at F
Cal cul ated
Sul phur
ASTM D 2622
Hydrogen Sul fphi de
UOP 163
mg/kg
Total aci d number
ASTM D 664
mg KOH / g
2.23
Ki nemati c Vi scosi ty @ 30C
ASTM D 445
mm/s
194.9
ASTM D 445
mm/s
107.6
ASTM D 445
mm/s
64.37
ASTM D 445
mm/s
41.17
Pourpoi nt upper
ASTM D 5853
18
Pourpoi nt lower
ASTM D 5853
0.9041
25.0
mass %
0.081
<1
Wax Appearance Temperature
IP 389
43.5
Wax Diss ol ution Temperature
IP 389
60.7
Wax Content
UOP 46
mass %
N/A
Fl ashpoi nt
ASTM D 93
25.0
Rei d Vapour Pressure
ASTM D 6377
kPa
Nitrogen content
ASTM D 5762
mg/kg
5.5
1700
Basic Ni trogen
UOP 269
mg/kg
760
Carbon Resi due-MCRT
ASTM D 4530
mass %
5.08
Heptane Insol ubl e Asphaltenes
IP 143
mass %
<0,05
Sodium
IP 501
mg/kg
Vanadi um
IP 501
mg/kg
<1
Nickel
IP 501
mg/kg
13
Iron
IP 501
mg/kg
Calci um
IP 501
mg/kg
140
Zi nc
IP 501
mg/kg
<1
Cadmi um
AAS
g/kg
<50
Copper
AAS
g/kg
<50
Lead
AAS
g/kg
<50
Arseni c
HG-AAS
g/kg
<10
Mercury
HG-AAS
g/kg
<10
Organi c Chloride
ASTM D 4929
mg/kg
Anil i ne Poi nt
ASTM D 611
Sal t content
ASTM D 3230
l bs /1000bbls
<1
104.80
4.9
Water K.F.
ASTM D 4928
vol . %
0.51
Sedi ment content
ASTM D 4807
mass %
0.003
Ash
ASTM D 482
mass %
Calorifi c Val ue, Gross
ASTM D 240
MJ/kg
44.722
Calorifi c Val ue, Net
ASTM D 240
MJ/kg
42.061
Methane
DHA
mass %
<0,01
Ethane
DHA
mass %
0.01
Propane
DHA
mass %
0.06
i so-Butane
DHA
mass %
0.06
n-Butane
DHA
mass %
0.14
neo-Pentane
DHA
mass %
<0,01
i so-Pentane
DHA
mass %
0.14
n-Pentane
DHA
mass %
0.18
15-004019-0-RDAM
0.067
TRUE BOILING POINT DATA

CUT NO. CUT TEMP Density at 15 oC
% WEIGHT
% VOLUME
g / mL
CUT
CUM
CUT
CUM
15
0.5949
0.09
0.09
0.13
0.13
65
0.6713
0.36
0.44
0.48
0.61
95
0.7078
0.76
1.20
0.97
1.58
135
0.7652
1.12
2.32
1.32
2.90
160
0.7420
1.66
3.98
2.02
4.92
175
0.7830
0.88
4.86
1.02
5.94
205
0.8034
1.63
6.49
1.83
7.77
232
0.8240
2.04
8.53
2.24
10.01
275
0.8498
4.87
13.40
5.18
15.19
10
310
0.8669
4.99
18.39
5.20
20.39
11
342
0.8760
4.83
23.22
4.98
25.37
12
369
0.8825
4.33
27.55
4.44
29.81
13
445
0.8935
11.82
39.38
11.96
41.77
14
509
0.9067
13.62
52.99
13.57
55.34
15
557
0.9201
8.25
61.24
8.10
63.44
15-004019-0-RDAM
True Boiling Point Curve (ASTM D 2892 & ASTM D 5236)

15-004019-0-RDAM Doba Blend Crude Oil
600
% mass
% vol
550
500
450
Temperature (C)
400
350
300
250
200
150
100
50
0
0
20
40
60
80
100
Recovery (%)
15-004019-0-RDAM
ASSAY SUMMARY TABLE

1
WC
Properties
Yield on crude
Yield on crude
Cum.Yield
Cum.Yield
Density at 15C
Spec. Gravity @60/60 F
API gravity at F
Total Sulfur
Mercaptan sulfur
Hydrogen Sulfide
Acidity
Viscosity @ -20C
30 C
40 C
50 C
60 C
80 C
100 C
120 C
150 C
Paraffins
Naphthenes
Aromatics (including Bz, Tol)
Aromatics
Olefins
Research Octane Number
Motor Octane Number
Smoke point
Freezing point
Cloud point
Cold filter plugging point
Pour point upper
Pour point lower
Wax Appearance Temperature
Flash Point
VPCR4 (100 F)
Reid Vapor Pressure
Wax content
Total nitrogen
Basic nitrogen
Carbon residue
Asphaltenes
Sodium
Vanadium
Nickel
Iron
Calcium
Zinc
Cadmium
Copper
Lead
Arsenic
Mercury
Organic Chloride
Aniline point
Cetane Index
Refractive index at 70C
Characterisation, K-Factor
Salt
Water
Sediment
Ash
Calorific Value, Gross
Calorific Value, Net
Methane
Ethane
Propane
Isobutane
n-Butane
neo-Pentane
Isopentane
n-Pentane
Distillation - 10%
Distillation - 30%
Distillation - 50%
Distillation - 70%
Distillation - 90%
Remarks
15-004019-0-RDAM
Units
mass %
Vol%
mass %
vol. %
kg/L
mass %
mg/kg
mg/kg
mgKOH/g
cSt
cSt
cSt
cSt
cSt
cSt
cSt
cSt
cSt
mass %
mass %
mass %
Vol%
Vol%
RON
MON
mm
C
C
C
C
C
C
C
kPa
psi
mass %
mg/kg
mg/kg
mass %
mass %
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
g/kg
g/kg
mg/kg
C
lb/1000bbl
Vol%
mass %
mass %
MJ/kg
MJ/kg
mass %
mass %
mass %
mass %
mass %
mass %
mass %
mass %
C
C
C
C
C
0.9037
0.9041
25
0.081
2
Gases
IBP
15
0.09
0.13
0.09
0.13
0.5949
3
15
65
0.36
0.48
0.44
0.61
0.6713
0.6714
79.3
0.0008
4
4
5
Naphtha
65
95
95
175
0.76
3.66
0.97
4.36
1.20
4.86
1.58
5.94
0.7078
0.7584
0.7079
0.7586
68.4
55.0
0.0038
0.0034
3
2
<1
2.23
0.04
6
65
175
4.42
4.31
0.7495
0.7497
57.2
0.0035
2
0.04
194.9
107.6
64.37
41.17
8
9
Distillate Fuel
232
342
342
369
14.69
4.33
15.36
4.44
23.22
27.55
25.37
29.81
0.8643
0.8825
0.8647
0.8833
32.1
28.8
0.0416
0.080
5
4
0.04
5.222
0.59
2.17
1.420
4.202
11.41
8.307
1.082
81.6
17.5
0.9
69.7
66.7
18
3
43.5
25.0
5.5
0.80
N/A
1700
760
5.08
<0.05
5
<1
13
8
140
<1
<50
<50
<50
<10
<10
<1
104.80
7
Kerosene
175
232
3.67
4.07
8.53
10.01
0.8147
0.8150
42.1
0.0071
3
9.54
59.9
38.3
1.8
63.2
60.7
46.2
47.5
6.3
1.482
2.719
11.6
2.3
18.7
5.7
44.0
10.9
24.0
-52.7
15.7
-8.6
-11.9
-12
-12
15,0
20.0
3
11
Vacuum Gasoil
509
557
8.03
7.89
61.25
63.48
0.9171
0.9175
22.7
0.092
12
13
369
509
25.67
25.78
53.22
55.59
0.9023
0.9027
25.3
0.074
10
369
557
33.70
33.67
369
72.45
70.42
0.9070
0.9074
24.4
0.078
0.9297
0.9302
20.6
0.099
557
38.41
36.28
99.66
99.75
0.9568
0.9573
16.3
0.115
14
2.92
4.65
3.36
2.30
1.06
24.73
92.51
33.40
7.393
20.95
9.229
311.7
106.3
46.02
36
54
42
36
42
13.9
670
230
11.2
1600
470
0.50
13.3
910
280
0.16
N/A
2700
1095
7.55
0.29
3
1
18
14
172
<1
N/A
4100
1783
13.8
0.36
6
1
30
22
267
<1
95.60
104.20
97.25
1.4801
12.0
1.4890
12.0
1.4822
12.0
12.2
12.2
Resid
391.1
179.1
70.42
48.7
45.8
5.5
44.8
44.9
63.0
113.5
1.2
2.3
49
13.2
225
78.75
59.4
1.4713
11.8
7.82
60.55
40.8
12.2
11.9
12.0
11.7
68.65
48.6
1.4573
11.6
72.8
77.2
81.5
86.3
95.7
121.0
128.0
136.0
145.7
159.0
104.9
117.0
129.3
142.3
157.6
193.9
198.2
203.5
209.9
219.6
265.7
274.5
285.7
299.3
316.5
4.9
0.51
0.003
0.067
44.722
42.061
<0.01
0.01
0.06
0.06
0.14
<0.01
0.14
0.18
N/A = not applicable
Detailed Hydrocarbons Analysis of IBP - 15 C

TEST
METHOD
UNIT
RESULTS
Density @ 15C
calculated from GC
kg/L
0.5949
Composition
Methane
Ethane
DHA
DHA
mass %
mass %
<0.01
0.08
Propane
DHA
mass %
23.09
iso-Butane
DHA
mass %
20.27
n-Butane
DHA
mass %
neo-Pentane
DHA
mass %
32.43
0.40
iso-Pentane
DHA
mass %
n-Pentane
Cyclopentane
2,2-Dimethylbutane
DHA
DHA
DHA
mass %
mass %
mass %
10.59
8.76
<0.01
0.24
2,3-Dimethylbutane
DHA
mass %
0.66
2-Methylpentane
DHA
mass %
3-Dimethylpentane
n-Hexane
DHA
DHA
mass %
mass %
1.63
0.60
1.25
15-004019-0-RDAM
10
NAPHTHA CHARACTERISTICS (1)

3
RESULTS
RESULTS
TEST
METHOD
UNIT
Initial Boiling Point
ASTM D2892
C5
65
End Boiling Point
ASTM D2892
65
95
0.36
0.76
0.6713
0.7078
Cut Yield
mass %
Density @ 15C
ASTM D 4052
Calculated
0.6714
0.7079
API gravity at F
Calculated
79.3
68.4
Sulphur
ASTM D 5453
mass%
0.0008
0.0038
Mercaptan Sulphur
ASTM D 3227
mg/kg
Paraffins
ASTM D 5443
mass %
81.6
59.9
Naphthenes
ASTM D 5443
mass %
17.5
38.3
Aromaten
ASTM D 5443
mass %
0.9
1.8
RON
Calculated GC-MS
69.7
63.2
MON
Calculated GC-MS
66.7
60.7
Vapour Pressure (DVPE) at 100 F
ASTM D 5191
psi
9.54
7.82
Distillation - 10%
ASTM D 86
72.8
Distillation - 30%
ASTM D 86
77.2
Distillation - 50%
ASTM D 86
81.5
Distillation - 70%
ASTM D 86
86.3
Distillation - 90%
ASTM D 86
95.7
Characterisation, K Factor
UOP 375
15-004019-0-RDAM
kg/L
12.2
11
NAPHTHA CHARACTERISTICS (2)

5
RESULTS
RESULTS
TEST
METHOD
UNIT
ASTM D2892
95
65
End Boiling Point
ASTM D2892
175
175
mass%
3.66
4.42
0.7584
0.7495
Cut Yield
Density @ 15C
ASTM D 4052
Calculated
0.7586
0.7497
API gravity at F
Calculated
55.0
57.2
Sulphur
ASTM D 5453
mass%
0.0034
0.0035
Mercaptan Sulphur
UOP 163
mg/kg
Total Acid Number
ASTM D 664
mg KOH / g
0.04
0.04
Paraffins
ASTM D 5443
mass %
46.2
48.7
Naphthenes
ASTM D 5443
mass %
47.5
45.8
Aromaten
ASTM D 5443
mass %
6.3
5.5
Research Octane Number
ASTM D 2699
RON
44.8
Motor Octane Number
ASTM D 2700
MON
44.9
Distillation - 10%
ASTM D 86
121.0
104.9
Distillation - 30%
ASTM D 86
128.0
117.0
Distillation - 50%
ASTM D 86
136.0
129.3
Distillation - 70%
ASTM D 86
145.7
142.3
Distillation - 90%
ASTM D 86
159.0
157.6
UOP 375
11.9
12.0
15-004019-0-RDAM
kg/L
12
KEROSENE/DISTILLATE FUEL CHARCTERISTICS

7
RESULTS
RESULTS
TEST
METHOD
UNIT
ASTM D2892
175
232
End Boiling Point
ASTM D2892
232
342
mass %
3.67
14.69
0.8147
0.8643
Cut Yield
Density @ 15C
ASTM D 4052
kg/L
Calculated
0.8150
0.8647
API gravity at F
Calculated
42.1
32.1
Sulphur
ASTM D 2622
mass %
0.007
0.042
Mercaptan Sulphur
UOP 163
mg/kg
3.0
5.0
Total acid number
ASTM D 664
mg KOH / g
0.04
0.59
Kinematic Viscosity @ -20C
ASTM D 445
mm/s
5.222
Kinematic Viscosity @ 40C
ASTM D 445
mm/s
1.420
ASTM D 445
mm/s
1.082
ASTM D 445
mm/s
Aromatics
ASTM D 1319
vol %
11.6
18.7
Olefins
ASTM D 1319
vol %
2.3
5.7
Smoke Point
ASTM D 1322
mm
15.7
Freezing point
ASTM D 7153
24.0
-52.7
Cloudpoint
ASTM D 5771
-11.9
Cold Filter Plugging Point
ASTM D 6371
-12
Pourpoint
ASTM D 5950
-12
Wax content
UOP 46
mass %
2.3
Flashpoint
ASTM D 93A
63.0
113.5
Total Nitrogen
ASTM D 4629
mg/kg
1.2
49
Aniline Point
ASTM D 611
60.55
68.65
Cetane Index
ASTM D 4737
40.8
48.6
Refractie Index @ 70 C
ASTM D 1747
UOP 375
Distillation - 10%
ASTM D 86
Distillation - 30%
4.202
1.482
-8.6
1.4573
11.7
11.6
193.9
265.7
ASTM D 86
198.2
274.5
Distillation - 50%
ASTM D 86
203.5
285.7
Distillation - 70%
ASTM D 86
209.9
299.3
Distillation - 90%
ASTM D 86
219.6
316.5
15-004019-0-RDAM
13
DISTILLATE FUEL/VGO CHARACTERISTICS

9
10
RESULTS
RESULTS
TEST
METHOD
UNIT
ASTM D2892/D5236
342
369
End Boiling Point
ASTM D2892/D5236
369
509
mass %
4.33
25.67
0.8825
0.9023
Cut Yield
Density @ 15C
ASTM D 4052
Calculated
0.8833
0.9027
API gravity at F
Calculated
28.8
25.3
Sulphur
ASTM D 2622
mass %
0.080
0.074
Mercaptan Sulphur
UOP 163
mg/kg
Total acid number
ASTM D 664
mg KOH / g
2.17
ASTM D 445
mm/s
11.41
ASTM D 445
mm/s
8.307
ASTM D 445
mm/s
ASTM D 445
mm/s
2.719
Aromatics
ASTM D 1319
vol %
44.0
Olefins
ASTM D 1319
vol %
10.9
Cloudpoint
ASTM D 5771
15,0
Cold Filter Plugging Point
ASTM D 6371
20
Pourpoint
ASTM D 5950
36
Wax content
UOP 46
mass %
13.2
13.9
Total Nitrogen
ASTM D 4629
mg/kg
225
670
Basic Nitrogen
UOP 269
mg/kg
Aniline Point
ASTM D 611
Cetane Index
ASTM D 4737
59.4
Refractie Index @ 70 C
ASTM D 1747
1.4713
1.4801
UOP 375
11.8
12.0
15-004019-0-RDAM
kg/L
2.92
24.73
7.393
230
78.75
95.60
14
VGO CHARACTERISTICS
11
12
RESULTS
RESULTS
TEST
METHOD
UNIT
ASTM D2892/D5236
509
369
End Boiling Point
ASTM D2892/D5236
557
557
mass %
8.03
33.70
0.9171
0.9070
Cut Yield
Density @ 15C
ASTM D 4052
Calculated
0.9175
0.9074
API gravity at F
Calculated
22.7
24.4
Sulphur
ASTM D 2622
mass %
0.092
0.078
Total acid number
ASTM D 664
mg KOH / g
4.65
3.36
ASTM D 445
mm/s
92.5
33.40
ASTM D 445
mm/s
20.95
9.23
Pourpoint
ASTM D 5950
54.0
42.0
Wax content
UOP 46
mass %
11.2
13.3
Total Nitrogen
ASTM D 5762
mg/kg
1600
910
Basic Nitrogen
UOP 269
mg/kg
470
280
Carbon Residue - MCRT
ASTM D 4530
mass %
0.50
0.16
Aniline Point
ASTM D 611
104.2
97.25
Refractive Index @ 70 C
ASTM D 1747
1.4890
1.4822
UOP 375
12.00
12.0
15-004019-0-RDAM
kg/L
15
RESID CHARACTERISTICS
13
14
RESULTS
RESULTS
TEST
METHOD
UNIT
ASTM D2892/D5236
369
557
End Boiling Point
ASTM D2892/D5236
mass %
72.45
38.41
kg/L
0.9297
0.9568
Cut Yield
Density @ 15C
ASTM D 4052/ D70
Calculated
0.9302
0.9573
API gravity at F
Calculated
20.6
16.3
Sulphur
ASTM D 2622
mass %
0.099
0.115
Total acid number
ASTM D 664
mg KOH / g
2.30
1.06
ASTM D 445
mm/s
311.7
ASTM D 445
mm/s
106.3
ASTM D 445
mm/s
46.02
ASTM D 445
mm/s
179.1
ASTM D 445
mm/s
70.42
Pourpoint
ASTM D 97
36.0
42.0
Wax content
UOP 46
mass %
N/A
N/A
Total Nitrogen
ASTM D 5762
mg/kg
2700
4100
Basic Nitrogen
UOP 269
mg/kg
1095
1783
Carbon Residue - MCRT
ASTM D 4530
mass %
7.55
13.8
Heptane Insoluble Asphaltenes
IP 143
mass %
0.29
0.36
Sodium
IP 501
mg/kg
Vanadium
IP 501
mg/kg
Nickel
IP 501
mg/kg
18
30
Iron
IP 501
mg/kg
14
22
Calcium
IP 501
mg/kg
172
267
Zinc
IP 501
mg/kg
<1
<1
UOP 375
12.2
12.2
15-004019-0-RDAM
391.1
16

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