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K
1
ln 2
( K 2 K1 ) K1
1
10
ln
12
1 1
0.693
2 10
20
2.3 ( log10 log 2 )
=
0.693 8
t = 5.8 hrs.
2.
Sol.
Ans. : B
4 10-5 = 4 10-3 XB (use P = KH . XB)
XB = 10-2
X H2O = 0.99
X H2CO3 = 0.01
0.01
10
1000
0.99 18
18
H2CO3 H+ + HCO3
Ka1 >> Ka2
10
[H+] = CKa1 =
105
18
1
pH = (5 log 10/18)
2
= 2.62.
M=
3.
Sol.
Ans. : A
A(g) 3B(g) + 2C(g)
initially
P
O
O
At equation P x
3x
2x
2x = P/4
( P/4 ) . ( 3P/8 )
( 7P/8)
2
Kp =
4.
.
5.
Ans. : B
6.
Ans. : ABCD
7.
Ans. : C
8.
Ans. : A
9.
Ans. : D
Sol.
33 4
P
7.210
x = P/8.
Ans. : ABC
8RT
M
8R 560
VO2 =
32 103
8R 440
VCO2 =
44 103
Maximum vary is of He.
Varg =
10.
Ans. : C
11.
Ans. : ACD
Sol.
The complex is Ag ( CN )2
8R 500
20 103
8R 140
=
4 103
VHe =
VHe
12.
Ans. : ABD
13.
14.
15.
Ans. : A
Ans. : A
Ans. : C
Sol.
A = OH
B=
CH3
OH
CH3
C=
D=
O
16.
17.
18.
Sol.
Ans. : A
Ans. : D
Ans. : D
1.07 3600 1
D=
= 0.04 F
96500
= Fe3+ + e Fe2+
Fe2+ formed = 0.04 moles.
5 M 25 10-3 = 0.04
M = 0.32
Moles of Fe3+ left = (0.200 0.25 0.04)
= 0.01
M = 0.05
KMnO4 is a self indicator.
19.
Ans. : A T, B PR, C S, D Q;
20.
Ans. : A T, B S, C R, D PQ
Ans. : D
10
Sol.
ln [ x ] dx
1
10
10
= 0 dx + 0 dx + 1 dx + ..... + 1 dx + 2 dx + 2 dx
= 1 5 + 2 2 = 9.
22.
Sol.
Ans. : C
f(1+) = 1, f(1) = 0, f(1) = f(1+) f(1)
23.
Sol.
Ans. : C
Equation of the plane 3(x 1) + 0(y 1) + 4(z 1) = 0 3x + 4z = 7
|7|
7
=
Distance from origin =
5
32 + 42
24.
Ans. : B
Sol.
25.
Sol.
x2 y 2
Foci of
+
= 1 is (4, 0) and (4, 0).
25 9
For the hyperbola, ae = 4, e = 2, a = 2.
b2 = a2(e2 1) = 12.
x2 y 2
Equation of the hyperbola is
= 1.
4 12
Ans. B
)( )
r r r r
r
r
Since vectors a and b lie on the same plane, r a . a b = 0
r r r
r a b = 0 is the equation of the plane.
26.
Sol.
Ans. : D
= (5 sin 4 cos )2 = 41 sin2( ) 41.
27.
Ans. : C
Sol.
Z 1 Z 2 Z 3 = Z1 + Z2 + Z3 =
Z1
Z1
Z2
Z2
Z3
Z3
1
4
9
+
+
=1
Z1 Z 2 Z3
Ans. : C
Divide by tan2
(tan + cot )2 + 4a(tan + cot ) + 16 = 0
Let X = tan + cot
then, X2 + 4aX + 16 = 0 has two distinct roots if
16a2 64 > 0 (a + 2) (a 2) > 0 a (,2) (2, ) .. (1)
Also, for the interval (0, /2),
X = tan + cot 2 [ Q AM GM]
The two distinct roots of X2 + 4aX + 16 = 0 are each greater than or equal to 2.
Sum of roots = 4a > 4 a < 1
.. (2)
5
(3)
and f(2) > 0 4 + 8a + 16 > 0 a >
2
5
29.
Sol.
Ans. : ABCD
(i) By geometry, in AEF, AE = AF = AD sec A/2
AEF is isosceles.
(ii) Area of ABC = Area of ABD + Area of ADC
1
1
A
1
A
bc sin A = b . AD sin
+ c . AD sin
2
2
2
2
2
2bc
A
AD =
cos
.
b+c
2
A
2bc
(iii) From (i) AE = AD sec
=
= H.M. of b and c.
2 b+c
A
4bc
A
(iv) EF = EF + DF = 2ED = 2AD tan
=
sin
2
b+c
2
A
AA
2 2
B
D
F
30.
Sol.
Ans. : CD
Simplifying the given equation to eliminate the denominators
and let f(x) = A1(x a2) (x a3) + A2(x a1) (x a3) + A3(x a1) (x a2)
then f(a1) > 0, f(a2) < 0 and f(a3 > 0.
By the theorem on continuous functions we get the result.
31.
Ans. : CD
Sol.
2
M
2
3M
Ans. : ABCD
f(x) = f(1 x)
1
1
Put x = x +
then f x + = f x
2
2
1/2
f x + sin x dx = 0
2
1
1
Also, f(x) = f(1 x) and for x = , we have f( /2) = 0
Again, given f(1/4) = 0, f(3/4) = 0 and also f(1/2) = 0
But, Rolles theorem, f(x) = 0 at least twice in [0, 1].
1
Also,
f (1 t ) e
sin t
1/2
sin y
dy (by putting 1 t = y).
f ( y)e
dt =
1/2
33.
34.
35.
Sols.
Ans. : A
Ans. : A
Ans. : B
B
H
A
H
B
Ans. : C
Ans. : C
Ans. : C
Let P1 begin the letters chain writing to P2 and P3
Now, P2 on receiving a letter from P1 will write to two others persons other than himself.
So, P2 has (n 1) C2 choices including a choice in which he may write to P1.
m 2
C
Probability that P2 will not write to P1 is n1 2
C2
m 2
n 1
C2
C2
.
2
n3
Thus, the probability that P1 does not receive a letter at the second state =
n 1
Now, each of the four persons receiving a letter from P2 and P3 will write two letters each
to other persons.
4
n3
Probability that none of these four persons write letters to P1 is
. This is the third
n 1
stage .
By probability of none of the 8 recipients of the letters write letters to P1 in the 4th stage is
8
n3
n 1 .
n 1
Probability of P1 not receiving a letter in first M stages
th
22
23
n 3 n3 n3
n3
=
.....
n 1 n 1 n 1
n 1
2m 1
2m 1
n 3
=
n 1
39.
Sol.
2+ 22 + 23 +.....+ 2m 1
n 3
=
n 1
2m 2
Ans. :
1) Same ax + by + c = 0 is a focal chord of the parabola the angle between the tangents at
A and B is 90o.
ii) Equation of a circle touching y = x at (2, 2) is (x 2)2 + (y 2)2 + (y x) = 0
Since this touches the y-axis also ( 4)2 = 32 = 4 4 2 .
||
Min radius =
=42 2
2
z z1
iii) arg
represents the major arc of a circle chord subtending 45o on
=
4
z z2
circumference, and 90o at the centre.
45o
r2 + r2 = z1z2
2r = 6 r = 3 2
r r r
r r r
iv) a b c = a b c
rr r rr r
rr r rr r
a/ .c/ b/ a.b c = a/ .c/ b/ b.c a
rr r
rr r
a.b c = b.c a
r
r
a and c are collinear vectors
angle between them is zero.
2
Z2(3, 5)
( ) ( )
( ) ( ) ( ) ( )
( ) ( )
40.
Sol.
Ans. : A P, B S, C S, D Q.
A. k = 2
1
dy 2
2
1
dy
=
2 =
y1=
2
x 1
dx
dx
( x 1)
( x 1)3
( y 1)
d2y
dx 2
dy
= 2
4
( x 1)
dx
B. = 3
Max. distance = sum of the radii + distance between the centraes = 3
C. k = 3
2
f(x) = 3x2 6x 1 = 0 at x = 1
3
2
in [0, 4], x = 1 +
is a point of minimum.
3
Thus, max f(x) = max. { f (0), f (4)} = 15.
D. Ans. : 0
F(x) = (cos2 x 3)2 4 and 4 (cos2 x 3)2 9
Thus, min. of f(x) is zero.
Ans. : C
Sol.
y = y0 sin
42.
Ans. : A
t
V0
i = 1 e
R
Sol.
5 x
5 x
1
cos t sin
=
2l
2l
2
x = 10 cm, 50 cm, 70 cm, 110 cm, 130 cm.
L
where =
t
T
V0
t + e
charge flown = i dt =
R
0
V
V
V L
= 0 + e 1 1 = 0 = 02 .
R
Re
R e
A/2
A
S
O r
Z1(9, 5)
43.
Sol.
Ans. A
Q0
= L
2C
L =
44.
Sol.
Q0 2
= U0
2 ( 2C )
Q0 = 2 CU 0
U0
C
Ans. : B
a
f=m
2
mx - f = ma
mA 2
f=
sin t
3
mg
mA 2
max friction force =
3
45.
Ans. : B
Sol.
2
3Gm2
1
3Gm
Centre of mass is the inertial frame of reference. 3 mv 2
=
2r
d
2
v=
1 1
2Gm
2r d
3v
1 1
6Gm
2r d
46.
Ans. : A
Sol.
47.
Ans. : B
Sol.
Wab = 0
3Qd
2 A 0
VB VC =
3Q
(2d )
2 A 0
3R
Qab = N
( 2T0 )
2
Wbc = Nr ( 3T0 ) ln 3
Qbc = Nr ( 3T0 ) ln 3
5R
Qca = n
(T0 3T0 ) = 5NRT0
2
NRT0 ( 3ln 3 2 )
Efficiency =
NRT0 ( 3 + 3ln 3)
3ln 3 2
=
3 (1 + ln 3)
48.
Ans. : B
Sol.
Required = R +
49.
Sol.
Ans. : ABD
V0 ir iR = 0
2R ( 2R )
V0 ir 3V0 = 0
5V0
i i =
R
2
4R
+ R = 3R = 30 .
iR = 2V0 , iR = 3V0
Va ir = Vb
Vb Va = 2V0
25 LV0 2
1 5V0
L
=
2 R
R2
When S is opened + L 5V0 + 3V0 = 0 L = 2V0
UL =
3Q
2 A 0
9Qd
VA VC =
2 A 0
50.
Ans. : ACD
Sol.
UC UA = NCr(TC TA) =
QBC = NC p (TC TB )
5 P0V0
2
WABC =
51.
Ans. : ABCD
Sol.
M=
QABC = 4P0V0
P0 1 + r
I0 z =
0
2
3P V
Cr
( PCVC PAVA ) = 0 0
R
2
5P V
C
= P ( PCVC PBVB ) = 0 0
R
2
= 40R
C = 4R
0 1 + ( r ) R
= 40R3
xG =
y=
52.
Sol.
1
M
1
M
0 1 + ( R )( R cos ) = 0
0
2
0 1 + ( R )( R sin ) = 2 .
0
Ans. : ABCD
+8 3
1
i=
= A
from to + in cell 2
3 + 6 +1 2
1
1
P2 = 8 = 4W
P1 = 3 = 1.5
2
2
Cell 1 is charging. Cell 2 is discharging.
Power dissipated in the circuit
2
1
= ( 3 + 1 + 6 ) = 2.5 W.
2
53.
Sol.
Ans. : C
At t = 300 s
54.
Ans. : B
Sol.
1( sin(a0 ) ) =
cos =
2
3
4
2
sin 30 =
3
3
5
sin =
9
5
3
3m
60
55.
Sol.
Ans. : C
3 3 m
length of the shadow on the water surface = cot
2
=
5
56.
Ans. : D
Sol.
E 4 R 2 =
57.
Ans. : B
Sol.
For a = 0
d=
58.
Sol.
+ Ze
0
E=
d
= (R r)
R
3Ze
R3
Ans. : A
For E to linearly dependent on r
= constant
a=R
Ze
4 0 R 2
independent of a.
Ze = 4 r 2 dr
0
4
3
0
r3
So that E(4r2) =
59.
Sol.
E=
r
3 0
Ans. : A Q, B T, C R, D P
1
X L = L
XC =
C
XL
1 XL
=
= 2 ( LC ) = 9n 2 ( LC ) = 9
X C C X C
XL = 9R
Z=
(8R ) + R
2
65 R
V
1
I0 = 0
I 0 XL
9R
65
I0 R
v
vR = 0 sin t
I 0 XC
9
2
V
= 0 cos t
9
65V0
vad =
sub t where cos =
9
65
2
cos =
65V0
1
cos t + cos 1
9
65
8V
v
v
vcd = 0 sin (t + ) . = 0 sin t
= 0 sin t
9
9
9
=
vbd
60.
Sol.
Ans. : A Q, B P, C R, D S.
M
m
v0 = mv1 v2
2
2
2v1 v2 = v0
. (1)
m l
m l ml 2
v2
v0 =
12
2 4
2 4
2l 3v2 = 3v0 . (2)
l
e=1
+ v1 + v2 = v0 .. (3)
4
solving equations (1), (2) and (3) v1 =
VG
m
( v0 ) + m ( 0 ) v
= 2
= 0
3m
3
2
8v0
15
v2 =
v0
15