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Chapter 4d
pe = 20.77-pH
The upper limit of pe is 20.77 at a pH of zero, and 6.77 at a pH of 14.
While the lower boundary is defined by the pe or the Eh and pH values for which
liquid water is in equilibrium with H2(g) at 1 bar pressure.
H+ = e- = 1/2H2(g)
logK = 0
pe=-pH
Chapter 4d
Chapter 4d
Chapter 4d
Chapter 4d
low pe conditions.
In deep or older groundwaters, any remaining organic matter will most likely be
refractory (not easily utilized by bacteria), such as coal and redox conditions often
dont change in these systems due to biological activity.
Contamination in groundwater can create redox zones from anoxic near the point
of contamination to oxic downgradient.
Typically the wastes are anoxic (such as from the bottom of a landfill), and as the
plume moves away from its source it is gradually oxidized by a transfer of oxygen
from mixing with recharge and unpolluted water.