Documente Academic
Documente Profesional
Documente Cultură
NATIONAL
CHEMISTRY OLYMPIAD
NATIONAL EXAM PART 1
Prepared by the American Chemical Society Olympiad Examinations Task Force
60 questions
8 questions
2 lab problems
single-answer multiple-choice
problem-solving, explanations
laboratory practical
1 hour, 30 minutes
1 hour, 45 minutes
1 hour, 30 minutes
A periodic table and other useful information are provided on page 2 for student reference. Students should be permitted to use nonprogrammable calculators.
DIRECTIONS TO THE EXAMINEEPART I
DO NOT TURN THE PAGE UNTIL DIRECTED TO DO SO. Answers to questions in Part I must be entered on a Scantron
answer sheet to be scored. Be sure to write your name on the answer sheet; an ID number is already entered for you. Make a record
of this ID number because you will use the same number on both Parts II and III. Each item in Part I consists of a question or an
incomplete statement that is followed by four possible choices. Select the single choice that best answers the question or completes the
statement. Then use a pencil to blacken the space on your answer sheet next to the same letter as your choice. You may write on the
examination, but the test booklet will not be used for grading. Scores are based on the number of correct responses. When you
complete Part I (or at the end of one hour and 30 minutes), you must turn in all testing materials, scratch paper, and your Scantron
answer sheet. Do not forget to turn in your U.S. citizenship statement before leaving the testing site today.
Not valid for use as an USNCO Olympiad National Exam after April 26, 2005.
Distributed by the ACS DivCHED Examinations Institute, University of Wisconsin - Milwaukee, Milwaukee, WI.
All rights reserved. Printed in U.S.A.
ampere
atmosphere
atomic mass unit
atomic molar mass
Avogadro constant
Celsius temperature
centi prefix
coulomb
electromotive force
energy of activation
enthalpy
entropy
equilibrium constant
CONSTANTS
m
M
M
mol
h
P
k
Rf
s
T
t
V
EQUATIONS
E = Eo
1
1A
1
H
1.008
3
Li
RT
ln Q
nF
k E 1 1
ln 2 = a
k1 R T1 T2
H 1
ln K =
+ constant
R T
13
3A
5
B
14
4A
6
C
15
5A
7
N
16
6A
8
O
17
7A
9
F
18
8A
2
He
4.003
10
Ne
6.941
9.012
10.81
12.01
14.01
16.00
19.00
20.18
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
22.99
24.31
19
K
20
Ca
3
3B
21
Sc
4
4B
22
Ti
5
5B
23
V
6
6B
24
Cr
7
7B
25
Mn
8
8B
26
Fe
9
8B
27
Co
10
8B
28
Ni
11
1B
29
Cu
12
2B
30
Zn
58.69
63.55
65.39
69.72
72.61
74.92
78.96
79.90
83.80
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
26.98
28.09
30.97
32.07
35.45
39.95
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
39.10
40.08
44.96
47.88
50.94
52.00
54.94
55.85
58.93
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
(98)
44
Ru
101.1
45
Rh
102.9
106.4
107.9
112.4
114.8
118.7
121.8
127.6
126.9
131.3
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
85.47
87.62
88.91
91.22
92.91
95.94
55
Cs
56
Ba
57
La
72
Hf
73
Ta
74
W
132.9
137.3
138.9
178.5
180.9
183.8
186.2
190.2
192.2
195.1
197.0
200.6
87
Fr
88
Ra
89
Ac
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
111
112
114
(269)
(272)
(277)
(2??)
(223)
(226)
(227)
58
Ce
59
Pr
(262)
60
Nd
(263)
61
Pm
(262)
62
Sm
(265)
63
Eu
(266)
64
Gd
65
Tb
66
Dy
67
Ho
173.0
175.0
101
Md
102
No
103
Lr
144.2
(145)
150.4
152.0
157.3
158.9
162.5
164.9
167.3
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
(237)
(244)
(243)
(247)
(247)
(251)
(252)
(257)
(258)
70
Yb
(209)
168.9
140.9
238.0
209.0
69
Tm
90
Th
231.0
207.2
68
Er
140.1
232.0
Page 2
(261)
204.4
(259)
(210)
(222)
71
Lu
(262)
DIRECTIONS
When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.
1. Which solution produces a black precipitate when added
to an aqueous copper(II) solution?
(A) NH3
(B) (NH4)2S
(C) K2SO4
(D) NaOH
(B)
(C)
(D)
(B) NO2
(C) SiO 2
(D) SO2
(B) potassium
(C) sodium
(D) zinc
(B) 2.50
(C) 3.00
(D) 4.50
(C) Draw the liquid above the line on the pipet using a
pipet bulb. With a finger on the top of the pipet
allow the curve of the meniscus to drop to the line.
Place the tip of the pipet against the side of the
receiving container and allow the liquid to drain.
(A) 2
(B) 3
(C) 4
(D) 8
(A) I only
(B) II only
(A) MnO
(B) Mn2O3
(C) Mn3O4
(D) MnO2
Page 3
(B) 11/1
(C) 28/1
(D) 45/1
(B) 28.6
(C) 42.9
(D) 85.7
17. When NaF, MgO, KCl and CaS are listed in order of
increasing lattice energy, which order is correct?
(A) MgO, NaF, KCl, CaS
(B) 12 kJ
(C) 22 kJ
(D) 298 kJ
Bond Energies
kJ/mol
H-H
436
H-N
386
N-N
193
N=N
418
NN
941
(A) 995 kJ
(B) 590 kJ
(C) 67 kJ
(D) 815 kJ
Page 4
(B) 23
(C) 45
(D) 64
(B) 20.3 C
(C) 26.9 C
(D) 27.2 C
I.
II.
III.
rate
rate constant
Halflife
(A) I only
26. The equation and rate law for the gas phase reaction
between NO and H2 are;
2NO(g) + 2H2(g) r N 2(g) + 2H 2O(g)
Rate = k[NO]2[H 2]
What are the units of k if time is in seconds and the
concentration is in moles per liter?
(A) L. s. mol -1
(B) L2. mol -2. s-1
(C) mol . L-1. s-1
(B) 210 s
(C) 420 s
(D) 630 s
(B) II only
(B)
(C)
(D)
(B) step 2
(C) step 3
(D) step 4
(C) 25
(D) 4.010-4
(A) II only
(B) 50
(B) 0.80
(C) 2.80
(D) 3.40
Page 5
H2PO4
6.210-8
(B) 2.410-6
(C) 1.810-7
(D) 5.610-12
-7
(B) 8.410
(C) 1.310
-3
(D) 2.010-3
-5
(C) 1033
(D) 1078
(A) I only
(B) II only
(A) 0.355 V
(B) 0.178 V
(C) 0.178 V
(D) 0.355 V
(B) 0.22
(C) 0.33
(D) 0.66
(B) 5
(C) 7
(D) 9
(B) Br
(C) Ge
(D) Se
(B) Mg
(C) Al
I.
II.
III.
(D) K
atomic radius
density
electronegativity
(A) I only
(A) 0.16
Page 6
(B) 1026
(A) 1022
approximate value
Ag+(aq) + e r Ag(s) +0.80
of the equilibrium
Cr3+(aq) + 3e r Cr(s) 0.74
constant, Keq , at 25 oC for the reaction;
3Ag+(aq) + Cr(s) r Cr3+(aq) + 3Ag(s)
(A) alpha
(B) beta
(C) gamma
(A) resonance.
(B) the Lewis structure of O2.
(D) the hybridization of atomic orbitals in O2.
50. What is the geometry of the iodine atoms in the I3- ion?
(A) bent
(B) linear
(C) T-shaped
(D) triangular
O
S
O
(A) 0, 0
(B) 2, 0
(C) +2, 1
(B) 2
(B) CH3COOH
(C) ClCH2COOH
(D) ClCH2CH2COOH
(B) two
(C) three
(D) four
(B) meta-C6H4Cl2
(C) CH2ClBr
(D) CH3CH(Cl)CH2CH3
(D) +6, 2
(A) HCOOH
(D) SF6
2
(D) substitution
(A) one
(C) SbF5
(C) reduction
(B) polymerization
(A) BrF 3
(A) addition
(C) 3
END OF TEST
(D) 4
(B) aldehydes
(C) ethers
(D) alkynes
Page 7
Number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
Answer
B
D
A
C
D
D
A
C
A
B
D
A
D
D
A
A
D
D
C
C
A
D
D
B
A
B
C
D
C
B
Number
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
Answer
A
A
D
B
B
B
C
B
C
D
C
A
C
A
A
B
B
D
C
B
A
C
B
D
D
D
C
D
D
B