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FIITJEE
INSTRUCTIONS
A. General Instructions
1.
2.
3.
4.
5.
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Parts.
Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
Each part has only one section: Section-A.
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
Section-A (01 to 30) contains 30 multiple choice questions which have only one correct answer.
Each question carries +4 marks for correct answer and 1 mark for wrong answer.
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Useful Data
PHYSICS
2
g = 10 m/s
Planck constant
Charge of electron
e = 1.6 1019 C
Mass of electron
m e = 9.1 1031 kg
Density of water
water = 10 3 kg/m 3
Atmospheric pressure
Pa = 105 N/m 2
Gas constant
R = 8.314 J K1 mol1
CHEMISTRY
Gas Constant
Avogadro's Number Na
Plancks constant h
1 Faraday
1 calorie
1 amu
1 eV
=
=
=
=
=
=
=
=
=
=
8.314 J K1 mol1
0.0821 Lit atm K1 mol1
1.987 2 Cal K1 mol1
23
6.023 10
6.625 1034 Js
6.625 1027 ergs
96500 coulomb
4.2 joule
1.66 1027 kg
19
1.6 10 J
Atomic No:
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Physics
PART I
SECTION A
(Single Correct Choice Type)
This section contains 30 multiple choice questions. Each question has four choice (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1.
2m/s
A
2.
3.
O
3m
15 m
v = 20 m/s
1
mv 20 .
2
A tunnel is dug along a diameter of the planet and the particle is dropped into it from the surface,
when the body reaches the centre of the planet, its speed is
v
(A) v0
(B) 0
2
v0
(C) Zero
(D)
2
The binding energy of a particle of mass m with a planet, when it is on the planets surface, is
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4.
Consider the two identical particles shown in the given figure. They are
released from rest and can move towards each other under the influence of
their mutual gravitation forces. Speed of each particle, when the separation
reduces to half of initial value equals
GM
2GM
(A)
(B)
d
d
(C)
5.
GM
2d
d
M
A gas of adiabatic exponent is supplied heat at a constant pressure. What is the ratio between dQ,
dW and dU in the process
(B) 1 : 1 : 1
(C) : 1 : 1
(D) : 1 : 1
(A)
6.
: 1:
45
20m
10m
15m
7.
a(m/s2)
+2
O
t(sec)
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8.
(C)
9.
a0
(D) 2
(A) tan ()
(C) cot1()
sm
oot
L
(a0 g) sin
Find minimum value of the angle so that block of mass m does not
move on rough surface. The coefficient of static friction between the block
and surface is whatever may be the value of applied force F.
1
() Rough Surface
1
(B)
tan1( )
2
1
(D) cot 1( )
2
10.
A steel ring of radius r and cross-sectional area A is fitted on to a wooden disc of radius R(R > r). If
Youngs modulus be Y, then the force with which the steel ring is expanded is :
R
R r
(A) AY
(B) AY
r
r
Y R r
Yr
(C)
(D)
A r
AR
11.
A rod of length 40 cm has the coefficient of linear expansion 1 = 6 10 /C. Another rod of length l
has the coefficient of linear expansion 2 = 4 106/C. If the difference in the lengths of the two rods
always remain same at all temperatures, then the value of l is
(A) 26 cm
(B) 60 cm
(C) 80 cm
(D) 32 cm
12.
(C)
g
d
(D) 2
g
d
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13.
A body executes simple harmonic motion. The potential energy (PE), kinetic energy (KE) and total
energy (TE) are measured as a function of displacement x. Which of the following statements is true?
(A) TE is zero when x = 0
(B) PE is maximum when x = 0
(C) KE is maximum when x = 0
(D) KE is maximum when x is maximum
14.
15.
16.
For a particle executing simple harmonic motion, the correct variation of acceleration a with
displacement x is given by
a
a
(A)
(B)
(C)
(D)
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17.
An open organ pipe of length L vibrates in second harmonic mode. The pressure variation is
maximum, (neglect end corrections)
(A) at the two ends
L
(B) at a distance
from either end inside the tube
4
(C) at the midpoint of the tube
(D) none of these.
18.
19.
Three rods of the same mass are placed as shown in the figure. What
will be the co-ordinates of the center of mass of the system?
a
a
(A) (a/2, a/2)
(B)
,
2
2
(C) 2a , 2a
3
3
20.
agent
B
R
m
smooth
A
Y
(0, a)
O
(a, 0)
a a
(D) ,
3 3
The density of a liquid varies with depth h from the free surface as = kh. A small body of density
1 is released from the surface of liquid. The body will
21
(A) come to a momentary rest at a depth
from the free surface
k
(B) execute simple harmonic motion about a point at a depth 1 from the surface
k
1
(C) execute simple harmonic motion of amplitude
k
(D) all of the above
Space for rough work
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21.
At the center of a non-uniform ring of radius R, made up of two uniform halves of mass 2M and M (G :
Newtons gravitational constant)
(A) field and potential both are zero
(B) field is zero but potential is 3GM
R
GM
(C) field is zero but potential is
R
2GM
3GM
(D) magnitude of field is
and potential is
2
R
R
22.
For a satellite of mass m orbiting the earth very close to earths surface (mass of earth = M, radius of
earth = R) total energy is
(A) zero
(B) greater than zero
GMm
GMm
(C)
(D)
R
2R
23.
An ideal gas has initial volume V and pressure P. In doubling its volume the minimum work done will
be in the following process (of given processes)
(A) Isobaric process
(B) Isothermal process
(C) Adiabatic process
(D) None of the above
24.
A particle moving in the positive x-direction has initial velocity v0. The particle undergoes retardation
kv2, where v is its instantaneous velocity. The velocity of the particle as a function of time is given by
2v 0
(A) v = v0/(1 + kv0t)
(B) v
1 kt
v0
v0
(C) v
(D) v
kt
(1 k 2 v 20 t)
25.
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26.
The elongation of a freely hanging uniform steel rope, if its length is doubled, will increase in the ratio
of
(A) 2 : 1
(B) 4 : 1
(C) 8 : 1
(D) 16 : 1
27.
(B)
(C)
mV02
2
D
m, R
V0
A
(D) mV02 .
O
28.
A rope of mass m is looped in a circle of radius R and rotated with a constant angular velocity 0
about its axis in gravity free space. Find the tension in the rope ?
2
(A) T mR20
(B) 2 m R
(C) T
29.
30.
mR20
2
(D) 4mR20
The displacement function of a oscillating body is given by x = 0.3 sin 10 t where x and t are
6
A simple pendulum is attached to the roof of a stationary elevator. If the time period of oscillation is T
when it is stationary, what will be time period of oscillation when the elevator falls freely
(A) 0
(B) T/2
(C) 2T
(D) none of these
Space for rough work
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Chemistry
PART II
SECTION A
(Single Correct Choice Type)
This section contains 30 multiple choice questions. Each question has four choice (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1.
3NaClO
NaClO3 + 2NaCl
(A)
(B)
(C)
(D)
2.
It is disproportionation reaction
Oxidation number of chlorine decreases as well as increases in this reaction
This reaction is used for the manufacturing of halates
All the above
CaCO3(s)
CaO(s) + CO2(g)
In the reaction A2 (g) + 4B2 (g) 2AB4 (g), H 0. The decomposition of AB4 (g) will be not favored
at
(i) Low temperature and high pressure
(ii) High temperature and low pressure
(iii) Addition of inert gas at constant pressure
(iv) Addition of inert gas at constant volume
(v) Using catalyst
(vi) Compressing reaction mixture by mass less and friction less piston
(A) (ii), (iii)
(B) (i), (iv), (v), (vi)
(C) (i), (ii), (iii), (iv)
(D) (ii), (iii), (iv), (v), (vi)
4.
Diborane reacts with ammonia under different condition to give a variety of products. Which one of
among the following is not formed in these conditions?
(A) B2H6.2NH3
(B) B12H12
(C) B3N3H6
(D) (BN)3
Space for rough work
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5.
Heat
Z
LiH
B
X
Y LiBH4
Find the value of wave number in turns of Rydbergs constant, when transition of electron takes
place between two level of He+ ion whose sum is 4 and difference is 2.
(A) 8R/9
(B) 32R/9
(C) 3R/4
(D) none
7.
CH2CH3
The IUPAC name of the compund CH3CH2CH2 CH
CH
CH
CH2CH3
CH3 CH2CH3
CH3
CH3
(A) 3, 3 diethyl-4-methyl-5-isopropyloctane
(B) 3, 3 diethyl-5-methyl-5-isopropyloctane
(C) 4-isopropyl-5-metheyl-6, 6-diethyloctane
(D) 6, 6-diethyl-4-isopropyl-5-metheyloctane
8.
CN
C
(A)
(B)
(C)
(D)
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9.
12
Which one of the following structures represents a different compound from the other three?
(A) 1
(C) 4
(B) 2
(D) 3
10.
11.
When a substance A reacts with water it produces a combustible gas B and a solution of a substance
C in water. When another substance D reacts with this solution of C, it also produces the same gas B
even on reaction with dilute sulphuric acid at room temperature. A imparts a deep golden yellow
colour to a smokeless flame of Bunsen burner. A, B, C and D respectively are
(A) Na, H2, NaOH and Zn
(B) K, H2, KOH and Al
(C) Ca, H2, Ca(OH)2 and Sn
(D) CaC2, C2H2, Ca(OH)2 and Fe
12.
13.
A compound X on heating gives a colourless gas. The residue is dissolved in water to obtain Y.
Excess CO2 is bubbled through aqueous solution of Y when Z is formed. Z on gentle heating gives
back X. The X is
(A) CaCO3
(B) Ca(HCO3)2
(C) Na 2CO 3
(D) NaHCO3
Space for rough work
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14.
O
H3C
C
C
O
OMe
C
C
H3C
OMe
C
H
16.
Step : 1
2NO
N2O 2
Step : 2
N2O 2 H2
N2 O H2O
Step : 3
N2O H2
N2 H2O
(A) These steps cannot be the mechanism under any circumstances
(B) These steps could be the mechanism if step 1 is the slow step
(C) These steps could be the mechanism if step 2 is the slow step
(D) These steps could be the mechanism if step 3 is the slow step
17.
If Ca 3(PO4)2 and H3PO3 contain same number of P atom, then the ratio of oxygen atoms in these
compounds respectively is
(A) 8/3
(B) 2/3
(C) 3
(D) 4/3
Space for rough work
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18.
th
1
Cn01
n 1 t C
respectively. The t3/4 and t1/2 are related as
(A) t3 / 4 t1/ 2 2n1 1
(B) t 3/ 4 t1/ 2 2n1 1
(C) t3 / 4 t1/ 2 2n1 1
19.
In which on of the following species the central atom has the type of hybridization which is not the
same as that present in the other species?
(A) SF4
(B) I3
2
(C) SbCl5
(D) PCl5
20.
OH
OH
H3C
NO2
CH3
NO 2
(C)
H3C
OH
CH3
(D)
OH
O2N
H3C
CH3
NO2
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21.
(B)
Br
H
+
: NH 2
(C)
: NH 2
Br
(D)
Br
H
+
H
+:
22.
H
: NH 2
NH 2
C 6H 5CHC 6H 5
C 6H 5
CH
(II)
CH3 (V)
C 6H 5
CH
CH
CH2
(III)
CH 3
CH CH3
(VI)
CH 3
CH 2
CH3
CH3
23.
24.
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25.
16
The degree of dissociation of two weak acids, 1 and 2 are in ratio 1 : 2. The value of K a 2 10 4 ,
1
(A) 8 104
(C) 4 104
(B) 2 104
(D) 1 104
27.
Two moles of CO and one mole of O2 are taken in a container of volume one litre to form two moles
of CO2 according to equation:
2CO g O2 g
2CO 2 g ; H 560 kJ
The pressure in the vessel changes from 70 atm to 40 atm. If the gases deviate appreciably from
ideal nature (1.0 L atm = 0.1 kJ), then
(A) U = 555.895 kJ
(B) U = 518.95 kJ
(C) U = 557 kJ
(D) U = +518.95 kJ
28.
If the solubility of SrSO4 in water, 0.01 M Na2SO4 and 0.02 M Sr3(PO4) 2 be S1, S2 and S3, then select
the correct order of solubility
(A) S1 < S2 < S3
(B) S1 > S2 > S3
(C) S1 < S3 < S2
(D) S3 < S1 < S2
29.
The average speed of an ideal gas molecule at 27C is 0.3 ms1. The average speed of the same at
927C will be
(A) 0.6 ms1
(B) 0.3 ms1
1
(C) 0.9 ms
(D) 3 ms1
30.
Temperature (K)
26.
1000 A
900
800
700
C
600
B
500
400
300
200
100
D
0
5 10 15 20 25 30 35 40 45 50 55
Time (in minutes)
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Mathematics
PART III
SECTION A
Straight Objective Type
This section contains 30 multiple choice questions numbered 1 to 30. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct
1.
If l,m,n are in A.P., then the straight line lx + my + n = 0 will pass through the point
(A) (1, 2)
(B) (1, 2)
(C) (2, 1)
(D) (1, 2)
2.
Equation of lines which passes through the points of intersection of the lines 4x 3y 1 = 0 and 2x
5y + 3 = 0 and are equally inclined to the axes are
(A) y x = 0
(B) y 1 = 1(x 1)
(C) x 1 = 2(y 1)
(D) none of these.
3.
(B) y-axis
(D) none of these.
2
4.
5.
6.
(A) 2,
2
(B) (2, 2)
(D) (2, 11).
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7.
If latus rectum of an ellipse be equal to half of its minor axis then its eccentricity is
(A) rational number
(B) irrational number
(C) ellipse not possible
(D) Integer
8.
If distance between the directices be thrice the distance between the focii then eccentricity of the
ellipse is
1
2
(A)
(B)
3
3
1
7
(C)
(D)
.
2
8
9.
By shifting the vertex of a parabola which of the following will definitely change
(A) latus rectum
(B) axis of symmetry
(C) directrix
(D) focus
10.
x2 y2
1 from a focus is
a2 b2
(B) a(e cos)
(D) a(1 + 2cos).
x2 y2
x2 y2
1 have in common
25 16
25 16
(A) centre only
(B) centre, foci and directrices
(C) centre, foci and vertices
(D) centre and vertices only.
11.
The ellipse
12.
If x 7 4 3 then x
(A) 4
(C) 2
(B) 6
(D) 3.
Space for rough work
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13.
If l, m, n are real and l m, then the roots of the equation (l m)x 5(l + m)x 2 (l m) = 0 are
(A) complex
(B) real & distinct
(C) real and equal
(D) none of these.
14.
15.
16.
The sum of the digits in the unit place of all numbers formed with the help of 3, 4, 5 and 6 taken all at
a time is
(A) 180
(B) 108
(C) 118
(D) 181
17.
18.
If
19.
3 6
1
1 1x 2 x 2 , then the value of ar is
1 2x x 2
(A) 2r
(B) r + 1
(C) r
(D) r 1
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20.
If z1, z 2 and z3 are three distinct complex numbers and a, b, c are three positive real numbers such
a
b
c
a2
b2
c2
, then
=
| z2 z3 | | z3 z1 | | z1 z2 |
(z2 z3 ) (z3 z1 ) (z1 z 2 )
(A) 0
(B) abc
(C) 3abc
(D) (a + b + c)
that
21.
Let f(z) is a complex polynomial in variable z. When f(z) is divided by z i, the remainder is i and
when divided by z + i, the remainder is 1 + i, then, the remainder, when f(z) is divided by z2 + 1 , is
1
1
1
(A)
i z
(B) iz i
2
2
2
(C) iz + i + 1
(D) none of these
22.
23.
2
1
1
. Then
z1 z2 z3
A, B, C are collinear
circle through points A, B, C has centre at origin O
circle through A, B, C passes through origin
none of these
Let and be two distinct complex numbers such that . If real part of is positive and
may be
1
1
1
,
,
are in
1 Inx 1 Iny 1 Inz
(B) G.P.
(D) None of these
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25.
26.
Let x be the arithmetic mean and y, z be the two geometric means between any two positive
y 3 z3
numbers. Then the value of
is
xyz
(A) 2
(B) 3
(C) 1/2
(D) 3/2
27.
28.
29.
30.
(A) 2n 1
8
(C) n 1
3
x2 x3 x 4
to is valid for
2
3
4
(B) 1 < x < 1
(D) 1 x 1
(B) 2n 1
(D) n
Space for rough work
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