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Question1.
Selectthecorrectstatement(s):
[A]

Heisenberg'sprincipleisapplicabletostationary

[B]

Pauli'sexclusionprincipleisnotapplicabletophotons
ForanelectroninBohr'sorbit,theproductofvelocityandprincipalquantumnumberwillbeindependentofprincipalquantum
number
Quantumnumbers
andmdeterminethevalueofangularwavefunction

[C]
[D]

Question2.
FollowinggraphrepresentstheMaxwelldistributioncurveforanidealgasattwotemperatures

and

.Whichofthefollowing

option(s)aretrue?

[A]
[B]

Totalareaunderthetwocurvesisconstant
If
then
andhencehigherthetemperature,sharperthecurve

[C]
[D]

Thefractionofmoleculeshavingspeed=

decreasesastemperatureincreases

Question3.
Whichofthefollowingstatementsis(are)correct?
If
ionscanbereducedby

[A]
[B]

Cucanbeoxidizedby
ionscanbereducedby

[C]
[D]

Sncanbeoxidizedby

Question4.
If

bethefirst,secondandthirdionizationconstantofH3PO 4and

,thenwhichis(are)

correctstatement(s):
[A]
[B]
[C]
[D]
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Question5.
InaABunitcell(rocksalttype),assuming

formingfcc:

[A]

Thenearestneighbourof

is

[B]

Thenearestneighbourof

is

[C]

Thesecondnearestneighbourof

[D]

ThepackingfractionofABcrystalis

ion
ion
is

Question6.
Selectthecorrectstatement(s):
[A]

Theratelawoftheelementaryreaction

[B]

Theratelawforthecomplexreaction

[C]
[D]

mustbe
mightnotbe

Iftheexperimentallyobservedordersdifferfromthecorrespondingcoefficientsinthebalancedreaction,thereactionmustbe
complex
Iftheexperimentallyobservedordersdifferfromthecorrespondingcoefficientsinthebalancedreaction,thereactionmustbe
elementary

Question7.
Selectthecorrectstatement(s):
[A]
[B]
[C]
[D]

When

or

then

(whereT=temperature,Ea=activationenergy,k=rateconstant,A=Arrhenius

parameter)
Apositivecatalystcanchange
ofthereaction
Amixtureofreactantsmaybethermodynamicallyunstablebutkineticallystable
Anegativecatalystincreasestheactivationenergyofthereaction

Question8.
Thetotalvapourpressureofabinarysolutionsgivenby:
Where,
[A]
[B]
[C]
[D]

arethemolefractionsofcomponentsAandB.Thisindicatesthatthe:

VapourpressureofsolutionislessthanthepureBcomponent
VapourpressureofsolutionismorethanthatofpureAcomponent
VapourpressureofpureAis100mmHgandthatofpureBis260mmHg
ThevapourpressureofpureAandBare260mmHgand100mmHgrespectively

Question9.
Thegaseousproduct(s)expectedatroomtemperaturebyreactionofsodiumborohydrideandborontrifluorideunderanhydrous
conditionsis(are):
[A]
[B]
[C]
[D]

Question10.
Selectcorrectstatement(s)regarding
[A]
[B]

and

bonds:

bondliesonthelinejoiningthenucleiofbondedatoms
bondcloudliesoneithersideofthelinejoiningthenucleiofbondedatoms

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[C]
[D]

pibondisstrongerthan

pibond.

bondhasprimaryeffectonthedirectionofcovalentbond,while
covalentbond

bondhasnoprimaryeffectonthedirectionof

Question11.
Itisobservedthatthevoltageofagalvaniccellusingthereaction

varieslinearlywiththelog

ofthesquarerootofthehydrogenpressureandthecuberootoftheMx+concentration.Findthevalueofx.

Question12.
Howmanyofthefollowinghavenonzerodipolemoment?
I.SO 2II.PH3III.SO 3IV.XeO 2F2
V.BrF5VI.COCl2VII.POCl3VIII.SF6
IX.XeO 3X.BeCl2

Question13.
Howmanyofthefollowingarestatefunction?
I.InternalenergyII.Molarenthalpy
III.IrreversibleexpansionworkIV.Heatsupplied
V.GibbsfreeenergyVI.Entropy
VII.Reversibleexpansionwork

Question14.
Twobuffers(X)and(Y)ofpH4.3and6.3respectivelyarepreparedfromacidHAandsaltNaA.Bothbuffersare0.5MinHA.What
wouldbethepHofthesolutionobtainedbymixingequalvolumesofthetwobuffers?

[Given:

Question15.
EnoughsolidNH4HSandLiCl.3NH3areheatedinaclosedvesselat

IfKpforthefirstequilibriumat
equilibrium.

andthefollowingequilibriaareestablished.

is9atm2andthetotalpressureofthesystemis6atm,findthevalueofKpforsecond

Question16.
Forzeroorderreaction

,plotofconcentrationvstimeisasfollows.

Findhalflifeperiodinminutesiftheinitialconc.ofAbe1M.

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Question17.
Totalnumberofisomers(includingstereoisomers)obtainedbymonochlorinationof2,2,4trimethylpentaneis(are)__________.

Question18.
When2molofanalkalineearthmetalnitrateisdecomposedonheating,findthenumberofgaseousmolesintheproduct?

Question19.
MATCHTHEFOLLOWING:
Column1

Column2

Reversiblecoolingofanidealgasatconstant
A:
volume

1:

B: Reversibleisothermalexpansionofanidealgas

2:

C: Adiabaticexpansionofidealgasintovacuum

3:

D: Reversibleisothermalcompressionofanidealgas

4:
5:

Question20.
MATCHTHEFOLLOWING:
Column1Column2
(Oxyacids)(OxidationstateofindividualSatom)
Column1

Column2

A:

1: +6

B:

2: +5

C:

3: 0

D:

4:
5: +3

Question21.
Ifasatelliteorbitsasclosetotheearth'ssurfaceaspossible,
[A]
[B]
[C]
[D]

Itsspeedismaximum
Timeperiodofitsrotationisminimum
Thetotalenergyofthe'earthplussatellite'systemisminimum
Thetotalenergyofthe'earthplussatellite'systemismaximum

Question22.
TwoblocksA(5kg)andB(2kg)attachedtotheendsofaspringwithspringconstant1120N/mareplacedonasmoothhorizontalplane
withthespringinitsnaturallength.Simultaneouslyvelocitiesof3m/sand10m/salongthelineofthespringinthesamedirectionare
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impartedtoAandBasshowninfigure,then:

[A]
[B]
[C]
[D]

Whentheextensionofthespringismaximum,thevelocitiesofAandBarezero
Themaximumextensionofthespringis25cm
Maximumextensionandmaximumcompressionoccuralternately
Themaximumextensionofthespringis50cm

Question23.
Acylinderblockofdensity
ispartiallyimmersedinaliquidofdensity3
.Theplanesurfaceoftheblockremainsparalleltothe
surfaceoftheliquid.Theheightoftheblockis60cm.TheblockperformsSHMwhendisplacedfromitsmeanpositioniftheblockdoes
notcomeoutoftheliquid.[Useg=9.8m/s 2]
[A]
[B]
[C]
[D]

Themaximumamplitudeis20cm
Themaximumamplitudeis40cm
Thetimeperiodwillbe
seconds
Noneoftheabove

Question24.
AsquareloopofsidelisplacedintheneighborhoodofaninfinitelylongstraightwirecarryingacurrentI1.TheloopcarriesacurrentI2as
showninfigure.Inthisorientation:

[A]

Themagneticmomentoftheloopsis

[B]

Themagneticmomentoftheloopsis

[C]
[D]

Thepotentialenergyoftheloopisminimum
Thetorqueexperiencedbytheloopismaximum

Question25.
Aparallelplatecapacitoristobedesignedwithavoltagerating1kV,usingamaterialofdielectricconstant5anddielectricstrengthis
107V/m.Forsafety,fieldshouldnotexceedmorethan10%ofthedielectricstrength.Whatareacanbesafelyusedtomakea
capacitanceof88.5pF
[A]
[B]
[C]
[D]

0.01m2
0.001m2
0.1m2
0.02m2

Question26.
Aparticleismovinginxyplanewithy=x/2andv x =42t.Choosethecorrectoptions:
[A]
[B]
[C]
[D]

Initialvelocitiesinxandydirectionsarenegative
Initialvelocitiesinxandydirectionsarepositive
Motionisfirstretarded,thenaccelerated
Motionisfirstaccelerated,thenretarded

Question27.
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TwoconcentricshellshaveradiiRand2RchargesqAandqBandpotential2Vand(3/2)Vrespectivelyinthisconfiguration.NowshellB
isearthedandchargesonthembecome

and

.Then:

[A]
[B]
[C]
[D]

PotentialofAafterearthingbecomes(3/2)V
PotentialdifferencebetweenAandBafterearthingbecomesV/2

Question28.
AparticleofmassmandchargeqisfastenedtooneendofastringfixedatpointO.Thewholesystemliesonafrictionlesshorizontal
plane.Initially,themassisatrestatA.Auniformelectricfieldinthedirectionshownisthenswitchedon.Then:

[A]

ThespeedoftheparticlewhenitreachesBis

[B]

ThespeedoftheparticlewhenitreachesBis

[C]
[D]

ThetensioninthestringwhenparticlereachesatBis2qE
ThetensioninthestringwhentheparticlereachesatBisqE

Question29.
Potentialdifferenceacrosstheterminalsofanonidealbatteryis:
[A]
[B]
[C]
[D]

Zerowhenitisshortcircuited
Lessthanitsemfwhencurrentflowsfromnegativeterminaltopositiveterminalinsidethebattery
Zerowhennocurrentisdrawnfromthebattery
Greaterthanitsemfwhencurrentflowsfrompositiveterminaltonegativeterminalinsidethebattery

Question30.
AcapacitorCisconnectedtotwoequalresistancesasshowninthefigure.Then:

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[A]
[B]
[C]
[D]

QuestionRevision

Atthetimeofchargingofcapacitortimeconstantofthecircuitis2CR
AtthetimeofdischargingofcapacitortimeconstantofthecircuitisCR
Atthetimeofdischargingofthecapacitorthetimeconstantofthecircuitis2CR
AtthetimeofchargingofcapacitorthetimeconstantofthecircuitisCR

Question31.
Auniformcylinderrestsonacartasshown.Thecoefficientofstaticfrictionbetweenthecylinderandthecartis0.5.Ifthecylinderis4cm
indiameterand10cminheight,thenwhatistheminimumacceleration(inm/s 2)ofthecartneededtocausethecylindertotipover?

Question32.
2kgoficeat20oCismixedwith5kgofwaterat20oCinaninsulatingvesselhavinganegligibleheatcapacity.Calculatethefinalmassof
water(inkg)remaininginthecontainer.(Specificheatcapacityofice=0.5cal/gm/oC.Latentheatoffusionofwater=80cal/gm,specific
heatcapacityofwater=1cal/gm/oC

Question33.
Alongcontainerhasairenclosedinsideatroomtemperatureandatmosphericpressure(105Pa).Ithasavolumeof20000cc.Thearea
ofcrosssectionis100cm2andforceconstantofspringisk spring=1000N/m.Weslowlypushtheleftpistonisothermallytillitreaches
theoriginalpositionoftherightpistonwhichismovable.Finallengthofaircolumnisfoundtobe25hcm.Assumethatspringisinitially
relaxed.Findh.

Question34.
AuniformdiscofmassmandradiusRispivotedsmoothlyatitscentreofmass.Alightspringofstiffnesskisattachedwiththedisc
tangentiallyasshowninthefigure.Findtheangularfrequencyinrad/sforsmalloscillationsofthedisc.(Takem=5kgandk=10N/m).

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Question35.
Aclosedandanopenorganpipeofsamelengtharesetintovibrationssimultaneouslyintheirfundamentalmodetoproduce2beats.The
lengthofopenorganpipeisnowhalvedandofclosedorganpipeisdoubled.Nowfindthenumberofbeatsproduced.

Question36.
AcircularcurrentloopofradiusaisplacedinahypotheticalradialfieldBasshowninthefigure.Thenetforceactingontheloop
is_________.

Question37.
Aboystandingonalongrailroadcarthrowsaballstraightupwards.Thecarismovingonthehorizontalroadwithanaccelerationof
1ms 2andtheprojectionvelocityintheverticaldirectionis9.8ms 1.Howfarbehindtheboywilltheballfallonthecar?(Specifythe
answerinSIunit).

Question38.
Awoodencubeofside10cmanddensity0.8gm/cm3isfloatinginwater(density=1gm/cm3).Amassof(100x)gmisplacedoverthe
cubesothatcubeiscompletelyimmersedwithoutwettingthemass.Findthevalueofx.

Question39.
Column1containsalistofprocessesinvolvingexpansionofanidealgas.Matchthiswithcolumn2.Describingthethermodynamic
changeduringthisprocess.Indicateyouranswerbydarkeningtheappropriatebubblesofthe
matrixgivenintheOMR
Column1

Column2

Aninsulatedcontainerhastwochambersseparated
byavalve.ChamberIcontainsanidealgasandthe
chamberIIhasvacuum.Thevalveisopened.
A:

1: Thetemperatureofthegasdecreases

Anidealmonatomicgasexpandstotwiceitsoriginal
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B:

2: Thetemperatureofthegasincreasesorremains
constant

volumesuchthatitspressure
Anidealmonatomicgasexpandstotwiceitsoriginal

C: volumesuchthatitspressure

whereVis

3: Thegaslosesheat

itsvolume.
Anidealmonatomicgasexpandssuchthatits
pressurePandvolumeVfollowsthebehavior
showninthegraph

D:

4: Thegasgainsheat

Question40.
Ablockisprojectedwithaninitialvelocityv Block onalongconveyorbeltmovingwithvelocityv Belt (atthisinstant)havingconstant
accelerationaBelt .Markthecorrectoptionregardingfrictionactingontheblockafterlongtime(frictioncoefficientbetweentheblockand
belt=
).If:
Column1

Column2

A: vBlock=2vBeltandaBelt=0
B: vBlock=2vBeltandaBelt>
C: vBlock=2vBeltandaBelt=

g
g

1: Zero
2: fs:staticfriction(0<fs<fL )
3: fL :limitingfriction

D: vBlock=2vBeltandaBelt<

4: fK:kineticfriction

Question41.
Letnbethenumberofwaysinwhich5boysand5girlscanstandinaqueueinsuchawaythatallthegirlsstandconsecutivelyinthe
queue.Letmbethenumberofwaysinwhich5boysand5girlscanstandinaqueueinsuchawaythatexactlyfourgirlsstand
consecutivelyinthequeue.Then,thevalueof
[A]
[B]
[C]
[D]

is:

Oddinteger
Compositeinteger
Multipleof3
Multipleof5

Question42.
Letthecomplexnumber
[A]
[B]
[C]
[D]

(where

)satisfy

thenxcanbe:

1
2

Question43.
Ifafunctionsatisfiestherelation

and

,thenidentify

whichofthefollowingstatement(s)is(are)correct?
[A]

Equationf(x)=ex hastwosolutions

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[B]

QuestionRevision

Equationf(x)=ex hasexactlyonesolution

[C]

[D]

Question44.
If

suchthat

and

and

then:

[A]
[B]
[C]
[D]

Question45.
Iftangentdrawntothecurve

at

meetsthecurveagainatQ(x 1,f(x 1)).IfmAdenotesthe

slopeofthetangentatAandmOBdenotestheslopeofthelinejoining'O'originandapointBonthecurve,then:
[A]
[B]
[C]

,where

[D]

,where

Question46.
Let
I.
III.

besequencessuchthat
II.
IV.

Thenwhichofthefollowingis(are)correct?
[A]

[B]

[C]
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[D]

Question47.
Suppose

and

.IfCisanarbitraryconstantofintegrationthenwhichof

thefollowingis(are)correct?
[A]
[B]
[C]
[D]

Question48.
Let

and

then:

[A]
[B]
[C]

[D]

Question49.
Letf:

bedefinedby

.Whichofthefollowingstatement(s)is(are)correct?

[A]

f(x)hasexactlyonelocalmaximumandtwolocalminimumpoints

[B]

f(x)isstrictlyincreasingin

[C]

Absoluteminimumvalueoff(x)existsbutabsolutemaximumvalueoff(x)doesnotexist

[D]

Intheinterval

hastwodistinctroots

Question50.
Thefigureillustratesgraphofthefunction

definedin

.Identifythecorrectstatement(s):

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[A]

Rangeof

[B]

Domainof

[C]

Domainof

[D]

Rangeof

is
is
is
is

Question51.
Letf(x)satisfy

and

If

then

is

thenAis________.

Question52.
Foreachrealnumberm,thequadraticpolynomial,

passesthrough(a,c),thena+cis

_________.

Question53.
Thevalueof

isequalto__________.[Note:{y}denotesthefractionalpartofy]

Question54.
If

arethenthrootsofunityand
cannotbeequaltoAwhere

isanonrealcomplexcuberootofunity,thentheproduct
,thenA+1is_________.

Question55.

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Consideracurve,

.Ifareaenclosedbythecurve,tangenttoitatx=2andthexaxisis

wherepandqarerelativelyprimenumbers,thenthevalueof

is__________.

Question56.
Thesumoffirstntermsofthesequence

,isoftheform

.Thevalueof

is_________.

Question57.
If

thentheleastvalueof

is__________.

Question58.
Ifatwicedifferentiablefunctiony=f(x)satisfiestherelation
valueof

and

thenthe

is____________.

Question59.
Let

beequationofacircle.
Column1

Column2

A: Ifcircleliesinfirstquadrant,then
B: Ifcirclelieabovethexaxis,then

1: g<0
2: g>0

C: Ifcirclelieontheleftoftheyaxis,then

3:

D:

Ifcircletouchesthepositivexaxisanddoesnot
intersecttheyaxis,then

4: c>0
5: c<0

Question60.
Let

forall

and

forall

.MatchtheentriesinColumn1with

Column2.
Column1

Numberofdistinctrealrootsofequation
A:
where
canbe
B:

Numberofdistinctrealrootsofequation

Column2

1: 0

2: 1

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where
C:

D:

canbe

Numberofdistinctrealrootsofequation
where
canbe
Numberofdistinctrealrootsofequation
where

canbe

3: 2

4: 3
5: 4

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