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43.7
43.8
Molecular Bonds
Energy States and Spectra
of Molecules
Bonding in Solids
Free-Electron Theory of
Metals
Band Theory of Solids
Electrical Conduction in
Metals, Insulators, and
Semiconductors
Semiconductor Devices
Superconductivity
ANSWERS TO QUESTIONS
Q43.1
, where I is
2I
the moment of inertia of the molecule. A typical value for a
small molecule is on the order of 1 meV = 10 3 eV . Vibrational
energy is on the order of hf, where f is the vibration frequency
of the molecule. A typical value is on the order of 0.1 eV.
Electronic energy depends on the state of an electron in the
molecule and is on the order of a few eV. The rotational energy
can be zero, but neither the vibrational nor the electronic
energy can be zero.
energy for a diatomic molecule is on the order of
Q43.2
Q43.3
The conductive properties of a material depend on the electron population of the conduction band
of the material. If the conduction band is empty and a full valence band lies below the conduction
band by an energy gap of a few eV, then the material will be an insulator. Electrons will be unable to
move easily through the material in response to an applied electric field. If the conduction band is
partly full, states are accessible to electrons accelerated by an electric field, and the material is a good
conductor. If the energy gap between a full valence band and an empty conduction band is
comparable to the thermal energy k B T , the material is a semiconductor.
Q43.4
Thermal excitation increases the vibrational energy of the molecules. It makes the crystal lattice less
orderly. We can expect it to increase the width of both the valence band and the conduction band, to
decrease the gap between them.
545
546
Q43.5
First consider electric conduction in a metal. The number of conduction electrons is essentially fixed.
They conduct electricity by having drift motion in an applied electric field superposed on their
random thermal motion. At higher temperature, the ion cores vibrate more and scatter more
efficiently the conduction electrons flying among them. The mean time between collisions is
reduced. The electrons have time to develop only a lower drift speed. The electric current is
reduced, so we see the resistivity increasing with temperature.
Now consider an intrinsic semiconductor. At absolute zero its valence band is full and its
conduction band is empty. It is an insulator, with very high resistivity. As the temperature increases,
more electrons are promoted to the conduction band, leaving holes in the valence band. Then both
electrons and holes move in response to an applied electric field. Thus we see the resistivity
decreasing as temperature goes up.
Q43.6
In a metal, there is no energy gap between the valence and conduction bands, or the conduction
band is partly full even at absolute zero in temperature. Thus an applied electric field is able to inject
a tiny bit of energy into an electron to promote it to a state in which it is moving through the metal
as part of an electric current. In an insulator, there is a large energy gap between a full valence band
and an empty conduction band. An applied electric field is unable to give electrons in the valence
band enough energy to jump across the gap into the higher energy conduction band. In a
semiconductor, the energy gap between valence and conduction bands is smaller than in an
insulator. At absolute zero the valence band is full and the conduction band is empty, but at room
temperature thermal energy has promoted some electrons across the gap. Then there are some
mobile holes in the valence band as well as some mobile electrons in the conduction band.
Q43.7
Ionic bonds are ones between oppositely charged ions. A simple model of an ionic bond is the
electrostatic attraction of a negatively charged latex balloon to a positively charged Mylar balloon.
Covalent bonds are ones in which atoms share electrons. Classically, two children playing a
short-range game of catch with a ball models a covalent bond. On a quantum scale, the two atoms are
sharing a wave function, so perhaps a better model would be two children using a single hula hoop.
Van der Waals bonds are weak electrostatic forces: the dipole-dipole force is analogous to the
attraction between the opposite poles of two bar magnets, the dipoleinduced dipole force is
similar to a bar magnet attracting an iron nail or paper clip, and the dispersion force is analogous to
an alternating-current electromagnet attracting a paper clip.
A hydrogen atom in a molecule is not ionized, but its electron can spend more time elsewhere
than it does in the hydrogen atom. The hydrogen atom can be a location of net positive charge, and
can weakly attract a zone of negative charge in another molecule.
Q43.8
Ionically bonded solids are generally poor electric conductors, as they have no free electrons. While
they are transparent in the visible spectrum, they absorb infrared radiation. Physically, they form
stable, hard crystals with high melting temperatures.
Q43.9
Covalently bonded solids are generally poor conductors, as they form structures in which the atoms
share several electrons in the outer shell, leaving no room for conducting electrons. Depending on
the structure of the solid, they are usually very hard and have high melting points.
Q43.10
Metals are good conductors, as the atoms have many free electrons in the conduction band. Metallic
bonds allow the mixing of different metals to form alloys. Metals are opaque to visible light, and can
be highly reflective. A metal can bend under stress instead of fracturing like ionically and covalently
bonded crystals. The physical properties vary greatly depending on the composition.
Chapter 43
547
Q43.11
The energy of the photon is given to the electron. The energy of a photon of visible light is sufficient
to promote the electron from the lower-energy valence band to the higher-energy conduction band.
This results in the additional electron in the conduction band and an additional holethe energy
state that the electron used to occupyin the valence band.
Q43.12
Along with arsenic (As), any other element in group V, such as phosphorus (P), antimony (Sb), and
bismuth (Bi), would make good donor atoms. Each has 5 valence electrons. Any element in group III
would make good acceptor atoms, such as boron (B), aluminum, (Al), gallium (Ga), and indium (In).
They all have only 3 valence electrons.
Q43.13
The two assumptions in the free-electron theory are that the conduction electrons are not bound to
any particular atom, and that the nuclei of the atoms are fixed in a lattice structure. In this model, it
is the soup of free electrons that are conducted through metals. The energy band model is more
comprehensive than the free-electron theory. The energy band model includes an account of the
more tightly bound electrons as well as the conduction electrons. It can be developed into a theory
of the structure of the crystal and its mechanical and thermal properties.
Q43.14
A molecule containing two atoms of 2 H, deuterium, has twice the mass of a molecule containing
two atoms of ordinary hydrogen 1 H . The atoms have the same electronic structure, so the molecules
have the same interatomic spacing, and the same spring constant. Then the moment of inertia of the
double-deuteron is twice as large and the rotational energies one-half as large as for ordinary
1
times that of H 2 .
hydrogen. Each vibrational energy level for D 2 is
2
Q43.15
Rotation of a diatomic molecule involves less energy than vibration. Absorption of microwave
photons, of frequency ~ 10 11 Hz , excites rotational motion, while absorption of infrared photons, of
frequency ~ 10 13 Hz , excites vibration in typical simple molecules.
Q43.16
Yes. A material can absorb a photon of energy greater than the energy gap, as an electron jumps into
a higher energy state. If the photon does not have enough energy to raise the energy of the electron
by the energy gap, then the photon will not be absorbed.
Q43.17
From the rotational spectrum of a molecule, one can easily calculate the moment of inertia of the
molecule using Equation 43.7 in the text. Note that with this method, only the spacing between
adjacent energy levels needs to be measured. From the moment of inertia, the size of the molecule
can be calculated, provided that the structure of the molecule is known.
SOLUTIONS TO PROBLEMS
Section 43.1
P43.1
Molecular Bonds
q2
e1.60 10 j e8.99 10 j N =
=
e5.00 10 j
19 2
(a)
F=
(b)
1.60 10 19 8.99 10 9
q 2
=
U=
J 2.88 eV
4 0 r
5.00 10 10
4 0 r 2
10 2
je
2
548
P43.2
We are told
K + Cl + 0.7 eV K + + Cl
and
Cl + e Cl + 3.6 eV
or
Cl Cl + e 3.6 eV .
By substitution,
(a)
LM OP .
N Q
B O
L1 1 O B =
= M P
P
2 A B PQ
N4 2Q A
dU
2A
= 12 Ar 13 + 6Br 7 = 0 yielding r0 =
dr
B
(b)
E = U r = U r = r = 0
0
LM A
MN 4 A B
2
16
B2
4A
This is also the equal to the binding energy, the amount of energy given up by the two
atoms as they come together to form a molecule.
(c)
L 2e0.124 10
r =M
MN 1.488 10
e1.488 10
E=
4e0.124 10
120
60
60
(a)
eV m6
eV m6
120
*P43.4
eV m12
j OP
PQ
16
= 7.42 10 11 m = 74.2 pm
eV m12
= 4.46 eV
I + e I + 3.06 eV
to obtain
K + I K + + I + 4.34 3.06 eV .
(b)
LM FG IJ
MN H K
dU 4
=
12
dr
r
At r = r0 we have
= 2 1 6
r0
13
+6
FG IJ OP
H r K PQ
7
FG IJ
H K
dU
= 0 . Here
dr
r0
13
FG IJ
H K
1
2 r0
= 2 1 6 0.305 nm = 0.272 nm = .
Then also
LF 2 r I F 2 r I OP
L1 1 O
G
+ E = 4 M P + E
U br g = 4 MG
J
J
r
r
MNH
N4 2Q
K H
K PQ
= E U br g = 1.28 eV + 3.37 eV = 4.65 eV =
1 6
12
1 6
0
= + Ea
Chapter 43
(c)
af
F r =
LM FG IJ
MN H K
dU 4
=
12
dr
r
13
FG IJ OP
H r K PQ
7
rrupture
Fmax =
FG 42 IJ
H 156 K
LM
MN
f LM FG IJ
MN H K
= 6.55 nN
13 6
FG IJ
H K
dF 4
=
156
dr 2
r
16
4 4.65 eV
42
12
0.272 nm
156
549
14
+ 42
FG IJ OP = 0 when
H r K PQ
8
19
Nm
m
Therefore the applied force required to rupture the molecule is +6.55 nN away from the
center.
(d)
LF
LMF I F I OP
I F I
GMH r + s JK GH r + s JK P + E = 4 MMGH 2r + rs JK GH r2 + s JK
N
Q
N
L 1 F s I 1 F s I OP
= 4 M G1 + J
MN 4 H r K 2 GH1 + r JK PQ + E
L 1 F s s I 1 F1 6 s + 21 s I OP + E
= 4 M G 1 12 + 78
MN 4 H r r JK 2 GH r r JK PQ
12
U r0 + s = 4
1 6
12
where k =
P43.5
2
0
s
s2
s
s2
+ 78 2 2 +12 42 2 + Ea +
r0
r0
r0
r0
= + E a + 0
g b g
OP
PQ + E
2
0
U r0 + s U r0 +
1 6
=12
12
FG s IJ + 36 s
Hr K
r
2
0
1 2
ks
2
72 72 4.65 eV
=
= 3 599 eV nm 2 = 576 N m .
2
r02
0.305 nm
k BT 10 3 eV = 10 3 1.6 10 19 J
T
1.6 10 22 J
~ 10 K .
1.38 10 23 J K
550
Section 43.2
P43.6
fe
132.9 126.9
m1 m 2
=
1.66 10 27 kg = 1.08 10 25 kg
m1 + m 2 132.9 + 126.9
je
I = r 2 = 1.08 10 25 kg 0.127 10 9 m
E=
(a)
a f
I
1 2
I =
2
2I
J = 0 gives E = 0
= 1.74 10 45 kg m 2
J J +1
2I
e6.626 10
=
4 e1.74 10
J = 1 gives E =
a f
34
Js
45
kg m 2
= 6.41 10 24 J = 40.0 eV
hf = 6.41 10 24 J 0 to f = 9.66 10 9 Hz
f=
(b)
P43.7
2
E1
h
=
=
r 2
h
hI 4 2 r 2
For the HCl molecule in the J = 1 rotational energy level, we are given
r0 = 0.127 5 nm.
Erot =
Taking J = 1 , we have
a f
J J +1
2I
Erot =
1 2
I or =
2
2 2
= 2 .
I
I2
Therefore, = 2
P43.8
hf = E =
I=
4 h 2
2 hf
2I
fe
h
2
2 f
2I
a f
1 1+1 =
2I
a 4f
6.626 10 34 J s
2
= 2.62 10 47 kg m 2 .
1.055 10 34 J s
= 5.69 10 12 rad s .
2
47
2.62 10
kg m
= 2
a f
je
2 2+1
FIG. P43.7
IJ
K
FG
H
L a1 ufa35 uf OPr
I=M
N 1 u + 35 u Q
e2.30 10
11
Hz
= 1.46 10 46 kg m 2
Chapter 43
P43.9
I = m1 r12 + m 2 r22
m1 r1 = m 2 r2
and
r1 + r2 = r .
Then r1 =
m 2 r2
m1
so
m 2 r2
+ r2 = r
m1
and
r2 =
m1 r
.
m1 + m 2
Also, r2 =
m1 r1
.
m2
Thus,
r1 +
m1 r1
=r
m2
and
r1 =
m2r
m1 + m 2
I = m1
P43.10
where
bm
m 22 r 2
m 2 m12 r 2
m1 m 2 r 2 m 2 + m1
g=m m r
1
g bm + m g
bm + m g
22.99a35.45f
=
a22.99 + 35.45f e1.66 10 kgj = 2.32 10 kg
I = r = e 2.32 10
kg je0.280 10 mj = 1.81 10
+ m2
m1 + m 2
27
(a)
= r2 .
26
26
45
kg m 2
a f 2 I 1a1 + 1f = 3 I I = 2 I = 42h I
2I
kg m j
c 4 I e3.00 10 m sj4 e1.81 10
=
=
= 1.62 cm
2h
J sj
2e6.626 10
F I
The energy of a rotational transition is E = G J J where J is the rotational quantum number of the
HIK
hc
(b)
2 2+1
45
34
P43.11
551
higher energy state (see Equation 43.7). We do not know J from the data. However,
E =
hc
e6.626 10
34
je
J s 3.00 10 8 m s
j F 1 eV I .
GH 1.60 10 J JK
19
(mm)
0.120 4
0.096 4
0.080 4
0.069 0
0.060 4
E (eV)
0.010 32
0.012 88
0.015 44
0.018 00
0.020 56
and I =
E1
e1.055 10 J sj F 1 eV I =
=
b0.002 56 eVg GH 1.60 10 J JK
34
E1 =
= 0.002 56 eV
19
2.72 10 47 kg m 2 .
r=
2.72 10 47
m = 0.130 nm.
1.62 10 27
552
P43.12
(a)
(b)
1 2 1
kA = hf :
2
2
A=
For HF,
A=
e6.626 10
hf
=
k
34
je
J s 6.69 10 13 s
320 N m
e6.626 10
34
je
J s 8.72 10 13 s
970 N m
j = 1.18 10
j = 7.72 10
12
11
m = 0.011 8 nm .
m = 0.007 72 nm .
m1 m 2
35
=
1.66 10 27 kg = 1.61 10 27 kg
m1 + m 2 36
Evib =
P43.14
(a)
k
= 1.055 10 34
480
= 5.74 10 20 J = 0.358 eV
1.61 10 27
a16 ufa16 uf
a16 uf + a16 uf = 8 u = 8e1.66 10 kg j = 1.33 10 kg .
The moment of inertia is then I = r = e1.33 10
kg je1.20 10 mj = 1.91 10
kg m .
27
26
(b)
10
e1.055 10
=
J a J + 1f =
2I
2e1.91 10
= e 2.91 10
Jj J a J + 1f .
2
26
j J a J + 1f .
kg m j
34
Js
Erot
Thus
Erot
And for J = 0 , 1, 2 ,
FG
H
1
2
FG
H
1
1 eV
3.14 10 20 J
2
1.60 10 19
Evib = v +
Evib = v +
IJ
K
IJ e
K
FG
H
= v+
IJ e
K
46
23
1
1.055 10 34 J s
2
jFGH
27
46
Chapter 43
P43.15
553
In Benzene, the carbon atoms are each 0.110 nm from the axis and each hydrogen atom is
0.110 + 0.100 nm = 0.210 nm from the axis. Thus, I = mr 2 :
je
j + 6e1.67 10
I = 6 1.99 10 26 kg 0.110 10 9 m
27
je
kg 0.210 10 9 m
= 1.89 10 45 kg m 2 .
34
24
45
ja f
eV J J + 1
The first five of these allowed energies are: Erot = 0 , 36.9 eV, 111 eV, 221 eV, and 369 eV .
*P43.16
We carry extra digits through the solution because part (c) involves the subtraction of two close
numbers. The longest wavelength corresponds to the smallest energy difference between the
rotational energy levels. It is between J = 0 and J = 1 , namely
hc
hc
4 2 Ic
= 2 =
. If is the reduced mass, then
Emin
h
I
j = e1.624 605 10
m j e 2.997 925 10
I = r 2 = 0.127 46 10 9 m
=
4 2 1.624 605 10 20
20
ms
6.626 075 10 34 J s
35 =
(a)
m2
j = e2.901 830 10
27
je
23
m kg
kg
37 =
(b)
27
je
kg
(c)
P43.17
hf =
h2
4 2 I
je
46
2
kg m 2 6.42 10 13 s
4 2 If 4 1.46 10
=
= 558
J=
h
6.626 10 34 J s
(1)
554
*P43.18
We find an average spacing between peaks by counting 22 gaps between 7.96 10 13 Hz and
9.24 10 13 Hz :
f =
I=
*P43.19
a9.24 7.96f10
13
Hz
= 0.058 2 10 13 Hz =
22
h
4 2 f
F
GH
1 h2
h 4 2 I
I
JK
6.63 10 34 J s
= 2.9 10 47 kg m 2
4 2 5.82 10 11 s
We carry extra digits through the solution because the given wavelengths are close together.
(a)
FG
H
IJ
K
2
1
hf +
J J +1
2
2I
EvJ = v +
a f
1
hf ,
2
E00 =
E11 E00 = hf +
hf +
2
I
2
I
(b)
je
34
J s 2.997 925 10 8 m s
2.211 2 10
hc
(1)
e6.626 075 10
34
je
J s 2.997 925 10 8 m s
2.405 4 10
3
I
= 7.252 89 10 21 J
3 1.054 573 10 34 J s
7.252 89 10 21 J
(2)
= 4.60 10 48 kg m 2
From (1):
f=
e1.054 573 10 J sj
J s e 4.600 060 10
kg m je6.626 075 10
34
8.983 573 10 20 J
6.626 075 10 34
48
= 1.32 10 14 Hz
(c)
= 8.258 284 10 20 J
I =
e6.626 075 10
=
hc
= 8.983 573 10 20 J
E11 E02 = hf
hf
2
3
1
3 2
, E02 = hf +
hf +
I
I
2
2
E11 =
1
1
m H = 1.007 825u = 8.367 669 10 28 kg .
2
2
So r =
4.600 060 10 48 kg m 2
8.367 669 10 28 kg
= 0.074 1 nm .
34
Js
Chapter 43
P43.20
The emission energies are the same as the absorption energies, but the final state must be below
v = 1, J = 0 . The transition must satisfy J = 1 , so it must end with J = 1 . To be lower in energy, it
hf photon = Evib
v =1
+ Erot
J =0
j eE
vib v = 0
+ Erot
J =1
j = eE
vib v =1
Evib
v=0
j eE
Erot
rot J = 1
J =0
Ix =
2
2
2
4
mr 2 + mr 2 = m 2.00 10 15 m .
5
5
5
Section 43.3
P43.22
FG R IJ
H 2K
+m
FG R IJ
H 2K
2
m
2.00 10 10 m .
2
e
=
e
2
2
j = I = b1 2gme2.00 10
I j I
b4 5gme2.00 10
Ix
y
x
10
15
j
mj
2
2
5
10 5
8
e j
= 6.25 10 9 .
Bonding in Solids
F 10 m I ~ 10 .
GH 0.261 10 m JK
e10 mj FGH 0.26110 10m m IJK ~ 10
3
17
m3 .
P43.23
P43.24
555
FG
H
IJ b
K
j ee
j FG 1 1 IJ = 1.25 10
j H 8K
1.60 10 19
ke e2
1
9
= 1.747 6 8.99 10
U=
1
r0
m
0.281 10 9
ge
18
J = 7.84 eV
Visualize a K + ion at the center of each shaded cube, a Cl ion at the center
of each white one.
The distance ab is
Distance ac is
Distance ad is
2 0.314 nm = 0.444 nm .
2 0.314 nm = 0.628 nm .
22 +
e 2 j a0.314 nmf =
2
0.769 nm .
FIG. P43.24
556
P43.25
ke e2 ke e2 ke e2 ke e2 ke e2 ke e2 ke e2 ke e2
+
+
+
+
2r
2r
3r
3r
4r
4r
r
r
2k e 2
1 1 1
= e
1 + +
2 3 4
r
e e e e e e
+ + +
U=
FG
IJ
H
K
x
x
x
But, lna1 + xf = 1
+
+
2
3
4
2
so, U =
2r
3r
FIG. P43.25
2kee
e
ln 2 , or U = k e
where = 2 ln 2 .
r
r
Section 43.4
Section 43.5
P43.26
FG IJ
H K
23
h 2 3n e
EF =
2 m 8
L
e6.626 10 J sj
=M
MM 2e9.11 10 kg je1.60 10
N
34
31
19
OPF 3 I
G J
J eV j PH 8 K
QP
23
n e2 3
or
FG
H
8 2mEF
ne =
3
h2
IJ
K
32
ja fe
n Ag = 10.6 10 3 kg m3
So an average atom contributes
(a)
3 2
= 5.80 10 28 m 3 .
atom I F
1u
J
jFGH 1108
u K GH 1.66 10
27
I = 5.91 10
J
kg K
28
m 3 .
5.80
= 0.981 electron to the conduction band .
5.91
1
mv 2 = 7.05 eV
2
v=
(b)
23
31
kg 5.48 1.60 10 19 J
8 2 9.11 10
=
3
3
6.626 10 34 J s
P43.28
FG IJ
H K
h 2 3n e
2 m 8
fe
2 7.05 eV 1.60 10 19 J eV
9.11 10
31
kg
j=
1.57 10 6 m s
1
eV .
40
Chapter 43
P43.29
557
je
(a)
(b)
P43.30
EF
F h I FG 3n IJ
=G
H 2m JK H 8 K
2
23
e6.626 10
=
2e9.11 10
34
31
j LM 3e2.54 10
8
kg j M
N
2
Js
28
m 3
j OP
PQ
23
= 5.05 10 19 J = 3.15 eV
The melting point of silver is 1 234 K. Its Fermi energy at 300 K is 5.48 eV. The approximate fraction
of electrons excited is
e
a
jb
g
j
1.38 10 23 J K 1 234 K
k BT
=
2% .
EF
5.48 eV 1.60 10 19 J eV
P43.31
fe
E EF k B T
e b E EF g
k BT
+1
= 0.950
1
1 = 0.052 6
0.950
E EF
= ln 0.052 6 = 2.94
k BT
E EF
P43.32
1.60 10 19 J eV
d = 1.00 mm , so
V = 1.00 10 3 m
g E = CE 1 2 =
af
af
gE =
or
E = 5.28 eV .
= 1.00 10 9 m 3 .
8 2 m 3 2
h
E1 2
8 2 9.11 10 31 kg
e6.626 10
34
Js
3 2
a4.00 eVfe1.60 10
19
J eV
af
g E = 8.50 10 46 m 3 J 1 = 1.36 10 28 m 3 eV 1 .
So, the total number of electrons is
a fa f e
jb
ge
558
P43.33
Eav =
af
1
EN E dE
ne 0
af
af
EF
1
ne
CE 3 2 dE =
EF
C
ne
2C 5 2
EF .
5n e
E 3 2 dE =
af
N aEf = CE
N E = 0 for E > EF ;.
At T = 0 ,
C 3 3 2
= EF , so that
ne 2
Eav =
12
8 2 m e3 2
h3
FG 2 IJ FG 3 E IJ E
H 5KH 2 K
3 2
F
5 2
F
E1 2
3
EF .
5
sin k x L = 0
and
k x L = , 2 , 3 , .
Similarly,
sin k y L = 0
and
k y L = , 2 , 3 ,
sin k z L = 0
and
k z L = , 2 , 3 ,
FG n x IJ sinFG n y IJ sinFG n z IJ .
H L K H L K H L K
2m
+
+
=
From
aU Ef ,
x
y
z
F n n n I = 2m E
a f
GH L L L JK
= A sin
2
x
2
y
2
z
E=
2 2
n x + n y2 + n z2
2
2m e L
n x , n y , n z = 1, 2 , 3 , .
(a)
n x = n y = n z = 1, with E =
(b)
3 2 2
2m e L2
af
g a8.50 eV f C a8.50f
=
g a7.00 eV f C a7.00f
g E = CE 1 2 .
12
12
= 1.10 .
12
a f eb CEg + 1 .
N a8.50 eV f a8.50f L e a
=
M
N a7.00 eV f a7.00f MN e a
N a8.50 eV f a8.50f L
=
N a7.00 eV f a7.00f MN e a
N a8.50 eV f
= 1.55 10
N a7.00 eV f
NE =
E EF k B T
f
f
OP .
+ 1 PQ
OP .
+ 1Q
12
7.00 7 .00 k BT
12
8 .50 7.00 kB T
12
12
2.00
1.50 0 .025 9
25
+1
Comparing this result with that from part (a), we conclude that very few states with E > EF
are occupied.
Chapter 43
Section 43.6
P43.36
559
(a)
fe
(b)
P43.37
c 3.00 10 8 m s
=
= 1.09 10 6 m = 1.09 m (in the infrared region)
f 2.75 10 14 Hz
Photons of energy greater than 2.42 eV will be absorbed. This means wavelength shorter than
je
6.626 10 34 J s 3.00 10 8 m s
hc
=
= 514 nm .
E
2.42 1.60 10 19 J
All the hydrogen Balmer lines except for the red line at 656 nm will be absorbed.
hc
34
je
J s 3.00 10 8 m s
j J
Eg =
P43.39
e6.626 10
P43.38
650 10
e6.626 10
=
hc
max
34
je
J s 3.00 10 8 m s
1.00 10
1.91 eV
j F 1 eV I = 1.24 eV .
GH 1.60 10 J JK
19
Thus, the energy gap for the collector material should be E g 1.24 eV . Since Si has an energy gap
E g 1.14 eV , it will absorb radiation of this energy and greater. Therefore, Si is acceptable as a
material for a solar collector.
P43.40
If the photon energy is 5.5 eV or higher, the diamond window will absorb. Here,
bhf g
max
hc
min
min = 2.26 10
*P43.41
min =
= 5.5 eV :
7
a =
me ke e2
2
je
fe
m = 226 nm .
6.626 10 34 J s 3.00 10 8 m s
hc
=
5.5 eV
5.5 eV 1.60 10 19 J eV
ke
in hydrogen, changes to
FG IJ
H K
FG
H
FG IJ
H K
IJ b
K
2
me
me
me
a0 =
=
=
11.7 0.052 9 nm = 2.81 nm .
0. 220m e
mke e2
m
me ke e2
m
ke e2 1
and here
2 a0 n 2
F I
GH JK
ke e2 1
ke e2
m En
=
=
2
2a n
me 2
2 m e m a0
For n = 1 , E1 = 0.220
13.6 eV
11.7 2
= 0.021 9 eV .
560
Section 43.7
P43.42
Semiconductor Devices
I = I 0 e ea V f
Thus,
e ea V f
and
V =
k BT
I
ln 1 +
.
e
I0
At T = 300 K ,
V =
k BT
1 .
k BT
IJ
K
FG
H
e1.38 10
=1+
23
I
I0
ja
J K 300 K
1.60 10
19
a
f a f
V = a 25.9 mV f lna0.100f =
(a)
If I = 9.00 I 0 ,
(b)
If I = 0.900 I 0 ,
59.5 mV .
The basic idea behind a semiconductor device is that a large current or charge can be
controlled by a small control voltage.
P43.43
P43.44
The voltage across the diode is about 0.6 V. The voltage drop across the resistor is
0.025 A 150 = 3.75 V . Thus, 0.6 V 3.8 V = 0 and = 4.4 V .
fa
First, we evaluate I 0 in I = I 0 e ea V f
ja
a f e
e
k BT
f
f
1.60 10 19 C 0.100 V
e V
200 mA
I
= 3.86
= 4.28 mA
=
= 3.86 so I 0 = ea V f k T
23
B
k BT
1
1 e
1.38 10
J K 300 K
e
If V = 100 mV ,
I = I 0 e ea V f
*P43.45
(a)
k BT
a f
ja
e V
= 3.86 ; and the current will be
k BT
j a
fe
je
I D = 10 6 A e V
IW =
0.025 V
1 ,
20
2.42 V V
745
je
Diode
Wire
10
I D = 10 6 A e 0. 200 V 0.025 V 1
0.1
V(volts)
= 2.98 mA
FIG. P43.45
2.42 V 0.200 V
= 2.98 mA . They agree to three digits.
IW =
745
I D = I W = 2.98 mA
(b)
V
0.200 V
=
= 67.1
ID
2.98 10 3 A
(c)
d V
dI D
=
dI D
d V
a f LM OP = LM 10 A e
N a f Q N 0.025 V
1
0 . 200 V 0.025 V
OP
Q
= 8.39
0.2
0.3
Chapter 43
Section 43.8
P43.46
(a)
(b)
Superconductivity
See the figure at right.
For a surface current around the outside of the cylinder as shown,
B=
N 0 I
or NI =
a0.540 Tfe2.50 10 mj =
=
e4 10 j T m A
2
10.7 kA .
FIG. P43.46
P43.47
B
I
B
=L
=A
.
t
t
t
Thus,
A B 0.010 0 m 0.020 0 T
I =
=
= 203 A .
L
3.10 10 8 H
a f b
gb
The direction of the induced current is such as to maintain the B field through the ring.
P43.48
(a)
V = IR
If R = 0 , then V = 0 , even when I 0 .
(b)
f
f
155 57.8 mA
I
1
=
=
= 43.1 1
R
V
3.61 1.356 mV
R = 0.023 2
(c)
FIG. P43.48
Additional Problems
P43.49
(a)
Since the interatomic potential is the same for both molecules, the spring constant is the
same.
Then f =
1
2
where 12 =
12 u + 16 u
14 u + 16 u
Therefore,
f14 =
1
2
14
1
2
12
FG IJ = f
H K
12
14
12
12
= 6.42 10 13 Hz
14
6.86 u
= 6.15 10 13 Hz .
7.47 u
561
562
(b)
FG IJ r = FG IJ I
H K
H K
F 7.47 u IJ e1.46 10 kg m j = 1.59 10 kg m
I =G
H 6.86 u K
The molecule can move to the b v = 1, J = 9g state or to the b v = 1, J = 11g state. The energy it
I 14 = 14 r 2 =
14
12
12
14
12
12
46
14
(c)
46
LMFG 1 + 1 IJ hf
2K
NH
hc LF
1I
= MG 1 + J hf
E =
H
N
2K
E =
or
hc
14 + 9 9 + 1
14
14
14
14
14
14
14
=
These are: =
and
P43.50
c
f14 10
b2 I g
or =
14
c
f14 + 11
b2 I g .
14
3.00 10 8 m s
6.15 10 13 Hz 10 1.055 10 34 J s
3.00 10 8 m s
6.15 10 13 Hz + 11 1.055 10 34 J s
2 1.59 10 46 kg m 2
2 1.59 10 46 kg m 2
je
I = r 2 = 1.16 10 26 kg 1.20 10 10 m
= 4.45 10 14 rad s,
= 4.96 m
= 4.79 m .
m
2
= 1.67 10 46 kg m 2 .
For a rotational state sufficient to allow a transition to the first exited vibrational state,
2
2I
a f
a f
J J + 1 = so J J + 1 =
2 I
je
2 1.67 10 46 4.45 10 14
1.055 10
34
j = 1 410 .
Thus J = 37 .
P43.51
FG
H
Emax = 4.5 eV = v +
8.25 > 7.5
P43.52
1
2
IJ
K
so
34
14
v=7
With 4 van der Waal bonds per atom pair or 2 electrons per atom, the total energy of the solid is
10 atoms I
jFGH 6.02 4.00
JK =
g
E = 2 1.74 10 23 J atom
23
5. 23 J g .
563
Chapter 43
P43.53
ke e2
B
+ m.
r
r
The total potential energy has its minimum value U 0 at the equilibrium spacing, r = r0 . At this point,
dU
= 0,
dr r = r0
dU
dr
or
P43.54
=
r = r0
F
GH
k e e 2 m 1
r0 .
m
Thus,
B=
U 0 =
I
JK
k e2
d
B
e + m
dr
r
r
=
r = r0
kee2
r02
F I
GH JK
mB
= 0.
r0m +1
FG
H
kee2
k e2
k e2
1
1
1
+ e r0m 1 m = e
r0
m
r0
m
r0
IJ
K
1
3
hf + 4. 48 eV = hf + 3.96 eV is the depth
2
2
of the well below the dissociation point. We see hf = 0.520 eV , so the depth of the well is
1
1
hf + 4.48 eV = 0.520 eV + 4.48 eV = 4.74 eV .
2
2
P43.55
(a)
For equilibrium,
dU
= 0:
dx
d
Ax 3 Bx 1 = 3 Ax 4 + Bx 2 = 0
dx
(b)
(c)
3 0.150 eV nm3
3A
=
= 0.350 nm
3.68 eV nm
B
Fx =
U0 = U x= x =
0
a
e
A
B
AB 3 2
BB 1 2
x 03 x 0 3 3 2 A 3 2 3 1 2 A 1 2
3 2
2 3.68 eV nm
2B 3 2
=
32 12
3 A
3 3 2 0.150 eV nm3
12
= 7.02 eV .
dU
= 3 Ax 4 Bx 2
dx
dF
dx
= 0.
x = xm
FG 6 A IJ .
HBK
F B IJ BFG B IJ = B = a3.68 eV nmf
= 3 AG
H 6 A K H 6 A K 12 A 12e0.150 eV nm j
F 1.60 10 J I FG 1 nm IJ = 1.20 10
= 7.52 eV nm G
H 1 eV JK H 10 m K
Thus,
12 Ax 5 + 2Bx 3
Then
Fmax
or
Fmax
x = xm
12
= 0 so that x m =
19
N = 1.20 nN .
564
P43.56
(a)
For equilibrium,
dU
= 0:
dx
d
Ax 3 Bx 1 = 3 Ax 4 + Bx 2 = 0
dx
3A
.
B
(b)
(c)
Fx =
A
B
AB 3 2
BB 1 2
B3
= 3 2 3 2 1 2 1 2 = 2
.
3
27 A
3 A
x0 x0 3 A
dU
= 3 Ax 4 Bx 2
dx
(a)
= 12 Ax 5 + 2Bx 3
x = xm
x = x0
= 0 then Fmax = 3 A
dU
dr
At equilibrium separation, r = re ,
FG B IJ
H 6AK
FG B IJ =
H 6AK
a r r
a r r
= 2 aB e b e 0 g 1 e b e 0 g = 0 .
r = re
e abre r0 g = 1 ,
or
re = r0 .
(b)
(c)
af b g
br r g + 12 ddrU br r g
1
U ar f 0 + 0 + a 2BafL ae b g ae b g e e b
MN
2
U r U r0 +
dU
dr
r = r0
2 r r0
r = r0
r r0
(d)
B2
.
12 A
2 r r0
g 1 jO
QP br r g Ba br r g
1
1
kx = k br r g
2
2
0
r = r0
k = 2Ba 2 .
f=
ha
1
1
= hf =
2
2
1
2
a
2
2B
B
.
2
B
.
8
ha
B
.
8
Chapter 43
T=0
P43.58
E
EF
0
0.500
0.600
0.700
0.800
0.900
1.00
1.10
1.20
1.30
1.40
1.50
T = 0.1TF
af
bE E g1 bT T g
e
e
e
e
e
e
e
e0
e +
e +
e +
e +
e +
bE E g1 bT T g
f E
T = 0.2TF
F
e
10 .0
e
e 5.00
e 4.00
e 3.00
e 2.00
e 1.00
e0
e 1.00
e 2.00
e 3 .00
e 4.00
e 5 .00
1.00
1.00
1.00
1.00
1.00
1.00
0.500
0.00
0.00
0.00
0.00
0.00
af
f E
1.000
0.993
0.982
0.953
0.881
0.731
0.500
0.269
0.119
0.047 4
0.018 0
0.006 69
T = 0.5TF
bE E g1 bT T g
F
e
5.00
e
e 2.50
e 2.00
e 1.50
e 1.00
e 0.500
e0
e 0 .500
e 1.00
e 1.50
e 2.00
e 2.50
af
f E
bE E g1 bT T g
F
e
2
.
00
0.993
e
0.924
e 1.00
0.881
e 0.800
0.818
e 0.600
0.731
e 0. 400
0.622
e 0. 200
0.500
e0
0.378
e 0. 200
0.269
e 0. 400
0.182
e 0 .600
0.119
e 0 .800
0.075 9 e 1.00
FIG. P43.58
P43.59
(a)
FIG. P43.59
FG
H
U = 6 +
12
2
IJ k e
3K r
= 2.13
565
k e2
kee2
with = 2.13 .
or U = e
r0
r0
af
f E
0.881
0.731
0.690
0.646
0.599
0.550
0.500
0.450
0.401
0.354
0.310
0.269
566
(b)
U = 2.13 + 3
f k re
e
= 0.866
kee2
.
r0
So we see that the electrostatic potential energy is not even attractive to 4 terms, and that the
infinite series does not converge rapidly when groups of atoms corresponding to nearest
neighbors, next-nearest neighbors, etc. are added together.
4.3 eV
P43.30
2%
P43.4
P43.32
3.40 10 17 electrons
P43.6
P43.34
P43.36
P43.8
1.46 10 46 kg m 2
P43.38
1.91 eV
P43.10
P43.40
226 nm
P43.12
P43.42
P43.44
4.19 mA
P43.46
P43.48
P43.50
37
P43.52
5.23 J g
P43.54
4.74 eV
P43.56
(a) x 0 =
P43.58
P43.14
P43.16
P43.18
2.9 10 47 kg m 2
P43.20
P43.22
(a) ~ 10 17 ; (b) ~ 10 5 m 3
P43.24
P43.26
P43.28
(a) 1.57 Mm s;
(b) larger by 10 orders of magnitude
B2
3A
B3
; (b) 2
; (c)
B
27 A
12 A