CBSE CBSE Class 12th Chemistry Question Paper Set I 2014 2

th
CBSE Class 12 Chemistry Solved Question Papers 2014
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Solved Question Paper 2014

Subject: Chemistry
Class: XII
Set: I
1. What is the effect of temperature on chemisorption?
Ans.1
Chemisorption increases with increase in temperature.
2. What is the role of zinc metal in the extraction of silver?

Ans.2
Zn acts as a reducing agent in the extraction of silver.
2 Ag CN 2
( aq )
Zn( s ) 2 Ag( s ) Zn CN 4
2
( aq )
3. What is the basicity of H3PO3?

Ans.3
2
3
H3 PO3 2H HPO
It is dibasic in nature. Thus, its basicity is 2
4. Identify the chiral molecule in the following pair:
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Ans.4
5. Which of the following is a natural polymer?

Buna-S, protein, PVC
Ans.5
Protein is a natural polymer.
6. The conversion of primary aromatic amines into diazonium salts is known as _______?
Ans.6
The conversion of primary aromatic amines into diazonium salts is known as diazotisation
reaction.
7. What are the products of hydrolysis of sucrose?

Ans.7
Hydrolysis of sucrose gives glucose and fructose.
8. Write the structure of p-methyIbenzaldehyde.
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Ans.8
9. An element with density 2.8g/cm forms of f.c.c. unit cell with edge length 4 10 cm.
23
1
Calculate the molar mass of the element. [Given: NA = 6.022 10 mol ]
Ans.9
Given
8
a 4 10 cm
d 2.8 g / cm 3
Lattice is fcc type. Thus,
z4
Now,
ZM
d 3
a NA
2.8
4 M
4 10
8 3
6.022 10
23
2.8 64 1024 6.022 1023

M
4
M 27 g / mol
Thus, molar mass of the element is 27g/mol.
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10.
(i) What type of non-stoichiometric point defect is responsible for the pink colour of
LiCl?
(ii) What type of stoichiometric defect is shown by NaCl?
Ans.10
(i)
The metal excess defect caused by anionic vacancies is responsible for the pink colour
of LiCl.
(ii)
The Schottky defect is shown by NaCl.
OR
How will you distinguish between the following pairs of terms?

(i) Tetrahedral and octahedral voids
(ii) Crystal lattice and unit cell
Ans.10
(i)
Tetrahedral void: It is surrounded by 4 spheres.

Octahedral void: It is surrounded by 6 spheres.
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Crystal lattice: Arrangement of the constituent particles of a crystal in a regular threedimensional network is called crystal lattice.
(ii)
Unit cell: It is the smallest three-dimensional part of a crystal lattice. When these cells
joined each other they make whole crystal lattice.
11. State Kohlrausch's law of independent migration of ions. Why does the conductivity of a
solution decrease with dilution?
Ans.11
Kohlrausch's law of independent migration of ions states that the limiting molar
conductivity of an electrolyte can be represented as the sum individual contributions of its
cations & anions.
Conductivity of a solution decreases with dilution as with dilution number of ions per unit
volume decreases.
12. For a chemical reaction R P , the variation in the concentration (R) vs. time (t) plot is
given as
(1) Predict the order of the reaction.

(2) What is the slope of the curve?
Ans.12
(i)
Graph shows a zero order reaction.
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Rate R
(ii)
For a zero order reaction, Slope = K
13. Explain the principle of the method of electrolytic refining of metals. Give one example.
Ans.13
Electrolytic refining:
It is the process of refining impure metals by using electricity. In this process, anode is
made up of impure metal and cathode is made up of a strip of pure metal. A solution of a
soluble salt of the same metal is taken as the electrolyte.
When an electric current is passed, metal ions from the electrolyte are deposited at the
cathode as pure metal and the impure metal from the anode dissolves into the electrolyte in
the form of ions. The impurities present in the impure metal gets collected below the anode.
This is known as anode mud.
Example: Pure aluminium is obtained from aluminium ore by the electrolytic refining
method
14 . Complete the following equations:
(i) P4 + H 2 O
(ii) XeF4 + O 2 F2
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Ans.14
(i) P4 H 2 O No reaction
(ii) XeF4 O2 F2 XeF6 O2
15. Draw the structures of the following:

(i) XeF2
(ii) BrF3
Ans.15
(i) XeF2
(ii) BrF3
16. Write the equations involved in the following reactions:

(i) Reimer - Tiemann reaction
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(ii) Williamson synthesis

Ans.16
(i)
Reimer-Tiemann reaction:
In the presence of sodium hydroxide, phenol is treated with chloroform &introduces CHO
group at the ortho position of the benzene ring.
This reaction is known as the Reimer-Tiemann reaction.

The intermediate is hydrolyzed in the presence of alkalis to produce salicyclaldehyde.
(ii)
Williamson ether synthesis:

It is a laboratory method to prepare symmetrical and unsymmetrical ethers.
Alkyl halide is reacted with sodium alkoxides & forms ether.
R ' O Na R X R O R ' NaX

Sodium alkoxide
Alkyl
Ether
halide
This reaction involves SN2 attack of the alkoxide ion on the alkyl halide.
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If the alkyl halide is secondary or tertiary, then elimination competes over substitution.
17. Write the mechanism of the following reaction:

HBr
CH3CH2OH
CH3CH2 Br + H2O
Ans.17
18. Write the names of monomers used for getting the following polymers:
(i) Bakelite
(ii) Neoprene
Ans.18
(i)
Monomers of Bakelite are Phenol and formaldehyde
(ii)
Monomer of Neoprene is Chloroprene
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19.
(a) Calculate r G 0 for the following reaction :

Mg s + Cu
2+
2+
aq Mg aq
+ Cus
Given : +2.71 V, 1F = 96500 C / mol

(b) Name the type of cell which was used in Apollo space programme for providing
electrical power.
Ans.19
(a)
Given cell reaction is:
Mg s Cu 2 aq Mg 2 aq Cu s
E
0
cell
2.71 V
r G nFE
0
0
cell
r G 2 96500 2.71
0
r G 523030 J/mol
0
(b) The fuel which uses the reaction of hydrogen with oxygen to form water was used in
Apollo programme for providing electrical power.
20. The following data were obtained during the first order thermal decomposition of SO2Cl2
at a constant volume:
Experiment
Time/sec
Total pressure/atm
0.4
100
0.7
Calculate the rate constant.

(Given: log 4 = 0.6021, log 2 = 0.3010)
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Ans.20
SO2 Cl2( g ) SO2( g ) Cl2( g )

At t 0
P0
At t t
P0 p
Now,
Pt P0 p p p
Pt P0 p
p Pt P0
for a first order reaction,
P0
2.303
k
log
t
P0 p
P0
2.303
k
log
t
2 P0 Pt
At t 100 s
2.303
0.4
k
log
100
0.8 0.7
k 1.386 10
sec
21. What are emulsions? What e their different types? Give one example of each type.
Ans.21
Emulsion: Emulsions are the colloidal solution in which both the dispersed phase and
dispersion medium are liquids.
There are two types of emulsions:
(a) Oil in water type: In this, oil is the dispersed phase while water is the dispersion
medium. For example- vanishing cream, milk, etc.
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(b) Water in oil type: In this, water is the dispersed phase while oil is the dispersion
medium. For example- butter, cold cream, etc.
22. Give reasons for the following:

(i) (CH3)3 P = O exists but (CH3)3 N = O does not.
(ii) Oxygen has less electron gain enthalpy with negative sign than sulphur.
(iii) H3PO2 is a stronger reducing agent than H3PO3.
Ans.22
(i)
The d-orbitals are absent in nitrogen atom. This restricts nitrogen to expand its
coordination number beyond four. Hence, (CH 3)3N=O does not exist.
(ii)
Oxygen is the smallest element of group 16. Due to its small size, the incoming electron
is not accommodated with ease As a result; oxygen has less electron gain enthalpy than
sulphur.
(iii)
H3PO3 has one PH bond & H3PO2 has two P-H bonds. Thus, H3PO2 can release 2
hydrogen atoms while H3PO3 can release one hydrogen atom. Hence, H3PO2 is a
stronger reducing agent than H3P03.
23. Write the IUPAC name of the complex Cr NH 3 4 Cl 2 Cl

(i) What type of isomerism is exhibited by the complex Co en 3
3+
(en = ethane-1,2-diamine)
(ii) Why is [NiCI4]2- paramagnetic but [Ni (CO)4] is diamagnetic?

(Atomic no.: Cr = 24, Co = 27, Ni = 28)
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Ans.23
(i)
Cr NH3 4 Cl2 Cl
IUPAC name = Tetraamminedichlorochromium(IlI) chloride
(ii)
3+
The complex Co en 3 exhibits optical isomerism.

Its optical isomers are:
(iii)
2-
Chloride is a weak field legend & carbonyl is a strong weak field legend. In [NiCl4] ,
the oxidation state of Ni is +2. Chloride does not pair up d-orbital electrons. Thus, the
two unpaired electrons present in the valence d-orbitals are responsible of paramagnetic
nature of the complex. On the other hand, carbonyl pair up the d-orbital electrons. As a
result no electrons are left unpaired and the complex becomes diamagnetic in nature.
Q.24
(a) Draw the structures of major mono halo products in each of the following reactions:
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(b) Which halogen compound in each of the following pairs will react faster in SN2 reaction?
(i) CH 3 Br or CH 3 I
(ii) CH 3 3 C - Cl or CH 3 - Cl
Ans.24
(a)
(b)
In the SN2 mechanism, the reactivity of halides for the same alkyl group increases in the
following order.
RF << RCl < RBr < RI
As size increases, the halide ion becomes a better leaving group. Thus, CH3I will react
faster than CH3Br in SN2 reactions with OH .

(i)
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In case of (CH3)3CCl, the attack of the nucleophile at the carbon atom is hindered because
of the presence of bulky substituents on that carbon atom. In case of, there are no bulky
substituents on the carbon in CH3Cl. Hence, CH3Cl reacts faster than (CH3)3CCl in SN2
reaction with OH.
25. Account for the following:

(i) Primary amines (R-NH2) have higher boiling point than tertiary amines (R3N).
(ii) Aniline does not undergo Friedel- Crafts reactions:
(iii) (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Ans.25
(i) In primary amines, two hydrogen atoms are present whereas in tertiary amine, there are no
Hatoms. Due to the presence of Hatoms, primary amines undergo intermolecular
Hbonding.
(ii) As a result, extra energy is required to break the hydrogen bonds of primary amines. Thus,
primary amines have higher boiling points than tertiary amines.
(i) AlCl3 is acidic in nature & aniline is a strong base. Hence, aniline reacts with AlCl3 to form
a salt.
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(ii) But it does not undergo the Friedel-Crafts reaction. It happens because of the positive
charge on the N-atom. This leads to deactivation of electrophilic substitution in the benzene
ring takes place.
(i)
Basic strength in aqueous solution depends on 2 factors:
Steric factor- alkyl group is larger than hydrogen atom which causes steric
hindrances. As the number of alkyl group increases, the steric hindrances
increase in the same direction.
Amines form H-bonds with water molecules & release hydration energy &
forms protonated amines. Protonated amines are more stable. Greater the
hydration enthalpy more is the stability of protonated amine. Thus greater is the
tendency of the amine to form cation leading to greater base strength of the
amine.
Hence, the order of the basic strength in aqueous phase is:

Secondary > Tertiary > Primary
OR
Give the structures of A, B and C in the following reactions:

Sn+HCl
NaNO2 +HCl
273K
H2O
(i) C6 H 5 NO2
A
B
H 2 O/ H +
NH 3
Br2 +KOH
(ii) CH 3 CN
A
B C
Ans.25
(i)
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(ii)
26. Define the following terms as related to proteins:

(i) Peptide linkage
(ii) Primary structure
(iii) Denaturation
Ans.26
(i) Peptide linkage:
When COOH group of one molecule of an amino acid and NH2 group of another
molecule of the amino acid is reacted, amide is formed. In this reaction, elimination of a
water molecule takes place. This linkage is known as a peptide linkage.
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(ii)
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Primary structure:
It is a specific sequence of linkages between amino acids in a polypeptide chain. Different
sequences are present in different proteins. Any change in the sequence creates a different
protein.
(iii)Denaturation:
Protein has is a unique 3-dimensional structure and a unique biological activity. In such
condition, it is active & takes part in reactions, & is known as native protein. However,
when the native protein is subjected to physical changes such as change in temperature or
chemical changes such as its H-bonds are disturbed, change in pH. These activities disturb
the structure of protein. As a result, unfolding of the globules takes place which uncoils the
helix. In this form, the protein loses its biological activity. This loss of biological activity
by the protein is known as denaturation.
Denaturation destroys the secondary and the tertiary structures of the protein, but it does
not alter the primary structure.
For example: Coagulation of egg white when an egg is boiled
27. On the occasion of world Health Day, Dr. Satpal organized a 'health camp for the poor
farmers living in a nearby village. After check-up, he was shocked to see that most of the
farmers suffered from cancer due to regular exposure to pesticides and many were diabetic.
They distributed free medicines to them. Dr. Satpal immediately reported the matter to the
National Human Rights Commission (NHRC). On the suggestions of NHRC, the government
decided to provide medical care, financial assistance, setting up of super-speciality hospitals
for treatment and prevention of the deadly disease in the affected villages all over India.
(i)
Write the values shown by

(a) Dr. Satpal
(b) NHRC
(ii)
What types of analgesics are chiefly used for the relief of pains of terminal cancer?
(iii)
Give an example of artificial sweetener that could have been recommended to

diabetic patients.
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Ans.27
(i) (a) Dr. Satpal is an altruist
(b) Responsibility
(ii) Narcotic analgesics are used for the relief of pains of terminal cancer.
(iii)Saccharin
28.
(a) Define the following terms:
(i) Molarity
(ii) Molal elevation constant (Kb)
(b) A solution containing 15 g urea (molar mass = 60 g/mol) per litre of solution in water
has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180
g/mol) in water. Calculate the mass of glucose present in one litre of its solution.
Ans.28
(a)
(i) Molarity: It can be defined as the number of moles of the solute dissolved in one Litre of
the solution.
moles of solute
Molarity, M
volume of solution in Litre
(ii) Molal elevation constant (Kb): It is defined as the elevation in boiling point of a solution
when one mole of a non-volatile solute is dissolved in one kilogram of a volatile solvent.
(b)
CRT
n
RT
V
we know that urea solution is isotonic with glucose solution.
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Thus,
nglu cos e
nurea
RT
RT
V
V
nglu cos e
15
60 V
V
1
nglu cos e
4
1
m 180 45 g
4
Thus, mass of glucose present is 45 g.
OR
(a) What type of deviation is shown by a mixture of ethanol and acetone? Give reason.
(b) A solution of glucose (molar mass = 180 g/mol) in water is labelled as 10% (by mass) what
would be the molality and molarity of the solution? (Density of solution = 1.2 g/ml)
Ans.28
(a) Mixture of ethanol & acetone shows positive deviation from Raoults law. Pure ethanol
possesses hydrogen bonding. On addition of acetone, some hydrogen bonds break &
mixture shows positive deviation.
(b)
10 g of glucose in present in = 100 g of the solution
10 g of glucose is present in = (100 10) g
= 90 g of water
M C6 H12 O6 180 g / mol
nC6 H12 O6
10
0.056 mol
180
Thus,
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0.056
Molality of solution
0.62 m
0.09
90
nH 2 O
5 mol
18
density 1.2 g / mL
100
3
V
83.33 10 L
1.2
Now,
0.056
Molarity of solution
0.67 M
3
83.33 10
29.
(a) Complete the following equation:
27
(i) Cr2 O + 2OH

4
(ii)MnO + 4H + 3e
(b) Account for the following:
(i) Zn is not considered as a transition element.
(ii) Transition metals form a large number of complexes.
0
3+
2+
3+
2+
(iii) The E value for the Mn /Mn couple is much more positive than that for Cr /Cr
couple.
Ans.29
(a)
(i) Cr2 O72 2OH 2Cr2O42 H 2O
(ii) MnO 4 H 3e MnO2 2 H 2 O

(b)
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(i)
(ii)
(iii)
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Zinc has the stable filled valence shell d10 electronic configuration in its ground state as
well as in its most common oxidation state of +2. Thus, it is not considered as a
transition element.
Transition elements possess vacant d-orbitals to accommodate electrons for bond
formation. Also, ions formed by transition metals have small sizes and high ionic
charges. Thus, they form a large number of complexes.
3+
2+
3+
2+
The E value for Mn / Mn is much more positive than that for Cr /Cr .
This is because Mn2+ is more stable because of half filled orbitals than Mn3+
So, the reduction of Cr3+ /Cr2+ is easier than the reduction of Mn3+/ Mn2+.
OR
(i)
With reference to structural variability & chemical reactivity, write the

differences between lanthanoids & actinoids.
(ii)
Name a member of the lanthanoid series which is well known to exhibit +4

oxidation state.
(iii)
Complete the following equations:

-
MnO4 + 8H + 5e
(iv)
3+
3+
Out of Mn & Cr , which is more paramagnetic & why?
Ans.29
(i)
Lanthanoids & actinoids:

a) Actinoids has far greater irregularities in metallic radii than lanthanoids. Thus,
actinoids shows a variety of structures.
b) The ionisation enthalpies of the early actinoids are lower than those of the early
lanthanoids.
c) Actinoids are more reactive and have more complex magnetic properties than
lanthanoids.
(ii)
Cerium exhibits +4 oxidation state
(iii)
MnO4 8H 5e Mn 4H 2O
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3+
(iv)
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3+
Mn has four unpaired electrons in its valence shell whereas Cr has three unpaired
3+
3+
electrons. Thus, Mn is more paramagnetic than Cr
30.
(a) Write the products formed when CH3CHO reacts with the following reagents:
(i) HCN
(ii) H2N-OH
(iii) CH3CHO in the presence of dilute NaOH
(b) Give simple chemical tests to distinguish between the following pairs of compounds:
(i) Benzoic acid and Phenol
(ii) Propanal and Propanone
Ans.30
(a)
i.
ii.
CH 3 CHO HCN CH 3 CH (CN ) OH

2-Hydroxypropanenitrile
CH 3CHO NH 2 OH CH 3 CH NOH H 2 O
Acetaldoxime
iii.
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(b)
(i) Propanal and propanone can be distinguished by tollens test, fehlings test & Iodoform
test.
Tollens test
Propanal can be reduces Tollens reagent. But, propanone does not reduce Tollens reagent
as it is a ketone.
CH 3CH 2CHO 2 Ag NH 3 2 3OH CH 3CH 2COO Ag 4NH 3 2H 2O

Propanal
Tollen's reagent
Pranoate ion
silver mirror
Fehlings test
Propanal being an aldehyde reduces Fehlings solution to a red-brown precipitate of Cu2O,
but propanone being a ketone does not.
CH 3CH 2CHO 2Cu
5OH CH 3CH 2COO Cu2O 3H 2O
Propanal
Pranoate ion
brown ppt
(ii) Phenol and benzoic acid can be distinguished by ferric chloride test.
Ferric chloride test:
Phenol reacts with neutral FeCl3 to form an iron-phenol complex giving violet colouration.
3
6C6 H 5OH FeCl3 Fe OC6 H 5 6 3H 3Cl

Phenol
Iron-Phenol complex
But benzoic acid reacts with neutral FeCl3 to give a buff coloured ppt. of ferric benzoate.
3C6 H 5COOH FeCl3 C6 H 5COO 3 Fe 3HCl

Benzoic acid
ferric benzoate
Buff coloured ppt

OR
(a) Account for the following:

(i) CI-CH2COOH is a stronger acid than CH3COOH.
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(ii) Carboxylic acids do not give reactions of carbonyl group.

(b) Write the chemical equations to illustrate the following name reactions:
(i) Rosenmund reduction
(ii) Cannizzaro's reaction
(c) Out of CH3CH2-CO-CH2-CH3 and CH3CH2-CH2-CO-CH3, which gives iodoform test?
Ans.30
(a)
(i)
Chlorine is an electron withdrawing group & it increases the acidity of carboxylic

acid by stabilizing the conjugate base due to delocalisation of the negative charge
by resonance effects.
(ii)
Lone pairs present in carboxylic acid are involved in resonance. Thus, it doesnt
show the reactions of carbonyl group.
(b)
(i)
Rosenmund reduction:
(ii)
Cannizzaro reaction:
Aldehydes which have dont have -hydrogen, they undergo this reaction. In this,
aldehydes undergo self oxidation-reduction on treatment with concentrated alkalis. In this
reaction, two molecules of aldehydes participate where one is reduced to alcohol and the
other is oxidized to carboxylic acid.
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For example:
2CH 3CHO Conc.KOH CH 3CH 2OH CH 3COOK
Ethanal
Ethanol
Potassium Ethanoate
(c)
CH 3CH 2 CH 2 CO CH 3 3NaOI CHI 3 CH 3CH 2COONa 2 NaOH

yellow
ppt
CH3CH 2 CO CH 2CH3 NaOI No yellow ppt
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CBSE Class 12 Chemistry Solved Question Papers 2014

Solved Question Paper 2014

2. What is the role of zinc metal in the extraction of silver?

3. What is the basicity of H3PO3?

It is dibasic in nature. Thus, its basicity is 2

4. Identify the chiral molecule in the following pair:

CBSE Class 12 Chemistry Solved Question Papers 2014

5. Which of the following is a natural polymer?

7. What are the products of hydrolysis of sucrose?

8. Write the structure of p-methyIbenzaldehyde.

CBSE Class 12 Chemistry Solved Question Papers 2014

2.8 64 1024 6.022 1023

CBSE Class 12 Chemistry Solved Question Papers 2014

The Schottky defect is shown by NaCl.

How will you distinguish between the following pairs of terms?

Tetrahedral void: It is surrounded by 4 spheres.

CBSE Class 12 Chemistry Solved Question Papers 2014

(1) Predict the order of the reaction.

Graph shows a zero order reaction.

CBSE Class 12 Chemistry Solved Question Papers 2014

For a zero order reaction, Slope = K

14 . Complete the following equations:

CBSE Class 12 Chemistry Solved Question Papers 2014

15. Draw the structures of the following:

16. Write the equations involved in the following reactions:

CBSE Class 12 Chemistry Solved Question Papers 2014

(ii) Williamson synthesis

This reaction is known as the Reimer-Tiemann reaction.

Williamson ether synthesis:

R ' O Na R X R O R ' NaX

CBSE Class 12 Chemistry Solved Question Papers 2014

17. Write the mechanism of the following reaction:

Monomers of Bakelite are Phenol and formaldehyde

Monomer of Neoprene is Chloroprene

CBSE Class 12 Chemistry Solved Question Papers 2014

(a) Calculate r G 0 for the following reaction :

Given : +2.71 V, 1F = 96500 C / mol

Calculate the rate constant.

CBSE Class 12 Chemistry Solved Question Papers 2014

SO2 Cl2( g ) SO2( g ) Cl2( g )

CBSE Class 12 Chemistry Solved Question Papers 2014

22. Give reasons for the following:

23. Write the IUPAC name of the complex Cr NH 3 4 Cl 2 Cl

(ii) Why is [NiCI4]2- paramagnetic but [Ni (CO)4] is diamagnetic?

CBSE Class 12 Chemistry Solved Question Papers 2014

The complex Co en 3 exhibits optical isomerism.

CBSE Class 12 Chemistry Solved Question Papers 2014

faster than CH3Br in SN2 reactions with OH .

CBSE Class 12 Chemistry Solved Question Papers 2014

25. Account for the following:

CBSE Class 12 Chemistry Solved Question Papers 2014

Basic strength in aqueous solution depends on 2 factors:

Hence, the order of the basic strength in aqueous phase is:

Give the structures of A, B and C in the following reactions:

CBSE Class 12 Chemistry Solved Question Papers 2014

26. Define the following terms as related to proteins:

CBSE Class 12 Chemistry Solved Question Papers 2014

Write the values shown by

Give an example of artificial sweetener that could have been recommended to

CBSE Class 12 Chemistry Solved Question Papers 2014

CBSE Class 12 Chemistry Solved Question Papers 2014

CBSE Class 12 Chemistry Solved Question Papers 2014

(i) Cr2 O + 2OH