Topper's Choice Pawan Sir

PART I : CHEMISTRY
PAPER – II
SECTION – I
Single Correct Choice Type
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.

1. The compounds P, Q and S

O
COOH OCH3 C
O

HO H3C
P Q S
where separately subjected to nitration using HNO3/H2SO4 mixture. The major product formed in each case
respectively, is
O
COOH OCH3 C
O
(A )
HO H3C O2 N
NO2 NO2

O
COOH OCH3 C
O
(B )
HO NO2 H3C NO2
NO2
NO2
O
COOH OCH3 C
O
(C )
HO H3C NO2
NO2

O
COOH OCH3 C
O NO2
(D )
HO H3C NO2
NO2
Key: (C)
COOH COOH

Sol.:
P
NO2

OH OH

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OCH3
NO2

CH3
O O
S C O C O NO2

2. Assuming that Hund’s rule is violated, the bond order and magnetic nature of the diatomic molecule B2 is
(A) 1 and diamagnetic (B) 0 and diamagnetic
(C) 1 and paramagnetic (D) 0 and paramagnetic.
Key: (A)
Sol.: → 10 electron
B2 ⎯⎯
2 2 2
σ1S σ *1S σ2S σ *22S Π12px Π12p y (If Hund’s rule is obeyed)
2 2 2
σ1S σ *1S σ2S σ *22S Π 22px Π 02p y (If Hund’s rule is violated)
6−4
B ond=
order =1
2
Paramagnetic if Hund’s rule is obeyed
Diamagnetic of Hund’s rule is violated.

3. The packing efficiency of the two-dimensional square unit cell shown below
is
( A) 39.27% (B) 68.02%
( C) 74.05% (D) 78.54%.

L
Key: (D)
Sol.: Let us consider the squerare plane (given)
Area = L2
A rea covered by 2 × Πr 2 (two circle)
4r = 2 L
2
r= L
4
2
⎛ 2 ⎞ 4 Π L2
Ar =ea 2 ⋅ Π ⎜⎜ L ⎟⎟ = ΠL2 ⋅ =
⎝ 4 ⎠ 16 4
Π L2
Pa cking efficiency = × 100
4 × L2
3.14
= × 100 = 78.5%.
4
4. The complex showing a spin-only magnetic moment of 2.82 B.M. is
) Ni ( CO )4 (B ) [ NiCl4 ]
2−
(A
2−
(C ) Ni ( PPh 3 )4 (D ) ⎡⎣ Ni ( CN )4 ⎤⎦
Key: (B)

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Ni + — 4S 3d
3d 4s 4p

2 unpaired electron (n = 2)
µ = n ( n + 2 ) = 8 BM
= 2.82 BM.
O
(1) NaOH/Br2
5. I n the reaction H3C C T the structure of the Product T is
O
NH2 (2) C
Cl

O
H3C C O
O C NH
(A) (B) C CH3
O

O
H3C C O
H3C NH NH C
(C ) C
(D)
O

Key: (C)
O O
O
C Cl
C NH2 NH2 NH C

(2)
(1) NaOH / Br2
Sol.: ⎯⎯⎯⎯⎯⎯⎯⎯
Hoffman Bromide reaction
→
Acylation

CH3 CH3 CH3

6. The species having pyramidal shape is
(A) SO3 (B ) BrF3
2−
(C ) SiO 3 (D) OSF2
Key: (D)

S
Sol.:
O F
F
Py ramidal

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ranging from 0 to 9. The correct digit below the question no. in the ORS is to be bubbled.

7. Silver (atomic weight = 108 g mol–1) has a density of 10.5 g cm–3. The number of silver atoms on a surface
of area 10–12 m2 can be expressed in scientific notation as y × 10 x . The value of x is
Key: (7)
Sol.: Consider a single layer square shaped arrangement of n × n silver atoms. Also assume the radius of each
silver atom r.
Area of the layer = (2rn)2= 10-12m2 = 10-8cm2
Mass of the layer
Su rface area × thickness × density = number of atoms × mass of single atom.
10 −8 × 2r × 10.5 = n 2 × 108 × 1.66 × 10 −24 [put 2rn = 10–4]
∴ n 3 = 5.855 × 1010
n 3.82 × 103
∴ number of silver atoms on the surface
= n 2 = ( 3.82 × 103 )
2

= 1.4592 × 107
∴ x = 7.
8. Among the following, the number of elements showing only one non-zero oxidation state is
O, Cl, F, N, P, Sn, Tl, Na, Ti
Key: (2)
Sol.: Fluorine and sodium shown only one non zero oxidation state, fluorine show – 1 and sodium shown + 1.
9. One mole of an ideal gas is taken from a to b along two paths denoted by the solid and the dashed lines as
shown in t he graph below. If the work done along the solid line path is w s and that along the dotted line
path is wd, then the integer closest to the ratio wd/ws is
4.5
4.0 a
3.5
P 3.0
(atm.) 2.5
2.0
1.5
1.0
0.5 b
0.0
0.0 0.5 1.0 1. 5 2. 0 2.5 3.0 3.5 4.0 4.5 5.0 5. 5 6. 0
V(lit.)
Key: (2)
Sol.: wd = 4× 1.5 + 1 × 15 + 0.80 × 2.5
= 9.375
v2
ws = 2.33 pV log
v1
5.5
= 2.33 × 4 × 0.5 log
0.5
≈ 4.606

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w d 9.375
= ≈2.
w s 4.606
10. The total number of diprotic acids among the following is
H3PO4 H2SO4 H3PO3 H2CO3 H2S2O7
H3BO3 H3PO2 H2CrO4 H2SO3
Key: (6)
Sol.: The total number of diprotic acids are 6
O O O

S P C
HO OH HO H HO OH
O OH

O O O O

S O S OH Cr S
HO HO HO OH
O OH
O O
11. Total number of geometrical isomers for the complex [RhCl(CO)(PPh3)(NH3)] is
Key: (3)
Sol.: The total number of geometrical isomers for the complex [RhCl(O)(PPh3)(NH3)] is 3.
A B A B A C
M M M
D C C D D B

SECTION – III
Paragraph Type
This section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice questions have to
be answered. Each of these question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for Questions 12 to 14

Two aliphatic aldehydes P and Q react in the presence of aqueous K2CO3 to give compound R, which upon
treatment with HCN provides compound S. On acidification and heating, S gives the product shown below :
H3C OH
H3C

O
O
12. The compounds P and O respectively are :
CH3 CH3
CH H H3C H CH H H H
(A) C
(B) C
H3C C H3C C
and and
O O O O
H3C CH2 H3C CH2
H H
H3C H H H
CH C CH C
(C ) and
C (D) and
C
O O
CH3 O CH3 O

Key: (B)

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O
CH3
C
C H
(B) H3C
CH
H3C OH

O CH3
O
CH3
C CH
H H3C C
CH CH
(C ) (D) CH H
H3C
CH2 CH
OH H3C OH
Key: (A)
14. The compounds S is
O O
CH3 CH3
C C
CH C H
H
(A) CH (B) H3C
H3C
CH2 H2 C
CN CN

CN CN
CH3 CH3
CH CH
OH
C
CH CH OH
(C ) (D) H3C
H3C
CH2 CH2
OH
OH
14. (D)
Sol.:(12-14)
H
H3C
C H H H
H3C C C

O O
(P) (Q)
K2 CO 3

H
H3C
C O
C
H
H3C C H

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HO HO CH3
CH3
α γ
H3 O β
→ H3C
HCN
⎯⎯⎯ C C CH2 OH ⎯⎯⎯
→ H3C C C CH2 OH

CN CH3 CO2 H CH3

(R)
(S)
∆

HO

O
O

Cyclic ester (lactone)

Paragraph for Questions 15 to 17

The hydrogen-like species Li2+ is in a spherically symmetric state S1 with one radial node. Upon absorbing
light the ion undergoes transition to a state S2. The state S2 has one radial node and its energy is equal to the
ground state energy of the hydrogen atom.

15. Th e state S1 is
(A) 1s (B) 2s
(C ) 2p (D) 3s
Key: (B)
Sol.: No. of radial node = n – – 1
S ince state S1 has 1 radial node it must be 2s orbital with n = 2 and = 0.
∴ (B)

16. Energy of the state S1 in units of the hydrogen atom ground state energy is
( A) 0.75 (B) 1.50
( C) 2.25 (D) 4.50
Key: (C)
13.6 2
Sol.: Energy of state S1 = − × 3 eV/atom
22
= −13.6 × 2.25 eV / atom
= 2.25 times energy of ground state of hydrogen atom.
∴ (C)

17. The orbital angular momentum quantum number of the state S2 is

(A) 0 (B) 1
(C ) 2 (D) 3
Key: (B)
Sol.: Energy of S2 level = –13.6 eV/atom
13.6 × 32
− = −13.6
n2
∴ P.Q.N of level S2 = 3
S ince S2 has one radial node being present in 3rd shell it must be 3p orbital.
∴ The orbital angular momentum quantum number
i.e., Azimuthal quantum number of S2 = 1.

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18. Match the reactions in Column I with appropriate options in Column II.
Column I Column II
(A) (p) Racemic mixture
N2Cl
NaOH/ H 2 O
OH ⎯⎯⎯⎯→ N N OH
0° C

(B ) O (q) Addition reaction

OH OH CH3
C
H 2 SO4
H3C C C CH3 ⎯⎯⎯ → H3C C CH3

CH3 CH3 CH3

(C ) O OH (r) S ubstitution reaction

C 1. LiAlH 4
⎯⎯⎯⎯
2. H O+
→ CH
3

CH3 CH3

(D) Base S (s) Coupling reaction

HS Cl ⎯⎯⎯
→

(t) Carbonation intermediate

Key: (A – r, s), (B –t), (C – p, r), (D – r)

Sol.: (A) N2 H OH ⎯⎯
→ N N OH

CH3 CH3 CH3 CH3 CH3

+
H3C C C CH3 H
⎯⎯ → H3C C C CH3 ⎯⎯
→ H3C C C CH3
(B )
OH OH OH CH3 O

O OAlH3 HO

(C )
H2 O
C CH3 ⎯⎯⎯
LiAlH 4
→ C CH3 ⎯⎯⎯
→ C CH3

H H

( D) Intramolecular substitution reaction

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19. All the compounds listed in Column I react with water. Match the result of the respective reactions with the
appropriate options listed in Column II.
Column I Column II
(A) ( CH3 )2 SiCl2 (p) Hydrogen halide formation

(B ) XeF4 (q) Redox reaction

(C ) Cl2 (r) Reacts with glass
(D) VCl5 (s) Polymerization
(t) O2 formation

Key: (A – p, s), (B –p, qUW), (C – p, q), (D – p)

CH3 CH3

Sol.: (A) H3C Si Cl → H3C

2H 2 O ⎯⎯ Si OH ⎯⎯
→ Polymerisation

H OH ( silicons )

2XeF4 + 3H2O ⎯⎯
→ Xe + XeO3 + 3H2F2 + F2 , 6XeF4 +12H2O-->4Xe+2XeO3+ 12H2F2 + 3O2

(B ) SiO2 + 4HF ⎯⎯
→ SiF4 + 2H2O

SiF4 + 2HF ⎯⎯
→ H2SiF6

(C ) Cl2 + H2O ⎯⎯
→ HOCl + HCl.

(D) → must form HCl on hydrolysis

VCl5 + H 2 O ⎯⎯

Topper's Choice ..............Pawan Sir

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