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Hydrogen Reconversion
Course Renewable Energies 2011/12
Introduction
The hydrogen energy system overview
The meaning of the hydrogen energy system
The Laboratory for Integrated Energy Systems - main parts of the system
Characteristics of hydrogen
Thermal properties of ideal gases summary
Combustion of hydrogen
Low heating value LHVH2 and high heating value HHVH2 of hydrogen
Energy density of fuels
Heating value of gas mixtures
Minimal air consumption Lmin
Air fuel ratio
Low heating value of the air fuel mixture LHVAFM
Volumetric change at the reaction
Methane number of gases
Catalytic combustion of hydrogen
Catalytic burners
Use of catalytic burners in boilers
Hydrogen as a fuel for internal combustion engines (ICE)
Hydrogen as a fuel for gas turbines
Safe use of hydrogen
Photovoltaic
Installation
Windmill
Water Power Station
Electrical
Energy
Electrolyseur
Hydrogen prod.
from biomass
Electrical Energy
Fuel Cell
Power and Heat
Cogeneraton Plant
Hydrogen
Hydrogen Storage System
Hydrogen Reconversion
Thermal Energy
Boiler, Cooker,
Burner
Mechanical Energy
Gas Turbine,
Combustion Engine
Hydrogen Energy Reconversion
100 kW windmill
Ventis 20-100
10 kWp photovoltaik
installation
2. Characteristics of hydrogen
hydrogen
petrol
0,02
0,24
mJ
Vol-%
4 - 75
18
cm/s
ca. 190
ca. 40
Vol-%
29,53
1,76
kJ/m3
3240
3835
2. Characteristics of hydrogen
2. Characteristics of hydrogen
Ignition limits of
hydrogen and methane
and there mixtures
Source:
Winter, Nietsch: Hydrogen
as an energy carrier,
Springer Verlag 1988
2. Characteristics of hydrogen
2. Characteristics of hydrogen
2. Characteristics of hydrogen
state of
aggregation
: gas
volume
: 2 x 60 dm3
: steel wrapped
with fibres
(Aramid)
mole-ratio [-]
air-fuel-ratio [-]
Air
Water vapour
Hydrogen
Porous catalyst
Schematic model of a hydrogen burner
Dipl.-Ing. (FH) Christian Sponholz
Burner stick
1 - Ignition coil
2 - Air inlet control
3 - Gas valves
4 - Cables for thermocouples
5 - Pressure control unit
6 - Air deficiency switch
7 - Pressure control unit with safety valve
8 - Fan (radial)
9 - Air filter cover
10 - Automatic starter unit
praxis verstehen chancen erkennen zukunft gestalten
understanding reality facing challenges creating future
Contents:
Introduction
External mixture formation for hydrogen operated engines
Project : Experimental hydrogen car Ford Escort
Project : External hydrogen mixture formation for diesel engines
Internal mixture formation for hydrogen
Project : Internal mixture formation for hydrogen in a combustion
chamber
Summary
characteristics of hydrogen
unit
hydrogen
petrol
mJ
0,02
0,24
Vol-%
4 - 75
18
cm/s
ca. 190
ca. 40
Vol-%
29,53
1,76
kJ/m3
3240
3835
intensive research and developement for hydrogen operated Ottoengines started in germany in the 1970s
most important german automobile manufacturers with selfdeveloped engines are :
BMW (750hL, 12-cylinder Otto-engine, VH=5,4 dm3, P=150 kW)
Daimler-Benz 1985-1988 (MB310 Truck, 4-cylinder Otto-engine,
VH=2,3 dm3, P=75 kW)
MAN (SL202 Bus, 6-cylinder Otto-engine, VH=12 dm3, P=140
kW)
Photos : BMW AG
Displacement: 6 dm3
Power: 191 kW
gas mixer
mixture-charged engine
air-charged engine
Fig.:
cross-section through the
cylinder head of a BMW bifuel engine with intake
manifold (left); gasoline
injection valve (top); hydrogen
injection valve (bottom)
Picture: BMW
Fig.:
cross-section of the hydrogen
engine with fuel injection valve
MAN H2866 UH
6-cylinde-4-stroke cycle
12 litres, 140 kW
Picture: MAN
Dipl.-Ing. (FH) Christian Sponholz
state of
Aggregation
: gas
volume
: 2 x 60 dm3
manufacturer
type
dispacement
compression ratio
ignition timing
used air / fuel ratio
max. power
: Ford
: 4 cylinder - 4 stroke Otto engine
: 1400 cm3
: 9,5 : 1
: 10 BTDC
: 1,8 - 3,0
: 18 kW (n = 3900 min-1);
(previously 55 kW with petrol)
max. power
efficiency e
ignition timing
used air / fuel ratio
: 31 kW (n = 5000 min-1);
(previously 55 kW with petrol)
: max. 0,39
: 0 - 18 BTDC
: 1,8 - 2,0
TC
CPS
Fig.: crank angle sensor
TC
pZ(VZ) at different ignition timings, n=2000 min-1, TP=40%, =1,8 (ZZP=IT) (TP=throttle position)
Dipl.-Ing. (FH) Christian Sponholz
pZ(VZ) at different ignition timings, n=2000 min-1, TP=40%, =1,8 (ZZP=IT) (TP=throttle position)
Dipl.-Ing. (FH) Christian Sponholz
Md(IT), e(IT) at different ignition timings, n=2000 min-1, TP=40%, =1,8, (ZZP=IT) (TP=throttle position)
Dipl.-Ing. (FH) Christian Sponholz
Tproc(), Tex(), NOX() at different air-fuel-ratios, n=2000 min-1,Md=30 Nm, IT=5 BTDC
Dipl.-Ing. (FH) Christian Sponholz
Tproc(), Tex(), NOX() at different air-fuel-ratios, n=2000 min-1,Md=30 Nm, IT=5 BTDC, WOT=Wide Open Throttle
Dipl.-Ing. (FH) Christian Sponholz
Black: Efficiency e at different engine speed and load (DK=TP=throttle position - load)
Red: Efficiency e at different engine speed and load equivalent (DK* - load equivalent)
Dipl.-Ing. (FH) Christian Sponholz
H2+Air
Air
Exhaust gas
1 gas valve
2 safety valve
3 pressure regulator
4 max. pressure control switch
5 safety valve
6 min. pressure control switch
7 mass flow controller
8 air filter
9 hydrogen sensor
10 mixing chamber
11 pressure control switch backfiering
Efficiency for Diesel- and Dual-Fuel-Operation depending on diesel fuel mass flow
Dipl.-Ing. (FH) Christian Sponholz
charged engine
exhaust turbocharger
mechanical charger
common-rail
injection pump
Research
project at FH
Stralsund:
Prof. Dr.-Ing. W.
Beckmann,
Dipl.-Ing. J.
Brcker
LHVH2,H2(L),pH2(L),
TH2(L)
V = const.
cond. 1
pAir(Bk)
TAir(Bk)
Air(Bk)
mAir(Bk)
cond. 2
p(Bk)=f(t)
T(Bk)=f(t)
m(Bk)=f(t)
mEx-gas(Bk)
Research
project at FH
Stralsund:
Prof. Dr.-Ing. W.
Beckmann,
Dipl.-Ing. J.
Brcker
Research
project at FH
Stralsund:
Prof. Dr.-Ing. W.
Beckmann,
Dipl.-Ing. J.
Brcker
Research
project at FH
Stralsund:
Prof. Dr.-Ing. W.
Beckmann,
Dipl.-Ing. J.
Brcker
Research
project at FH
Stralsund:
Prof. Dr.-Ing. W.
Beckmann,
Dipl.-Ing. J.
Brcker
Research
project at FH
Stralsund:
Prof. Dr.-Ing. W.
Beckmann,
Dipl.-Ing. J.
Brcker
Picture: Hydrogen as an
energy carrier
Winter, Nitsch; 1988
Dipl.-Ing. (FH) Christian Sponholz
Source: EADS
MAN
Max-Planck-Institut
Messer Griesheim
Uhde
Linde
Lufthansa
Airport Munich
Drger
BAM
Fachhochschule Aachen
Overview :
German Russian cooperation project Cryoplane started 1990
Target : use of cryogenic fuels (LNG, LH2) for aircraft engines
1990 1992 analysis of feasibility
Developement of components for the fuel system and for the aircraft
engines
Main part developemet of low-pollutant combustion chambers for
hydrogen
Latest activities :
Tests with special developed combustion chambers for hydrogen
Operation of gas turbine with hydrogen on a testbed
Planning of a hydrogen operated airplane
NOX-emissions depending
on load
Source: Fachhochschule
Aachen
Dipl.-Ing. (FH) Christian Sponholz
NOX-Emissions of gas
turbines
Source: H2-Cryoplane,
Airbus
No
No
No
Yes
Yes
2. Is an explosive mixture by dissemination in air possible ?
Yes
3. Analysis of quantities and sources of explosive atmosphere necessary !
4. Is a dangerous explosive atmosphere possible ?
Yes
5. Protection against explosion necessary !
6. Restrict the formation of an explosive atmosphere as far as possible !
7. Is the formation of an dangerous explosive atmosphere restricted ?
No
8. Further protection against explosion necessary !
A dangerous explosive atmosphere is existing by gases and vapours:
permanent, long-term : Zone 0
at times : Zone 1
at failure-free operation
at often failures
at failure-free operation
10. Precautions by design, which limits the effects of an explosion to a safe degree.
praxis verstehen chancen erkennen zukunft gestalten
understanding reality facing challenges creating future