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Time : 3 Hrs.
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11.
(10 X 2 = 20 Marks)
T
=
s
(b)
Cp
C
(c)
12.
(10 X 2 = 20 Marks)
= -
T
U =
T
p
S v
T
p
p + T ( / T)p
( / p)T
(a) An ideal gas (Cp = 5 and C = 3 cal/gm mole K)is at 1 atm has a volume and of
V1 = 22.4 m3. It is brought to P2 = 10 atm and V2 = 2.24 m3 by the following
reversible processes.
(i)
Isothermal compression.
(ii)
Adiabatic compression followed by cooling at constant pressure.
(iii)
Heating at constant volume followed by cooling at constant pressure.
Calculate ,, U and H for each step of this overall process.
OR
(b) A pressure cylinder contains 50 litres of nitrogen weighing 400 grams. What is
the maximum temperature to which the cylinder could be exposed, if the pressure
in the cylinder should not exceed 80 atmospheres absolute? The compressibility
factor at the above conditions for nitrogen is 0.946.
RT1
r -1
1 - P2
P1
r-1/ r
Show also that this equation, for an isothermal process for which r = 1 reduces to
W = RT ln P1
P2
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