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Xudong Chen
Jikai Zhou
Hohai University
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h i g h l i g h t s
" Strength and porosity of cement mortar has been measured.
" Strength decreases with increasing porosity.
" Suitability of existing expressions relating strength and porosity is assessed.
" Extended Zheng model is good representation of experimental data.
" Compressive/tensile strength ratio decreases with increase porosity.
a r t i c l e
i n f o
Article history:
Received 5 July 2012
Received in revised form 26 September
2012
Accepted 21 November 2012
Keywords:
Strength
Porosity
Cement mortar
a b s t r a c t
The compressive, exural and splitting tensile strength of cement mortar has been measured and interpreted in terms of its porosity. The authors rst reviewed the existing porositystrength relationships
(Ryshkewithch, Schiller, Balshin and Hasselman model) and assessed the suitability of existing relationships. The Zheng model for porous materials has been used to evaluate the porositystrength relationship
of cement mortar. Over the porosity ranges examined, the extended Zheng model is good representation
of the experimental data on the strength of cement mortar. Based on the generality of the assumptions
used in the derivation of the extended Zheng model, this model for cement mortar can be applied for
other cement-based materials. The experimental data also show that the ratio between compressive
strength and indirect tensile (splitting tensile and exural) strength of cement mortar is not constant,
but is porosity dependent. The ratio decreases with increase porosity values of cement mortar.
2012 Elsevier Ltd. All rights reserved.
1. Introduction
The fact that a reduction of porosity in a solid material increases
its strength in general, and the strength of cement-based materials
in particular, was recognized long ago [13]. It has also been discovered that porosity has an important role in the frost resistance
of concrete [46]. Furthermore, porosity has a role in the relationship between mechanical properties of concrete, such as the
compressive strength-modulus of elasticity relationship [7]. The
practical importance of durability of cement-based materials
created such an upsurge in research activities that our knowledge
concerning the relationship between pore structure and frost
resistance of concrete is much more complete than the strength
porosity relationship. This does not mean that no efforts have been
made for the development of quantitative relationships between
strength and porosity but rather that these efforts have been sporadic [810] and the results have less than satisfactory.
In the eld of more basic research, the pore structure of cementbased materials has been a dominant topic [2,1114]. But experimentally measurement of a relevant porosity parameter has
proved to be extremely difcult in cement-based materials,
because of the special character of the hydration products formed
[15]. Hence the results obtained will depend not only on the measuring principle but also on the drying method used prior to the
porosity measurements [16]. But even with these problems solved,
a connection between the porosity and strength has to be established. The inuence of porosity on the strength of cement-based
material has already been investigated. Taking an empirical approach, Powers [11] was able to deduce an equation which relates
the compressive strength of mortar cubes to a function of the gelspace ratio. Schiller [17] using a theoretical approach deduced an
equation relation the strength of material to the porosity. He applied this equation to experimental data on gypsum plasters and
obtained a good t for compressive and tensile strengths. Some
excellent reviews [1820] of the effect of porosity on the strength
of concrete presented some of the more important empirical and
theoretical equation for relating strength to porosity. The profusion
of the possible equation is enormous and whilst one equation is
870
r r0 1 pb
r r0 ekp
r n ln
p0
p
2. Experimental details
2.1. Materials and mix compositions
An adequate number of series of cement mortar compositions were prepared to
study the strengthporosity relationship. Cement mortar samples were prepared
from ordinary Portland cement 42.5. The ne aggregate used for mortar specimens
was river quartzite sand. The sand was passed through a No. 4 sieve before use. Four
watercement ratio (w/c), 03, 0.5, 0.6 and 0.7, were used for cement mortar. The
corresponding sandcement ratio (s/c) for all cement mortars is 1.2. Mixing was
done in a small mixer. Casting was completed in two layers which were compacted
on a vibrating table. The cast specimens were covered with polyurethane sheet and
damped cloth in a 20 2 C chamber and were demoulded at the age of 1 day. For
strength and porosity tests, the specimens were cured in saturated limewater at
20 2 C until the test age 7 and 28 days.
r r0 cP
W ssd W d
100%
W ssd W w
where p is the porosity (100%), Wssd is the specimen weight in the saturated surfacedry (SSD) condition (g), Wd is the specimen dry weight after 24 h in oven (g), and Ww
is the weight of saturated specimen (g).
This method has been used to measure the porosity of the cement-based materials successfully [15,2830].
871
r
2Ec
r
pa
r
m
pc p
pc
872
r a
K Ic
m=2
pc p
K Ic
pc
p
2cE
8
9
where KIc is the fracture toughness of porous material; a is a coefcient concerning stress state.Wagh et al. [51] given the porosity
dependence of the fracture toughness as:
K Ic K Ico
1=2
pc p
1 p2=3
pc
10
"
#1=2
1m
pc p
2=3
r a K Ico
1 p
pc
11
"
#1=2
1:85
pc p
2=3
r r0
1 p
pc
12
Table 1
Estimated values for r0 and pc.
Loading regime
pc
r0
Compression
Splitting tension
Flexure
0.562
0.768
0.783
69.4
9.74
5.56
0.989
0.996
0.993
The exural and splitting tensile tests are much cheaper, simpler and quicker to carry out because the samples are smaller,
and the set up time for the tests is much less. All quantitative data
reported so far referred exclusively to compressive strength [7]. In
this section, we explore the role of porosity and how it inuences
the correlation between indirect tensile and compressive strength.
From a number of other investigators [7,21,5557], a simple power
law model has become one of the most widely used analytical
models for describing the relationship between the indirect tensile
(splitting tensile/exural) strength and compressive strength of
concrete. From the experimental results, we can write a new
expression for the ratio between indirect tensile strength and compressive strength, as a function of porosity:
873
indicated by Eqs. (13) and (14) are in conformity with the ndings
of Odler and Robler [58].
5. Conclusions
The dependence of compressive, splitting tensile and exural
strength on porosity for cement mortar was analysed empirically
and theoretically in this paper. The following conclusions can be
drawn:
Fig. 7. Effect of porosity on the ratio between compressive strength and splitting
tensile strength of cement mortar.
rC
4:12 p0:236
rF
13
rC
7:45 p0:221
rS
14
Fig. 8. Effect of porosity on the ratio between compressive strength and exural
strength of cement mortar.
(1) Ryshkewithchs exponential and Schillers logarithmic formulae for the porositystrength relationship of cement mortar are numerically indistinguishable except in the
neighborhood of the extremes of 0% and 100% porosity. Simple linear relationship of Hasselman model shows articial
intercept with the abscissa at porosity less than the initial
porosity and predicts negative strength at higher porosities.
Although the initial porosity of the material enters in the
model of Schiller, the predicted strength increase with the
decrease in porosity is too high.
(2) Over the porosity ranges examined, the extend Zhengs
model are good representations of the experimental data
on the strength of cement mortar. This model requires two
parameters to dene the strength characteristics of cement
mortar and the parameters can account the changes in loading regime (splitting tension, exure or compression). Based
on the generality of the assumptions used in the derivation
of the extended Zhengs model, this model for cement mortar can be applied for other cement-based materials.
(3) The experimental data also show that the ratio between
compressive strength and indirect tensile (split-tensile and
exural) strength of cement mortar is not constant, but is
porosity dependent. The ratio decreases with increase porosity values of cement mortar.
Acknowledgement
The authors are grateful to the National Natural Science Foundation (Nos. 50979032 and 51178162) for the nancial support.
References
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