SET-3

H$moS> Z.

Series SSO

Code No.

amob Z.

56/3/P

narjmWu H$moS >H$mo Cma-nwpVH$m Ho$ _wI-n

>na Ad` {bIo &

Roll No.

Candidates must write the Code on the

title page of the answer-book.

H$n`m OmM H$a b| {H$ Bg Z-n _o _w{V n> 15 h &

Z-n _| Xm{hZo hmW H$s Amoa {XE JE H$moS >Z~a H$mo N>m Cma -nwpVH$m Ho$ _wI-n> na
{bI| &
H$n`m OmM H$a b| {H$ Bg Z-n _| >26 Z h &
H$n`m Z H$m Cma {bIZm ew$ H$aZo go nhbo, Z H$m H$_mH$ Ad` {bI| &
Bg Z-n H$mo nT>Zo Ho$ {bE 15 {_ZQ >H$m g_` {X`m J`m h & Z-n H$m {dVaU nydm
_| 10.15 ~Oo {H$`m OmEJm & 10.15 ~Oo go 10.30 ~Oo VH$ N>m Ho$db Z-n H$mo nT>|Jo
Ama Bg Ad{Y Ho$ XmamZ do Cma-nwpVH$m na H$moB Cma Zht {bI|Jo &
Please check that this question paper contains 15 printed pages.
Code number given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
Please check that this question paper contains 26 questions.
Please write down the Serial Number of the question before
attempting it.
15 minute time has been allotted to read this question paper. The question
paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the
students will read the question paper only and will not write any answer on
the answer-book during this period.

agm`Z {dkmZ (gmpVH$)

CHEMISTRY (Theory)

{ZYm[aV g_` : 3 KQ>o

A{YH$V_ AH$ : 70

Time allowed : 3 hours

56/3/P

Maximum Marks : 70
1

P.T.O.

gm_m` {ZX}e :
(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)

g^r Z A{Zdm` h &

Z g`m 1 go 5 VH$ A{V bKw-Cmar` Z h Ama `oH$ Z Ho$ {bE 1 AH$ h &
Z g`m 6 go 10 VH$ bKw-Cmar` Z h Ama `oH$ Z Ho$ {bE 2 AH$ h &
Z g`m 11 go 22 VH$ ^r bKw-Cmar` Z h Ama `oH$ Z Ho$ {bE 3 AH$ h &
Z g`m 23 _y`mYm[aV Z h Ama BgHo$ {bE 4 AH$ h &
Z g`m 24 go 26 VH$ XrK-Cmar` Z h Ama `oH$ Z Ho$ {bE 5 AH$ h &
`{X Amd`H$Vm hmo, Vmo bmJ Q>o~bm| H$m `moJ H$a| & H$Hw$boQ>am| Ho$ Cn`moJ H$s AZw_{V
Zht h &

General Instructions :
(i)

All questions are compulsory.

(ii)

Questions number 1 to 5 are very short answer questions and carry

1 mark each.

(iii)

Questions number 6 to 10 are short answer questions and carry 2 marks

each.

(iv)

Questions number 11 to 22 are also short answer questions and carry

3 marks each.

(v)

Question number 23 is a value based question and carry 4 marks.

(vi)

Questions number 24 to 26 are long answer questions and carry 5 marks

each.

(vii)

Use log tables, if necessary. Use of calculators is not allowed.

1.

{XE JE `m{JH$ H$m AmB.`y.nr.E.gr. Zm_ {b{IE

CH2 = C CH2 OH
|
CH3
Write the IUPAC name of the given compound :
CH2 = C CH2 OH
|
CH3
56/3/P

2.

Zn2+ Ho$

Cu2+ Ho$

bdU g\o$X hmoVo h O~{H$

bdU aJrZ hmoVo h & `m|

Zn2+ salts are white while Cu2+ salts are coloured. Why ?
3.

{ZZ{b{IV `w_ _|

SN1 A{^{H$`m

CH3 CH2 Br

VWm

H$mZ A{YH$ VoOr go H$aoJm

CH3
|
CH3 C CH3
|
Br

Which would undergo SN1 reaction faster in the following pair :

CH3
|
CH3 CH2 Br and CH3 C CH3
|
Br
4.

Zn2+

Ho$$

_mob H$mo

Zn

_| AnM`Z H$aZo _| {H$VZo Amdoe (MmO) H$s Amd`H$Vm hmoVr

How much charge is required for the reduction of 1 mol of Zn2+ to Zn ?

5.

_IZ H$s n[a{jV mdWm Ama n[ajonU _m`_ H$mo {b{IE &

Write the dispersed phase and dispersion medium of butter.

6.

H$mbog

[Pt(en)2Cl2]2+

H$m AmB.`y.nr.E.gr. Zm_ {b{IE & Bg H$mbog mam {H$g

H$ma H$s g_md`dVm {XImB OmVr h

AWdm
AmB.`y.nr.E.gr. n{V H$m Cn`moJ H$aVo hE {ZZ{b{IV Cnghg`moOZ `m{JH$m| Ho$ {bE
gym| H$mo {b{IE :
(i)
hogmEo_rZH$mo~mQ>(III) bmoamBS>
(ii)
nmoQ>{e`_ Q>oQ>mbmoamBS>mo{ZH$boQ>(II)
56/3/P

P.T.O.

Write down the IUPAC name of the complex [Pt(en)2Cl2]2+. What type of
isomerism is shown by this complex ?
OR
Using IUPAC norms write the formulae for the following coordination
compounds :

7.

(i)

Hexaamminecobalt(III) chloride

(ii)

Potassium tetrachloridonickelate(II)

{ZZ{b{IV H$mo CZH$s jmar` j_Vm Ho$ ~T>Vo H$_ _| `dpWV H$s{OE
(i)

C6H5 NH2, C6H5 CH2 NH2, C6H5 NH CH3

Arrange the following in increasing order of their basic strength :

(i)

8.

C6H5 NH2, C6H5 CH2 NH2, C6H5 NH CH3

EH$ Admnerb {dbo` Ho$ {db`Z H$m dWZmH$ EH$ ew {dbm`H$ go A{YH$ `m| hmoVm
h ? dWZmH$ H$m C`Z EH$ AUwg` JwUY_ `m| h ?
Why does a solution containing non-volatile solute have higher boiling
point than the pure solvent ? Why is elevation of boiling point a
colligative property ?

56/3/P

9.

{ZZ{b{IV AUwAm| H$s gaMZmE {b{IE

(i)

H2SO3

(ii)

XeOF4

Write the structures of the following molecules :

10.

(i)

H2SO3

(ii)

XeOF4

A{^{H$`m H$s Xa n[a^m{fV H$s{OE & Xmo H$maH$ {b{IE Omo A{^{H$`m H$s Xa H$mo ^m{dV
H$aVo h &

Define rate of reaction. Write two factors that affect the rate of reaction.
11.

{ZZ{b{IV A{^{H$`mAm| Ho$ `oH$ Ho$ _w` CnmX H$s gaMZmE {b{IE

Write the structure of the major product in each of the following

reactions :

56/3/P

P.T.O.

12.

{ZZ{b{IV Ho$ {bE H$maU Xr{OE

(i)

\$sZmb AnojmH$V EWoZmb Ho$ A{YH$ Abr` h &

(ii)

_oWmgr_oWZ H$s VwbZm _| EWoZmb H$m dWZmH$ CVa h &

(iii)

(CH3)3C O CH3, HI
CH3OH Ama (CH3)3C I

Ho$ gmW A{^{H$`m H$aHo$ _w` CnmXm| Ho$ $n _|

XoVm h Z {H$

(CH3)3C OH

Ama

CH3I.

Give reasons for the following :

(i)

Phenol is more acidic than ethanol.

(ii)

Boiling

point

of

ethanol

is

higher

in

comparison

to

methoxymethane.
(iii)

(CH3)3C O CH3 on reaction with HI gives CH3OH and

(CH3)3C I as the main products and not (CH3)3C OH and CH3I.

13.

O~ E{WbrZ bmBH$mb (C2H6O2) H$m 31 g Ob Ho$ 500 g _| Kwbm hAm hmo, V~ {db`Z
Ho$ {h_mH$ H$m n[aH$bZ H$s{OE & (Ob Ho$ {bE Kf = 1.86 K kg mol1)

Calculate the freezing point of the solution when 31 g of ethylene glycol

(C H O ) is dissolved in 500 g of water. (K for water = 1.86 K kg mol1)
2

14.

6 2

{ZZ{b{IV nXm| H$mo n[a^m{fV H$s{OE :

(i)
A^m` EH$H$ gob ({{_{Q>d `y{ZQ> gob)
(ii)

emQ>H$s Xmof

(iii)

bmoh-Mw~H$d

Define the following terms :

56/3/P

(i)

Primitive unit cells

(ii)

Schottky defect

(iii)

Ferromagnetism
6

15.

O~ Vmn_mZ 300 K go 310 K n[ad{VV hmoVm h V~ EH$ W_ H$mo{Q> H$s A{^{H$`m H$m Xa
pWamH$ 2 102 go ~T>H$a 4 102 hmo OmVm h & g{H$`U D$Om (Ea) H$m n[aH$bZ
H$s{OE &

(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)

The rate constant of a first order reaction increases from 2 102 to
4 102 when the temperature changes from 300 K to 310 K. Calculate
the energy of activation (Ea).
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)
16.

(a)

(b)
(a)

{ZZ{b{IV H$mbogm| Ho$ gH$aU Ama AmH$ma {b{IE

(i)

[ CoF6]3

(ii)

[Ni(CN)4]2

(na_mUw H$_mH$ : Co = 27, Ni = 28)

NH3 Ama CO _| go H$mZ-gm {bJS> gH$_U YmVw Ho$ gmW A{YH$ WmB
H$mbog ~ZmVm h Ama `m| ?

Write the hybridization and shape of the following complexes :

(i)

[ CoF6]3

(ii)

[Ni(CN)4]2

(Atomic number : Co = 27, Ni = 28)

(b)

Out of NH3 and CO, which ligand forms a more stable complex
with a transition metal and why ?

17.

{ZZ{b{IV nXm| H$mo n[a^m{fV H$s{OE :

(i)
~mC{Z`Z J{V>
(ii)
noQ>rH$aU
(iii) ~h-AmpdH$ (_Q>r_m{bHy$ba) H$mobmBS>

Define the following terms :

56/3/P

(i)

Brownian movement

(ii)

Peptization

(iii)

Multimolecular colloids
7

P.T.O.

18.

19.

(i)

YmVwAm| Ho$ OmoZ n[aH$aU Ho$ nrN>o `m {gmV hmoVm h

(ii)

H$mna Ho$ {ZH$fU _| {g{bH$m H$s `m ^y{_H$m hmoVr h

(iii)

H$mQ> Am`aZ {H$g H$ma {nJ Am`aZ go {^ hmoVm h

(i)

What is the principle behind the zone refining of metals ?

(ii)

What is the role of silica in the extraction of copper ?

(iii)

How is cast iron different from pig iron ?

{ZZ{b{IV ~hbH$m| Ho$ EH$bH$m| Ho$ Zm_ Ama CZH$s gaMZmE {b{IE
(i)

~wZm-S

(ii)

pbQ>b

(iii)

nmbrdmB{Zb bmoamBS>

Write the names and structures of the monomers of the following

polymers :

20.

56/3/P

(i)

Buna-S

(ii)

Glyptal

(iii)

Polyvinyl chloride

(i)

O~ D-byH$mog
Cgo {b{IE &

(ii)

Eo_rZmo Ab C^`Y_u `dhma X{eV H$aVo h & `m|

(iii)

{dQ>m{_Z

(i)

Write the product obtained when D-glucose reacts with H2N OH.

(ii)

Amino acids show amphoteric behaviour. Why ?

(iii)

Why cannot vitamin C be stored in our body ?

H2N OH

C h_mao

go A{^{H$`m H$aVm h V~ Omo CnmX mV hmoVm h,

eara _| O_m `m| Zht ah gH$Vm h

?
?

21.

{ZZ{b{IV $nmVaU Amn H$go H$a|Jo

(i)

C6H5CONH2

(ii)

Eo{ZbrZ H$mo \$sZmb _|

(iii)

EWoZZmBQ>mBb H$mo EWoZEo_rZ _|

H$mo

C6H5NH2 _|

AWdm
O~ Eo{ZbrZ H$mo {ZZ{b{IV A{^H$maH$m| Ho$ gmW CnMm[aV {H$`m OmVm h, V~ g~
amgm`{ZH$ g_rH$aUm| H$mo {b{IE :
(i)

Br2 Ob

(ii)

CHCl3 + KOH

(iii)

HCl

How do you convert the following :

(i)

C6H5CONH2 to C6H5NH2

(ii)

Aniline to phenol

(iii)

Ethanenitrile to ethanamine
OR

Write the chemical equations involved when aniline is treated with the
following reagents :

56/3/P

(i)

Br2 water

(ii)

CHCl3 + KOH

(iii)

HCl
9

P.T.O.

22.

{ZZ{b{IV Ho$ {bE H$maU Xr{OE

N2 H$_

(i)

H$_ao Ho$ Vmn_mZ na

(ii)

dJ 16 Ho$ Vdm| Ho$ g^r hmBS>mBS>m| _|

h &

(iii)

JmoVmImoam| Ho$ CnH$aU _| hr{b`_ AmgrOZ Ho$ {bE EH$ VZwH$mar Ho$ $n _| `w$
hmoVr h &

A{^{H$`merb h &
H2Te

g~go A{YH$ ^mdembr AnMm`H$

Give reasons for the following :

23.

56/3/P

(i)

N2 is less reactive at room temperature.

(ii)

H2Te is the strongest reducing agent amongst all the hydrides of

Group 16 elements.

(iii)

Helium is used in diving apparatus as a diluent for oxygen.

OdmZ ~m| _| _Yw_oh Ama AdgmX (CXmgr) H$s ~T>Vr g`m H$mo XoIH$a, EH$ {g
Hy$b Ho$ q{gnb lr bwJmZr Zo EH$ go{_Zma H$m Am`moOZ {H$`m {Og_| A` q{gnbm| Ama
~m| Ho$ _mVm-{nVmAm| H$mo Am_{V {H$`m & `h {ZU` {b`m J`m {H$ Hy$bm| _| gS>o hE
ImZo H$s dVwE ~X H$s OmE Ama dm`dYH$ dVwE Ogo gyn, bgr, XY, Am{X CnbY
H$amB OmE & Chm|Zo `h ^r {ZU` {b`m {H$ Hy$bm| _| amoO mVH$mb H$s Eogo~br Ho$ g_`
~m| H$mo AmYm KQ>o H$m emar[aH$ `m`m_ A{Zdm` $n go H$am`m OmE & N> _mh Ho$
nMmV, lr bwJmZr Zo A{YH$Va Hy$bm| _| {\$a dm` narjU H$am`m Ama ~m| Ho$
dm` _| AZwn_ gwYma nm`m J`m &
Cn`w$ {ddaU H$mo nT>H$a {ZZ{b{IV Zm| Ho$ Cma Xr{OE :
(i)
lr bwJmZr mam {H$Z _y`m| (H$_-go-H$_ Xmo) H$mo X{eV {H$`m J`m

(ii)

EH$ {dmWu Ho$ $n _|, Amn Bg {df` _| H$go OmJ$H$Vm \$bmEJo

(iii)

CXmgr Xa H$aZo Ho$ S>g `m h ? EH$ CXmhaU Xr{OE &

(iv)

EH$ _Yw_oh Ho$ amoJr Ho$ {bE {_R>mB ~ZmZo Ho$ {bE Omo _rR>mH$mar A{^H$maH$
(_YwH$a) `w$ hmoVm h, CgH$m Zm_ Xr{OE &
10

Seeing the growing cases of diabetes and depression among young

children, Mr. Lugani, the principal of one reputed school organized a
seminar in which he invited parents and principals. They all resolved
this issue by strictly banning junk food in schools and introducing
healthy snacks and drinks like soup, lassi, milk, etc. in school canteens.
They also decided to make compulsory half an hour of daily physical
activities for the students in the morning assembly. After six months,
Mr. Lugani conducted the health survey in most of the schools and
discovered a tremendous improvement in the health of the students.
After reading the above passage, answer the following questions :
(i)

What are the values (at least two) displayed by Mr. Lugani ?

(ii)

As a student, how can you spread awareness about this issue ?

(iii)

What are antidepressant drugs ? Give an example.

(iv)

Name the sweetening agent used in the preparation of sweets for a

diabetic patient.

24.

(a)

(b)

>{ZZ{b{IV H$mo H$maU g{hV n> H$s{OE

(i)

Zr Ama Hf

(ii)

gH$_U YmVwE {d{dY CnM`Z AdWmE X{eV H$aVo h &

(iii)

Obr` {db`Z _|

bJ^J g_mZ na_mUw {`mAm| dmbo h &

Cu+ Am`Z

WmB Zht h &

{ZZ{b{IV g_rH$aUm| H$mo nyU H$s{OE

(i)

2 MnO2 + 4 KOH + O2

(ii)

2 Na2CrO4 + 2 H+

AWdm
56/3/P

11

P.T.O.

(a)
E0 2
(M / M)
E0

(b)

Cr

Mn

Fe

Co

Ni

Cu

0.91

1.18

0.44

0.28

0.25

+ 0.34

_mZm| Ho$ {XE JE AmH$S>m| go {ZZ{b{IV Zm| Ho$ Cma Xr{OE

(i)

E0

_mZ `m| AndmX-d$n YZm_H$ h

(ii)

E0

_mZ `m| A` Vdm| H$s VwbZm _| A{YH$ G$Um_H$ h

(iii)

H$mZ-gm ~bVa AnMm`H$ h

(Cu 2 / Cu )
(Mn 2 / Mn )

Cr2+

`m

Fe2+ ? H$maU

Xr{OE &

EopQ>Zm`S>| ~hma namg _| CnM`Z AdWmE `m| {XIbmVr h ? EopQ>Zm`S>m| Ama

bWZm`S>m| Ho$ ~rM agm`Z H$s H$moB EH$ g_mZVm {b{IE &

(a)

Account for the following :

(i)
Zr and Hf have almost similar atomic radii.
(ii) Transition metals show variable oxidation states.
(iii) Cu+ ion is unstable in aqueous solution.

(b)

Complete the following equations :

(i)

2 MnO2 + 4 KOH + O2

(ii)

2 Na2CrO4 + 2 H+
OR

(a)
E0 2
(M / M)

Cr

Mn

Fe

Co

Ni

Cu

0.91

1.18

0.44

0.28

0.25

+ 0.34

From the given data of E 0 values, answer the following questions :

(i)

Why is E0

(ii)

Why is E0

(Cu 2 / Cu )

(Mn 2 / Mn )

value exceptionally positive ?

value highly negative as compared to

other elements ?
(iii)
(b)
56/3/P

Which is a stronger reducing agent Cr2+ or Fe2+ ? Give

reason.

Why do actinoids show a wide range of oxidation states ? Write one

similarity between the chemistry of lanthanoids and actinoids.
12

25.

(a)

C2H3OCl

(b)

{ZZ{b{IV Ho$ ~rM ^oX (AVa) H$s{OE

(c)

AmpdH$ gy dmbm EH$ `m{JH$ A XemB JB A{^{H$`mAm| H$s mIbm

H$aVm h & {ZZ{b{IV A{^{H$`mAm| _| A, B, C Ama D H$s gaMZmE {b{IE :

(i)

C6H5 COCH3

(ii)

~oOmoBH$ Ab Ama _o{Wb ~oOmoEQ> _|

2-_o{Wb`yQoZob

Ama

C6H5 CHO

_|

H$s gaMZm {b{IE &

AWdm
(a)

(b)

O~ EogrQ>moZ (CH3 CO CH3) {ZZ{b{IV A{^H$maH$m| go A{^{H$`m H$aVm

h, Vmo mV _w` CnmXm| H$s gaMZmE {b{IE :
(i)

Zn Hg/gm HCl

(ii)

H2N NHCONH2/H+

(iii)

CH3MgBr

Ama BgHo$ ~mX

H3O+

{ZZ{b{IV H$mo CZHo$ dWZmH$ Ho$ ~T>Vo hE H$_ _| `dpWV H$s{OE

C2H5OH, CH3 CHO, CH3 COOH

(c)

`m{JH$m| Ho$ {ZZ{b{IV `w_ _| AVa H$aZo Ho$ {bE EH$ gm_m` amgm`{ZH$ OmM
Xr{OE :
CH3CH2CHO

56/3/P

Ama

CH3CH2COCH3

13

P.T.O.

(a)

A compound A of molecular formula C2H3OCl undergoes a series

of reactions as shown below. Write the structures of A, B, C and D
in the following reactions :

(b)

(c)

Distinguish between the following :

(i)

C6H5 COCH3 and C6H5 CHO

(ii)

Benzoic acid and methyl benzoate

Write the structure of 2-methylbutanal.

OR

(a)

Write the structures of the main products when acetone

(CH3 CO CH3) reacts with the following reagents :

(b)

(i)

Zn Hg/conc. HCl

(ii)

H2N NHCONH2/H+

(iii)

CH3MgBr and then H3O+

Arrange the following in the increasing order of their boiling

points :
C2H5OH, CH3 CHO, CH3 COOH

(c)

Give a simple chemical test to distinguish between the following

pair of compounds :
CH3CH2CHO and CH3CH2COCH3

56/3/P

14

26.

(e.m.f.) Ama G

{ZZ{b{IV gob Ho$ {bE {dwV-dmhH$ ~b

H$m n[aH$bZ H$s{OE

Mg (s) | Mg2+ (0.001 M) || Cu2+ (0.0001 M) | Cu (s)

{X`m J`m h

: E0

(Mg 2 / Mg )

= 2.37 V, E0

(Cu 2 / Cu )

= + 0.34 V.

AWdm
(a)

KCl

{db`Z Ho$

0.20 mol L1 H$s

MmbH$Vm

_moba MmbH$Vm Ama {d`moOZ-_mm

0

(K+) = 73.5 S cm2 mol1

(b)

h & BgH$s

n[aH${bV H$s{OE & {X`m J`m h

(Cl) = 76.5 S cm2 mol1.

Ama

_H$ar gob {H$g H$ma H$s ~Q>ar h

bm^Xm`H$$ `m| h

()

2.48 102 S cm1

`h ewH$ (S>mB) gob H$s Anojm A{YH$

Calculate e.m.f. and G for the following cell :

Mg (s) | Mg2+ (0.001 M) || Cu2+ (0.0001 M) | Cu (s)
Given : E0

(Mg 2 / Mg )

= 2.37 V, E0

(Cu 2 / Cu )

= + 0.34 V.

OR
(a)

The

conductivity

2.48 102 S cm1.

of

0.20 mol L1

Calculate

its

solution
molar

of

KCl

conductivity

is
and

degree of dissociation (). Given (K+) = 73.5 S cm2 mol1 and

0

(Cl) = 76.5 S cm2 mol1.

(b)

What type of battery is mercury cell ? Why is it more advantageous

than dry cell ?

56/3/P

15

P.T.O.