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Because standard reference books contain data in diverse units, we include Tables A.l and
A.2 to aid the conversion of values from one set of units to another. Those units having no
connection with the SI system are enclosed in parentheses. The following definitions are noted:
U.S. defined foot 3.048 x
m
U.S. defined inch 2.54 x
m
U.S. liquid gallon
U.S. defined pound mass (avoirdupois)
4.535 9237 x
kg
force to accelerate
by 32.1740 (ft)
atm standard atmospheric pressure 101 325 Pa
(psia) E pounds force per square inch absolute pressure
pressure exerted by 1 mm mercury at 273.15 K
and standard gravity
(cal) thermochemical calorie
(Btu) international steam table British thermal unit
(lb mole) mass in pounds mass with numerical value equal to the molar mass
(R) absolute temperature in
(ft)
(in)
(gal)
(lb,)
The conversion factors of Table A.1 are referred to a single basic or derived unit of the
SI system. Conversions between other pairs of units for a given quantity are made as in the
following example:
thus
750.061
= 760.00
0.986 923
630
Length
Mass
Force
Pressure
Volume
Density
Energy
Power
I m=
cm
= 2.204 62 (lb,)
N = 1 kg m
(dyne)
=
0.224 809
kg
bar =
=
=
Pa =
= 1 dyne
= 0.986 923 atm
= 14.5038 (psia)
= 750.061 torr
1 m3 =
cm3
= 35.3147
= 264.172 (gal)
= 1 m 3P a =
= 9.869 23 cm3 atm
dyne cm =
erg
=
= 0.239 006 (cal)
= 5.121 97 x
= 9.478 3 x
(Btu)
kg m2
W=
=
= 239.006 (cal)
= 737.562
= 0.947 83 (Btu)
= 1.341 02 (hp)
bar
= 0.737 562
=
R = 8.314 J
= 83.14 cm3 bar
82.06 cm3 atm
(cal)
=
= 0.7302
=
= 8.314 m3 Pa
= 8314 cm3
= 82 363.95 cm3 torr
= 1.986
= 10.73
0.082 06 m3 atm
Appendix B
Listed here for various chemical species are values for the molar mass (molecular weight),
acentric factor critical temperature critical pressure
critical compressibility factor
critical molar volume
and normal boiling point
Abstracted from Project 801,
Design Institute for Physical Property Data of the American Institute of Chemical Engineers,
they are reproduced with permission. The full data compilation is published by T. E. Daubert,
R. Danner, H. M. Sibul, and C. C. Stebbins, Physical and Thermodynamic Properties
Chemicals: Data Compilation, Taylor Francis, Bristol, PA, 1,405 chemicals, extant 1995.
Included are values for 26 physical constants and regressed values of parameters in equations
for the temperature dependence of 13 thermodynamic and transport properties.
Electronic versions by the same authors include:
Molar
Methane
Ethane
Propane
n-Butane
n-Pentane
n-Hexane
n-Heptane
n-Octane
n-Nonane
n-Decane
Isobutane
Isooctane
Cyclopentane
Cyclohexane
Methylcyclopentane
Methylcyclohexane
Ethylene
Propylene
cis-2-Butene
trans-2-Butene
Isobutylene
Cyclohexene
Acetylene
Benzene
Toluene
Ethylbenzene
Cumene
o-Xylene
m-Xylene
p-Xylene
Styrene
Naphthalene
Biphenyl
Formaldehyde
Acetaldehyde
Methyl acetate
Ethyl acetate
Acetone
Methyl ethyl ketone
Diethyl ether
Methyl t-butyl ether
Methanol
16.043
30.070
44.097
58.123
72.150
86.177
100.204
114.231
128.258
142.285
58.123
114.231
70.134
84.161
84.161
98.188
28.054
42.081
56.108
56.108
56.108
84.161
56.108
54.092
82.145
26.038
78.114
92.141
106.167
120.194
106.167
106.167
106.167
104.152
128.174
154.211
30.026
44.053
74.079
88.106
58.080
72.107
74.123
88.150
32.042
0.012
0.100
0.152
0.200
0.252
0.301
0.350
0.400
0.444
0.492
0.181
0.302
0.196
0.230
0.235
0.087
0.191
0.205
0.280
0.194
0.190
0.212
0.187
0.210
0.262
0.303
0.326
0.310
0.326
0.322
0.297
0.302
0.365
0.282
0.291
0.331
0.366
0.307
0.323
0.281
0.266
0.564
190.6
305.3
369.8
425.1
469.7
507.6
540.2
568.7
594.6
617.7
408.1
544.0
511.8
553.6
532.8
572.2
282.3
365.6
420.0
435.6
428.6
504.0
417.9
425.2
560.4
308.3
562.2
591.8
617.2
631.1
630.3
617.1
616.2
636.0
748.4
789.3
408.0
466.0
506.6
523.3
508.2
535.5
466.7
497.1
512.6
45.99
48.72
42.48
37.96
33.70
30.25
27.40
24.90
22.90
21.10
36.48
25.68
45.02
40.73
37.85
34.71
50.40
46.65
40.43
42.43
41.00
31.40
40.00
42.77
43.50
61.39
48.98
41.06
36.06
32.09
37.34
35.36
35.11
38.40
40.51
38.50
65.90
55.50
47.50
38.80
47.01
41.50
36.40
34.30
80.97
0.286
0.279
0.276
0.274
0.270
0.266
0.261
0.256
0.252
0.247
0.282
0.266
0.273
0.273
0.272
0.269
0.281
0.289
0.277
0.273
0.275
0.265
0.275
0.267
0.272
0.271
0.271
0.264
0.263
0.261
0.263
0.259
0.260
0.256
0.269
0.295
0.223
0.221
0.257
0.255
0.233
0.249
0.263
0.273
0.224
or
cm3
m3
98.6
145.5
200.0
255.
313.
371.
428.
486.
544.
600.
262.7
468.
258.
308.
319.
368.
131.
188.4
239.3
233.8
237.7
354.
238.9
220.4
291.
113.
259.
316.
374.
427.
369.
376.
379.
352.
413.
502.
115.
154.
228.
286.
209.
267.
280.
329.
111.4
184.6
231.1
272.7
309.2
341.9
371.6
398.8
424.0
447.3
261.4
372.4
322.4
353.9
345.0
374.1
169.4
225.5
266.9
276.9
274.0
336.3
266.3
268.7
356.1
189.4
353.2
383.8
409.4
425.6
417.6
412.3
411.5
418.3
528.2
254.1
294.0
330.1
350.2
329.4
352.8
307.6
328.4
337.9
Molar
Ethanol
2-Propanol
Phenol
Ethylene glycol
Acetic acid
n-Butyric acid
Benzoic acid
Acetonitrile
Methylamine
Ethylamine
Nitromethane
Carbon tetrachloride
Chloroform
Dichloromethane
Methyl chloride
Ethyl chloride
Chlorobenzene
Tetrafluoroethane
Argon
Xenon
Helium 4
Hydrogen
Oxygen
Nitrogen
Chlorine
Carbon monoxide
Carbon dioxide
Carbon disulfide
Hydrogen sulfide
Sulfur dioxide
Sulfur trioxide
Nitric oxide (NO)
Nitrous oxide
Hydrogen chloride
Hydrogen cyanide
Water
Ammonia
Nitric acid
Sulfuric acid
for
= 0.79 and
Appendix C
Table C.l
Table C.2
Table C.3
Table C.4
Constants in equation
Chemical species
Paraffins:
Methane
Ethane
Propane
n-Butane
iso-Butane
n-Pentane
n-Hexane
n-Heptane
n-Octane
Ethylene
Propylene
Miscellaneous organics:
Acetaldehyde
Acetylene
Benzene
Cyclohexane
Ethanol
Ethylbenzene
Ethylene oxide
Formaldehyde
Methanol
Styrene
Toluene
Miscellaneous inorganics:
Air
Ammonia
Bromine
Carbon monoxide
Carbon dioxide
Carbon disulfide
Chlorine
Hydrogen
Hydrogen sulfide
Hydrogen chloride
Hydrogen cyanide
Nitrogen
Nitrous oxide
Nitric oxide
Nitrogen dioxide
Dinitrogen tetroxide
Oxygen
Sulfur dioxide
Sulfur
Water
NH3
CO
HCN
NO
NO2
SO3
BT
T (kelvins)from 298.15 to
1500
1500
1500
1500
1500
1500
1500
1500
1500
4.217
6.369
9.001
11.928
11.901
14.731
17.550
20.361
23.174
1.702
1.131
1.213
1.935
1.677
2.464
3.025
3.570
4.108
9.081
19.225
28.785
36.915
37.853
45.351
53.722
62.127
70.567
-2.164
-5.561
-8.824
-11.402
-11.945
-14.111
-16.791
-19.486
-22.208
1500
1500
1500
1500
1500
1500
1500
5.325
7.792
10.520
13.437
16.240
19.053
21.868
1.424
1.637
1.967
2.691
3.220
3.768
4.324
14.394
22.706
31.630
39.753
48.189
56.588
64.960
-4.392
-6.915
-9.873
-12.447
-15.157
-17.847
-20.521
1000
1500
1500
1500
1500
1500
1500
1.693
6.132
-0.206
2.734
-3.876
3.518
1.124
-0.385
2.264
2.211
2.050
0.290
17.978
1.952
39.064
26.786
63.249
20.001
55.380
23.463
7.022
12.216
50.192
47.052
-6.158
1500
1500
1500
1500
6.506
5.253
10.259
10.720
13.121
8.948
15.993
5.784
4.191
5.547
15.534
12.922
2000
1800
3000
2500
2000
1800
3000
3000
2300
2000
2500
2000
2000
2000
2000
2000
2000
2000
2000
2000
3.509
4.269
4.337
3.507
4.467
5.532
4.082
3.468
4.114
3.512
4.326
3.502
4.646
3.590
4.447
9.198
3.535
4.796
6.094
4.038
3.355
3.578
4.493
3.376
5.457
6.311
4.442
3.249
3.931
3.156
4.736
3.280
5.328
3.387
4.982
11.660
3.639
5.699
8.060
3.470
0.575
3.020
0.056
0.557
1.045
0.805
0.089
0.422
1.490
0.623
1.359
0.593
1.214
0.629
1.195
2.257
0.506
1.056
1.450
-13.301
-8.882
-20.928
-6.002
-18.476
-9.296
-1.877
-3.450
-16.662
-15.716
. . . . ..
. ... . .
.. . . . .
.. . . . .
. . . . ..
. . . . ..
...
. ... ..
......
......
... .
. . . .. .
. . . .. .
.. . ...
. . . .. .
.... . .
.. .. . .
... ...
from H. M. Spencer,
Eng. Chem., vol. 40,
2152-2154, 1948; K. K.
Mines Bull. 584, 1960; L. B.
Mines Bull. 672, 1982.
U.S.
-1.299
-0.016
-0.186
-0.154
-0.031
-1.157
-0.906
-0.344
0.083
-0.232
0.151
-0.725
0.040
-0.928
0.014
-0.792
-2.787
-0.227
-1.015
-2.028
0.121
636
APPENDIX
+ BT +
C (graphite)
Cu
Na
S (rhombic)
(quartz)
from K. K. Kelley,
Mines Bull. 584, 1960;
Bur Mines Bull. 672, 1982.
L. B. Pankratz,
Ammonia
Aniline
Benzene
+ BT +
A
Carbon tetrachloride
Chlorobenzene
Chloroform
Cyclohexane
Ethanol
Ethylene oxide
Methanol
Sulfur trioxide
Toluene
Water
on correlations presented by
Miller, Jr., G. R. Schon; and
C. L. Yaws, Chem.
vol.
p. 129, 1976.
Methane
Ethane
Propane
n-Butane
n-Pentane
n-Hexane
n-Heptane
n-Octane
Ethylene
Propylene
Miscellaneous organics:
Acetaldehyde
Acetic acid
Acetylene
Benzene
Benzene
Cyclohexane
Cyclohexane
Ethanol
Ethanol
Ethylbenzene
Ethylene oxide
Formaldehyde
Methanol
Methanol
Methylcyclohexane
Methylcyclohexane
Styrene
Toluene
Toluene
State
(Note 2)
(Note 1)
(Note 1)
638
State
(Note 2)
(Note 1)
-46
-59 800
-1206 920
-795 800
-2607 900
-986 090
CO
HCN
NO
-635 090
-393 509
-110525
-92 307
135 100
-20 630
-272 000
-824 200
-1118400
-178 200
-408 610
-712 580
-1012 650
-1311 300
-174 100
90 250
33 180
82 050
9 160
-1130 680
-4081 320
-411 153
-425 609
-296 830
-395 720
-441 040
-813 989
-241 818
-285 830
(Note 1)
-16 450
-26 500
-64 900
-1128 790
-748 100
-8101900
-898 490
-868 070
-604 030
-394 359
-137 169
-95 299
124 700
-33 560
-742 200
-1015 400
- 166 900
-80 710
-111 250
86 550
51 310
104 200
97 540
-1044 440
-384 138
-393 133
-379 494
-419 150
-300 194
-371 060
-690 003
-744 530
-228 572
-237 129