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CHEMISTRY I
CHAPTER 1
Atomic Structure
Atomic Composition
3 subatomic particles made up all atoms:
Electrically positive protons
Electrically neutral neutrons
Electrically negative electrons
Structure of An Atom
Subatomic Particles
Protons and electrons are the only particles that have a
charge.
Protons and neutrons have essentially the same mass.
The mass of an electron is so small we ignore it.
Symbols of Elements
Atomic Number
Atomic Mass
X
Z
Mass number
Element symbol
Atomic number
Example :
What is the atomic number and the mass
number of the element FLUORINE that
contains 9 protons and 10 neutrons ? Write
the element symbol.
Atomic number =
Mass number =
Isotopes
Isotopes are same atomic number with different
masses.
Isotopes have different numbers of neutrons.
11
C
6
12
C
6
13
C
6
14
C
6
Exercise
How many neutrons are in each isotope of
oxygen? Write the symbol of each isotope.
Oxygen (atomic no.) = 8
a) Oxygen-16 b) Oxygen-17 c) Oxygen-18
Example :
Isotope Isotope mass (amu)
63
29Cu
65
29Cu
62.9298
64.9278
Abundance
(%)
69.09
30.91
Periodic Table
It is a systematic
catalog of the
elements.
Elements are
arranged in order
of atomic number.
Periodicity
Periodic Table
The rows on the
periodic chart are
periods.
Columns are groups.
Elements in the same
group have similar
chemical properties.
Mole Concept
Mole is a chemical unit used in
quantitative measurement of particles
involved in chemical reactions
A mole is the amount of a substance that
contains as many elementary entities
(atoms, molecules, ions or other particles)
as there are atoms in exactly 12 g of the
carbon-12 isotope.
Using Moles
Avogadros Number
One mole always contains the same
number of particles, no matter what the
substance is.
1 mole = 6.0221415 x 1023 particles
This value is known as Avogadros
number in honour of Amedeo Avogadro,
an Italian lawyer and physicist (17761856)
Empirical Formula
Simplest formula
Gives the smallest whole-number ratio of
atoms present in a compound
Molecular Formula
True formula
Total number of atoms of each element
present in one molecule of a compound
Knowing the relative numbers of atoms of
each element in a molecule
Molecular Formula
Molecular formula = [Empirical formula]n
where n should be integers (n = 1, 2, 3)
To determine molecular formula from
empirical formula, the molar mass must
be obtained from experiment
%A
%B
gA
gB
x mol A
x mol B
Ratio gives
formula
x mol A
y mol B
Find mole ratio
AxBy
Example 1:
Finding Empirical Formula
25.00g of orange compound, contains 6.64g
of potassium, 8.84g of chromium and 9.52g
of oxygen
K, Cr, O
Given the molar mass
K = 39.40 g/mol
Cr = 52.00 g/mol
O = 16.00 g/mol
mass(g )
mol(mol)
molecularw eight (gmol )
1
Atom
Cr
Mass (g)
6.64 g
8.84 g
9.52 g
Mol
Atom Ratio
Wholenumber
Mol Ratio
Empirical
formula
Atom
Cr
Mass (g)
6.64 g
8.84 g
9.52 g
Mol
Mol Ratio
Wholenumber
Mol Ratio
Empirical
formula
6.64 g
8.84 g
9.52 g
39.40 g/mol 52.00 g/mol 16.00 g/mol
= 0.170 mol = 0.170 mol = 0.595 mol
0.170
0.170
=1
0.170
0.170
=1
0.595
0.170
3.5
1x2=2
1x2=2
3.5 x 2 = 7
K2Cr2O7
Atom
Mass (%)
73.14 %
7.37 %
19.49 %
Mass (g)
Mol
Mol Ratio
Empirical
formula
Atom
Mass (%)
73.14 %
7.37 %
19.49 %
Mass (g)
73.14 g
7.37 g
19.49 g
Mol
73.14 g
12.011 g/mol
= 6.089 mol
7.37 g
1.008 g/mol
= 7.312 mol
19.49 g
15.999 g/mol
= 1.218 mol
Mol Ratio
6.089 mol
1.218 mol
= 4.999 5
7.312 mol
1.218 mol
= 6.003 6
1.218 mol
1.218 mol
=1
Empirical
formula
C 5H 6O
]n = 164.2 g/mol
Learning Outcomes
Determine the empirical and molecular
formulae of compounds and calculate
their relative formula/molecular mass
Use atomic number and mass number to
differentiate different element and
different isotopes of the same element