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DOCTORA L T H E S I S
Hans Gedda
Preface
Since April 1999 I have been conducting experimental and theoretical research in the field of
laser cladding at the Division of Manufacturing Systems at Lule University of Technology.
The experimental work was mostly performed in our laser laboratory. Some work has been
done at Duroc AB in Ume, Lule and at Nottingham University.
Several people have been important in completition of this work. I sincerely thank my
supervisor John Powell who has guided and supported me throughout this research.
I would like to express my gratitude to Professors Alexander Kaplan and Claes Magnusson for
discussions, suggestions through this work. I would also like to thank all my friends and
colleagues at the division for all their help and fruitful discussions.
I would finally thank my family, Birgitta, Petrus and Emilia for their love, support and patience
during the work.
Lule, October 2004
Hans Gedda
Abstract
This thesis presents an investigation into the laser cladding process using CO2 and Nd:YAG
lasers. The work is divided into six chapters:
Chapter one is an introduction the subject of laser cladding. This presents a general overview
of the two common laser cladding methods and some applications for the processes. This
chapter concludes with abstracts, main figures and conclusions from all chapters in the thesis.
Chapter two is an investigation into the energy redistribution during CO2 and Nd:YAG laser
cladding. Experimental absorption measurements by calorimetry were carried out to analyse
how much of the energy is lost by reflection etc. It was found that the Nd:YAG laser cladding
process is approximately twice as energy efficient as the CO2 laser cladding process.
Chapter three investigates the process parameters which affect the finished product when
cladding into pre machined groves including; groove geometry, powder application method
and laser type.
Chapter four presents preliminary experimental results from two new processes; Laser casting
and Laser clad-casting. Laser casting is a process similar to blown powder laser cladding but
without the final product joined to the substrate. The substrate acts as a mould and the casting
retains the topological features of the substrate. Laser clad-casting involves the production of a
clad layer between machined copper blocks. Clad tracks can therefore be achieved with large
depth to width ratios and pre determined cross sections.
Chapter five describes a new technique for the production of solid wire or rods from powder
by laser melting. Three techniques have been developed to ensure that the molten powder
solidifies as a rod or wire rather than a series of droplets. The techniques can be used to
produce welding rods, tensile test samples and other solid pieces from a wide range of powder
mixes.
Chapter six presents experimental data in conjunction with mathematical models are used to
explain various aspects of laser casting and laser cladding by the preplaced powder method.
Also the interaction of the melt pool with the powder bed is analysed to identify why laser
castings have microscopically uneven surfaces.
ii
Contents
Page
Preface
Abstract
ii
Contents
iii
Chapter
25
1. Gedda, H., Powell, J., Wahlstrm, G., Li, W-B., Engstrm, H.,
Magnusson, C.: Energy Redistribution During CO2 Laser Cladding
(Published in Journal of Laser Applications. vol. 14, no. 2,
pp. 78-82. May 2002)
2. Gedda, H., Powell, J., Kaplan, A.: A Process Efficiency Comparison
of Nd:YAG and CO2 Laser Cladding (Published in Welding in the
World, vol. 46, Special Issue. pp.75-86. July 2002)
Chapter III: Laser Cladding into pre machined grooves
41
Powell, J., Gedda, H., Kaplan, A.: Proceedings of the 1st Pacific
International Conference on Applications of Lasers and Optics
(PICALO)April 19-21, 2004 Melbourne, Australia. Submitted for
publication in Journal of Laser Applications.
Chapter IV: Laser Casting and Laser Clad-Casting: New processes
for rapid prototyping and production
53
65
iii
75
Chapter I
Introduction to laser cladding
Cladding material
(a)
V
(b)
Powder stream in
Workpiece
Focal point
Figure 3. Cross section of a coaxial nozzle.
2 Commercial examples
Industrial applications require parts with good wear, corrosion and hardness properties and laser
cladding is a process which can fulfill all these requirements. Laser cladding can be used to
good effect in processes which require a high productivity combined with flexibility without
compromising on quality.
A high and uniform quality with a low heat input makes this process suitable for a wide range
of applications in which minimum distortion is desired.
Examples of industrial laser cladding applications are:
Improved wear resistance of bearings, valves, axles, cutting tools and other parts where
the working conditions are very severe
Laser beam
PP Laser
beam
Powder stream
PB
PB
PD
PE
PA
PA
PF
PF
Substrate
Substrate
Where:
PA = Power reflected off the surface of the clad zone.
PB = Power reflected off the powder particles as they approach the weld pool.
PD = Power lost by radiation from the cladding zone.
PE = Power lost by convection from the cladding zone.
PF = Power lost by conduction from the clad zone to the substrate.
PG = Power absorbed by the powder particles which do not enter the cladding melt
pool.
Laser Beam
Powder
Particles
Insulated
Calorimeter
Figure 2. The experimental arrangement for the analysis of the absorption and
reflection of the energy by the powder cloud.
Conclusions
1. Ignoring the trivial contributions of convective and radiative cooling etc, the laser
power applied to the cladding process is redistributed in the following ways:
Laser type
CO2
Nd:YAG
Power reflected off the cladding melt
50%
40%
Power reflected off the powder cloud
10%
10%
Power used to heat the substrate
30%
30%
*
Power used to melt the clad layer
10%
20%
*
This value includes powder and substrate melting.
2. Nd:YAG lasers are approximately twice as energy efficient as CO2 lasers for cladding in
the range of parameters covered in this paper ( and by implication, the higher power (5
kW) range covered in our earlier work [2]) i.e. given the same laser power, Nd:YAG
lasers are capable of approximately double the cladding rates of CO2 lasers.
As a large proportion (30%) of the laser power is consumed in heating the substrate it is likely
that substrate pre heating by a cheaper power source* would improve the profitability of laser
cladding. (* flame, plasma, induction etc).
Powder
depth 0 mm
Wedge of powder
Powder
depth 2
mm
Substrate
200 mm
Groove
Figure 3. Schematic preplaced powder.
4 mm
Figure 4. Cross sections of grooves showing that even when there is sufficient
melt to produce a flat surface the clad layer does not do so when preplaced
powder is used.
4 mm
a)
0.1 mm
b)
Figure 5. a) A cross section of the type of clad profile achieved for preplaced powder cladding if the groove must
be completely filled. 5b) A micrograph showing the clad substrate interface weld.
4 mm
Figure 6. Blown powder cladding results for 46 g/min powder flow at a process speed of 0.5 m/min
(CO2 laser).
4 mm
Figure 7. The concave top profile of an under filled groove clad
by the blown powder method.
10
4 mm
Figure 8. A pair of preplaced powder clad tracks produced under identical conditions except for
the depth of the powder used. (3.5 kW CO2 laser, spot size 4 mm, cladding speed 0.5 m/min)
powder deep a = 0.75 mm powder deep, b = 1.75 mm of powder.
Laser beam
Figure 9. The change in cross section of a clad track as more powder is added (x remains
approximately constant as its width is determined by the laser beam diameter on the melt
pool).
11
Clad layer
Removed excess
Lubricant supply
clad material
and debris
removal conduits
Substrate
12
45
45
10-15 mm
5 mm Unmelted
layer of
powder
particles
No interfacial
melting
13
3 mm
a)
b)
c)
Figure 12. Successful laser clad-casting of cross hatched grooves. a) substrate (mould), b) substrate and
casting, c) casting. Process parameters: laser power 3 kW (Nd:YAG), beam diameter 5 mm, process speed
0.8 m/min., Ni based powder, powder flow 80 g/min (in Ar), inter-track distance 3mm.
Figure 13 shows the difference between standard laser cladding (a+b) and clad-casting (c).
Clad layer
a) Standard clad
cross section
Machining
line
b) Maximum height
clad track (semi circular
cross section)
c) Required clad
cross section
Figure 13. Standard clad track cross section (a, b) and the required cross section (c ).
14
Substrate
Machined
copper blocks
Clamping
3 mm
Figure 15. A cross section of the clad-cast track deposited between copper blocks. (substrate width:
3mm,clad track height: 3.5 mm). Process parameters: powder feed (Nickel alloy) 40 g/min, cladding
speed 0.5 m/min, laser power 3.5 kW (CO2), beam diameter 4 mm.
Conclusions
It has been demonstrated that two new laser cladding techniques are possible and that they may
provide novel answers to future production requirements.
Laser casting can be used to produce surface castings in high strength alloys to generate tool
bits or stamping dies etc.
Laser clad-casting can be employed to make clad tracks with large depth to width ratios and
pre determined cross sections.
15
Powder
Mould
Mould
Substrate
a) Cross section of
mould and powder
before laser irradiation
b) During laser
processing
16
3 mm
Cross section
5 mm
Cross section
6 mm
Cross section
5 cm
General view
General view
General view
17
18
Wires or rods can be cast from metal powder using a high power laser as a heat
source.
Metal powders which have been laser melted do not readily solidify as uniform cross
section rods unless the tendency to form strings of droplets is inhibited.
The presence of side wall or net shape moulds can result in rods which are ovoid or
circular in cross section and approximately 100% dense. Wires incorporated into the
powder bed can have the same effect in the absence of moulds.
The casting techniques discussed in this paper could be used to produce wires or rods
of a very wide range of alloys and alloy-ceramic mixtures.
19
a) 0,1 m/min
b) 0,2 m/min
c) 0,9 m/min
d) 2,1 m/min
1 mm
e) 3,3 m/min
f) 3,8 m/min
Figure 20. Cross sections of clad tracks made under identical conditions (laser power 3500 W, powder bed
depth 1 mm) at different speeds.
20
Figure 22. Vertical temperature distribution through the preplaced powder and substrate for different time
steps [9].
Figure 23. Calculated maximum melting depth through the powder (1 mm thick) and substrate ( >> 1
mm) as a function of the processing speed.
21
50
N
40
E
N*E
30
20
10
0
0
50
100
150
200
Figure 25. The particle size distribution and proportion of the incident energy needed to melt the particles
of different sizes in this batch.
22
Figure 26. Calculated heating and melting of powder grains of different diameter touched by the melting
front and subsequent smoothing of the droplets.
Figure 27 is a magnified photograph of the surface of a laser casting. The part of the surface
shown is that which was in contact with the substrate. This photograph supports the model
results presented in Figure 10 as it demonstrates that the liquid surface was covered in partially
melted particles.
0,1 mm
Figure 27. The surface of a laser cast specimen (This surface was in contact with the substrate).
23
4 Conclusions
This analysis of melt solid interactions has helped to explain the following points about the
laser cladding and casting processes;
a) There is a wide parameter range over which dilution free cladding can be achieved by
the preplaced powder process. This is primarily due to the difference in thermal
conductivity of the powder bed and substrate.
b) If the process parameters are set outside the range mentioned above the result will be
either a dilute clad layer (see figure 3a) or a casting process (see figure 2) depending on
whether or not the power input to the process is increased or decreased.
c) The physics of powder particle melting by contact with a liquid pool makes it different
to achieve laser casting with a smooth surface.
5 References
1.
2.
3.
Yellup, JM. (1995). Laser Cladding using the powder blowing technique. Surface
Coating Technology, Vol. 71, no. 2, pp. 121-128
4.
Frenk, A., Vandyoussefi, M., Wagnire, J. D., Zryd, A., Kurz, W. (1997).
Analysis of the laser-cladding [laser surfacing] process for stellite on steel.
Metallurgical and Material Transactions B, Vol. 28B, pp. 501-508
5.
6.
7.
8.
Powell, J., Henry, P.S., Steen, W.M. (1988) Laser cladding with preplaced
powder. Analysis of thermal cycling and dilution effects. Surface engineering, Vol
4. no. 2, pp. 141-149
9.
Chapter II
Energy Redistribution in Laser Cladding; A
comparison of Nd:YAG and CO2 lasers
25
26
Abstract
Blown powder laser cladding is a cost effective way of producing a surface layer to withstand
wear and corrosion. However, the cladding process is slow. Therefore is it of great interest to
investigate how much of the laser power is used in the cladding process and how much is
reflected etc. In this investigation an Nd:YAG and a CO2 laser have been compared as energy
sources for the process. Every aspect of the energy redistribution during cladding has been
analysed. The main energy loss to the process for both lasers is by reflection from the melt pool
and the powder cloud. It was found that the Nd:YAG laser cladding process is approximately
twice as energy efficient as the CO2 laser cladding process.
Keywords: Laser cladding; Laser processing, Energy redistribution, Surface treatment.
27
1 Introduction
Blown powder laser cladding involves projecting a stream of metal powder (in an inert gas jet)
into a laser generated melt pool on the surface of a metal substrate (see figure 1).
Laser beam
Powder particles
Clad layer
28
Laser beam
PP Laser
beam
Powder stream
PB
PD (Power radiated)
PD
PE
PB
PA
PA
PF
PF
Substrate
Substrate
Ptot = PC+PL
(1)
(2)
Where:
PP = The power utilised in melting the cladding powder.
PS = The power utilised in melting the surface of the substrate in order to
achieve aclad/substrate weld.
PL in equation 1 can be similarly expanded:
PL = PA+PB+PD+PE+PF+PG
29
(3)
To cover metal A with a known thickness of metal B at the fastest possible rate
with a high quality interfacial bond.
Returning to equation 1 it is clear that the process can be speeded up if there is an increase in
the proportion laser power available producing the clad layer PC. The requirement here would
be to melt enough powder to achieve the correct clad thickness at a faster linear speed. Such an
increase in PC must not be employed to melt the substrate to a greater depth. The process must
be accelerated to achieve the same (minimum) substrate melt depth at a higher process speed.
To summarise:
The efficiency of laser cladding could be improved by minimising any of the losses
in equation 3. This would lead to an increase in PC and the process could be
accelerated to produce the same clad depth with a minimal depth of substrate
melting.
Earlier work by the present authors [1] quantified the individual elements of equations 1,2 and
3 for CO2 laser cladding. The results of that work concluded that the laser power was
redistributed in the following proportions:
Power reflected off the workpiece (PA)
Power reradiated from the workpiece (PD)
Power reflected off the particles (PB)
Power absorbed by the process (PC+PF)
= 50%
= 1%
= 9%
= 40%
100%
30
2 Experimental work
2.1 General
The substrate material used in this study was (SS 2172) steel with the following composition:
Table 1. Steel composition (substrate)
wt %
C
0.16
Si
0.22
Mn
0.94
P
0.014
S
0.022
V
0.06
N
0.009
Fe
98.6
Fe
0.3
Co
63.4
The cladding material was cobalt based with the following composition:
Table 2. Cladding powder composition
wt %
Cr
27.2
C
0.27
Si
1.0
Mo
5.5
Ni
2.3
The substrate specimens were grit blasted before cladding was carried out. The laser used was a
Rofin Sinar RS 6000 CO2 laser with a maximum output power of 6 kW and the Nd:YAG
laser was a Haas Laser HL 3006 D 4 kW. The powder feeder was a TECFLO TM 5102. The
shielding/carrier gas employed to propel the powder was argon.
2.2 The power absorbed by or reflected off the powder cloud above the clad zone
During the cladding process the laser beam must travel through the powder cloud in order to
reach the cladding zone (see figure 2). A proportion of the laser energy is reflected off the
powder cloud and is lost to the cladding process. Another portion of the incident energy is
absorbed by the particles but some of this energy is also lost to the process because not all the
heated particles join the cladding melt pool.
A simple experiment was set up to discover what proportion of the original laser power would
penetrate the powder cloud (see figure3 below). A commercially available power probe was
used to measure the laser power with and without the powder stream turned on. The powder
flow rates were typical of the cladding process as were all the other process parameters. The
average results from several such tests are presented in table 3. The energy absorbed by the
powder cloud was directly measured by measuring the average temperature rise of the powder
31
Insulated
Calorimeter
Figure 3. The experimental arrangement for the analysis of the absorption and
reflection of the energy by the powder cloud.
Table 3. Power absorbed and reflected by the powder cloud irradiated by the two types of laser
Laser
type
Nd:YAG
CO2
Laser
output
Power *
Powder
flow
rate
Post
powder
cloud
power
(Watts)
(g/min)
(Watts)
2743
(100%)
2695
(100%)
30
2506
(91%)
2457
(91%)
30
Total
power
reflected
and
absorbed by
the powder
cloud **
(Watts)
237
(9%)
238
(9%)
Power
absorbed
by powder
cloud **
Power
Reflected
off powder
cloud (PB)
**
(Watts)
18
(1%)
22
(1%)
(Watts)
224
(8%)
218
(8%)
It is clear from table 3 that we now have an approximate value for PB (the power reflected off
the powder cloud) for the parameter range covered here:
PB = 8 % Ptot for the Nd:YAG laser and the CO2 laser
(4)
One other component of equation 3 can also be identified from table 3 after the same
parameters were used for actual cladding. This parameter is PG, the level of power absorbed by
particles which do not enter the cladding melt pool. A number of cladding trials were carried
out and these showed that, over this range of parameters, the proportion of particles which
formed the clad track was 60% (The range was 57%-63%). It can then be concluded that 40%
of the heat collected by the powder cloud (1% Ptot see table 3) does not contribute to the
cladding process.
i.e. PG = 0.4 % Ptot for both types of laser
32
(5)
(6)
Where:
In this case the surface temperature of the melt was approximately 2300 K [1] and its surface
area was 19 mm2.
This gives a maximum value for PD of:
PD= 5.7 * 10 8 * ( 2300) 4 * 19 * 10 6 = 30 Watts
PD 1% of Ptot for both the Nd:YAG and the CO2 laser
(7)
(8)
(9)
Where:
h = Heat transfer coefficient.
A = Surface area of the hot body.
t = The difference in temperature between the body and the cooling gas.
Evaluation of h from a standard text on the subject [2] gives us a value of approximately 100
W/m2K.
Q = 100 * ( * 0.0025 2 )* 2000
PE = 3.9 Watts
Or PE = 0.1% Ptot for both Nd:YAG and CO2 laser
33
(10)
(11)
(12)
Nd:YAG
CO2
From our earlier results:
Laser output
Power (Ptot)
Power input to
clad sample (Pin)
(Watts)
(Watts)
2743
2695
1367
1044
Power % input
to sample
49%
39%
(14)
PA = 41.1 % (Nd:YAG)
(15)
(16)
PA = 51.1 % (CO2)
(17)
So far this is the first time that the measurements from the two types of laser have shown an
appreciable difference. In summary it can be said that, for the CO2 laser, approximately half of
the laser power is reflected from the cladding zone. For the Nd:YAG laser this value is reduced
to approximately 40%. These generally high reflectivity values confirm the work of other
authors in the field [3] who suggest that the onset of melting is associated with a rise in material
reflectivity. This is because a molten surface in an inert atmosphere (in this case argon) is
smooth and oxide free. This smooth, oxide free surface acts as a better reflector than the solid,
rough, oxidised surface which exists before melting. It is well known [4] that metals have a
lower reflectivity for the 1.06 m radiation of Nd:YAG lasers than for the 10.6 m radiation
of CO2 lasers and this is confirmed by the above results. As we will see later in this paper, this
reduction in reflectivity for the Nd:YAG laser results in a marked increase in process efficiency
when cladding as compared to a CO2 laser.
34
Clad layer
Melted
substrate
Figure 4. The cross sectional geometry of a blown powder laser clad layer. Note: the melted substrate and
cladding material are mixed together during the process.
As figure 4 demonstrates, the production of a clad layer usually involves melting the surface
layers of the substrate. The amount of substrate melting can range from minimal to levels
where the clad layer is really a dilute alloy of the substrate and cladding material.
Clad layer
HAZ
6.2 mm
Melted
substrate
35
(18)
0.7 m/min
1.0 m/min
1.4 m/min
b) Nd:YAG laser
3 mm
0.7 m/min
1.0 m/min
1.4 m/min
Figure 6. Clad cross sections at increasing process speed for both types of laser. (laser power 2700 W,
laser spot diameter 5 mm, powder flow rate 40 g/min.
It is clear that a substantial amount of substrate was melted in each case. On average the melt
was found to consist of a 40% substrate; 60% clad material mix for the CO2 laser and 55%
substrate and 45% metal mix for the Nd:YAG laser. As a simplification, the material properties
necessary for equation 18 were taken as being for a 50:50 mixture of cladding material and
substrate.
= 8020 kg/m3
Cp
= 500 J/kg K
Hm = 300 kJ/Kg
36
(19)
(20)
(21)
(22)
This is the result which would be expected given that all extra laser power which joins the
process when an Nd:YAG laser is used is involved in the melting process , (see previous
section).
37
3 Discussion
Figure 7 presents schematics of the redistribution of energy during the laser cladding process
for both types of laser.
CO2
Nd:YAG
% of power % of power
100%
100%
50%
40%
1%
100%
8%
8%
40%
50%
40%
50%
10%
20%
30%
Figure7. Schematic of the redistributions of energy during the laser cladding process
(percentages are approximate).
For the sake of clarity PE (convective losses) and PG (lost powder losses) have been left out of
figure 7 as their contribution to the energy balance is negligible.
38
3 mm
Figure 8. A demonstration of the doubling of the process speed possible when using an Nd:YAG rather
than CO2 laser.(The powder feed rate was increased from 30 g/min for the CO2 laser to 50 g/min for
the Nd:YAG laser but the laser power ( 3kW) and spot size (5 mm) were kept constant.)
The doubling of the process efficiency shown in figures 7 and 8 would not be possible if the
powder absorbed in heating the substrate (PF see fig 7) changed as more power was absorbed
by the process. PF remains steady (in this case at 30%) because it is determined by the amount
of power the substrate needs to absorb before surface melting is initiated. This is a threshold
value, which will not charge with increasing absorptivity. This being the case, any increase in
absorbed power will be entirely available to the melting process.
39
4 Conclusions
1. Ignoring the trivial contributions of convective and radiative cooling etc, the laser
power applied to the cladding process is redistributed in the following ways:
Laser type
Nd:YAG
CO2
Power reflected off the cladding melt
50%
40%
Power reflected off the powder cloud
10%
10%
Power used to heat the substrate
30%
30%
Power used to melt the clad layer*
10%
20%
*
This value includes powder and substrate melting.
2. Nd:YAG lasers are approximately twice as energy efficient as CO2 lasers for cladding in
the range of parameters covered in this paper ( and by implication, the higher power (5
kW) range covered in our earlier work [2]) i.e. given the same laser power, Nd:YAG
lasers are capable of approximately double the cladding rates of CO2 lasers.
3. As a large proportion (30%) of the laser power is consumed in heating the substrate it is
likely that substrate pre heating by a cheaper power source* would improve the
profitability of laser cladding. (* flame, plasma, induction etc).
5 References
1.
Gedda, H., Powell, J., Wahlstrm, G., W-B, Li., Engstrm, H., Magnusson, C.
(2002). Energy Redistribution During CO2 Laser Cladding. Journal of Laser
Applications, Vol. 14, pp. 78-82
2.
3.
Bloehs, W., Grnenwald, B., Dausinger, F., Hgel. (1996). Recent progress in
laser surface treatment. Part 1: Implications of laser wavelength. Journal of Laser
Applications, Vol. 8, pp. 15-23
4.
40
Chapter III
Laser Cladding into pre machined grooves
41
42
Abstract
When laser cladding is used to improve the wear characteristics of a substrate it is not always
necessary to clad the whole surface. Wear resistant individual tracks can be clad directly onto
the substrate or into pre machined grooves. This paper investigates the process parameters
which affect the finished product when cladding into groves including; groove geometry,
powder application method and laser type.
1 Introduction
Laser cladding is a process by which a metal powder is melted onto the surface of a metal
substrate. There are two common methods of providing powder for this process;
a) Pre placed powder; where a layer of powder is applied to the surface of the substrate and
subsequently melted by the laser (see figure 1a).
b) Blown powder; where powder is propelled into the cladding melt pool by means of a non
oxidising gas stream (see figure 1b).
Laser beam
Cladding material
a)
b)
Laser cladding can be used to provide a protective coating of hard or corrosion resistant metal
on a weaker substrate. Tracks of the harder, powdered material are laid down next to each
other to form a new surface as shown in figure 2.
4 mm
Figure 2. A cross section of a laser clad layer of Ni-based material on a low carbon (SS 2172) steel.
The individual clad tracks which go to make up a clad layer have their cross sectional shape
determined by a number of factors including laser power, laser beam width and powder
characteristics etc. Typical individual clad tracks produced by the preplaced and blown powder
methods are presented in cross section in figure 3.
1 mm
HAZ
Substrate
Significant substrate
melting
Figure 3b. A typical cross section of a clad track produced by the blown powder method.
It is clear from figure 3 that individual tracks of laser melted powder would not generally be
useful in an engineering context as the harder material forms a ridge on the substrate. This is
different situation from that experienced in the field of laser surface hardening. Surface
hardening [1-3] (which does not affect the substrate surface flatness) has been successfully used
to extend the wear life of components by applying single tracks rather than covering an entire
surface with a hardened layer. This use of single tracks reduces laser processing costs and the
thermal input to the component.
44
One early application of single track hardening was employed by the automobile industry to
improve the wear characteristics of a piston and cylinder [4]. In this case a spiral track was
produced on the piston and this interacted with three or four straight hardened lines down the
length of the internal face of the cylinder.
In order to replicate the advantages of the single track approach for cladding it is necessary to
deposit the cladding material into pre machined grooves. This paper investigates the effect of
the cross sectional shape of the grooves on the eventual clad track.
2 Experimental work
If grooves are to be filled with cladding material it is important to optimise the cross sectional
geometry of the groove. For this experiment V shaped grooves were produced with included
angles of 30, 45, 60, and 90.
The gap at the top of the grooves was kept constant at 4 mm. These grooves were clad using
CO2 and Nd:YAG lasers both operating at a power of 3 kW. The substrate was mild steel and
the cladding material was Nickel based super alloy (see table 1).
Both the pre-placed and blown powder techniques were investigated as follows;
a) For blown powder the mass flow of the powder stream (in Argon) was increased in five
steps from 22 to 46 grams per minute.
b) For pre placed powder a wedge of powder was prepared over the groove as shown in
figure 4. The depth of the powder increased from zero at one end of the groove to 2
mm at the other end (200 mm away).
A photograph of a groove clad in this way is presented in figure 5. This use of a wedge of
powder is useful in demonstrating the progressive effect of an increase in powder depth. All
powder wedge samples were produced at a process speed of 0.5 m/min.
Table I. Equipment and Parameters
CO2 laser, Rofin Sinar RS 6000 (6 kW)
Nd:YAG, Haas Laser HL 3006 D (4 kW)
Spot size at top of groove (both laser ) = 4
mm
Substrate, SS 2172 Mild steel (0.16% C)
Cladding Material, Nickel based (80% Ni,
20% Cr)
Powder feeder, Sulzer Metco Single 10 C
45
Powder
depth 0 mm
Wedge of powder
Powder depth 2
mm
Substrate
200 mm
Groove
3 Results
A. CO2 laser; Preplaced Powder
Figure 6 shows cross sections of the preplaced powder cladding trials at the section in the
sample where there was enough melt to fill the top of the groove. It is clear that for all these
samples the melt has not assumed a flat top surface. In all these cases the melt has retained its
circular curvature towards the top of its cross section. It is also noticeable that there is a pore
along the bottom of the clad groove for angles less than 90.
4 mm
Figure 6. Cross sections of grooves showing that even when there is sufficient
melt to produce a flat surface the clad layer does not do so when preplaced
powder is used.
46
Figure 7 demonstrates that the addition of more powder to the melt results in a clad trace
which over fills the groove. This sample also demonstrates the very low amount of substrate
melting which is often typical of pre placed powder cladding [5].
4 mm
7a)
0.1 mm
7b)
Figure 7. A cross section of the type of clad profile achieved for preplaced powder cladding if the groove must be
completely filled. 7b A micrograph showing the clad substrate interface weld.
B. CO2 laser; Blown Powder
Figure 8 shows the cross sections of blown powder cladding for the four types of groove at a
powder flow rate of 46 g/min and a process speed of 0.5 m/min.
4 mm
Figure 8. Blown powder cladding results for 46 g/min powder flow at a process speed of 0.5 m/min
(CO2 laser).
Figure 8 reveals that the 30 groove is unsuitable to the process because the powder stream does
not project sufficient material into the bottom of the groove. The 45 and 60 groove are
successfully filled with almost flat top surface although there are small linear pores at the bottom
of the grooves. The 90 grooved sample has become overfilled with melt at this powder flow
rate as its cross sectional area is considerably smaller than those for the other angles.
47
As far as producing an overall flat surface is concerned, samples b and c in figure 8 are much
more successful than the preplaced powder samples shown in figure 6. The reason why these
cross section are flatter must be attributed to the action of the powder jet gas flow on the
solidification dynamics of the melt. This point is supported by figure 9 which shows that under
filled grooves produced by the blown powder method had concave rather than convex top
profiles. Figure 9 also demonstrates the increased substrate melting common to blown powder
cladding.
4 mm
4 mm
Figure 10. Tracks made by Nd:YAG laser and preplaced powder when there is enough melt to fill the
groove. Once more the melt retain its curved upper surface.
D. Nd:YAG laser; Blown Powder
Figure 11 shows the results of blown powder cladding with the Nd:YAG laser and the
maximum flow rate. Once again the 45 groove produces an almost flat top surface and because
of its smaller cross section the 90 groove is overfilled. It was noticed however that the 90
samples for both types of laser did not produce flat clad surfaces even at lower powder flows.
This retention of a curved upper melt surface is possibly related to the superior heat sink
capacity of the 90 grooves.
4 mm
Figure 11. Blown powder cladding results for 46 g/min powder flow at a process
speed of 0.5m/min (Nd:YAG laser).
48
4 Discussion
Before we analyse the cross section of the clad groove samples it is important to make a few
remarks about cladding onto flat surfaces. Figure 12 shows the cross sections of two clad tracks
produced under identical conditions except for the depth of the preplaced powder involved.
4 mm
Figure 12. A pair of preplaced powder clad tracks produced under identical conditions except for
the depth of the powder used. (3.5 kW CO2 laser, spot size 4 mm, cladding speed 0.5 m/min)
powder deep a = 0.75 mm powder deep, b = 1.75 mm of powder.
At first glance the two cross sections in figure 12 look similar to the types of cross section (and
those shown in figure 3) we would expect of droplets of any liquid on a substrate.
It is tempting therefore to apply the same type of physical analysis to the clad cross sections as
far as contact angle and surface tension are concerned. However, the situation for laser cladding
is not that simple. For a droplet of a liquid on a solid surface, the contact angle is determined
by the various surface tensions associated with the liquid, the solid and the surrounding air (see
figure 13). If more liquid is added to the droplet the contact angle does not change but the
contact area between the droplet and the solid increases (see figure 14).
lg
Gas
sg
Liquid
sl
Solid
Figure 13. The surface tension forces which determine the contact angle for a
droplet of liquid on a solid.
49
Smaller droplet
Larger droplet
Figure 15. The change in cross section of a clad track as more powder is added (x remains
approximately constant as its width is determined by the laser beam diameter on the melt
pool).
It is clear from figure 15 that the upper surface of the melt will always assume a shape which is
part of a circle but this circle is intersected by a cord of (approximately) fixed length and
represents the melt- substrate interface. The cross section shape of an individual clad track is
therefore largely determined by two parameters; the volume of the clad track per unit length
(which gives us the size of the part circle in figure 15) and the diameter of the laser beam on
the cladding melt pool (which gives us the width of the melt-substrate interface). For this
reason it is not possible to match the interaction of a groove angle to the contact angle of the
melt in order to achieve a flat surface. On the other hand the grooves investigated here do have
an effect on the clad finished product.
It is clear from the results given in figures 6 and 8 that if the aspect ratio of the groove is too
large then the melt will not be able to fill it adequately. These figures also demonstrate the
point that grooves with an acute internal angle will tend to have a cavity at their base.
This cavity is probably the result of melt surface tension which would limit minimum radius
achievable by the melt. The larger included angle of 90 tended to encourage complete
penetration of the melt into the groove.
50
The result given here also reveal that there is no fundamental effect on the process by changing
from CO2 to Nd:YAG laser.
If a flat topped clad groove is required these results imply that preplaced powder will never give
the desired product. On the other hand it seems clear that the downward thrust of the
gas/powder feed in blown powder cladding can help to flatten the top surface of the melt.
However, a flat clad surface may not give optimum performance. It has been noted in some
single track hardening studies that the track is accompanied on either side by softened areas
which are prone to accelerated wear. This wear results in erosion as shown in figure 16.
Substrate
Figure 16. A Schematic cross section of a laser hardened
track.
This eroded channels were found to be beneficial to the wear behaviour of the components as
they allowed the flow of lubricant to the hard, load bearing area and the removal of wear
particles [6].
This principle could be extended to laser cladding of grooves in certain cases. If a clad groove
of the type shown in figure 6 was produced and the protecting clad material was ground away
the remaining shallow grooves next to the clad track could supply lubricant and debris removal
conduits as shown in figure 17.
Clad layer
Removed excess
Lubricant supply
clad material
and debris
removal conduits
Substrate
51
5 Conclusions
1. It is possible to produce almost flat topped filled grooves by either CO2 and Nd:YAG
laser if blown powder cladding is employed.
2. Pre placed powder cladding does not give flat typed clad filled grooves. However the
process may be used to produce a clad track with shallow grooves on either side which
could aid lubrication (Once the central protruding part of the clad layer has been
machined away).
3. Grooves with too large an aspect ratio cannot be effectively filled with melt.
4. The contact angle of a clad melt on a substrate can be varied and is determined by the
laser beam diameter and the amount of powder supplied to the melt.
6 Acknowledgements
We gratefully acknowledge the financial support from VINNOVA, SSF and Kempe
Foundation.
7 References
1.
Migliore, L. (1996). Laser material processing. Marcel Dekker Inc New-York. ISBN 08247-9714-0, pp. 209-237
2.
Ruiz, J., Lopez, V., Fernandez, B J. (1996). Effect of the surface laser treatment on the
microstructure and wear behaviour of grey iron. Materials and Design, ISSN
0261-3069, Vol. 17, no. 5-6, pp. 267-273
3.
4.
5.
Powell. J. (1988) Laser Cladding With Preplaced Powder; Analysis of thermal cycling
and dilutions effects. Surface Engineering, Vol. 4, no. 2, pp. 141-149
6.
Steen W, M., Powell, J. (1981). Laser Surface Treatment Materials in Engineering, Vol.
2, no. 3, pp. 157-162
52
H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
Chapter IV
Laser Casting and Laser Clad-Casting: New
processes for rapid prototyping and
production.
53
H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
54
H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
Abstract
This paper presents preliminary experimental results from two new processes:
1. Laser casting involves a process similar to blown powder laser cladding but the final
product is not joined to the substrate. The substrate surface therefore acts as a mould in
a laser casting process and the eventual casting retains the topological features of the
substrate.
2. Laser clad-casting involves the production of clad tracks which are welded as usual to a
substrate but which are laid down between machined copper blocks. The eventual clad
track therefore has its cross sectional profile determined by the blocks which are
removed after completion of the cladding process. In this way clad tracks with large
depth to width ratios can be achieved with pre determinated cross sections.
Keywords: Laser cladding, Laser processing, Laser casting, Laser clad-casting
55
H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
1 Introduction
This paper presents the preliminary results of an experimental program investigating two new
processes: Laser casting and laser clad-casting. As a technique, laser casting is similar to blown
powder laser cladding but the aim in this case is to produce a clad layer which is not fused to
the substrate. The resulting clad layer retains the topological features of the surface of the
substrate which effectively acts as the mould in a casting process. An example of the detached
casting and its mould is presented in figure1.
Figure 1. A Laser casting and the mould it was produced with. (Process parameters:
laser 3 kW (Nd:YAG), cladding speed 0.8 m/min, powder feed (cobalt alloy)
80g/min).
During laser clad-casting the clad track is welded to the substrate as usual but the cross sectional
profile of the track is determined by copper blocks which act as moulds and are later removed.
An example of such a clad-cast track is shown in figure 2.
3 mm
56
H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
2 Laser casting
The experimental set up for laser casting is similar to that for blown powder laser cladding.
Schematics of both processes are presented in figure 3.
Laser beam
Powder feed
45
45
10-15 mm
5 mm
Unmelted layer of
powder particles
No interfacial
melting
The powder feed nozzle is much nearer the melt pool than it is for cladding.
3. The laser beam is defocused to approximately twice the original diameter normally
used for cladding (in this case from 4 to 8 mm diameter).
This reorganisation of the powder delivery and power density has a fundamental effect on the
process which prevents the substrate from melting. This effect is demonstrated in figure 3.
Figure 3a shows that, during blown powder laser cladding, the laser beam directly irradiates
both the surface of the molten cladding material and the substrate. The result is the
establishment of a fusion line beneath the original surface of the substrate. This ensures good
adhesion of the clad layer as it is welded to the substrate. In the case of laser casting (figure3b)
the powder flow conditions are such that a layer of unmelted powder builds up immediately in
front of the molten cladding zone. This has two effects:
57
H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
1. The powder layer shields the substrate from direct laser heating and thereby inhibits
substrate melting.
2. The powder layer cools the lower part of the melt by becoming melted into it.
Another important influence on the temperature distribution in the melt is the shadowing
effect of the powder cloud. The powder cloud absorbs energy from the incident laser beam
and casts an increasingly dense shadow over the melt pool as the mass flow rate is increased.
Also, the upper particles in the powder cloud cast a shadow over the lower particles [1]. The
particle cloud therefore tends to transport energy from the laser beam towards the top part of
the melt (where the hotter upper particles land) and away from the lower part (where the
cooler, shadowed particles land).
All of these effects reduce the ability of the cladding melt-laser combination to melt the
substrate. The result is a clad layer which is not welded to the surface of the substrate.
3 Experimental procedure
3.1 General
For the purposes of the experimental runs the following equipment and materials were
employed:
Laser model: Haas Laser HL 3006 D (4 kW) Nd:YAG. Laser power 3 kW.
Powders: Stellite 8 (Cobalt base), Deloro Alloy NO 35 S (Nickel base), ASP 60 (Iron base).
The powder chemical compositions are presented in table 2-4 below.
Powder feeder: TECFLO TM 5102.
Powder feeding: 80-110 g/min.
Powder feed gas: Argon.
Process speed: 0.6-1.0 m/min.
Substrate (mould): single and cross-hatched V shaped groves with an internal angle of 90
with depths of 2,4 and 6 mm. The mould chemical composition is presented in table 1 below.
Chemical Composition
Table1. Steel composition (mould)
C
0.16
wt %
Si
0.22
Mn
P
S
0.94
0.014
0.022
Melting point (Tm) = 1773 K
V
0.06
N
0.009
Fe
98.6
Cr
C
Si
Mo
Ni
Fe
27.2
0.27
1.0
5.5
2.3
0.3
Powder size 45-150m (Tm) = 1459-1656 K
58
Co
63.4
H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
Table3. Fe based powder composition
wt %
Cr
C
V
Mo
Fe
4.2
2.3
6.5
7.0
69.5
Powder size 45-150m (Tm) = 1473-1573 K
Co
10.5
Cr
C
Si
B
Ni
3.7
0.4
3.5
1.6
86.5
Powder size 38-106m (Tm) = 1223-1423 K
Fe
2.0
3 mm
a
b
c
Figure 4. Sucessful laser clad-casting of cross hatched grooves. a) substrate (mould), b) substrate and
casting, c) casting. Process parameters: laser power 3 kW (Nd:YAG), beam diameter 5 mm, process speed
0.8 m/min., Ni based powder, powder flow 80 g/min (in argon), inter-track distance 3mm.
59
H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
P
VD
(1)
Where P is the laser power, V the process speed and D the laser spot diameter. Generally as
P/VD is increased there is a tendency for increased welding of the clad layer to the substrate.
60
H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
As P/VD is decreased there is a tendency for the melt not to contact the substrate. In this case,
as for excessive powder, the casting bears no relationship to the mould.
Powder and substrate type
In our investigations we found that the easiest and best quality results were achieved with the
nickel based alloy. Tables 1-4 reveal that, of the three powder alloys, the nickel based alloy has
a melting point ( 1300 K) which is furthest removed from that of the substrate ( 1800 K).
This means that the operating window for molten/solid contact between the two materials
without welding would be greater than for the other alloys. Wet contact without welding is
necessary for an accurate casting and this is made easier by a large difference in casting mould
melting point or by melt substrate incompatibility. Other types of incompatibility could be
chemical (i.e ceramic substrate moulds could be used) or thermal (e.g. water cooled substrates
or high conductivity alloys could be used). The difference in performance of the three alloys
used here is clear from figure 8.
The melting point, although important, is not the only powder characteristic governing the
castability of the material. Melt viscosity and surface tension also play a significant role in the
casting process. Both these material properties should be minimised for high quality casting and
this would an interesting topic for future work.
a ) Cobalt based
b) Iron based
c) Nickel based
Figure 8. A comparison of the casting capabilities of the three alloys tested. Process parameters: 3
kW (Nd:YAG), beam diameter 5 mm, process speed 0.8 m/min, Ni based powder, powder flow
90 g/min.
3.3 Possible future development
These early results have demonstrated that it is possible to use the laser as a power source to
produce shallow surface casts in high strength alloys. Although the castings take on the
macroscopic surface features of the moulds they are not microscopically smooth. This is
because the outer surface is covered in powder particles which melted immediately before
solidification began. This is an area for future investigation which may involve the use of high
melting point moulds and cladding material with suitable liquid flow characteristics. At this
early stage it is not possible to forecast future applications of this technique although these may
include the production of abrasive surfaces or hard cutting tools. Refinement of the process
could result in the production of stamping dies.
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H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
4 Laser Clad-Casting
Laser clad-casting is a simple development of standard laser cladding which was stimulated by
an industrial inquiry. The company involved wanted to extend the life of piston rings by
adding a clad layer to the outer diameter. This clad layer was to be of a wear resistant material
and, to prolong life even further, was to be gradually increasing in thickness towards the edge.
The first concern from the laser cladding point of view was the aspect ratio of the clad track.
Generally, blown powder laser cladding gives a single clad track cross section which is a
truncated semicircle as shown in figure 9a. The maximum height of a single clad track is
achieved when the track is semicircular in cross section as shown in figure 9b. This customer
however, required a better aspect ratio than the 2:1 limit of a semicircle. They needed a post
machined aspect ratio of approximately 1:1 as shown in figure 9c. From figure 9c it is also clear
that they required the clad layer deposit to have sides which were diverging from the line of
the substrate at an angle of 10.
Clad layer
a) Standard clad
cross section
Machining
line
b) Maximum height
clad track (semi circular
cross section)
c) Required clad
cross section
Figure 9. Standard clad track cross section (a, b) and the required cross section (c ).
In order to achieve the clad profile required, copper blocks were machined and clamped to
either side of the substrate as shown in figure 10.
62
H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
Substrate
Machined
Machined
copperblocks
blocks
copper
Clamping
3 mm
Figure 11. A cross section of the clad-cast track deposited between copper blocks. (substrate width:
3mm,clad track height: 3.5 mm). Process parameters: powder feed (Nickel alloy) 40 g/min, cladding
speed 0.5 m/min, laser power 3.5 kW (CO2), beam diameter 4 mm.
Figure 11 clearly shows that the required clad profile has been achieved. The integrity and low
dilution levels of the clad layer are typical of the standard laser cladding process. In this case a
single, high aspect ratio, track has been produced on the edge of a narrow substrate. The depth
of the deposit could of course be increased by overalying another track on this one. The
process could also be extended to the laying of tall, narrow walls on flat substrates to produce
enclosures or stamping tools.
63
H.Gedda: Chapter IV-Laser Casting and Laser Clad-Casting: New process for rapid
prototyping and production
Apart from the ability to produce deep clad layers laser clad-casting has two other advantages
over the standard process:
a) The process is more energy efficient than standard laser cladding. In this case 24% of the
laser energy was utilised in the melting process as compared to 20% for standard laser
cladding with an Nd:YAG laser [2] (This value is only 10% for standard CO2 laser
cladding [2]).
b) The powder catchment efficiency is higher for clad-casting than for cladding. i.e. in this
example of clad-casting the powder catchment efficiency was 96 %. (Standard cladding
value 60%) [3]. This improves deposition rates and minimises substrate melting
because a greater proportion of the laser energy is involved in melting the incoming
powder. This improvement in powder catchment efficiency is clearly a function of the
valley-like geometry of the clad-cast melt zone. A geometry of this type tends to
channel powder into the weld pool rather than allowing it to spray all over the substrate
surface. (Which happens in standard laser cladding).
5 Conclusions
It has been demonstrated that two new laser cladding techniques are possible and that they may
provide novel answers to future production requirements.
Laser casting can be used to produce surface castings in high strength alloys to generate tool
bits or stamping dies etc.
Laser clad-casting can be employed to make clad tracks with large depth to width ratios and
pre determined cross sections.
6 References
1.
2.
3.
Gedda, H., Powell, J., Wahlstrm, G., W-B, Li., Engstrm, H., Magnusson,
C. (2002). Energy Redistribution During CO2 Laser Cladding. Journal of Laser
Applications, Vol. 14, no. 2, pp. 78-82
64
Chapter V
Laser Wire Casting
65
66
Abstract
This paper describes a new technique for the production of solid wire or rods from powder by
laser melting. Three techniques have been developed to ensure that the molten powder
solidifies as a rod or wire rather than a series of droplets. The straight rods or wires produced in
this way have an almost circular cross section, are several millimetres in diameter and can be
pore free. The techniques can be used to produce welding rods, tensile test samples and other
solid pieces from a wide range of powder mixes. The rapid thermal cycle involved means that
hitherto difficult to produce mixtures and alloys can now be produced in the solid form in
seconds.
1 Introduction
Previous work by the present authors [1] investigated novel applications of blown powder laser
cladding techniques to produce castings or castings which were simultaneously clad to substrates
[2]. This paper extends this work to the production of cast wires or rods from pre placed
powder beds. Simply traversing a defocused laser over the surface of a powder bed was found to
give unsatisfactory results because the melt has a natural tendency to form a series of large
droplets which may or may not be connected to each other [3] as shown in figure 1.
15
mm
2 Experimental work
2.1 Equipment and materials used
For the purposes of the experimental runs the following equipment and materials were
employed:
Laser model: Rofin Sinar RS 6000 CO2. Laser power 3500 W. Laser beam defocused to 3
mm.
Powder: Stellite 8 (Cobalt base). The powder chemical composition is presented in table 1
below.
Process speed: 0.4 m/min.
Wire: (Ni-based) The chemical compositions is presented in table 2 below.
Substrate: The substrate (mould bottom) chemical composition is presented in table 3 below.
Mould: Cu-blocks.
Chemical Composition
Table 1. Co based powder composition
Cr
27.2
wt %
C
0.27
Si
1.0
Mo
5.5
Ni
2.3
Fe
0.3
Co
63.4
wt %
Ni
Cr
Mo
Fe
59.3
21.2
13.2
0.2
3.3
2.7
wt %
C
0.16
Si
0.22
Mn
0.94
P
0.014
S
0.022
68
V
0.06
N
0.009
Fe
98.6
Wire
Powder
Substrate
a) Cross section of mould and
powder before laser irradiation
b) During laser
processing
69
3 mm
5 mm
Cross section
6 mm
Cross section
Cross section
5 cm
a)
General view
b)
General view
c)
General view
Figure 3. A selection of results of the side contact mould laser casting process.
It is clear from the results presented in figures 3a-b that the wires or rods produced by this
method are of ovoid cross section and are close to 100% dense. They are also generally straight
along most of their length. Figure 3c demonstrates that, if the mould walls are too far apart, the
melt reverts to its droplet forming behaviour. It is the suppression of this behaviour which is
the main advantage of the use of side walls. The mechanism of suppression will be discussed
later.
70
4 mm
200 m
50 mm
6 mm
a) Cross sections
b) General view
72
1.3 mm
3 Discussion
Figure1 demonstrates that there is a natural tendency for liquid metal to gather together in
droplets. (This is not true if the mass of liquid is large because, in that case, gravity overcomes
the surface tension effects which create droplets). Droplets are formed because the liquid
attempts to achieve its lowest energy state and this is satisfied when the liquid has the lowest
surface to volume ratio. The shape with the lowest surface to volume ratio is the sphere and
therefore small volumes of liquid tend to form spheroids. If a laser melts a track across a bed of
metal powder and does not simultaneously weld the track to the substrate (as in laser cladding)
[4], then the solidifying liquid will attempt to form spheroidal droplets in order to minimise its
surface energy. Figure 1 shows that these spheroids are extended in the direction of movement
of the laser and are often joined together. This sort of morphology is a compromise between
the sphere forming influence of the surface tension of the melt and the line forming influence of
the movement of the melt front (which, obviously, follows the laser movement).
The presence of a side wall or net shape mould prevents the bulging of the melt bead necessary
to the production of spheroids. This is clearly demonstrated by figure 3 which shows that
spheroids are created if the gap between the side wall moulds is too great. At narrower gaps the
side walls only allow the melt to solidify with a linear morphology which creates a wire with a
consistent cross section.
The use of a wire as a melt guidance device also produces rectilinear solidification without
droplet formation. In this case the wire and powder material were Ni-based (Tm 1400 K)
and Co-based alloy (Tm 1600 K) respectively. This proximity in melting point resulted in
the original wire being entirely melted during the process but this doesnt necessarily have to be
the case. Whether or not the original wire is melted it acts as a solidification nucleation site and
inhibits the formation of droplets.
Of the three processes discussed in this paper the one which produces the highest quality
product is, of course, the use of net shape moulds. Using this technique it should certainly be
possible to produce wires or rods over a wide range of diameters and lengths.
The compositional range of rods formed in this way is extremely wide and could include metal
matrices with hard, abrasive ceramic particles as well as exotic alloy combinations.
73
3 Conclusions
Wires or rods can be cast from metal powder using a high power laser as a heat source.
Metal powders which have been laser melted do not readily solidify as uniform cross
section rods unless the tendency to form strings of droplets is inhibited.
The presence of side wall or net shape moulds can result in rods which are ovoid or
circular in cross section and approximately 100% dense. Wires incorporated into the
powder bed can have the same effect in the absence of moulds.
The casting techniques discussed in this paper could be used to produce wires or rods
of a very wide range of alloys and alloy-ceramic mixtures.
4 References
1.
Powell, J., Gedda, H., Kaplan. A. (2002). Laser Casting and Laser Clad-Casting:
New processes for rapid prototyping and production. Conf. Proc. (ICALEO)
Scottsdale, AR, 14-17, October 2002
2.
3.
Powell, J. (1983). Laser Cladding. PhD Theses Imperial College of Science and
Technology, Dept. Of Metallurgy, London UK.
4.
74
Chapter VI
Melt-Solid Interactions in laser cladding and
laser casting
75
76
Abstract
Experimental data in conjunction with mathematical models are used to explain various aspects
of laser casting and laser cladding by the preplaced powder method. Results include an
explanation of the large range of process parameters over which low dilution clad deposits can
be produced. Also the interaction of the melt pool with the powder bed is analysed to identify
why laser castings have microscopically uneven surfaces.
Kewords: laser, cladding, casting
77
1 Introduction
The process of laser cladding has been the subject of scientific research and commercial
applications since the late 1970s [1-5]. There are two basic methods of using a laser to clad one
metal with another; the preplaced powder method and the blown powder method. These two
techniques are illustrated in figure 1.
Laser beam
Cladding material
3 mm
78
2 Experimental procedure
For the purpose of this study a number of clad tracks were produced over a wide range of
process speeds. The experimental details are provided in Table 1.
Table 1. Equipment and Parameters
CO2-laser, Rofin Sinar RS 6000 (6 kW)
Laser power range 100 - 4000 W
Laser spot diameter = 4 mm
Substrate, SS 2172 Mild steel (0.16% C)
Cladding Material, Cobalt based (Stellite 21)
Process speed range 0,1 m/min- 4 m/min
79
a) 0,1 m/min
b) 0,2 m/min
c) 0,9 m/min
d) 2,1 m/min
1 mm
e) 3,3 m/min
f) 3,8 m/min
Figure 3. Cross sections of clad tracks made under identical conditions (laser power 3500 W, powder bed
depth 1 mm) at different speeds.
80
Substantial substrate melting is only a feature of the lowest speed even though sound
cladding is possible at speeds over twenty times this value.
There are a broad range of process speeds over which the amount of substrate melting
is trivial (0,2 m/min-2,1 m/min).
Although the melt cross sectional area decreases with process speed the rate of decrease
is surprisingly small. For example the cross section of b is 5.1 mm2 and this decreases to
3.5 mm2 (69 %) for d which was produced at approximately ten times the speed of b.
The contact angles of the melt to the substrate show good wetting characteristics from
a to d but poor wetting in cases e and f. The clad layer in the case of the highest speeds
(e and f) is not in full contact with the substrate.
The main contra- intuitive feature of figure 3 is the surprisingly low amount of substrate
melting over a wide range of process speeds. This phenomenon was first discussed by
Powell [1, 2] who postulated a three stage melting process for preplaced powder laser
cladding;
1. The laser rapidly melts the powder before the melt touches the substrate because,
prior to substrate contact the melt is surrounded by low conductivity powder.
2. Once the melt touches the substrate it looses a great deal of heat by conduction.
This leads to partial solidification of the melt. As a result the melt-liquid interface
does not move into the body of the substrate.
3. If the laser energy continues to irradiate the top surface of the melt, the energy
will eventually move the melt/solid interface back down through the clad layer
and across into the body of the substrate.
Figure 5 presents a graphical description of the three stage process derived from a one
dimensional mathematical model.
Figure 5 Vertical temperature distribution through the preplaced powder and substrate for different time
steps [1,2].
81
T ( x, y, z ) = Ta +
v x2 + y2 + z2 x
exp
2
2K x 2 + y 2 + z 2
APL
(1)
Where :
x,y and z = A Cartesian coordinate system
T(x,y,z) = The temperature field at any position x, y, z.
Ta = Ambient temperature
PL = Laser beam power
A = Absorptance of the surface to the incident laser light
v = The speed traveled by the laser beam in the x direction
K = Thermal conductivity (assumed constant)
= Thermal diffusivity (assumed constant)
The extension of Equation 1 involves the addition of an infinite number of mirror sources [9]
arranged along the vertical axis. This mathematical method replicates the insulating effect of
the powder bed. Thus expanded, Equation 1 becomes;
APL
T ( x, y, z ) = Ta +
2K
i =
1
x 2 + y 2 + ( z + 2id )
v x 2 + y 2 + ( z + 2id )2 x
(2)
exp
where
i = Mirror source index
d = The powder depth
After melt substrate contact the heat flow reverts to that described in Equation 1. This
constitutes a change from two dimensional heat flow (Equation 2) to three dimensional
(Equation 1).
82
Figure 6. Calculated maximum melting depth through the powder (1 mm thick) and substrate ( >> 1
mm) as a function of the processing speed.
Figure 6 qualitatively supports the results shown in figure 3; only the lowest speeds involve
substrate melting, corresponding to 3-dimensional heat conduction, (Equation 1). Then there
is a range of speeds over which no substrate melting takes place but the powder is melted
completely. Throughout this range the calculation continuously flips from three dimensional
to two dimensional heat-flow and this effectively freezes the movement of the melt front at the
substrate surface. At the highest speeds (here 1.6 m/min or higher) the powder is not
completely melted throughout its depth and no melt substrate contact is achieved. The
calculation in this region is governed entirely by Equation 2
83
Melt
Powder bed
Clad layer
Substrate
Figure 8. The geometry of preplaced powder cladding.
P =
4rp3
3
[c p (Tm Ta ) + H m ]
(3)
Where:
P = Thermal power flowing into the particle
= Interaction duration until melting
rp = Powder particle radius
= Specific mass density of the particle
cp = Specific heat capacity
Tm = Melting temperature
Hm = Latent heat of melting
Figure 9 shows the distribution of the particle diameters in the powder used in this
investigation. The dotted line on this figure shows the level of energy needed to melt the
particles as a function of radius and the broken line demonstrates the proportion of the incident
energy needed to melt the various particle sizes in the batch.
84
40
E
N*E
30
20
10
0
0
50
100
150
200
Figure 9. The particle size distribution and proportion of the incident energy needed to melt the particles of
different sizes in this batch.
As particle heating by the advancing melt front is a highly complex mechanism, the simplified
model of Eq. (3) is applied here in order to estimate the duration for heating and melting a
particle for given heat flux.
According to figure 9 the energy required for heating and melting a particle is proportional to
its volume. Table 2 gives the melting times for a number different sized particles and it can be
seen that doubling the particle diameter multiplies the melting time by a factor of eight. It
must also be born in mind that a change in incident power (or heat flux) leads only to a linear
change in melting time.
Diameter 2rp [m]
60 m
90 m
120 m
150 m
0.8 ms
2.7 ms
6.4 ms
12.5 ms
Table 2: Calculated melting time of a single particle depending on its diameter (steel,
prescribed power per particle 0,885 W)
R
R
85
Where:
p = Pressure from surface tension
s
= Surface tension
R , R = Local radii of curvature of the two liquids
Earlier work by Kaplan [7] modelled the collapse of gaseous cavities (bubbles and keyholes) in
liquid weld pools and the force acting upon them. This approach, based on the theory of water
bubbles and drops [12-15] can be used to model the reverse situation i.e. liquid droplets
surrounded by a gas. Potential flow theory is applied via the time dependent Bernoulli
Equation which considers the curvature affected surface tension force and the inertia of the
melt close to the surface:
2
s
p u s,n
(5)
= s
l
2
t
l = Liquid density
us,2n = Surface speed normal component
Locally the flow can be split into two cylindrical components , perpendicular to each other,
which can be superimposed. Continuity liquid mass flow in a cylindrical coordinate system
with the radial coordinate r is determined by the flow potential field [12, 14]:
M& (t ) 1
(t ) =
(6)
4 l r
Spatial derivation yields the velocity field:
u (t ) =
M& (t ) 1
4 l r 2
(7)
Note that the mass flow rate M& implicitely results from the calculation.
As for the heat conduction equation, superposition of the surface solutions of two
perpendicular cylinders of radius R, R, respectively, at their coinciding surface gives:
s (t ) =
u s,n (t ) =
M&
4 l
1
1
R
R
1
M& (t ) 1
+ 2
2
4 l R (t ) R (t )
(8)
(9)
Again, this solution is valid only at the surface and its vicinity, but is important to take into
account the local surface curvature in the radial and vertical direction governing the
consolidation situation studied here. The above solution can be locally applied to the surface
position r as a function of (z,t).
s
86
(10)
Where:
Figure 10. Calculated heating and melting of powder grains of different diameter touched by the melting
front and subsequent smoothing of the droplets.
The black spheres correspond to the solid state and the percentage of the enthalpy consumed
related to the enthalpy required for melting is shown in each solid sphere, (refer also to Table
1). In the calculation the particles are assumed to have penetrated the melt by 20 % of their
radius, however, the sensitivity of this parameter is low. Note that wetting and liquid motion is
87
0,1 mm
Figure 11. The surface of a laser cast specimen (This surface was in contact with the substrate).
5 Conlusions
This analysis of melt solid interactions has helped to explain the following points about the
laser cladding and casting processes;
a) There is a wide parameter range over which dilution free cladding can be achieved by
the preplaced powder process. This is primarily due to the difference in thermal
conductivity of the powder bed and substrate.
b) If the process parameters are set outside the range mentioned above the result will be
either a dilute clad layer (see figure 3a) or a casting process (see figure 2) depending
on whether or not the power input to the process is increased or decreased.
c) The physics of powder particle melting by contact with a liquid pool makes it difficult
to achieve laser casting with a smooth surface.
88
6 Acknowledgements
The authors gratefully acknowledge the support from the Swedish funding bodies VINNOVA
and SSF within the VINST programme.
7 References
1.
2.
Powell, J., Henry, P.S, Steen, W. M. (1988). Laser cladding with preplaced
powder. Analysis of thermal cycling and dilution effects. Surface Engineering,
Vol.4 no.2, pp. 141-149
3.
Riabkina- Fishman, M., Zahavi, J. (1996). Laser alloying and cladding for
improving surface properties. Applied Surface Science, Vol. 106, no. 1-4, pp.
263-267
4.
Yellup, JM. (1995). Laser Cladding using the powder blowing technique.
Surface Coating Technology, Vol 71. no. 2, pp 121-128
5.
6.
Powell, J., Gedda, H., Kaplan, A. (2002). Laser Casting and Laser Clad
Casting: New processes for rapid prototyping and productionn. Conf. Proc.
(ICALEO) Scottsdale, AR, 14-17 October 2002
7.
8.
9.
10.
11.
12.
89
14.
15.
Legendre, D., Bore, J., Magnaudet, J. (1998). Physics of Fluids, Vol. 10, pp.
1256-1272
16.
17.
90