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INTRODUCTION:
PROCESS :-
water.The drums are inspected and any debris collected at the bottom drum
removed manually.
During alkali boil out operation ,important parameters like pressure,
feeding rate ,temperature and water analysis etc. are systematically logged.
The boiler is then prepared for steam blowing operations.
Another Method-2
RECOMMENDED PROCEDURE FOR ALKALI BOIL OUT
1.0 Objective:
Once the boiler light up is carried out, preoperational cleaning is taken up in which alkali
boil out forms the first activity.
Alkali Boil out at an elevated pressure of 40 Kg/cm 2 (Drum Pressure) is carried out prior
to acid cleaning to meet the following objective:
It mostly converts the entire interior scale to magnetic oxide that could be easily
dissolved by acid solvents used during acid cleaning.
Loose metal oxides are removed from the system leaving a lesser quality of oxides
for acid digestion.
Surface cracks are developed over the scale layer, benefiting better acid
penetration and effective cleaning in shorter time.
As the total time for acid injection, retention and draining is restricted to a
maximum of 6 hours, partial removal of oxides and better surface preparation help in
achieving the pickling operation in the recommended time limit.
Removal of oil, greases, dirt and any preservative organic coating is ensured. This
helps in accomplishing effective acid cleaning and surface exposure.
2.0 Procedure
2.1
Scope
The scope of cleaning during this operation includes a portion of feed line, entire
evaporative system of the boiler and the economizer.
2.2
Technique
Alkali boil out at a pressure of 40 Kg/cm 2 is carried out using a combination of Tri-sodium
Phosphate (concentration 1000 ppm as Na3 PO4 12H2O) and Di Sodium Phosphate
Hepta Hydrate (concentration 500 ppm as Na2 HPO4-7H2O).
2.3
Preparation
Boiler should be ready in all respects for light up and raising the drum
pressure to 40 Kg/cm2.
All the drum internals including the secondary steam separators are in
position as per the drawings.
Boiler drain header may be connected to storm water drain suitably with
temporary line and well supported.
2.4
Following chemicals to be made available: TPS 300 Kg; DSP 150 Kg.
Process
1.
Fill the boiler with dematerialized water upto the bottom of the drum.
2.
Mix the required quantity of Na3 PO4 & Na2 HPO4 with DM water in small
increments and prepare a homogeneous solution in a 200-liter drum.
3.
Add the total quantity of chemicals into the steam drum through the drum
manhole, close the manhole and raise the water level to minimum visibility in the
gauge glass.
4.
Light up the Boiler as per O & M instructions and slowly raise the drum pressure
in increments of 5, 10, 20, 25, 30 & 40 Kg/cm 2. Monitor and record the expansion
movement of the boiler by the expansion markers already provided at different
locations. If any obstruction is noticed stop increasing boiler pressure and remove
the obstruction.
5.
Maintain the drum pressure at 40 Kg/cm2, with minimum possible firing rate
adjusted and with boiler startup vent valve full open, for two hours for better
digestion of the impurities by the chemicals.
6.
Put out the fire and issue blow down through low point drain by opening the
valve, for one-minute duration. Ensure that the drum level does not fall below the
visibility limit of the gauge glass.
7.
Make up the drum level and again light up the boiler to raise the pressure to 40
Kg/cm2 with the same firing rate for next two hours. The blow down as described
earlier is repeated.
8.
After every blow down operation, collect drum water sample and analyze for
phosphate, pH value and oil level content. Replenish phosphate concentration
through HP dozing system as much as possible to maintain half of the initial
sample result.
9.
The process of boiling out for two hours and blowing down is repeated till the oil
content in drain sample shall be no longer detected (> 5 ppm or traces) in two
consecutive samples or till 8 blow down are completed, whichever is later. A
minimum of 12 hours of boil out is a must in any case. Repeat the boil out with
additional chemicals, if oil level is found high.
10.
Kill the boiler fire after the completion of boil out operations and allow for
natural cooling. Hot drain the boiler when the drum pressure touches 2.0 Kg/cm 2.
11.
Fill the boiler upto the minimum drum level and back flush the super
heaters into the drum, raising level up to normal. Drain the boiler continuing the
super heater back flushing with hydrazine DM water with pH 10 and hydrazine
200 ppm. Similarly fill and drain the boiler several times till the alkalinity in super
heater and boiler drain water is less than 25 ppm.
12.
The hand hole pipes in the ring header are cut as a preparatory work for
acid cleaning. Clean the ring header through these connections with a highpressure water jet.
Another method:
STANDARD PROCEDURE FOR CHEMICAL CLEANING (DRUM TYPE NATURAL
CIRCULATION BOILER)
1.01
Introduction:
Advanced steam, data in modern power stations demand high purity of steam in
order to prevent fouling of the turbine and safe operation of the power plant.
High purity of steam depends on the cleanliness of the waterside of the Boiler.
Boiler components during manufacture in shop from raw material to final shape
and during erection at site undergo both physical and chemical changes. These
include rust due to atmospheric corrosion and formation of oxides of iron due to
the heat treatment at shop. The other common impurities found are lubricants,
grease, silica in the form of silicates, etc.
Basic Technique:
Chemical cleaning of the boiler will be carried out by a pickling solution of 4%
inhibited Hydrochloric Acid by circulation method. To intensify the action of
Hydrochloric Acid and to dissolve silicious impurities, Ammonium Bi Fluoride of
0.1% concentration after mixing is added to the cleaning solution. To lessen the
action of acid on parent metal suitable inhibitor is added to the pickling solution.
In the final phase of cleaning the freshly pickled surfaces are protected from
corrosion by a passivity layer of magnetite formed chemically by the addition of
Hydrazine and Ammonia. The above layer is reinforced further by the process of
second stage passivation, at a later stage, at a drum pressure of 40 kg/cm.
In the above process, the chlorides formed during the process are easily
soluble and go readily into solution. Cleaning time for the process is less
compared to any other cleaning solvent even at low cleaning solution velocities.
1.03
Scope of Cleaning:
The scope of cleaning includes a portion of the feed line and complete
evaporative system of the Boiler. Superheater and reheaters are excluded from
the cleaning circuit. During pickling the superheater connecting tubes will be
plugged suitably from inside the drum and remain filled and pressurized with
Ammoniated Hydrazene water confirming to pH 10.0 and Hydrazene content not
less than 200 ppm. The reheaters will remain dry through out the process.
Check that the plugs can hold more than 5 kg/cm pressure before closing the
drum manhole. To facilitate fixing the plugs the drier assemblies are removed
and for fixing orifice plate on down comers the primary and secondary
separators are removed. The pressurization of superheater system will be done
by pressurizing pump as shown in schematic drawing on page 13 of 13.
1.04
of the system forming undesirable gas cushions. These are continuously taken
out through drum air vents. Representative water wall tube samples are hung
inside the drum as well as in the dissolving tank to ascertain quality of cleaning.
3.04.01
3.04.02
Dissolving Tank
Mild steel tank of 20 m3 capacity is fabricated and provided with the
following fittings.
Provision for overflow, level indication, a perforated header for heating
steam, supply lines from DM water, steam, acid, return piping from the
system, suction pipe with wire mesh at the entry, drain connections to
atmosphere with valves.
The tank shall be provided on the top with walkway along with handrails
around for handling of chemicals. The tank shall be welded by approved
quality welders and insulated.
3.04.03
ii)
iii)
iv)
v)
vi)
3.04.04
Effluent Disposal
2.
3.
4.
Treatment of effluents 1, 3, 4 and D.M. water rinse drains can be either in waste
water treatment plant (if provided) or D.M. water plant neutralizing pit.
Phosphates are neutralized with hydrochloric acid, hydrazine and ammonia with
bleaching powder and adequately diluted with water. Customer has to decide
based on the capability of the wastewater treatment plant to recover D. M. water
from the final product. However for the picking process (effluent 2) it is preferable
to dig an eathern pit of 300 m3 and the entire boiler drain be dumped in it.
Necessary temporary drain lines, raw waterlines to neutralization pit has to be
laid accordingly. Adequate lime has to be dosed and mixed to raise the pH to 8.0.
Agitate the solution with compressed air.
a)
Add fly ash and expose the solution to solution to sunlight. Dilute the solution
and check for fluoride content to be within local pollution control limits (< 2
ppm). Later on the remnants are buried with mud.
b)
Alternatively the solution may be slowly pumped out with a 10-m3 pump into
the plant drain canals, flooding with raw water to limit fluoride content to less
than 2 ppm. A typical pollution control board requirement in India is given
below:
Parameter
Maximum Limit
1. PH
5.0 to 9.00
2. Temperature C
45
2100
100
10
7. Chlorides mg/1
600
8. Sulphates mg/1
1000
9. Fluorides mg/1
1.5
50
0.2
0.1
0.1
0.2
0.01
Nitrogen Capping
Nitrogen capping is done during operations to protect the freshly exposed metal
surfaces after pickling from being corroded due to exposure to atmospheric air,
upto neutralizing boil out.
A scheme of connections of N2 cylinders to the boiler system is shown in the
figure on page 13 of 13.
Required number of cylinders of suitable capacity is connected to the bus, which
in turn is connected to the drum air vents through a stop valve and a non-return
valve. In case the smaller cylinders are envisaged for the capping, 2 nos. of
manifold systems to accommodate 15 cylinders each connected through two nos.
of heavy duty regulators may be employed.
The stop valve in the Nitrogen line and the air vent valve nearer the drum are
kept open and the other air vent valve on drum is kept closed. All other air vents
in the system are kept closed to prevent ingress of air into the system. As the
dumping of the system starts nitrogen enters through the non-return valve into
the system and offers effective blanketing. When the system is completely
drained and filled with nitrogen, the stop valve in the nitrogen line shall be closed.
The pressure of nitrogen in the system is to be maintained slightly above
atmospheric pressure, say about 5-10 PSI control draining operation accordingly.
When the system is getting filled for next operation, the nitrogen in the system is
vented through the airline prevents entry of water or chemical solution to
nitrogen piping system.
3.04.06
a)
Procedure
Acid Pickling:
i)
ii)
iii)
Admit steam into the mixing tank and raise the temperature
of circulating water to 60C as measured in return line. Continue
circulation for eight hours for the purpose of hot flushing and drain
the system completely.
iv)
v)
vi)
vii)
viii)
ix)
x)
b)
D. M. Water Rinse
i)
ii)
iii)
iv)
c)
ii)
iii)
iv)
d)
DM Water Rinse
i)
ii)
iii)
e)
Neutralization
i)
ii)
iii)
f)
Passivation
The objective of passivation is to prevent corrosion since the cleaned surfaces
are more susceptible for corrosion at a very fast rate. The corrosion is
prevented by providing a thin layer of magnetite (first stage), which gets
strengthened in the subsequent firing of the boiler (second stage).
i)
ii)
iii)
The chemicals viz. Ammonia liquor, for raising the pH to 9.6 and
hydrazene, to get a concentration of 200 ppm are charged in the operating
feed water tank. The boiler is filled by feed pump upto normal operating
level in drum and lighted up with one or two oil burners. The steam
pressure in drum is gradually raised to 40 kg/cm and maintained at that
value. Water samples are taken from feed line to find out hydrazine
concentration and pH value. The boiler is kept in service for 24 hours
maintaining the hydrazine concentration not less than 20-25 ppm in feed
water.
At the end of the process, the boiler is boxed up and allowed for natural
cooling. At 1 or 2 kg/cm the superheater air vents are opened and at
about 90C (Drum temperature) the water in the system is drained and
the system is left aerated.
The second stage passivation marks the end of the chemical cleaning
process.
Name of Chemical
Qty.
1.0
375 kg
2.0
750 kg
35 Tones
260 Ltrs.
Citric Acid
520 kg
Ammonia: 25%
165 Ltrs
7.0
560 Ltrs.
8.0
Nitrogen Cylinders
200 Nos.
Ammonium Bifluoride
1150 kg.
10.0
Hydrated Lime
25 Tones
11.0
Bleaching Powder
5 Tones
in M3
a. Water walls
130
b. Drum
34
c. Economizer
30
d. Superheater
108
e. Reheater
Sl. No.
1. PIPE
48
DESCRIPTION
DIA 273 X 6.25
QUANTITY
300 METERS
2. PIPE
50 METERS
3. PIPE
300 METERS
4. PIPE
40 METERS
5. PIPE
300 METERS
6. REDUCER
01 NO.
7. REDUCER
01 NO.
8. REDUCER
01 NO.
9. REDUCER
03 NOS.
10. REDUCER
01 NO.
11. REDUCER
01 NO.
12. REDUCER
01 NO.
13. BEND
30 NOS.
14. BEND
09 NOS.
15. BEND
30 NOS.
16. BEND
08 NOS.
17. REDUCER
05 NOS.
18. REDUCER
05 NOS.
NO. REQUIRED
UTILITY
1)
NB 300 (GATE)
PUMP SUCTION
2)
NB 250 (GLOBE)
PUMP DISCHARGE
3)
NB 250 (GATE)
12
4)
DISCHARGE NRV
5)
NB 200 (GATE)
6)
NB 150 (GATE)
SYSTEM VALVES
7)
NB 150 (GLOBE)
8)
NB 100 (GATE)
SYSTEM VALVE
9)
NB 40 (GATE)
15
10) NB 25 (GATE)
15
11) NB 25 (GLOBE)
10
2.
3.
4.
5.
2
20
0.25 KG/CM
7 NO
PUMP DISCH.
2.
0.20 KG/CM
4 NO
SYSTEM
3.
0.100C
THERMOWELLS
6 NO
6 NO
SYSTEM IN /OUT