TUGAS DINAMIKA KIMIA

Nama

: Eva Qomariyah Mabruroh

NIM

: 4311413038

Rombel

: 001

BAB 2
3) The catalysed decomposition of H 2O2 in aqueous solution was followed by titrating
samples with KMnO4 at various time intervals to determine undecomposed H 2O2
Time/min
5
10
20
30
50
Volume of KMnO4/cm3
37.1
29.8
19.6
12.3
5.0
Show graphically that the reaction is first order and determine the rate constant.
Jawab :

vol KMnO4/cm3
40
30
vol KMnO4/cm3 20
10

f(x) = - 0.7x + 36.8

vol KMnO4/cm3
R = 0.93
Linear (vol
KMnO4/cm3)

0
0 20 40 60
t/m

slope = -0,69758
slope = kr/2.303
kr =1,6065
5) During the hydrolysis of an alkyl bromide
RBr + OH- ROH + Brin aqueous alcohol, it was found that it took 47 x 10 3 s to liberate 0.005 mol/dm3 of
free bromide ion when the initial reactant concentrations were both 0.01 mol/dm 3.
The same percentage conversion took 4.7 x 10 3s with initially 0.1 mol/dm 3 of both
reactants. Calculate the rate constant of the hydrolysis reaction.
Jawab :
t1

4,70E+

04
4,70E+
t2
a1
a2
x1

03
0,01
0,1
0,005

a1-x1
1/(a1-

0,005

x1)
1/a1
Kr

200
100
2,13E-03

7) The neutralisation reaction of nitroethane in aqueous solution proceeds according

to the rate equation

OH
d [OH ] d [C2 H 5 N O5 ]
=
=k [ C 2 H 5 N O2 ]
dt
dt
Experiment at 00C with initial concentration of both reactants equal to 0.01mol/dm 3
give a value of 150 s for the reaction half-life. Calculate the corresponding rate
constant at 00C.
Jawab :
T
A
t0.5

0C
0,01
150

t0.5 = 1/(Kr.a)
K =
r

0,666667

9) In the second-order reaction between isobutyl bromide and sodium ethoxide in

ethanol at 950C, the initial concentration of bromide was 0.05050 mol/dm 3 and of
ethoxide was 0.0762 mol/dm3. The decrease x in the concentration of both the
reactants was measured as follows
103x/ mol dm3 0
5.9
10.7
Time/min
0
5
10
Caculate the rate constant for the reaction.

16.6
17

23.0
30

27.7
40

33.5
60

BAB 3
3) The hydrolysis of t-butyl iodide follows first-order kinetics at 26 0C
ButI + H2O ButOH + HI
The conductivity of the solution was measured with time as follows
Time/min
106 x conductivity/
-1

0
5.5

2
13.0

4
20.0

15

20

6
26.0

8
31.0

10
36.0

17
46.0

22
51.5

m-1
Jawab :
grafik
2
1.5
1
0.5
0
0

10

25

30

Slope = -0,02913
Slope = -kr/2,303
Kr = 0,06708
5) The optical rotations for the mutarotation of -glucose at 20 0C are as follows
/degrees

20.26

18.92

16.82

15.22

14.0

13.18 10.60

6
Time/min
10
20
40
60
80
100
equilibrium
Show that the reaction is first order and calculate the rate constant
k1 + k-1
Jawab :
Reaksi orde satu:
0 -

9,66

log10[0 - ]

0,9849 0,9201 0,7938 0,6646 0,5391 0,4116

time/min

10

grafik

8,32

20

6,22

40

4,62

60

3,46

80

2,58

100

28
56.0

65.0

1.2
1
0.8
0.6
0.4
0.2
0
0

20

40

60

80

100

120

Slope = -0,00637
Slope = -kr/2,303
Kr = 0,01467
7) Reaction of diacetone alcohol with alkali to give acetone produces a volume
change, which is measured on a cathetometer as the reaction proceeds. From the
following data obtained by G. Akerlof (J. Am. chem. Soc., 49 (1927), 2955) with 5
percent diacetone alcohol by volume in a KOH solution of concentration 2 mol dm -3,
calculate the order and the rate constant.
Time/s

24.4 35.

Chathetomete

48.

64.

28.

32.

r
reading

8.0

20.0 24.

75.8 89.4 106.

6
34.0 36.0 38.0

133.

183.

40.0

42.0

Jawab :
Reaksi orde satu:
C - C0

35,3

23,3

19,3

15,3

11,3

9,3

7,3

5,3

3,3

1,3

log10[0

- 1,55

1,36

1,28

1,18

1,05

0,096

0,86

0,72

0,51

0,11

02

74

56

47

31

85

33

43

85

39

time/min

24,4

35

48

64,8

75,8

89,4

106,

133,

183,

grafik

43.3

2
1.5
1
0.5
0
0

20

40

60

80 100 120 140 160 180 200

Slope = -0,00783
Slope = -kr/2,303
Kr = 0,01803
9) The decomposition of ethylene oxide
C2H4O CH4 + CO
At 687 K gave the following results
Time pressure/torr

116.5

122.6

125.7

128.7

133.2

Time/min
0
5
7
9
12
Show that the rections of first order and calculate the rate constant
Jawab :
Reaksi orde satu:
2p0-p/torr
log10

116,5

110,4

107,3

104,3

99,8

91,6

[2p0- 2,066

2,042

2,030

2,018

1,999

1,961

p/torr ]

t/s

12

18

Grafik

141.4
18

2.1
2.05
2
1.95
1.9
0

Slope = -0,00589
Slope = -kr/2,303
Kr = 0,0136

10 12 14 16 18 20