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IITJEE CHEMISTRY SAMPLE PAPER - I

SOLUTIONS
SECTION I
Straight Objective Type
1.

(b)

In OSF4, BP = 5, LP = 0 and hence the hybridization is sp3d and shape is trigonal

bipyramidal.

2.

(a)

H3BO3 + 2H2O

3.

(d)

k1
k2

[B(OH)4] + H3O+
K

3B ;

k1
[B]3
; [B] =
[A]
k2

k1
k2

k1
where k =
k2

1/ 3

rate = k 3 [B] k[A]

Ae
E

4.

(a)

5.

(d)

A1e
A 2e

E / RT

E1
3

E2
3

E1 / RT
E 2 / RT

1/ 3

[A]1 / 3
1/ 3

k3

1/ 3

A 3e

E 3 / RT

E3 = 70.0 kJ.

For salt involving anionic hydrolysis A + H2O

HA + OH weaker is the acid

HA; more is hydrolysis of A ions and hence more is the pH. Hence Ka is least for the
acid HZ.

S nC V ln

T2
T1

nR ln

V2
V1

C V (ln 2)

R ln

1
2

C V ln 2 R ln 2 ln 2(C V

R)

6.

(d)

Enantiomers are the mirror images and non-superimposable.

7.

(c)

CH3CH2CH=CH2

NBS

CH3CHCH=CH2
Br

8.

(a)

CH3CH2Br + Mg
(X)

dry ether

alc. KOH

CH2=CHCH=CH2

(X)

(Y)

CH3CH2MgBr
(Y)

CH3CH2MgBr + HCH
(Z)

CH3CH2CH2OMgBr

H3O+

CH3CH2CH2OH

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SECTION II
Reasoning Type
9.

(b)

2NO2(g) ; Q C

N2O4(g)

[ NO 2 ] 2
[N 2O 4 ]

When inert gas is added under the condition of constant pressure, volume increases.
Hence, QC decreases and reaction moves in forward direction to achieve equilibrium.
10.

(a)

11.

(a) Statement-1 and statement-2 both are correct and statement-2 is the correct explanation
of the statement-1. Protection by acetylation makes the ring less prone to oxidation as
electron density in the ring decreases.

12.

(c)
SECTION III
Linked Comprehension Type
PassageI

13.

(d) Bromine water being a weak oxidising agent cant oxidize ketones.

14.

(c) Number of moles of fructose = 10

CH2OH

103 = 102

C=O
HCOH
HOCH
HOCH
CH2OH
L Fructose
1 molecule will require 5 molecules of HIO4. Hence 102 moles will require 5
HIO4.
15.

102 moles of

(d) On oxidation with HNO3, fructose yields a mixture of tartaric acid and glycollic acid, both
containing fewer carbon atoms than six.
PassageII

16. (d) KE = eV0 = h h

Hence, slope

h
.
e

V0

h
e

h
e

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17. (b) eV0 = h

For same V0,
Hence, B >

18.

(d) 2E E
4E
3

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= h eV0
is higher for B

V0

hc

E hc
3
3hc
3
E

hc
E

SECTION IV
Matrix Match Type

1.

(A) 2 ; (B) 3 ; (C) 1, 3 ; (D) 4

2.

(A) 1 ; (B) 3 ; (C) 4 ; (D) 2

SECTION V
Subjective or Numerical Type
Atomic weight
M
9
n
n
Let the metals chloride has formula MCln.
Atomic weight of MCln = 66.75 2
Hence, MM + 35.5n = (66.75 2)
9n + 35.5 n = 133.50
133.5
n
3
44.5
Hence, valency of the element = 3

1.

Equivalent weight =

2.

Number of moles of Butane in cylinder finally

Initial number of moles

V
RT
n

15 10 3
58

PV
8 V
=
RT
R T

10 V
R T

15 10 3
58 10
8 15 10 3
58 10

206.89

Mass finally present = 11999.62 g = 11.99 kg

Amount of gas leaked out = 3 kg.

12.0 kg

A B