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t
e
States of Matter
n
.
a
4 Marks Questions
h
b
i
A: Particles of a gas are in constant & random motion. Collisions of gas molecules
are perfectly elastic.
t
a
r
p
u
d
a
n
e
e
.
w
w
2
1
pV = mnurms
3
t
e
n
2
2
1
pV = mnurms
3
2
.
a
h
2
1
mnurms = K.E.
2
b
i
t
a
r
p
pV = Constant
u
d
a
b) Charle's law:
2
1
pV = mnurms
3
n
e
e
.
ww
2
2
1
pV = mnurms
3
2
as KE = KT
2
pV = KT
3
V
2 K
=
T
3 p
R-23-11-14
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V
At Constant p, = Constant
T
Q. State Graham's law of diffusion.
t
e
n
.
a
h
b
i
t
a
r
1
r
rCH
Munknown
4
=
r unknown
MCH
4
p
u
d
a
n
Munknown
4
=
tCH
MCH
Vunknown
4
4
Munknown
360
10
= 2 =
15
120
16
e
e
.
w
w
w
tunknown
VCH
t
e
n
.
a
h
Munknown = 2 2 16 = 64
Q: What is R.M.S. speed? Find R.M.S., most probable and average speeds of
SO2 at 27C.
b
i
t
A: Square root of mean of square of speeds of all the molecules of a gas is called
R.M.S. speed.
3RT
R.M.S. speed = Urms =
M
3 8.314 300
= 3.42 102 m sec1
Urms =
64 / 1000
2RT
Most probable speed = Ump =
M
a
r
p
u
d
a
n
e
e
.
ww
8RT
Average speed = Uav =
M
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(or) 0.9213 Urms
t
e
2 Marks Questions
n
.
a
n=5
h
b
i
T = 27 + 273 = 300 K
t
a
r
R = 8.314 J mol1 K1
3
= 5 300 8.314
2
p
u
d
= 18706.5 J
a
n
e
e
.
w
w
3
3
A: K.E.H : K.E.O = nH TR : nO TR
2
2
2
2
2
2
= nH : nO
2
2
WH WO
3
4
1
2
= 2 :
= : = 1.5 : = 12 : 1
2 32
8
MH MO
2
2
Q: Which of the gases diffuses faster among N2, O2, CH4? Why?
.
a
h
b
i
t
t
e
n
a
r
p
u
d
a
n
e
e
.
w w
Q: Give the ratio of R.M.S., Average, Most probable speeds of gas molecules.
A: UM.P. : UAV : UR.M.S
2RT
8RT
3RT
=
: :
M
M
M
= 2 : 8/ : 3
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Q: What is critical temperature? Give its value for CO2.
A: The temperature above which any gas cannot be liquified even by applying high
pressure.
t
e
TC of CO2 = 30.98C
n
.
a
h
b
i
t
a
r
p
u
d
a
n
e
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.
w
w
t
e
n
.
a
h
b
i
t
a
r
p
A: The force acting per unit length perperpendicular the line drawn.
Units: N m1 (in SI System)
du
a
n
e
e
.
ww
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