CHEMISTRY

(1) The coordination number of a metal crystallizing in a

hexagonal closed-packed structure is?
12
4
8
6
(2) An ionic compound has unit cell consisting of A ions at the
corners of a cube and B ions on the centres of the faces of
cube. The empirical formula of this compound is?
AB
A 2B
A 3B
AB3
(3) In a compound, atoms of element Y form ccp lattice and
those of element X occupy 2/3rd of tetrahedral voids. The
formula of the compound is?
X4Y3
X2Y3
X2Y
X3Y4
(4) Which of the following exists as covalent crystals in the solid
state?
Silicon
sulphur
phosphorus
iodine
(5) In which of the following crystals alternate tetrahedral voids
are occupied?
NACL
ZNS
CAF 2
NA2O
(6) The volume of atoms present in a face-centred cubic unit cell
of a metal is?
(r is the atomic radius)
20/3 pie r^3
24/3 pie r^3
12/3 pie r^3
16/3 pie r^3
(7) Copper crystallizes in fcc with a unit cell length of 361 pm.
What is the radius of copper atom?
108 pm
127 pm
157 pm
181
pm

(8) A solid has a bcc structure. If the distance of the closest

approach between two atoms is 1.73 A0. The edge length of
the cell is?
200 pm
under root(1.5) pm
142.2 pm
under root 2 pm
(9) In a face centred cubic lattice, atom A occupies the corner
positions and the atom B occupies the face centre positions. If
one atom of B is missing from one of the face centred points,
the formula of the compound is?
A2 B
AB2
A2B3
A2B5
(10)Experimentally it was found that a metal oxide has the
formula M0.98O. Metal M, is present as M2+ AND M3+ in its oxide.
Fraction of the metal which exists as M3+ would be (in %)?
4.08
6.05
5.08
7.01
(11) A mixture of A and B components show negative deviation
as,
Delta V mix is positive
A-B interaction is weaker than A-A and B-B interaction
Delta H mix is positive
A-B interaction is stronger than A-A and B-B interaction
(12) During depression of freezing point in a solution, the
following are in
equilibrium:
Liquid
Liquid
Liquid
Liquid

solvent, solid solvent

solvent, solid solute
solute, solid solute
solute, solid solvent

(13)The molecular mass of benzoic acid in benzene as

determined by depression
in freezing point method corresponds to?
ionization of benzoic acid

dimerization of benzoic acid

trimerization of benzoic acid
salvation of benzoic acid
(14)Lowering in vapour pressure is highest for?
0.2M urea

0.1M glucose

0.1M MgSO 4

0.1 M Bacl2

(15) Which aqueous solution exhibits highest boiling point?

0.015M glucose
0.01M Na2SO4

0.01M KNO3

0.015M urea

(16) At 270C, the osmotic pressure of a solution containing 4.0

gram solute (of
molar mass 246) per litre at 27 0C is?
(R=0.0821)
0.1 atm

0.4atm

0.2 atm

0.8atm

(17) A solution has an osmotic pressure of 0.821 atm at 300K. Its

concentration would be?
0.066M

0.66M

0.033M

0.33M

(18) The freezing point (in0C) of a solution containing 0.1 gram of

K3[Fe(CN)6] in 100 gram of water is? (MM=329 and Kf = 1.86)
- 2.3 X 10^-2
1.2 X 10^-2

- 5.7 X 10^-2

- 5.7 X 10^-3

(19) A 5.2 molal aqueous solution of methyl alcohol is supplied.

What is the mole fraction of methyl alcohol in the solution?
0.1

0.190

0.086

0.050

(20) In a 0.2 molal aqueous solution, of weak acid HX(the degree

of dissociation=0.3) the freezing point is?(given Kf = 1.85).
- 0.260C

+480C

-0.48 0C

-0.360C

(21) The correct relation between gibbs energy change in a

reaction and the corresponding equilibrium constant (Kc) is?
Delta G0=RT ln Kc
(-)Delta G0=RT ln Kc
Delta G=RT ln Kc
(-)Delta G=RT ln Kc
(22) The metal that cannot be produced on reduction of its oxide
is?
K

Mn

Cr

Fe

(23) The standard reduction potential values of three metallic

cations, X,Y and Z are 0.52, - 3.03, - 1.18 respectively. The order
of reducing power of the corresponding metals is?
Y>Z>X

X>Y>Z

Z>Y>X

Z>X>Y

(24) Limiting molar conductivities for nacl, kbr and kcl are
126,152,150 S cm^2 per mole respectively. The limiting molar
conductivity of nabr is?

302

176

278

128

(25) The amount of silver deposited on passing 2.0 faraday of

charge through an aqueous solution of AgNO3 is?
54gram

108 g

216 g

324 g

(26) Aluminium oxide can be electrolysed at 10000Cto furnish Al

metal.The cathode reaction is, Al 3+ + 3e -------------- Al. how
much electricity is required to prepare 5.12 kg of Al by this
method?(in coloumb)
5.49 X 107
5.49 X 1010

1.83 X 107

5.49 X 104

(27) The oxidation potential of a hydrogen electrode at pH = 10

and pH2=1 is?
0.51V

0.00V

0.59V

0.059V

(28) For the redox change,

Zn + Cu2+ ----------------- Zn2+ + Cu
Taking place in a cell of E0=1.10 volt. E

cell

for the cell would

be?
1.07 V

0.82 V

2.14 V

180 V

(29) Four successive member of the first row transition elements

are listed below. Which of them is expected to have the highest E 0
( M3+ / M2+) value?
Mn

Fe

Co

Cr

(30) The standard reduction potential of Cu2+ / Cu and Cu2+ / Cu+

are 0.337 and 0.153V respectively. The standard electrode
potential of Cu+/Cu half cell is?
0.184 V
0.490 V

0.872 V

0.521 V

PHYSICS
(1) On moving a charged particle of 20coulombs by 2 cm, 2 J of
work is done, then the potential difference between the points
is?
0.1V
8V
2V
0.5V
(2) The number of electrons to be put on spherical conductor of
radius 0.1 m, to produce an electric field of 0.036 N/C just
above the surface is?
2.4 X 105
2.5 X 10
2.6 X 105
2.7 X 105
(3) There are three concentric thin spheres of radius
a,b,c(a>b>c). The total surface charge densities on their
surfaces are +m,-m,+m respectively. The magnitude of
electric field at a distance r (distance from centre such that
a>r>b) is?( I have denoted the symbol epsilon knot by k)
1

m(b2- c2)
k . r2

m(a2 + b2)
k . r2

none of these

(4) A mercury drop of water has a potential V on its surface.

1000 such drops combine to form a new drop. Find the
potential on the surface of the new drop.
1V
10V
100V
1000V

(5) Three equal charges Q are placed at the vertices of an

equilateral triangle. What should be the value of a charge,
that when placed at the centroid, reduces the interaction
energy of the system to zero?
-Q/2
-Q/3
-Q/2(ROOT 3)
-Q/ROOT 3
(6) If the net electric field flux passing through a closed surface
is zero, then the electric field at the surface will be?
(a)0
(b)same at all places
(c) depends on the location of points
(d) infinite
(7) Electric potential V in space as a function of co-ordinates is
given by, V=
1/x + 1/y + 1/z. Then find the electric field intensity at
(1,1,1).
i +j +k
i +j k
i -j +k
- i +j +k
(8) An electric dipole is kept in the electric field produced by a
point charge.
Dipole will experience a force
Dipole will experience a torque
It is impossible to find a path(not closed) in the field on which
work required to move the dipole is zero.
Dipole can be in stable equilibrium
(9) Mark the wrong statement,
(a)Equipotential surface never cross each other
(b)For a uniformly charged non conducting sphere, the electric
potential at the centre of the sphere is 1.5 times that of the
surface.
(c)If potential in the certain region is non-zero constant, then
the electric field at that region will also be non-zero constant.
(d)Inside a spherically uniformly charged shell, the electric
field is zero but the electric potential is the same as that of the
surface.
(10) Particle A has charge +q and particle B has charge +4q,
each having the same mass m. When allowed o fall from rest

through the same potential difference, the ratio of their

speeds(va/vb) will be?
2/1

4/1
(11)Four equal charges Q are placed at the four corners of a
square of side a. The work done In removing a charge (- Q)
from the centre of the square to infinity is?(I have denoted
epsilon knot by k)
0
(root2)Q2
(root2)Q2
Q2
4 pie k a
pie k a
2 pie k a
(12)A point charge +q is places at the mid point of the cube of
side L. The electric flux emerging from the cube is?( I have
denoted epsilon knot by k)
q/k
0
6ql2
q
k
6l 2k
(13)Two point charges q and +q are located at points (0,0, - a)
and (0,0,a) respectively. What is the electric potential at
point(0,0,z)?( as usual k is epsilon knot here)
Q.a
Q.
2Q.a
2Q.a
2
2
2
4 pie k z
4 pie k a
4 pie k(z - a )
4 pie k(z2+
a2 )
(14)The magnitude of the electric field on the surface of a sphere
of radius r having a uniform surface charge density m is?(kepsilon)
m/k
m/2k
m/k r
m/2kr
(15)An electric dipole placed in a non-uniform electric field
experiences,
A force but no torque
A torque but no force
A force as well as a torque
Neither a force nor a torque.
(16)An electric dipole placed with its axis in the direction of a
uniform electric field experiences,

A force but no torque

A torque but no force
A force as well as a torque
Neither a force nor a torque.
(17)A hollow metallic sphere is charged such that the potential at
its centre is V. The potential at its surface of the sphere is?
Zero
V
more than V
less than
V
(18)Two metallic identical spheres A and B carrying equal
positive charge +q at a certain distance apart. The force of
repulsion between them is F. A third uncharged sphere of
same size is brought in contact with sphere A and then
removed. It is then brought in contact with sphere B and
removed. What is the new force of repulsion between A and B?
F
3F/8
F/2
F/4
(19)A particle of mass m and charge q is released from rest in a
uniform electric field E. The kinetic energy attained by the
particle after moving a distance x is?
qEx2
qE2x
qEx
q2Ex
(20)The magnitude of electric intensity at a distance x from a
charge Q is E. An identical charge is placed at a distance 2x
from it. Then the magnitude of the force it experiences is?
qE
2qE
qE/2
qE/4
(21)Two parallel plate capacitors of capacitances C and 2C are
connected in parallel and charged to a potential difference V
by a battery. The battery is then disconnected and the space
between the plates of the capacitor of capacitance C is
completely filled with a material of dielectric constant K. The
potential difference across the capacitors now becomes?
V/(K + 1)
2V/(K + 2)
3V/(K + 2)
3V/(K + 3)

(22)The plates of a parallel plate capacitor is charged to 100 V. A

2mm thick plate is inserted between the plates. Then to
maintain the same potential difference, the distance between
the capacitor plates is increased by 1.6mm. The dielectric
constant of the plate is?( This particular model of question is
very important..if you solve it, good.if you dont then make
sure that you learn the concept behind it very well).
5
1.25
4
2.5
(23)A parallel combination of 0.1 M ohm resistor and a 10 micro
farad capacitor is connected across a 1.5V source of negligible
resistance. The time(in seconds) required for the capacitor to
get charged up to 0.75V is approximately?
Infinite
loge 2
log10 2
zero
(24)Two identical metal plates are given positive charges Q1 and
Q2(<Q1) respectively. If they are brought close together to
form a parallel plate capacitor with capacitance C. the
potential difference between them is?
Q1 + Q2
Q1+Q2
Q1-Q2
Q1-Q2
2C
C
C
2C
(25)If the charge on a capacitor is increased by 2 coulomb, the
energy stored in it is increased by 21%. The original charge on
the capacitor(in coulomb Is)?
10
20
30
40
(26)A potential difference of 0.8 V is maintained between the
ends of the metal wire of length 1.0 m. The number density of
free electrons in the metal is 8.0 X 1028 per m3 and the
electrical conductivity of the metal is 6.4 X 10 7/ohm/metre.
Find the drift speed of the electrons.( in mili-metre per
second).

4mm/sec
7mm/sec

2mm/sec

3mm/sec

(27)A wire of resistance 5 ohm is drawn out so that its length is

increased to twice of its original length. Find the new
resistance if the wire.
10
20
30
40
(28)A wire is stretched to make it 0.1% longer. What is the %
change in its resistance?
0.1%
0.2%
0.3%
0.4%
(29)A galvanometer of resistance 20 ohm gives full scale
deflection wen a current of 1mA is passed through it. How will
you convert it to a voltmeter that can read voltages up to 5V?
High resistance connected in parallel of 4960 ohm
High resistance connected in series of 4980 ohm
High resistance connected in parallel of 4980 ohm
High resistance connected in series of 4960 ohm
(30)The effective resistance of a number of resistors connected
in parallel is x ohm. When one of the resistors is removed, the
effective resistance becomes y ohm. The resistance of the
resistor removed is?
x . y.
x.y
y-x
under root(xy)
x+y
y-x

If not for you, I wouldnt know

what true love really meant.
Id never feel this inner peace;
I couldnt be content.
If not for you, Id never have
the pleasures of romance.
Id miss the bliss, the craziness,

Of loves sweet, silly dance.

I have to feel your tender touch;
I have to hear your voice;
No other one could take your place;
Youre it; I have no choice.
I splash into the pleasure, all consuming;
Im joyfully insane,
my passion for you deep, and fully blooming;
Long after, sweet warm flickers still remain.
You make my body sizzle with your kisses,
And yet theres so much more;
My heart is kindled, too; It knows what bliss is,
This closeness that Ive never felt before.
My body and my heart belong to you;
Im peaceful and complete.
I see more adventures coming for us two,
we creatures of the tender chill and heat.
If not for you, Id be adrift;
I dont know what Id do;
Id be searching for my other half,
Incomplete, if not for you.