Documente Academic
Documente Profesional
Documente Cultură
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CONTENTS
MATERIALS .....................................................................................
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ABOUT TECNOCOMMERZ
INTRODUCTION
1
Let us introduce you the ACEQUISA-TECNOCOMMERZ group.
Since 1983, year that Acequisa was founded, we have been a specialist stockist
and supplier of bars, plates, flanges, tubes and fittings in special stainless steels,
superalloys of nickel, Cr and Mo, Titanium, tantalum, cupronickels and other special alloys. Developing our activity mainly throught the Iberian Peninsula (Spain
and Portugal).
In 2005, as an answer to a global demand, Tecnocommerz is created to export
more than 20 years experience in this field to international markets.
TECNOCOMMERZ
Ctra. Madrid-Irn, Km. 245 Naves Radial I, 2A/2B
09007 BURGOS
Telph. 00 34 947 47 51 48 Fax 00 34 947 47 51 49
E-mail: sales@tecnocommerz.com
info@tecnocommerz.com
N-620 MOTORWAY
BURGOS-VALLADOLID
N-620
BURGOS-VALLADOLID
Villalvilla
N-120
LEN-BURGOS
Towards
Madrid
N-1
N-620
Towards
Vitoria-Francia
Towards
Centro Urbano
N-1
MADRID-IRN
Towards
Vitoria-Francia
Towards N-623
Santander
Direccin
Madrid
Direccin
Vitoria-Francia
Direccin
Santander
Direccin
Vitoria-Francia
Villatoro
Villimar
N-623
SANTANDER-BURGOS
Towards
City Centre
Towards N-1
Vitoria-Francia
Roundabout
N-1
IRN-MADRID
Towards
Vitoria-Francia
Towards N-623
Santander
Toll
Motorway
Castaares
Traffic lights
Va Servicio
TECNOCOMMERZ
HOTEL
N-120
BURGOS-LOGROO
AUTOPISTA
BURGOS-FRANCIA
Va Servicio
Exit 2
Rubena - Villafra
Toll Motorway
13:35
N-1
Direccin
Santander
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Towards
Vitoria-Francia
N-623
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PRESENTATION
GLOSSARY
Annealed:
Metallurgical condition for products having undergone a special heat treatment that allows more
sophisticated metalworking techniques such as certain types of machining of forming.
In the case of austenitic and austeno-ferritic steels, this state corresponds to the solution annealed state.
Descaled rolled bars:
Hot processed peeled bars: 1X finishing as per EN 10088-3 (1C for the non-peeled black bars).
Ground bars:
Cold processed bars obtained by grinding; 2B an 2G finishing as per EN 10088-3 for the tolerances h9 and <h8 respectively.
Heat treated:
Metallurgical condition obtained by quenching + tempering.
Material number:
No. of the steel registered with the European Registration Office. The number is found in the STAHLEISENLIST N 9.
Mechanical properties:
1 MPa = 1 N/mm2.
For profiles and bars with a thickness < 35 mm having undergone a final cold run, the maximum
HB hardness values or the maximum tensile strength values can be respectively increased:
by 60 units and 150 MPa, and the minimum elongation value can be decreased to 10%, for
ferritic and martensitic steels.
by 100 units and 200 MPa, and the minimum elongation value can be decreased to 20%, for
austenitics.
EN 10088-3.
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QUALITY:
v
Trazability in all our products is
assured.
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Material
AISI 310S
AISI 316L
AISI 317L
AISI 317LMN
AISI 321
AISI 321 H
AISI 347
AISI410
AISI431
W.Nr, or
1,4841
1,4404
1,4438
1,4439
1,4541
1,4878
1,4550
1,4006
1,4057
S31254
AL-6XN
904L
1,4547; F44
1,4539
Duplex S31803
Ferralium 255
Super duplex F55
Super duplex S32750
1,4462; F51
1,4507; F61
1,4501
1,4410; F3
17-4PH
20Cb3
Hastelloy B3
Hastelloy C22
Hastelloy C276
Hastelloy C4
Incoloy 028
Incoloy 330
Incoloy 800
Incoloy 800H
Incoloy 800HT
Incoloy 825
Incoloy A286
Incoloy DS
Inconel 600
Inconel 601
Inconel 625
Inconel 718
Inconel X750
Monel 400
Monel K500
Niquel 200
Niquel 201
2,4060; 2,4066
2,4061; 2,4068
5 Nickels:
N02200
N02201
6 Exotic metals:
N50250.....
Niobium
Tantalo
Titanio Gr 1, 2 y 7
Zirconium
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PRODUCTS, we supply:
Round bars
Hexagon bars
Bored bars
Forged bars
Blanks and rings
Tube plates
Tubes
Plates
Flanges
Elbows
Tess
Reductions
Caps
Plates
Plates cutting according to your needs
11
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PRODUCTS, we supply:
Flanges ANSI-DIN
Fittings
Bolting according to your drawings
12
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PRODUCTS, we supply:
Flanges
Forgings
Special forgings
13
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PRODUCTS, we supply:
Collars
Forget fittings
Wire mesh
14
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PRODUCTS, we supply:
Special flanges
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PRODUCTS, we supply:
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1/8
10,3
1/4
13,7
10
3/8
17,1
15
1/2
21,3
20
3/4
26,7
25
33,4
32
1 1/4
42,2
40
1 1/2
48,3
50
60,3
65
2 1/2
73,0
80
88,9
3 1/2
101,6
100
114,3
125
141,3
150
168,3
200
219,1
250
10
273,0
300
12
323,8
350
14
355,6
400
16
406,4
450
18
457
500
20
508
22
559
600
24
610
NOTE:
5S
1,65
0,8
1,65
1,0
1,65
1,3
1,65
1,7
1,65
1,9
1,65
2,4
2,11
3,8
2,11
4,6
2,11
5,2
2,11
5,8
2,77
9,5
2,77
11,3
2,77
14,8
3,40
22,6
3,96
31,3
3,96
34,4
4,19
41,6
4,19
46,8
4,78
59,3
4,78
65,2
5,54
82,5
10 S
1,24
0,3
1,65
0,5
1,65
0,6
2,11
1,0
2,11
1,3
2,77
2,1
2,77
2,7
2,77
3,2
2,77
4,0
3,05
5,3
3,05
6,5
3,05
7,4
3,05
8,4
3,40
11,6
3,40
13,8
3,76
20,0
4,19
27,8
4,57
36,0
4,78
41,3
4,78
47,3
4,78
53,3
5,54
68,6
5,54
75,5
6,35
94,5
10
20
6,35
54,7
6,35
62,6
6,35
70,6
6,35
78,6
6,35
86,5
6,35
94,5
30
1,45
0,3
1,85
0,5
1,85
0,7
2,41
1,1
2,41
1,4
2,90
2,2
2,97
2,9
3,18
3,5
3,18
4,5
4,78
8,0
4,78
9,9
4,78
11,4
4,78
12,9
6,35
33,3
6,35
42,4
6,35
49,7
7,92
67,9
7,92
77,8
7,92
87,7
9,53
117,2
9,53
129,1
9,53
141,1
7,04
36,8
7,80
51,8
8,38
65,2
9,53
81,3
9,53
93,3
11,13
122,4
12,70
155,1
12,70
171,1
14,27
209,6
STD
40
60
XS
40 S
80 S
1,73
0,4
2,24
0,6
2,31
0,9
2,77
1,3
2,87
1,7
3,38
2,5
3,56
3,4
3,68
4,1
3,91
5,5
5,16
8,6
5,49
11,3
5,74
13,6
6,02
16,1
6,55
21,8
7,11
28,3
8,18
42,6
9,27
60,3
9,53
73,9
9,53
81,3
9,53
93,3
9,53
105,2
9,53
117,2
9,53
129,1
9,53
141,1
2,41
0,5
3,02
0,8
3,20
1,1
3,73
1,6
3,91
2,2
4,55
3,3
4,85
4,5
5,08
5,5
5,54
7,6
7,01
11,4
7,62
15,3
8,08
18,6
8,56
22,3
9,53
31,0
10,97
42,6
12,70
64,6
12,70
81,6
12,70
97,4
12,70
107,4
12,70
123,3
12,70
139,2
12,70
155,1
12,70
171,1
12,70
187,1
10,31
79,7
11,13
94,6
12,70
123,3
14,27
155,8
15,09
183,4
17,48
255,4
10,31
53,1
12,70
81,6
14,27
109,0
15,09
126,7
16,66
160,1
19,05
205,7
20,62
247,8
22,23
299,3
24,61
355,3
80
100
120
140
IDENTICAL TO XS-80S
O.D.
(MM)
IDENTICAL TO STD-40S
NPS
(INCH)
IDENTICAL TO 10S
DN
(MM)
IDENTICAL TO 5S
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15,09
96,0
17,48
132,1
19,05
158,1
21,44
203,5
23,83
254,6
26,19
311,2
28,58
373,8
30,96
442,1
15,09
75,9
18,26
114,8
21,44
159,9
23,83
195,0
26,19
245,6
29,36
309,6
32,54
381,5
34,93
451,5
38,89
547,7
11,13
28,3
12,70
40,3
14,27
54,2
18,26
90,4
21,44
133,1
25,40
187,0
27,79
224,7
30,96
286,6
34,93
363,6
38,10
441,5
41,28
527,0
46,02
640,0
20,62
100,9
25,40
155,2
28,58
208,1
31,75
253,5
36,53
333,2
39,67
408,3
44,45
508,1
47,63
600,6
52,37
720,2
160
XXS
4,75
2,0
5,56
2,9
6,35
4,3
6,35
5,7
7,14
7,4
8,74
11,1
9,53
14,0
11,13
21,4
7,47
2,6
7,82
3,7
9,09
5,5
9,70
7,9
10,15
9,7
11,07
13,4
14,02
20,4
15,24
27,7
13,49
33,5
15,88
49,1
18,26
67,6
23,01
111,3
28,58
172,3
33,32
238,8
35,71
281,7
40,49
365,4
45,24
459,4
50,01
564,8
53,98
672,3
59,54
808,2
17,12
41,0
19,05
57,4
21,95
79,2
22,23
107,9
25,40
155,2
25,40
187,0
Green values are wall thicknesses in mm, other values are weights in kg/m.
Specific steel weight used for calculation is 8.0.
Titanium weight is approximately 57% of the table values.
DN = Nominal Diameter. SI description of pipe size in mm.
NPS = Nominal Pipe Size - description of pipe size in inch.
O.D = Outside Diameter of pipe.
Sch5S and 10S do not permit threading according to ANSI B1.20.1.
Sch40S and 80S in the table are applicable up to and including 12.
17
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DIN.
AISI.
UNS.
AFNOR.
BS.
JIS
SS.
GOST
1.4000
403(410S)
S 41008
Z6C13
403 S17
SUS 403
2301
08Ch13
405
S40500
Z6CAI13
405 S17
SUS 405
410
430
S 41000
S43000
Z12C13
Z8C17
2302
2320
12Ch13
12Ch17
420
S42000
Z20C13
SUS 420J1
SUS 420J2
2303
20Ch13
1.4024
X15Cr13
410
S 41000
SUS 410J1
1.4028
1.4031
X30Cr13
X38Cr13
(X40Cr13)
X46Cr13
420
420
S 42000
S 42000
Z30C13
Z40C14
410 S21
430 S15
430 S17
420 S29
420 S37
420 S45
420 S29
410 S21
420 S45
SUS 410
SUS 430
1.4021
X6Cr13
(X7Cr13)
X6CrAl13
(X7CrAl13)
X10Cr13
X6Cr17
(X8CR17)
X20Cr13
SUS 420J2
SUS 420J2
2304
2304
30Ch13
40Ch13
420
S42000
420 S45
40Ch13
X20CrNi172
(X22CrNi17)
X6CrTi17
(X8CrTi17)
X6CrTi12
431
S43100
Z40C14
Z38C13M
Z15CN 16-02
431 S29
SUS 431
2321
20Ch17N2
XM8
430Ti
409
Z8CT17
SUS 430LX
08Ch17T
S 40900
Z6CT12
SUH 409
X5CrNi1810
(X5CrNi189)
X10CrNiS189
(X12CrNiS188)
X2CrNi1911
(X2CrNi 189)
(G-X2Cr189)
X12CrNi177
304/304H
S 30400
Z6CN18-09
409 S19
409 S17
304 S31
SUS 304
2332
08Ch18N10
303
S 30300
Z10CNF 18-09
303 S21
SUS 303
2346
304L
S 30403
2352
2333
03Ch18N11
S 30100
304 S12
304 C12
304 S11
301 S21
SCS 19
SUS304L
301
SUS 301
X2CrNiN 1810
X5CrNiMo17122
X2CrNiMo17132
(X2CrNiMo1810)
(G-X2CrNiMo1810)
X2CrNiMoN17133
(X2CrNiMoN1813)
X2CrNiMo18143
(X2CrNiMo1812)
304LN
316
316L
S 30453
S 31600
S 31603
Z2CN18-10
Z3CN19-10M
Z2CN18-09
Z12CN17-07
Z12Cn18-07
Z2CN18-10Az
Z6CND17-11
Z2CND 18-13
Z2CND17-12
304 S62
316 S16
316 S14
SUS 304LN
SUS 316
SUS 316L
2371
2347
2348
316LN
S 31653
Z2CND 17-13
SUS 316LN
2375
316L
S 31603
Z2CND 17-13
SCS 16
SUS 316L
2353
03Ch17N14M2
S 31600
Z6CND 17-12
SUS 316
2343
S 31703
Z2CND 19-15
316 S11
316 S12
316 S13
316 S16
316 S33
317 S12
SUS 317L
2367
S 31726
N 08310
S 44400
N 08925
Z2CND 19-15
317 S16
317 S16
SUS 317
2326
07Ch17N20M2D2T
1.4002
1.4006
1.4016
1.4034
1.4057
1.4510
1.4512
1.4301
1.4305
1.4306
1.4310
1.4311
1.4401
1.4404
1.4429
1.4435
1.4436
1.4438
1.4439
1.4449
1.4465
1.4505
1.4521
1.4529
X5CrNiMo17133
316
(X5CrNiMo1812)
X2CrNiMo18164
317L
(X2CrNiMo1816)
X2CrNiMoN17135 317LNM
X5CrNiMo1713
317
X1CrNiMoN25252
X5CrNiMoCuNb2018
440
X2CrMoTi182
X1NiCrMoCuN25206
08Ch11NYU
19
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Werkstoff-Nr.
DIN.
AISI.
UNS.
AFNOR.
BS.
JIS
SS.
GOST
1.4539
1.4541
X1NiCrMoCu25205
X6CrNiTi1810
(X10CrNiTi189)
904L
321
N 08904
S 32100
Z1NCDU25-2004
Z6CNT18-10
SUS 321
2562
2337
1Ch18N12T
1.4550
347
S 34700
Z6CNNb 18-10
SUS 347
2338
08Ch 18N12B
316Ti
N 08800
N 08028
S 31635
Z1NCDU31273Az
Z6CNDT 17-12
2350
10Ch17N13M2T
316 Cb
08Ch16N13M2B
318
310LC
HNV3
(405)
(430)
Z6CNDNb17-12
Z6CNDNb19-13
Z2CN25-20
Z8CA7
Z45CS9
Z10C13
Z10CAS18
1.4583
1.4586
1.4335
1.4713
1.4718
1.4724
1.4742
X6CrNiNb1810
(X10CrNiNb189)
X2NiCrAITi3220
X1NiCrMoCuN31274
X6CrNiMoTi17122
(X10CrNiMoTi1810)
X6CrNiMoNb17122
(X10CrNiMoNb 1810)
X10CrNiMoNb1812
X5CrMoCuNb2218
X1CrNi2521
X10CrAl7
X45CrSi93
X10CrAl13
X10CrAl18
321 S12
321 S20
(321 S31)
347 S17
347 S31
320 S31
320 S17
1.4749
1.4762
1.4821
1.4828
1.4833
1.4841
1.4845
X18CrN28
X10CrAl24
X20CrNiSi254
X15CrNiSi2012
X7CrNi2314
X15CrNiSi2520
X12CrNi2521
446-1
(446)
327
309
309S
314/310
310S
Z10CAS24
Z20CNS25-04
Z15CNS20-12
Z15CN24-13
Z12CNS25-20
Z12CN25-20
309 S24
310 S24
2361
Ch25
Ch24N12S1
20Ch25N20S2
10Ch23N18
1.4848
1.4864
(G-X40CrNiSi2520)
X12NiCrSi3616
330
N 08330
310 C40
Na 17
1.4871
X53CrMnNiN219
EV8
Z12NCS37-18
Z12NCS35-16
Z12NC37-18
Z52CMN21-09
SUH 1
SUS 430
SUH 21
SUH 309
SUS 3095
SUH 310
SUH 310
SUS 310S
SCH 21
SUH 330
1.4876
1.4876
1.4878
X10NiCrAlTi3320
X10CrNiAPTi3320
X12CrNiTi189
B163
B163
321H
N 08800
N 08810
Z8NC32-21
Z8NC32-21
Z6CNT18-12(B)
2337
1.4893
1.4362
1.4417
1.4460
X4CrNiMo2751
(X8CrNiMo275)
329
S 30815
S 32750
S 32304
S 31500
S 32900
NA 15(H)
NA 15
321 S20
(321 S12)
2368
2324
1.4462
X2CrNiMoN2253
S 31803
S 31200
S 31260
S 32550
S 32950
Z2CND22-05Az
1.4558
1.4563
1.4571
1.4580
20
401 S45
403 S17
430 S15
349 S54
SUH 35
SUH 36
NCF 8000
SUS 321
SUS 329J1
SCH 11
SCS 11
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The most suitable alloy for a given environment bearing in mind that no allowance is made for the effects
of heat transfer, erosion, galvanic effects or the influence of minor impurities present in mixtures.
2. Materials are rated according to the determined corosion rate in a particular environment:
A= Corrosion rate less than 0-1 mm/y.
B= Corrosion rate less than 0-5 mm/a but greater than 0-1 mm/y.
C= Corrosion rate greater than 0-5 mm/y.
Corrosion rates less than 0-5 mm/a (A and B rating) are acceptable for most chemical and process plant.
3. The information should not be taken as an implied recommendation for the use of a particular material
in a specific environment. It should not be a substitute for in plant trials with sample test coupons.
4. Concentrations refer to aqueous solution or mixtures of gases in air.
5. Environments are listed in alphabetical order.
6. This data is typical of results obtained in these environments. However, these alloys are not limited to
the corrosives, temperatures or concentrations given.
N.B. The A rating can be misleading in that very often the corrosion rate is very much less than 0-1 mm/y.
Where thin-walled material is to be used and only very low corrosion rates can be tolerated, more precise corrosion data should be obtained.
Media
Acetaldehyde
Acetic Acid
Acetic Anhydride
Acetone
Acetylene
Acrolein
Air 100
Alcohol-Allyl
Ethyl
Methyl
Allyl Chloride
Aluminium Chloride
AluminiumSulphate (Alum.)
Ammonia Liquid
Ammonium Bicarbonate
Ammonium Carbonate
Ammonium Chloride (dry)
Ammonium Hydroxide
Ammonium Nitrate
Ammonium Phosphate
Ammonium Sulphate
Amyl Acetate
Amyl Choride
Aniline
Barium Chloride
Barium Hydroxide
Beer
Concentration %
Temperature C
Nickel
200 & 201
alloy
400
alloy
600
alloy
800
alloy
825
99
0-99
100
0-100
100
100
100
100
100
100
100
100
0-100
0-100
0-20
0-20
100
0-30
0-40
5
0-40
100
100
100
0-40
100
0-50
40
30
30
100
150
100
A
30
30
30
30
0-30
30
30
100
30
20
100
70
80
100
100
30
30
30
100
1040
100
30
A
C
B
A
A
B
A
A
A
A
A
B
C
C
B
B
A
A
C
B
B
A
A
A
B
B
A
B
A
A
A
A
A
B
B
C
B
C
B
B
A
B
C
B
B
A
A
B
B
A
B
A
A
A
A
B
B
C
B
B
B
A
B
B
B
B
B
A
A
A
A
A
A
B
A
A
A
A
B
C
B
A
B
C
A
C
A
A
A
B
A
B
A
B
B
B
A
A
A
A
A
A
B
A
A
A
A
A
B
A
A
B
B
A
B
A
A
A
A
A
B
A
B
A
A
A
21
CATALOGO
14/11/05
13:35
Pgina 22
Media
Concentration %
Temperature C
Nickel
200 & 201
alloy
400
alloy
600
alloy
800
alloy
825
0-40
100
100
100
0-20
100
100
100
100
0-100
0-25
0-30
100
100
100
100
A
B
A
B
A
A
A
B
C
A
B
A
A
A
A
A
B
A
B
A
A
A
B
B
A
B
A
B
A
B
A
B
A
A
B
A
A
A
B
C
A
B
A
A
A
A
A
A
A
B
A
B
A
A
A
B
B
B
A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
B
A
A
A
A
Chlorine, Dry
Chlorobenzene
Chlorosulphonic Acid
Chloroform
Chromic Acid
Citric Acid
Coffee
Copper Sulphate
Cresylic Acid
Dichloretuane
100
100
100
100
0-100
100
0-30
100
100
100
100
All
100
100
100
100
100
100
100
0-30
25
20
0-100
0-100
100
30-100
0-40
All
All
100
0-100
30
30
30
100
100
50
30
30
30
100
30
100
90
30
450
30
See Sodium
Hydroxide
550
30
30
100
30
30
100
100
30
30
700
30
30
30
30
700
30
30
30
30
30
30
30
30
100
30
100
50
30
30
30
150
B
A
B
A
C
B
A
C
B
A
B
B
A
A
B
A
C
C
C
B
B
A
B
C
B
B
A
B
A
A
B
B
B
A
C
B
A
C
B
A
B
B
A
A
B
A
C
C
B
B
C
A
B
A
B
B
A
B
A
A
A
B
B
A
C
B
A
C
B
A
A
B
B
A
A
A
B
A
C
C
C
B
B
A
B
C
B
A
A
B
A
A
A
B
A
C
B
A
B
B
B
A
B
B
A
B
A
A
A
C
B
B
B
B
A
C
A
B
A
A
B
A
A
C
B
B
A
B
A
A
A
B
A
A
A
A
A
A
A
B
A
A
B
B
A
A
A
A
A
A
A
A
A
100
0-37
100
10-100
100
500
35
35
35
35
350
A
A
C
C
A
C
C
A
A
C
C
A
A
C
C
A
C
C
C
B
B
C
A
B
A
B
B
A
C
C
A
B
B
All
30
Ethyl Acetate
Ethyl Cellulose
Ethyl Chloride
Ethylene Dichloride
Ethylene Glycol
Fatty Acids
Ferric Chloride
Ferric Nitrate
Ferric Sulphate
Fluoboric Acid
Fluosilicic Acid
Formaldehyde
Formic Acid
Fuel Oil
FurfuraI
Gelantine
Glucose
Glutamic Acid
Glycerine
Glycerol
High Temperature Salt
(nitrate/nitrite)
Hydraulic Oil
Hydrazine
Hydrobromic Acid
Hydrochloric Acid
Hydrocyanic Acid
Hydrofluoric Acid
Hydrogen Peroxide
(acid free)
22
CATALOGO
14/11/05
13:35
Pgina 23
Media
Hydrogen Sulphide
Hydroquinone
Insulin
Lactic Acid
Lead Acetate
Lemon Juice
Linseed Oil
Lithium Chloride
Lithium Hydroxide
Magnesium Carbonate
Magnesium Chloride
Magnesium Hydroxide
Magnesium Nitrate
Magnesium Sulphate
Maleic Acid
Mercuric Chloride
Mercuric Cyanide
Mercuric lodide
Mercurous Nitrate
Mercury
Methyl Alcohol
Methyl Chloride
Methyl Ethyl Ketone
Milk
Mine Water
Molasses
Mono (sodium, potassium
or ammonium) Phosphate
Naphthenic Acid
Nickel Chloride
Nickel Nitrate
Nickel Sulphate
Nitric Acid
Nitrobenzene
Oils, Crude
Oils, Essential
Oils, Mineral
Oils, Palm
Oils, Peanut
Oils, Sulphonated
Oils, Vegetable
Oleic Acid
Oleum
Orange Juice
Oxalic Acid
Oxidising gases
Palmitic Acid
Paraffin
Petrol
Phenol
Phenol Sulphonic Acid
Phosphoric Acid
Phthalic Anhydride
Picric Acid
Potassium Bicarbonate
Potassium Carbonate
Potassium Chlorate
Potassium Chloride
Potassium Chromate
Concentration %
Temperature C
Nickel
200 & 201
alloy
400
alloy
600
alloy
800
alloy
825
0-20
All
100
80
20
All
100
All
10
All
0-50
All
All
30
All
All
All
All
All
All
0-100
100
All
All
All
All
150
35
35
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
100
100
30
100
30
65
30
B
A
C
B
A
A
A
A
A
A
A
C
B
B
C
C
C
C
B
B
A
C
B
B
A
A
A
A
A
A
C
A
B
C
C
C
C
A
A
B
A
A
A
A
A
A
A
A
B
A
B
C
C
C
B
A
B
A
B
A
A
A
A
A
A
A
A
B
C
C
C
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
C
B
C
A
A
A
B
B
C
A
A
A
B
B
C
A
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
All
100
All
All
All
0-65
100
100
100
100
100
100
100
100
100
100
20
All
All
100
100
100
100
100
100
0-25
25-85
100
100
0-30
All
All
All
0-30
30
30
30
30
30
30
80
100
30
30
30
30
30
30
30
30
30
30
30
C
30
35
30
30
30
30
85
30
30
30
30
30
30
30
A
B
B
C
B
C
C
B
A
A
A
A
A
A
A
B
C
A
C
1000
A
A
A
A
B
B
A
B
C
A
A
B
A
A
A
A
B
C
B
C
C
B
A
A
A
A
A
A
A
B
C
A
B
550
A
A
A
B
B
A
A
A
C
A
A
B
A
B
A
A
B
B
B
B
C
B
A
A
A
A
A
A
A
A
A
A
B
1100
A
A
A
A
B
A
C
A
C
A
A
B
A
A
A
A
B
B
B
A
B
B
A
A
A
A
A
A
A
A
B
A
C
1100
A
A
A
A
B
B
C
B
C
A
A
B
A
B
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
A
B
900
A
A
A
A
A
A
A
A
B
A
A
A
A
A
23
CATALOGO
14/11/05
13:35
Pgina 24
Media
Potassium Cyanide
Potassium Dichromate
Potassium Ferricyanide
Potassium Hydroxide
Potassium Nitrate
Potassium Sulphate
Propane
Salicylic Acid
Sea Water
Silicon Tetrachloride
Silver Nitrate
Soap
Sodium Acetate
Sodium Bicarbonate
Sodium Bisulphate
Sodium Bromide
Sodium Carbonate
Sodium Chloride
Sodium Hydroxide
Sodium Metaphosphate
Sodium Metasilicate
Sodium Nitrate
Sodium Peroxide
Sodium Phosphate
Sodium Sulphate
Sodinm Sulphide
Steam
Stearic Acid
Sugar (liquid)
Sulphuric Acid
Sulphurous Acid
Tall Oil
Tannic Acid
Tartaric Acid
Tetraphosphoric Acid
Toluene
Trichloroethylene
Turpentine
Urea
Vinegar
Vinyl Chloride
Water
Xylene
Zinc Ammonium Chloride
Zinc Chloride
Zinc Nitrate
Zinc Sulphate
24
Concentration %
Temperature C
Nickel
200 & 201
alloy
400
alloy
600
alloy
800
alloy
825
0-30
0-20
0-30
0-50
0-50
All
10
100
All
100
100
All
100
All
All
10
0-50
30
All
0-50
50-75
All
0-50
10
All
100
All
All
All
100
All
All
0-15
15-75
75-96
0-60
100
10
58
100
100
100
100
50-100
100
100
100
100
0-40
0-100
10
20
100
30
30
30
100
30
30
100
30
100
30
30
30
30
30
30
30
A
30
30
30
30
30
30
30
100
30
30
30
450
30
30
30
30
30
100
30
30
30
30
100
100
30
375
30
30
100
100
100
30
30
30
B
B
B
A
A
B
B
A
A
A
A
C
A
B
B
B
B
B
B
A
A
B
A
B
B
B
A
A
B
A
A
A
B
C
C
A
B
B
C
A
A
A
A
A
A
B
B
C
B
B
B
A
A
B
B
A
A
A
A
C
A
B
B
A
B
B
A
A
A
B
A
B
B
B
A
A
B
A
A
A
A
B
C
A
B
B
C
A
A
A
A
A
A
B
B
B
C
B
B
B
B
B
B
B
A
A
A
A
A
B
A
B
B
B
B
B
B
A
A
A
A
A
A
B
A
A
A
A
A
A
B
C
C
A
B
B
B
A
B
A
B
A
A
A
A
B
B
B
B
B
B
B
B
B
A
A
A
A
A
B
B
A
B
B
B
B
B
A
A
B
B
A
A
A
C
A
A
B
A
A
A
B
B
C
C
A
B
B
A
B
A
B
B
A
A
B
C
C
B
B
B
A
B
B
B
A
A
A
A
A
A
B
A
A
A
A
B
A
A
A
A
A
A
A
A
B
A
A
A
A
A
A
A
A
A
B
A
B
A
A
A
B
A
A
A
A
A
A
B
B
A
A
CATALOGO
14/11/05
13:35
Pgina 25
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
A
A
A
A
B
B
B
B
B
B
B
268
213, ASTM A 269, ASTM A 271, ASTM A
376, ASTM B 677
789, ASTM A 790
161, ASTM B 163, ASTM B 165, ASTM B
407, ASTM B 423, ASTM B 444, ASTM B
668, ASTM B 729, ASTM B 677
338, ASTM B 861, ASTM B 337
43, ASTM B 68, ASTM B 75, ASTM B 88
111, ASTM B 315, ASTM B 395, ASTM B
543
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
A
A
B
A
B
B
B
B
B
B
268
249,
673,
789,
464,
516,
704,
775
338,
467,
ASTM
ASTM
ASTM
ASTM
ASTM
A
B
B
B
B
167,
127,
424,
265
169,
ASTM
ASTM
ASTM
ASTM
A
B
B
B
312
167
622
466
TITANIUM
COPPER AND COPPER ALLOYS
ASTM
ASTM
ASTM
ASTM
ASTM
ASTM
A
B
A
B
B
B
312,
674,
790
468,
517,
705,
ASTM B 862
ASTM B 543, ASTM B 608
PLATES:
STAINLESS STEEL
NICKEL AND NICKEL ALLOYS
TITANIUM
COPPER AND COPPER ALLOYS
FITTINGS:
STAINLESS STEEL
NICKEL AND NICKEL ALLOYS
TITANIUM
COPPER AND COPPER ALLOYS
ASTM
ASTM
ASTM
ASTM
ASTM
A
B
B
B
B
276,
160,
408,
348
148,
ASTM A 479
ASTM B 166, ASTM B 164, ASTM B 335,
ASTM B 425, ASTM B 446, ASTM B 472
ASTM B 271
25
CATALOGO
14/11/05
13:35
Pgina 26
CATALOGO
14/11/05
13:35
Pgina 27
AISI
304-321
347-316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
3/4
Schedule
5S
10S
126
163
1
Schedule
5S
10S
99
171
1.1/4
Schedule
5S
10S
78
134
1.1/2
Schedule
5S
10S
68
112
2
Schedule
5S
10S
54
92
2.1/2
Schedule
5S
10S
57
84
3
Schedule
5S
10S
47
68
3.1/2
Schedule
5S
10S
41
59
141
141
159
127
144
152
116
134
149
106
129
146
98
126
145
95
126
145
91
126
144
88
125
143
85
123
142
82
121
140
80
120
136
77
117
128
74
115
119
72
111
103
64
108
89
51
71
75
40
44
60
28
32
47
21
24
35
15
17
26
12
13
20
8
10
16
6
8
13
112
112
126
101
114
120
91
106
117
84
102
115
78
100
115
75
100
144
72
99
114
70
99
113
67
98
112
65
96
111
63
94
107
61
93
101
59
90
94
57
188
82
51
85
70
40
55
59
31
34
47
22
25
36
17
18
27
12
14
20
9
10
16
7
8
12
5
7
10
88
88
99
79
90
95
72
84
93
66
81
91
61
79
91
59
79
90
57
78
90
55
78
90
53
77
89
51
76
87
50
75
85
48
73
80
46
71
74
45
69
65
40
67
55
31
43
46
24
27
152
152
171
137
155
164
125
144
160
114
139
157
106
136
156
102
136
156
98
135
155
95
134
154
91
133
153
88
131
151
86
129
146
83
127
138
80
123
128
77
120
111
69
116
96
55
76
81
43
48
17
19
28
13
14
21
9
10
16
7
8
12
5
6
10
4
5
8
31
34
50
23
25
38
17
19
28
13
14
22
9
11
17
7
9
14
69
69
78
62
71
75
57
66
73
52
63
72
48
62
71
46
62
71
45
62
71
43
61
70
41
60
70
40
59
69
39
59
67
38
58
63
36
56
58
35
54
51
31
52
43
24
34
36
19
21
29
13
15
22
10
20
17
7
8
12
6
6
10
4
5
7
3
4
6
60
60
68
54
62
65
49
57
63
45
55
62
42
54
62
40
54
62
39
53
62
37
53
61
36
53
61
35
52
60
34
51
58
33
50
55
32
49
51
31
47
44
27
45
38
21
29
31
16
18
25
12
13
19
9
17
14
6
7
11
5
5
8
3
4
6
2
3
5
48
48
54
43
49
52
39
45
50
36
44
49
33
43
49
32
43
49
31
42
49
30
42
49
29
42
48
28
41
48
27
40
46
26
40
43
35
39
40
24
38
35
21
36
30
16
23
25
13
14
20
9
10
15
7
7
11
5
5
8
4
4
6
2
4
5
2
6
4
51
51
57
46
52
54
41
48
53
38
46
52
35
45
52
34
45
52
33
45
52
31
45
51
30
44
51
29
43
40
28
43
49
27
42
46
27
41
42
26
40
37
23
38
32
17
24
26
14
15
21
10
11
16
7
8
12
5
6
9
4
4
7
3
3
5
2
3
4
41
41
47
37
42
44
34
39
43
31
38
43
29
37
42
28
37
42
27
37
42
26
36
42
25
36
42
24
35
41
23
35
40
22
34
37
22
33
35
21
32
30
18
31
26
14
20
21
11
12
17
8
9
13
6
6
10
4
5
7
3
3
5
2
3
4
1
2
3
36
36
41
32
37
39
29
34
38
27
33
37
25
32
37
24
32
37
23
32
37
22
32
37
21
31
36
21
31
36
20
30
35
19
30
33
19
29
30
18
28
26
16
27
22
12
17
18
9
11
15
7
7
11
5
5
8
4
4
6
3
3
5
2
2
4
1
2
3
184
184
207
165
187
197
150
174
193
138
168
190
128
164
189
123
164
188
119
163
187
115
162
186
110
160
185
107
158
182
103
155
176
100
153
166
97
149
154
93
144
134
84
140
117
67
93
99
52
58
79
38
42
62
28
31
46
21
23
35
16
18
27
11
14
21
8
11
17
145
145
163
130
148
155
118
137
152
108
132
149
101
129
148
97
129
148
94
128
148
90
128
147
87
126
145
84
124
143
81
122
139
79
120
131
76
117
121
74
114
106
66
110
91
52
72
77
40
45
61
29
32
48
22
24
36
16
18
27
12
14
21
9
10
16
6
9
13
119
119
134
107
121
128
97
113
125
89
108
123
83
106
122
80
106
122
77
106
121
74
105
121
71
104
120
69
102
118
67
101
114
65
99
108
63
96
100
60
93
87
54
90
75
42
59
63
33
37
50
24
26
39
18
10
29
13
14
22
10
11
17
7
8
13
5
7
11
103
103
112
91
102
111
84
96
102
73
94
101
73
94
101
62
94
101
62
94
102
62
94
101
72
94
101
61
85
101
53
85
94
53
85
94
51
82
85
51
88
75
40
76
69
34
52
54
28
39
43
20
25
32
12
7
25
11
12
19
9
10
15
6
7
11
4
6
9
82
82
92
74
84
88
67
78
86
61
75
84
57
73
84
56
73
84
53
73
84
51
72
83
49
71
82
47
70
87
46
69
78
44
68
74
43
66
69
41
54
60
37
62
51
29
40
43
22
25
34
16
18
26
12
13
20
9
10
15
7
8
11
5
6
9
3
8
7
74
74
84
67
76
80
61
70
78
55
68
77
51
66
76
50
66
76
48
66
76
46
65
75
44
65
74
43
64
70
42
63
71
40
62
67
39
60
62
38
58
54
33
56
46
26
36
38
20
22
31
14
16
24
11
12
18
8
9
13
6
7
10
4
5
8
3
4
6
60
60
68
54
62
65
49
57
64
45
55
62
42
54
62
40
54
62
39
54
62
38
53
61
36
53
61
35
52
60
34
51
58
33
50
55
32
49
51
31
47
44
27
46
38
21
29
31
16
18
25
12
13
19
9
10
14
6
7
11
5
5
8
3
4
6
2
3
5
53
53
59
47
54
57
43
50
55
39
48
54
37
47
54
35
47
54
34
47
54
33
46
53
31
46
53
30
45
52
29
45
51
28
44
48
28
43
44
27
41
38
24
40
33
18
25
27
14
16
21
10
11
17
7
8
12
5
6
9
4
5
7
3
3
6
2
3
4
27
CATALOGO
14/11/05
13:35
Pgina 28
28
AISI
304-321
347-316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
5
Schedule
5S
10S
38
47
6
Schedule
5S
10S
32
40
8
Schedule
5S
10S
24
30
10
Schedule
5S
10S
24
30
12
Schedule
5S
10S
25
27
14
Schedule
5S
10S
21
26
16
Schedule
5S
10S
20
33
32
32
36
29
33
50
26
30
34
24
29
33
22
28
33
21
28
33
21
28
33
20
28
32
19
28
32
18
27
32
18
27
31
17
26
29
17
26
27
16
25
23
14
24
20
11
15
16
8
9
13
6
7
10
4
5
7
3
3
5
2
3
4
2
2
3
1
2
2
34
34
38
31
35
45
28
32
36
25
31
35
24
30
35
23
30
35
23
30
35
21
30
34
20
30
34
20
29
34
19
29
33
18
28
31
18
27
28
17
27
25
15
25
21
12
16
17
9
10
14
6
7
11
5
5
8
3
4
6
2
3
4
2
2
3
1
2
3
28
28
32
26
29
31
23
27
30
21
26
29
20
25
29
19
25
29
19
25
29
17
35
29
17
25
28
16
24
28
16
24
27
15
24
26
15
23
24
14
22
21
13
21
18
10
14
14
7
8
11
5
6
9
4
4
7
3
3
5
2
2
4
1
2
3
1
1
2
22
22
24
19
22
23
18
21
23
16
20
22
15
19
22
14
19
22
14
19
22
13
19
22
13
19
22
12
18
21
12
18
21
12
18
20
11
17
18
11
17
16
9
16
13
7
10
11
6
6
9
4
4
7
3
3
5
2
2
4
1
2
3
1
1
2
1
1
2
21
21
24
19
22
23
17
20
22
16
19
22
15
19
22
14
19
22
14
19
22
13
19
22
13
19
21
12
18
21
12
18
21
11
18
19
11
17
18
11
17
15
9
16
13
7
10
11
5
6
9
4
4
7
3
3
5
2
2
3
1
2
3
1
1
2
1
1
2
22
22
25
20
23
24
18
21
23
17
20
23
15
20
23
15
20
23
15
20
23
14
20
22
13
19
22
13
19
22
12
19
21
12
18
20
11
18
19
11
17
16
10
17
14
7
10
11
6
6
9
4
4
7
3
3
5
2
2
4
1
2
3
1
1
2
1
1
2
17
17
21
17
19
20
15
18
20
14
17
20
13
17
20
13
17
19
13
17
19
12
17
19
11
16
19
11
16
19
10
16
18
10
16
17
10
15
16
9
15
14
8
14
12
6
9
9
5
5
8
3
4
6
2
3
4
2
2
3
1
1
2
1
1
2
0,9
1
1
16
16
20
16
18
19
14
17
18
13
16
18
12
16
18
12
16
18
15
16
18
11
15
18
10
15
18
10
15
17
10
15
17
9
14
16
9
14
15
9
14
13
7
12
10
5
8
8
4
5
6
3
3
5
2
2
4
1
2
3
1
1
2
1
1
1
0,7
1
2
47
47
53
42
48
37
38
54
49
35
42
48
32
42
48
31
42
48
31
42
48
29
41
47
28
41
47
27
40
46
26
39
45
25
39
42
24
38
39
24
37
34
21
35
29
16
22
24
12
14
19
9
10
15
7
7
11
5
5
8
4
4
6
2
3
5
2
3
4
42
42
47
38
43
31
34
40
44
31
38
43
29
38
43
28
37
43
28
37
43
26
37
43
25
37
42
24
36
42
23
35
40
23
35
38
22
34
35
21
33
31
19
32
26
14
20
21
11
12
17
8
9
13
6
7
10
4
5
7
3
4
6
2
3
4
1
2
3
35
35
40
32
36
38
29
33
37
26
32
36
24
31
36
23
31
36
23
31
36
22
31
36
21
31
35
20
30
35
20
30
34
19
29
32
18
28
29
18
28
26
16
26
22
12
17
18
9
10
14
7
7
11
5
5
8
3
4
6
3
3
5
2
2
4
1
2
3
30
30
33
27
30
32
24
28
31
22
27
31
21
26
30
20
26
30
20
26
30
18
26
30
18
26
30
17
25
29
17
25
28
16
25
27
15
24
25
15
23
22
13
22
18
10
14
15
8
9
12
5
6
9
4
4
7
3
3
5
2
2
4
1
2
3
1
1
2
26
26
30
24
27
38
22
25
28
20
24
27
18
24
27
18
24
27
18
24
27
16
23
27
16
23
27
15
23
26
15
22
25
14
22
24
14
21
22
13
21
19
12
20
16
9
13
13
7
8
11
5
5
8
4
4
6
2
3
4
2
2
3
1
1
3
1
1
2
24
24
27
22
25
26
20
23
25
18
22
25
17
22
25
16
21
25
16
21
25
15
21
25
14
21
24
14
21
24
14
20
23
13
20
22
13
20
20
12
19
18
11
18
15
8
11
12
6
7
10
4
5
7
3
4
5
2
2
4
2
2
3
1
1
2
1
1
2
21
21
26
21
23
25
19
22
24
17
21
24
16
21
24
15
20
24
15
20
23
14
20
23
14
20
23
13
20
23
13
19
22
12
19
21
12
19
19
11
18
17
10
17
14
8
11
12
6
7
7
4
5
7
3
3
5
2
2
4
2
2
3
1
1
2
1
1
2
18
18
23
18
20
22
16
19
21
15
18
21
14
18
21
13
18
21
13
18
20
12
18
20
12
17
20
11
17
20
11
17
19
11
17
18
10
16
17
10
16
15
9
15
9
7
9
10
5
6
8
4
4
6
2
3
4
2
2
3
1
1
2
1
1
2
0,9
1
1
CATALOGO
14/11/05
13:35
Pgina 29
-29 to 38
93
149
204
260
316
343
371
399
427
454
482
510
538
566
593
621
649
677
704
732
760
788
816
AISI
304-321
347-316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
3/4
Schedule
5S
10S
267
375
1
Schedule
5S
10S
250
345
1.1/4
Schedule
5S
10S
205
287
1.1/2
Schedule
5S
10S
185
265
2
Schedule
5S
10S
156
225
2.1/2
Schedule
5S
10S
170 236
3
Schedule
5S
10S
148
209
3.1/2
Schedule
5S
10S
135
193
291
291
327
262
297
312
238
276
305
218
265
300
202
260
298
195
259
298
188
258
298
181
257
295
174
254
292
169
250
288
164
246
279
159
242
264
153
236
244
148
229
213
134
224
186
108
151
160
85
94
128
61
68
100
46
51
75
34
37
56
26
29
44
18
22
35
14
18
28
237
237
267
213
242
255
194
225
249
178
216
245
165
212
243
159
211
248
154
211
243
148
209
240
142
207
238
138
203
235
134
201
228
129
197
215
125
192
199
121
186
173
109
181
151
87
121
129
68
75
103
49
54
80
37
41
60
27
30
45
21
23
35
15
18
28
11
15
22
222
222
250
200
226
238
182
210
233
166
202
229
154
198
228
149
198
227
144
197
227
138
196
225
133
194
223
129
190
220
125
188
213
121
184
201
117
180
186
113
174
162
101
169
141
81
113
120
63
70
96
46
50
75
34
38
56
25
28
42
19
21
33
14
16
26
10
14
21
182
182
205
164
186
196
149
173
192
137
166
188
127
163
187
123
163
187
118
162
187
114
161
185
109
159
183
106
157
181
103
154
175
99
152
165
96
148
153
96
143
133
83
139
116
66
92
97
51
57
78
37
41
61
28
31
46
20
23
34
16
17
27
11
13
21
8
11
17
164
164
185
148
167
176
134
156
172
123
150
169
114
147
168
110
146
168
106
146
168
102
145
166
98
143
165
95
141
162
92
139
158
89
136
149
86
133
138
83
129
120
75
125
104
59
82
87
46
51
70
33
37
54
25
27
41
18
20
30
14
16
24
10
12
19
7
10
15
138
138
156
124
141
148
113
131
145
104
126
143
96
123
142
93
123
141
89
123
141
86
122
140
83
121
139
80
119
137
78
117
133
75
115
125
73
112
116
70
108
101
63
105
87
49
69
73
38
43
58
28
31
45
21
23
34
15
17
25
12
13
20
8
10
15
6
8
12
151
151
270
136
154
162
124
143
159
113
138
156
105
135
155
101
135
155
98
134
155
94
133
153
91
132
145
88
130
150
85
128
145
82
126
137
80
122
127
77
119
111
69
115
95
54
75
80
42
47
64
30
34
50
23
25
37
17
18
28
13
14
22
9
11
17
7
9
14
131
131
148
118
134
141
107
124
138
98
120
135
91
117
135
88
117
134
85
116
134
82
116
133
79
114
132
76
113
130
74
111
126
71
109
119
69
106
110
67
103
96
59
99
83
47
65
69
36
40
55
26
29
43
20
22
32
14
16
24
11
12
19
8
9
15
6
8
12
120
120
135
108
122
129
98
113
126
90
109
123
83
107
123
80
107
122
77
106
122
74
105
121
72
104
120
69
103
118
67
101
115
65
99
108
63
97
100
61
94
87
54
91
75
42
59
63
33
37
50
24
26
39
18
20
29
13
14
22
10
11
17
7
8
13
5
7
11
406
406
458
366
415
437
333
385
427
305
371
420
283
364
417
273
362
416
263
361
416
254
359
412
244
355
409
236
349
403
229
344
390
222
338
368
214
329
342
207
320
229
189
316
263
156
218
232
122
136
185
88
98
144
66
73
109
49
54
81
38
42
64
27
32
50
20
27
40
333
333
375
300
340
358
273
316
350
250
308
344
232
298
342
224
297
341
216
296
341
208
294
338
200
291
335
194
286
330
188
282
320
182
277
302
176
270
280
170
262
244
154
253
214
125
175
186
98
109
148
71
78
116
53
59
87
39
43
65
30
33
51
21
26
40
16
21
32
306
306
345
276
313
329
251
291
322
230
280
317
213
274
315
206
273
314
199
272
314
191
270
311
184
268
308
178
263
304
173
259
294
167
255
278
162
248
258
156
241
224
141
236
196
115
160
170
90
100
136
65
72
106
49
54
80
36
40
60
28
31
47
20
24
37
15
20
30
255
255
287
229
260
274
209
242
268
191
233
263
177
228
262
171
227
261
165
226
261
159
225
259
153
223
256
148
219
252
144
216
245
139
212
231
134
207
214
130
200
187
117
195
163
94
131
139
73
82
111
53
59
86
40
44
65
29
32
49
22
25
38
16
19
30
12
16
24
234
234
265
220
230
244
162
223
242
172
212
232
165
209
236
151
202
230
152
202
230
145
202
230
135
202
230
132
195
224
132
195
224
125
195
215
125
185
195
112
181
165
107
171
143
84
112
124
65
73
103
43
52
72
34
44
56
22
26
41
20
22
34
11
15
24
10
12
20
200
200
225
180
204
215
164
189
210
150
182
206
139
179
275
138
178
204
129
177
204
124
176
203
120
174
201
116
171
198
112
169
192
109
166
181
105
162
168
107
159
146
91
152
127
72
101
107
56
63
86
41
45
67
31
34
50
22
25
38
17
19
29
12
17
23
9
12
18
209
209
236
189
214
225
178
199
220
157
191
216
146
187
215
141
187
214
136
186
214
131
185
213
126
184
211
122
180
208
118
177
201
114
174
190
110
170
176
107
165
153
96
160
133
76
106
113
60
66
90
43
47
70
32
36
53
24
26
40
18
20
31
13
15
24
10
13
20
185
185
209
167
189
199
152
176
195
139
169
192
129
166
191
125
165
190
120
165
190
116
164
188
111
162
187
108
159
184
105
157
178
101
154
168
98
150
156
94
146
136
85
141
118
67
93
99
52
58
79
38
42
62
28
31
46
21
23
35
16
18
27
11
16
21
8
11
17
171
171
193
154
175
184
140
162
180
128
156
177
119
153
176
115
153
175
111
152
175
107
151
174
103
150
172
100
147
170
96
145
164
93
142
155
90
139
144
87
135
125
78
130
108
62
86
91
48
54
73
35
38
57
26
29
43
19
21
32
15
16
25
10
14
20
8
10
16
29
CATALOGO
14/11/05
13:35
Pgina 30
30
304-321
347-316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
304
321-347
316
5
Schedule
40S
80S
110
162
6
Schedule
40S
80S
100
156
8
Schedule
40S
80S
88
138
10
Schedule
40S
80S
79
110
12
Schedule
40S
80S
68
92
14
Schedule
40S 80S
62
84
16
Schedule
40S
80S
54
73
111
111
125
100
113
119
91
105
117
83
101
115
77
99
114
75
99
114
72
99
113
69
98
113
67
97
112
64
95
110
63
94
107
60
92
101
58
90
93
56
87
81
50
84
70
39
55
58
31
34
46
22
24
36
16
18
27
12
13
20
9
10
16
6
8
12
5
6
10
97
97
110
88
92
105
80
92
102
73
89
101
68
87
100
65
87
100
63
86
99
61
86
99
58
85
98
56
84
96
55
82
93
53
81
88
51
79
82
49
76
71
44
74
61
34
48
51
27
30
40
19
21
31
14
16
24
10
12
18
8
9
14
6
7
11
4
6
9
88
88
100
80
90
95
72
84
93
66
81
91
61
79
91
59
79
91
57
78
90
55
78
90
53
77
89
51
76
88
50
75
85
48
73
80
46
72
74
45
69
65
40
67
55
31
43
46
24
27
37
17
19
28
13
14
21
9
10
17
7
8
12
5
6
10
4
5
8
78
78
88
70
79
84
64
74
82
58
71
80
54
70
80
52
70
80
50
69
79
48
69
79
46
68
78
45
67
77
44
66
75
42
65
70
41
63
65
39
61
57
35
59
49
27
38
40
21
23
32
15
17
25
11
12
19
8
9
14
6
7
11
4
5
8
3
4
7
70
70
79
63
72
76
58
67
74
53
64
73
49
63
72
47
63
72
46
63
72
44
62
72
42
62
71
41
60
70
40
60
68
38
59
64
37
57
59
36
55
52
32
53
44
24
34
36
19
21
29
14
15
23
10
11
17
7
8
13
6
6
10
4
5
8
3
4
6
61
61
68
55
62
65
50
58
64
46
55
63
42
54
62
41
54
62
39
54
62
38
34
62
36
53
61
35
52
60
34
51
58
33
50
55
32
49
51
31
48
44
27
46
38
21
29
31
16
18
25
12
13
19
9
10
14
6
7
11
5
5
8
3
4
6
2
3
5
55
55
62
50
56
59
45
52
58
41
50
57
38
49
57
37
49
57
36
49
56
34
49
56
33
48
56
32
47
55
31
47
53
30
46
60
29
45
46
28
43
40
25
41
34
19
27
28
15
16
23
9
10
15
8
9
13
6
6
10
4
5
7
3
4
6
2
3
5
48
48
54
43
49
52
39
46
51
36
44
50
33
43
50
32
43
49
31
43
49
30
42
49
29
42
48
28
41
48
27
37
46
26
40
44
25
39
40
24
38
35
21
36
30
16
23
25
13
14
20
8
9
9
7
7
11
5
5
8
4
4
6
2
3
5
2
2
4
161
161
181
145
164
173
132
152
169
121
147
166
112
144
165
108
143
165
104
143
164
100
142
163
96
140
162
93
138
159
91
136
154
88
134
146
85
130
135
82
126
118
73
122
102
58
80
85
45
50
68
32
36
53
24
27
40
18
20
30
14
15
28
9
12
18
7
10
15
144
144
162
118
136
155
118
136
151
108
131
149
100
129
148
97
128
147
93
128
147
90
127
146
86
126
145
84
123
143
81
122
138
78
120
130
76
116
121
73
113
105
65
109
91
51
72
76
40
45
61
29
32
47
22
24
35
16
18
27
12
13
21
9
10
16
6
9
13
139
139
157
125
142
149
114
132
146
104
127
144
97
124
143
93
124
142
90
123
142
87
123
141
83
121
140
81
119
138
78
118
133
76
115
126
73
113
117
71
109
102
63
105
88
49
69
73
39
43
59
28
31
46
21
23
34
15
17
26
12
13
20
8
10
16
6
8
13
123
123
138
110
125
132
101
116
129
92
112
127
85
110
126
82
109
126
79
109
125
77
108
125
74
107
124
71
105
122
69
104
118
67
102
111
65
69
103
62
96
90
56
93
77
43
61
64
34
38
52
24
27
40
18
20
30
13
15
22
10
11
18
7
9
14
5
7
11
98
98
110
88
100
105
80
93
103
73
89
101
68
87
100
65
87
100
63
87
100
61
86
99
58
85
98
57
84
97
55
83
94
53
81
88
51
79
82
50
77
71
44
74
61
34
48
51
27
30
41
19
21
32
14
16
24
10
12
18
8
9
14
6
7
11
4
6
9
82
82
92
74
84
88
67
78
86
61
75
84
57
73
84
55
73
84
53
73
84
51
72
83
49
71
82
47
70
81
46
69
79
44
68
74
43
66
69
42
64
60
37
62
51
29
40
42
22
25
34
16
18
26
12
13
20
9
10
15
7
7
11
5
6
9
3
5
7
74
74
84
67
76
80
61
70
78
56
68
77
52
66
76
50
66
76
48
66
76
46
65
75
44
65
75
43
64
74
42
63
71
40
62
67
39
60
92
38
58
54
33
56
46
26
36
38
20
22
31
14
16
24
11
12
18
8
9
13
6
7
10
4
5
8
3
4
6
65
65
73
58
66
70
53
61
68
48
59
67
45
58
66
43
58
66
42
58
66
40
57
66
39
56
65
37
55
64
36
55
62
35
54
59
34
52
54
33
51
47
29
49
40
22
31
33
17
19
27
11
12
18
9
10
15
7
7
11
5
6
9
3
4
7
2
3
5
CATALOGO
14/11/05
13:35
Pgina 31
Bwg
in
mm
Bwg
in
mm
0
1
2
3
4
5
6
7
8
9
10
11
12
.340
.300
.284
.259
.238
.220
.203
.180
.165
.148
.134
.120
.109
8.636
7.620
7.213
6.578
6.045
5.588
5.156
4.572
4.190
3.759
3.403
3.048
2.768
13
14
15
16
17
18
19
20
21
22
23
24
25
.095
.083
.072
.065
.058
.049
.042
.035
.032
.028
.025
.022
.020
2.413
2.108
1.829
1.651
1.473
1.244
1.067
0.889
0.812
0.711
0.635
0.559
0.508
Swg
in
mm
Bwg
in
mm
0
1
2
3
4
5
6
7
8
9
10
11
12
.324
.300
.276
.252
.232
.212
.192
.176
.160
.144
.128
.116
.104
8.230
7.620
7.010
6.401
5.893
5.385
4.877
4.470
4.064
3.658
3.251
2.946
2.642
13
14
15
16
17
18
19
20
21
22
23
24
25
.092
.080
.072
.064
.056
.048
.040
.036
.032
.028
.024
.022
.020
2.337
2.032
1.829
1.626
1.422
1.219
1.016
0.914
0.813
0.711
0.610
0.559
0.508
10
31
CATALOGO
14/11/05
13:35
Pgina 32
CATALOGO
14/11/05
13:35
Pgina 33
WEIGHT OF FITTINGS
NOTE:
All weights in this section are based on approximate weights for steel.
Titanium weights can be calculated as 57% of the table values.
TYPE
SIZE INCHES
1/8
1/4
3/8
1/2
3/4
1 1/4
1 1/2
SIZE METRIC
10
15
20
25
32
40
50
Round Nipples
0,023
0,04
0,055
0,1
0,2
0,242
0,405
0,56
Hexagon Nipples
0,032
0,04
0,072
0,1
0,16
0,24
0,38
0,455
0,55
Reducing Nipples
0,038
0,055
0,09
0,142
0,205
0,35
0,405
0,51
End Caps
0,026
0,04
0,06
0,106
0,14
0,34
0,454
0,7
1,3
Unions
0,16
0,16
0,21
0,325
0,5
0,9
1,12
1,45
2,19
#Hexagon
90 Elbows
0,16
0,135
0,27
0,41
0,61
1,25
1,6
2,55
45 Elbows
0,12
0,11
0,23
0,34
0,555
0,85
1,4
2,1
Tees
0,255
0,225
0,325
0,6
0,8
1,41
1,4
2,27
3,05
*Reducing Tees
0,25
0,4
0,7
0,98
1,73
2,01
2,605
3,4
Welding Bosses
0,053
0,085
0,15
0,22
0,316
0,705
0,998
1,44
Couplings
0,035
0,05
0,08
0,15
0,22
0,31
0,71
1,05
1,5
Reducing Couplings
0,07
0,105
0,185
0,285
0,396
0,872
1,4
1,71
Half Couplings
0,02
0,024
0,035
0,075
0,15
0,2
0,335
0,5
0,71
TYPE
SIZE INCHES
1/8
1/4
3/8
1/2
3/4
1 1/4
1 1/2
SIZE METRIC
10
15
20
25
32
40
50
0,025
0,035
0,054
0,08
0,18
0,19
0,23
0,455
*Hexagon Bushes
0,009
0,016
0,029
0,057
0,095
0,172
0,255
0,4
0,58
0,029
0,029
0,057
0,085
0,142
0,227
0,51
0,624
1,021
0,057
0,057
0,085
0,113
0,17
0,34
0,51
0,709
1,361
11
33
CATALOGO
14/11/05
13:35
Pgina 34
APPROXIMATE WEIGHTS IN Kg
SIZE INCHES
1/8
1/4
3/8
1/2
3/4
1 1/4
1 1/2
SIZE METRIC
10
15
20
25
32
40
50
Couplings
0,039
0,05
0,06
0,115
0,18
0,25
0,4
0,48
0,8
#Reducing Couplings
0,066
0,071
0,132
0,22
0,325
0,44
0,575
1,3
Half Couplings
0,04
0,054
0,085
0,135
0,17
0,32
0,485
0,6
1,02
Tees
0,265
0,21
0,255
0,31
0,325
0,6
0,85
1,29
1,9
*Reducing Tees
0,289
0,323
0,415
0,448
0,81
1,32
1,675
2,55
Welding Bosses
0,072
0,085
0,135
0,205
0,3
0,41
0,56
1,225
End Caps
0,02
0,035
0,058
0,085
0,13
0,21
0,3
0,475
0,73
90 Elbows
0,155
0,13
0,13
0,225
0,29
0,5
0,75
1,1
1,7
45 Elbows
0,072
0,06
0,085
0,18
0,222
0,36
0,555
0,85
1,2
Unions
0,157
0,157
0,188
0,28
0,45
0,775
1,2
1,4
2,25
34
CATALOGO
14/11/05
13:35
Pgina 35
WEIGHT OF FITTINGS
(ANSI B16.11) 6000 LBS SOCKET-WELD FITTINGS
TYPE
APPROXIMATE WEIGHTS IN Kg
SIZE INCHES
1/8
1/4
3/8
1/2
3/4
1 1/4
1 1/2
SIZE METRIC
10
15
20
25
32
40
50
0,085
0,13
0,205
0,275
0,48
0,68
1,05
1,95
Couplings
#Reducing Couplings
0,1
0,148
0,272
0,355
0,5
0,75
1,275
2,2
Half Couplings
0,094
0,15
0,25
0,34
0,65
0,751
2,1
Tees
0,675
1,2
1,58
1,8
3,005
3,6
*Reducing Tees
0,805
1,359
1,85
2,3
3,68
4,15
Welding Bosses
0,09
0,135
0,2
0,27
0,4
0,6
1,78
End Caps
0,105
0,175
0,188
0,23
0,41
0,63
0,8
1,4
90 Elbows
0,4
0,628
1,4
2,35
45 Elbows
0,369
0,58
0,905
1,125
2,125
2,6
APPROXIMATE WEIGHTS IN Kg
SIZE INCHES
1/8
1/4
3/8
1/2
3/4
1 1/4
1 1/2
SIZE METRIC
10
15
20
25
32
40
50
0,040
0,054
0,085
0,135
0,170
0,320
0,485
0,600
0,925
0,105
0,130
0,180
0,225
0,290
0,550
0,80
1,100
1,400
0,170
0,215
0,285
0,325
0,501
0,750
0,951
1,600
2,100
APPROXIMATE WEIGHTS IN Kg
SIZE INCHES
1/8
1/4
3/8
1/2
3/4
1 1/4
1 1/2
SIZE METRIC
10
15
20
25
32
40
50
Round Nipples
0,191
0,272
0,43
0,716
1,008
Hexagon Nipples
0,045
0,06
0,08
0,12
0,195
0,3
0,48
0,493
0,61
#Hexagon Reducing
Nipples
0,04
0,055
0,07
0,085
0,138
0,275
0,39
0,3
0,504
Couplings
0,08
0,085
0,105
0,2
0,45
0,945
1,85
3,4
Reducing Couplings
0,088
0,105
0,126
0,245
0,509
1,35
1,455
2,222
3,955
Half Couplings
0,06
0,065
0,08
0,115
0,225
0,454
0,525
0,95
1,6
End Caps
0,06
0,065
0,085
0,145
0,2
0,335
0,585
0,75
1,45
90 Elbows
0,285
0,275
0,475
0,7
1,6
3,05
3,4
9,4
45 Elbows
0,265
0,245
0,225
0,625
0,95
1,12
2,125
2,6
4,3
Tees
0,48
0,425
0,6
0,9
1,65
2,1
3,5
4,4
8,5
*Reducing Tees
0,6
0,78
1,2
2,34
4,05
4,94
10,4
Welding Bosses
0,085
0,115
0,21
0,46
0,9
1,1
1,85
3,25
35
CATALOGO
14/11/05
13:35
Pgina 36
WEIGHT OF FITTINGS
90 ELBOWS, BUTT-WELD FITTINGS (LONG RADIUS)
N.B. SIZE
APPROXIMATE WEIGHTS IN Kg
Inches Metric
Sch
Sch
Sch
Sch
Sch
Sch
Std
Sch
Sch
Sch
5s
10s
10
20
30
40s
Wall
40
60
80s
XS
Sch
Sch
Sch
Sch
Sch
80
100 120
140
160
XXS
1/2
15
0,03
0,05
0,06 0,06
0,09
0,09
0,12
0,12
3/4
20
0,04
0,07
0,08 0,08
0,11
0,11
0,15
0,15
25
0,07
0,14
0,15 0,15
0,2
0,2
0,28
0,38
11/4
32
0,1
0,23
0,26 0,26
0,35
0,35
0,44
0,6
1 /2
40
0,15
0,3
0,4
0,4
0,55
0,55
0,65
0,95
50
0,3
0,5
0,7
0,7
0,95
0,95
1,4
1,7
2 /2
65
0,55
0,85
1,4
1,4
1,5
1,5
2,5
3,2
80
1,25
2,5
2,5
2,9
2,9
3,75
5,5
3 /4
90
1,2
1,65
100
1,6
2,1
7,5
125
2,7
3,65
6,8
6,8
9,3
9,3
12,7
15
18
150
4,4
5,45
11
11
16,8
16,8
23
26
29,5
200
8,8
10,2
17,25
19
22
22
55
54
10
250
16,8
18,15
25,85
33,15
41,5
12
300
24
27,25
37,2
49
60
14
350
28
39,95
50
59
70
70
16
400
38
51,6
64
78,3
95
95
95
125
18
450
48
65,4
82
99,85 139,15
120
120 176,15
20
500
58,4
84,9
100
146
194
146
146 228,35
311
194
22
550
120
24
600
88
146
146
220
318,25
220
532,5
282
36
27,25
34,8
34,8
53,9
53,9
61,16
75
60
61,25
81,7
80
80
107,4
123 140
157
180
70
83
109
94
94
135
188 190
224
247,45
162
125
125
202
260 274
323
367
231,5
158
422
545
607
770
220 363,15
236
40,5
52
85
97
109
8
12
53,9
177,97
38
1270
CATALOGO
14/11/05
13:35
Pgina 37
APPROXIMATE WEIGHTS IN Kg
Inches Metric
1/2
3/4
1
11/4
11/2
2
21/2
3
31/2
4
5
6
8
10
12
14
16
18
20
22
24
15
20
25
32
40
50
65
80
90
100
125
150
200
250
300
350
400
450
500
550
600
Sch
Sch
Sch
Sch
Sch
Sch
Std
Sch
Sch
Sch
5s
10s
10
20
30
40s
Wall
40
60
80s
11,35
21,35
33,15
52,5
71,25
92,15
135,8
214,3
0,05
0,06
0,11
0,18
0,3
0,53
1,05
1,88
2,25
3
5,1
8,25
16,5
31,13
45
52,5
71,25
90
109,5
165
0,05
0,06
0,11
0,18
0,3
0,53
1,05
1,88
2,25
3
5,1
8,25
16,5
31,13
45
52,5
71,25
90
109,5
165
0,02
0,03
0,05
0,08
0,11
0,23
0,41
0,75
0,9
1,2
2,03
3,3
6,6
12,45
18
21
28,5
36
43,8
66
0,04
0,05
0,1
0,17
0,23
0,38
0,64
0,94
1,24
1,58
2,74
4,09
7,65
11,1
13,61
17,35
20,44
25
29,96 37,5 39,5
38,7 48 52,2
49,05 61,5 65,35
63,68 75 109,5
90
0,07
0,8
0,15
0,26
0,39
0,67
1,05
2,03
2,8
4,2
6,5
11,75
18,15 24,35
37,7 37,7
48
54,5
56
54,45
74
66
104,3 106,7 104,3
118 154,35 110,6
154,35 208 135,8
XS
Sch
Sch
Sch
Sch
Sch
80
100 120
140
160
XXS
0,07
0,8
0,15
0,26
0,39
0,67
1,05
2,03
2,8
4,2
4,5
6,5
9
11,75
13,5
24,35
26,35 29
32
37,7 40,85 50 53
62
56
68 81,25 92
99
66 93,5 124 120 138,8
104,3 138 171,5 166 198
110,6 193 257,4 283 387
135,8 261 332 376 430
37
CATALOGO
14/11/05
13:35
Pgina 38
WEIGHT OF FITTINGS
45 ELBOWS, BUTT-WELD FITTINGS
N.B. SIZE
APPROXIMATE WEIGHTS IN Kg
Inches Metric
1/2
3/4
1
11/4
11/2
2
21/2
3
31/2
4
5
6
8
10
12
14
16
18
20
22
24
15
20
25
32
40
50
65
80
90
100
125
150
200
250
300
350
400
450
500
550
600
Sch
Sch
Sch
Sch
Sch
Sch
Std
Sch
Sch
Sch
5s
10s
10
20
30
40s
Wall
40
60
80s
0,02
0,02
0,04
0,05
0,08
0,15
0,28
0,5
0,6
0,8
1,35
2,2
4,4
8,3
12
14
19
24
29,2
44
0,03
0,04
0,07
0,11
0,15
0,25
0,43
0,63
0,83
1,05
1,83
2,73
5,1
9,08
13,63
20
25,8
32,7
42,45
73
10
15,85
24,5
35
47,5
69,45
97
159
0,03
0,04
0,08
0,13
0,2
0,35
0,7
1,25
1,5
2
3,4
5,5
11
20,75
30
35
47,5
60
73
110
0,03
0,04
0,08
0,13
0,2
0,35
0,7
1,25
1,5
2
3,4
5,5
11
20,75
30
35
47,5
60
73
88,98
110
25
32
41
50
60
73
10
18,5
24,75
37
46,5
56
73
110
0,05
0,06
0,1
0,18
0,28
0,46
0,75
1,45
2
3
4,65
8,4
13,6 17,4
29,95 26,95
30,85 40,85
40
40,85 54,5
47
62,5
81
62,5
87,15 115,75 79
113,5 155,5
97
XS
0,05
0,06
0,1
0,18
0,28
0,46
0,75
1,45
2
3
4,65
8,4
17,4
26,95
40
47
62,5
79
97
118
141
Sch
Sch
Sch
Sch
Sch
80
100 120
140
160
26
48,5
78,5
112
161,5
211
303,5
545
0,06
0,08
0,14
0,22
0,33
0,7
1,25
1,88
4,5
7,5
13
27,5
54,4
90
123,73
183
272,5
385
635
0,06
0,08
0,19
0,3
0,48
0,85
1,6
2,75
4
5,1
9
14,75
27
XXS
30,58
53,7
67,5
101
145,25
195,23
333,93
19
37,5
61,5
94
130
195
238
410
3,75
6,35
11,5
20,25
42,5
70
95
137
202,5
254
477
Sch
Sch
Sch
Sch
Sch
80
100 120
140
160
XXS
APPROXIMATE WEIGHTS IN Kg
Inches Metric
1/2
3/4
1
11/4
11/2
2
21/2
3
31/2
4
5
6
8
10
12
14
16
18
20
22
24
38
15
20
25
32
40
50
65
80
90
100
125
150
200
250
300
350
400
450
500
550
600
Sch
Sch
Sch
Sch
Sch
Sch
Std
Sch
Sch
Sch
5s
10s
10
20
30
40s
Wall
40
60
80s
5
8
13
16
21
30
42
74,5
0,03
0,06
0,1
0,14
0,2
0,25
0,35
0,7
1
1,1
2
3
5,5
9
15
16
21
26
34
52
0,03
0,06
0,1
0,14
0,2
0,25
0,35
0,7
1
1,1
2
3
5,5
9
15
16
21
26
34
42
52
7
13,6
25,5
38
52,5
66
94,5
120
0,05
0,09
0,13
0,19
0,23
0,3
0,45
0,85
1,3
1,6
2,7
4,4
8,35
13,6
22,5
27
31,5
36
42
60
0,01
0,02
0,04
0,05
0,08
0,1
0,14
0,25
0,4
0,43
0,8
1,2
2,2
3,6
6
6,4
8,4
10,4
13,6
20,8
0,01
0,02
0,05
0,07
0,1
0,13
0,18
0,36
0,5
0,55
1
1,5
2,75
4,45
7,5
8,17 14
10,67 18
13
22
17
29
35,5
26
44
4,5
6
10
13,5
18
22
34
52
19
24,5
31,5
42
56,75
96,5
XS
0,05
0,09
0,13
0,19
0,23
0,3
0,45
0,85
1,3
1,6
2,7
4,4
8,35
13,6 16,25
22,5 29,5
27 36,3
31,5 52,25
36 72,5
42 98,5
51
60
150
11
21
32,5
50
64
75
96
118
2,5
4
6
15,5 18,5
30
28
41
42
47
52
59
73
88
93
105 153
200 250
0,15
0,23
0,3
0,55
0,9
1,45
2,75
5
7,5
15,45
28,5
44,5
59,6
79
104
170
285
0,2
0,3
0,35
0,6
1
1,8
2,75
3,5
5,5
8,1
13,15
CATALOGO
14/11/05
13:35
Pgina 39
WEIGHT OF FITTINGS
EQUAL TEES, BUTT-WELD FITTINGS
N.B. SIZE
APPROXIMATE WEIGHTS IN Kg
Inches Metric
1/2
3/4
1
11/4
11/2
2
21/2
3
31/2
4
5
6
8
10
12
14
16
18
20
22
24
15
20
25
32
40
50
65
80
90
100
125
150
200
250
300
350
400
450
500
550
600
Sch
Sch
Sch
Sch
Sch
Sch
Std
Sch
Sch
Sch
5s
10s
10
20
30
40s
Wall
40
60
80s
XS
24,6
40
56,6
102
110
164
245
373
0,16
0,23
0,35
0,9
1,35
1,7
2,7
3,75
5
6,5
10
16
27
45
65
102
110
135
168
240
0,16
0,23
0,35
0,9
1,35
1,7
2,7
3,75
5
6,5
10
16
27
31,75
45
60
65
70,5
95
102 105
135
110 167
206,5
135 237,45 277
168 320 378,65
220
0,25
0,38
0,5
1,05
1,5
2,15
3
3,8
5,25
7,65
13,5
19,3
33
60
78
115
167
190
245
350
0,25
0,38
0,5
1,05
1,5
2,15
3
3,8
5,25
7,65
13,5
19,3
33
60
78
115
167
190
245
280
350
0,07
0,09
0,14
0,35
0,55
0,68
1,06
1,5
2
2,6
4
6,35
10,7
18
26
40,7
43,95
53,95
67,2
95,9
0,09
0,11
0,27
0,45
0,65
1,7
2,18
3
4,05
4,4
7,42
12,35
20
28,15
47,45
69,9 87,16
72,65 90,8
101,7 127,12
169,8 199,76
220
306,45 310
23
34,7
59
94,5
100
127
168
240
Sch
Sch
Sch
Sch
Sch
80
100
120
140
160
0,27
0,47
0,86
1,25
1,85
3,18
4
6,58
9
17,5
24
43,6 49,5
67,5 74
93
115 136,2 150
165 206 240
249 335 330
322 380 450
459 540 590
54
98,5
176,5
275
385
500
720
1180
17
25
39,5
70,35
120,3
183,85
300
425
590
790
1310
XXS
0,27
0,47
0,65
1,18
2
3
4,5
7,1
10,9
15
24
37,6
68
APPROXIMATE WEIGHTS IN Kg
Inches Metric
1/2
3/4
1
11/4
11/2
2
21/2
3
31/2
4
5
6
8
10
12
14
16
18
20
22
24
15
20
25
32
40
50
65
80
90
100
125
150
200
250
300
350
400
450
500
550
600
Sch
Sch
Sch
Sch
Sch
Sch
Std
Sch
Sch
Sch
5s
10s
10
20
30
40s
Wall
40
60
80s
XS
24,6
38,6
56,6
102
110
164
218
373
0,16
0,23
0,35
0,9
1,35
1,7
2,7
3,75
5
6,5
10
14
27
43,5
63
102
110
135
168
237
0,16
0,23
0,35
0,9
1,35
1,7
2,7
3,75
5
6,5
10
14
27
43,5
63
70,5
102
105
110
167
135 237,45
168 265,1
220
237 390,45
31,75
55
95
135
206,5
256,5
350,5
544,8
0,25
0,38
0,5
1,05
1,5
2,15
3
3,8
5,25
7,65
13,5
19,3
33
55
78
115
167
190
218
350
0,25
0,38
0,5
1,05
1,5
2,15
3
3,8
5,25
7,65
13,5
19,3
33
55
78
115
167
190
218
280
350
0,07
0,09
0,14
0,35
0,55
0,68
1,06
1,5
2
2,6
4
5,6
10,7
17,45
25,25
40,7
43,95
53,95
67,2
94,45
0,09
0,11
0,27
0,45
0,65
1,7
2,18
3
4,05
4,4
7,42
12,35
20
26,3
47,25
69,9 87,16
72,65 90,8
101,7 127,12
169,8 199,76
220
268,99 272
23
33,15
59
94,5
100
127
168
227
Sch
Sch
Sch
Sch
Sch
80
100
120
140
160
0,27
0,47
0,86
1,25
1,85
3,18
3,85
6,13
65,83
106,24
162,28
200
278,87
405,42
606,1
43,6
63,5
124,85
206
335
380
540
910
9
17,5
24
49,5
88,5
140,85
235
320
440
570
1060
49,25
95
158
275
360
475
680
1140
15,9
23
32,7
55,6
113
163,45
300
410
550
770
1270
XXS
0,27
0,47
0,65
1,18
2
3
4,2
6,6
10,9
15
23,15
37,6
51,3
39
CATALOGO
14/11/05
13:35
Pgina 40
WEIGHT OF FITTINGS
CONCENTRIC REDUCERS, BUTT-WELD FITTINGS
N.B. SIZE
APPROXIMATE WEIGHTS IN Kg
Inches Metric
1/2
3/4
1
11/4
11/2
2
21/2
3
31/2
4
5
6
8
10
12
14
16
18
20
22
24
15
20
25
32
40
50
65
80
90
100
125
150
200
250
300
350
400
450
500
550
600
Sch
Sch
Sch
Sch
Sch
Sch
Std
Sch
Sch
Sch
5s
10s
10
20
30
40s
Wall
40
60
80s
0,03
0,05
0,07
0,12
0,15
0,32
0,4
0,55
0,65
1,1
1,6
2,6
4,3
6
10,75
13,25
16
23,8
28,7
0,03
0,07
0,09
0,14
0,23
0,41
0,5
0,68
0,82
1,35
2
3,27
5,45
7,7
13,6
16,35
19,98
29,75
36,32
23
28
34
50
57
63
0,07
0,13
0,18
0,26
0,41
0,77
1
1,3
1,6
2,75
3,95
5
5,58
6,5
7,25 8,99
10,7
9,7 13,21
15
22,25 26,85 26,85
27,5 33,15 33,15
33,5 46,76
40
59,45
79
59,45
0,07
0,13
0,18
0,26
0,41
0,77
1
1,3
1,6
2,75
3,95
6,5
10,7
15 16,35
26,85 31,3
33,15 44
40
59,5
59,45 93
65,35
71,7 129,4
0,1
0,16
0,22
0,35
0,57
1,01
1,35
1,89
2,27
3,92
5,94
8
9,86
14,48 14,48
22,25 19,79
41,75 35,55
56,75
44
77,4 53,12
124,85 79
180,7 95,34
XS
0,1
0,16
0,22
0,35
0,57
1,01
1,35
1,89
2,27
3,92
5,94
9,86
14,48
19,79
35,55
44
53,12
79
86,71
95,34
Sch
Sch
Sch
Sch
Sch
80
100 120
140
160
16,35
28,5
44,25
78
112
145
305
540
0,15
0,23
0,27
0,48
0,95
1,35
1,9
3,65
6,35
10
16,5
29,5
49
86
121
159
340
610
0,14
0,2
0,3
0,45
0,9
1,35
1,8
3,2
3,85
6,35
9
14,5
XXS
3,65
6,35
7,5
11,8 13,5
17,25 20,45 24,5
28,15 32,65 38,15
52,25 64 73
73,5
83 97
97,6 116 136
159 163 178
XXS
APPROXIMATE WEIGHTS IN Kg
Inches Metric
1/2
3/4
1
11/4
11/2
2
21/2
3
31/2
4
5
6
8
10
12
14
16
18
20
22
24
15
20
25
32
40
50
65
80
90
100
125
150
200
250
300
350
400
450
500
550
600
Sch
Sch
Sch
Sch
Sch
Sch
Std
Sch
Sch
Sch
5s
10s
10
20
30
40s
Wall
40
60
80s
0,03
0,05
0,07
0,12
0,15
0,32
0,4
0,55
0,65
1,1
1,6
2,6
4,3
6
10,75
13,25
16
23,8
28,7
0,03
0,07
0,09
0,14
0,23
0,41
0,5
0,68
0,82
1,35
2
3,27
5,45
7,7
13,6
16,35
19,98
29,75
36,32
23
28
34
50
57
63
0,07
0,13
0,18
0,26
0,41
0,77
1
1,3
1,6
2,75
3,95
5
5,58
6,5
10,7
7,25 8,99
9,7 13,21
15
22,25 26,85 26,85
27,5 33,15 33,15
33,5 46,76
40
59,45
79
59,45
40
0,07
0,13
0,18
0,26
0,41
0,77
1
1,3
1,6
2,75
3,95
6,5
10,7
15 16,35
26,85 31,3
33,15 44
40
59,5
59,45 93
65,35
71,7 129,4
0,1
0,16
0,22
0,35
0,57
1,01
1,35
1,89
2,27
3,92
5,94
8
9,86
14,48 14,48
22,25 19,79
41,75 35,55
56,75
44
77,4 53,12
124,85 79
180,7 95,34
XS
0,1
0,16
0,22
0,35
0,57
1,01
1,35
1,89
2,27
3,92
5,94
9,86
14,48
19,79
35,55
44
53,12
79
86,71
95,34
Sch
Sch
Sch
Sch
Sch
80
100 120
140
160
16,35
28,5
44,25
78
112
145
305
540
0,15
0,23
0,27
0,48
0,95
1,35
1,9
3,65
6,35
10
16,5
29,5
49
86
121
159
340
610
3,65
6,35
7,5
11,8 13,5
17,75 20,45 24,5
28,15 32,65 38,15
52,25 64 73
73,5
83 97
97,6 116 136
159 163 178
0,14
0,2
0,3
0,45
0,9
1,35
1,8
3,2
3,85
6,35
9
14,5
CATALOGO
14/11/05
13:35
Pgina 41
WEIGHT OF FITTINGS
STUB ENDS, BUTT-WELD FITTINGS (ANSI B16.9)
N.B. SIZE
APPROXIMATE WEIGHTS IN Kg
Inches Metric
1/2
3/4
1
11/4
11/2
2
21/2
3
31/2
4
5
6
8
10
12
14
16
18
20
22
24
15
20
25
32
40
50
65
80
90
100
125
150
200
250
300
350
400
450
500
550
600
Sch
Sch
Sch
Sch
Sch
Sch
Std
Sch
Sch
Sch
5s
10s
10
20
30
40s
Wall
40
60
80s
8,84
14,87
19,29
28,57
32,14
44,2
55,8
65
75,9
0,13
0,18
0,29
0,41
0,54
0,98
1,54
2,1
2,47
2,99
5,22
6,79
10,28
17,86
21,88
28,57
32,14
38
41,96
46,88
50,45
12,81
23,8
32,23
44,2
56,7
74,2
88,4
109
128,6
0,14
0,2
0,38
0,54
0,67
1,34
2,05
2,8
2,94
4,17
7,41
10,27
15,63
23,94
29,38
39,73
42,86
50
55,81
62,07
67,41
18
19,75
24,25
36
42,95
50,05
7,99
12,1
14,64
15,8
16,65
21,3
31,7
37
45,55
23,21
32,59
43,3
56,25
65,63
78
91,52
28,13
38,84
54,92
71,88
91,52
112,1
142
160
18,21
33,57
47,32
5,27
9,6
13,04
21,83
38,98
55,8
XS
Sch
Sch
Sch
Sch
Sch
80
100 120
140
160
XXS
0,3
0,35
0,5 0,66
0,67 0,95
0,9
1,2
2,01 2,46
2,69 3,71
3,93 5,18
6,25
6,29 7,68
11,79 13,84
16,25 19,2
24,55 26,79 26,16
45,54 50,45
62,05 71,43
APPROXIMATE WEIGHTS IN Kg
Metric
15
20
25
32
40
50
65
80
90
100
125
150
200
250
300
350
400
450
500
550
600
Sch 5s
0,03
0,04
0,06
0,08
0,11
0,17
0,25
0,35
0,5
0,61
1,06
1,2
2,09
3,63
5,33
5,81
6,54
7,72
8,54
9,8
10,26
Sch 10s
0,04
0,06
0,08
0,1
0,14
0,2
0,33
0,44
0,63
0,76
1,33
1,51
2,61
4,54
6,67
7,26
8,17
9,65
10,67
11,6
12,83
Sch 40s
0,09
0,12
0,15
0,2
0,28
0,41
0,66
0,89
1,26
1,52
2,66
3,02
5,22
9,08
13,25
14,53
16,34
19,3
21,34
23
25,65
Sch 80s
0,12
0,16
0,22
0,31
0,39
0,69
1,05
1,46
1,54
2,49
3,55
5,49
9,97
13,75
19,64
29
37,5
49,25
60
77,5
88,25
41
CATALOGO
14/11/05
13:35
Pgina 42
WEIGHT OF FLANGES
150 lbs PIPE FLANGES
N.B. SIZE
Inches Metric
APPROXIMATE WEIGHTS IN Kg
N.B. SIZE
Inches Metric
Slip-on
and
Screwed
Socket
Weld
Weld
Neck
Blind
Lap
Joint
0,5
0,5
0,82
0,82
0,5
125
APPROXIMATE WEIGHTS IN Kg
Slip-on
and
Screwed
Socket
Weld
6,8
Weld
Neck
Blind
Lap
Joint
8,62
9,07
6,8
1/2
15
3/4
20
0,91
0,91
0,82
0,91
0,91
150
8,62
10,89
11,79
8,62
25
0,91
0,91
0,95
200
13,61
17,69
20,41
13,61
11/4
32
1,27
1,27
1,36
1,27
1,27
10
250
19,5
23,59
31,75
19,5
11/2
40
1,36
1,36
1,81
1,36
1,36
12
300
29,03
36,29
49,9
29,03
50
2,27
2,27
2,72
2,27
2,27
14
350
35,38
49,9
59,42
47,63
21/2
65
3,63
3,63
4,08
3,18
3,63
16
400
42,18
63,5
77,11
63,5
80
4,08
4,08
4,54
4,08
4,08
18
450
54,43
68,04
94,8
72,57
31/2
90
5,44
5,9
20
500
72,12
81,65
123,4
88,45
100
5,9
6,8
7,71
5,9
24
600
95,25
117,93
186,4
124,74
1/2
15
APPROXIMATE WEIGHTS IN Kg
N.B. SIZE
Inches Metric
Slip-on
and
Screwed
Socket
Weld
Weld
Neck
Blind
Lap
Joint
0,68
0,68
0,91
0,91
0,68
125
APPROXIMATE WEIGHTS IN Kg
Slip-on
and
Screwed
Socket
Weld
11,79
Weld
Neck
Blind
Lap
Joint
15,42
15,88
11,79
3/4
20
1,13
1,13
1,36
1,36
1,13
150
15,88
20,41
22,68
15,88
25
1,36
1,36
1,81
1,81
1,36
200
24,49
31,75
36,74
24,49
11/4
32
2,04
2,04
2,49
2,72
2,04
10
250
34,93
44,91
57,61
34,93
11/2
40
2,95
2,95
3,18
3,18
2,95
12
300
49,9
64,41
83,46
63,5
50
3,18
3,18
3,63
3,63
3,18
14
350
74,39
84,37
107,1
86,18
21/2
65
4,54
4,54
5,44
5,44
4,54
16
400
99,79
111,6
139,3
113,4
80
5,9
5,9
7,26
7,26
5,9
18
450
127
138,4
176,9
133,8
31/2
90
7,26
9,07
9,53
7,26
20
500
147,4
171,5
223,2
167,8
100
9,53
11,34
12,25
9,53
24
600
222,3
247,2
342
249,5
APPROXIMATE WEIGHTS IN Kg
N.B. SIZE
Inches Metric
Slip-on
and
Screwed
Weld
Neck
Blind
Lap
Joint
15,88
14,97
11,34
100
11,79
125
14,06
19,5
19,96
13,15
150
19,96
25,85
27,67
19,05
200
30,36
40,37
45,36
29,03
10
250
41,28
57,15
70,31
50,8
42
12
14
16
18
20
24
300
350
400
450
500
600
APPROXIMATE WEIGHTS IN Kg
Slip-on
and
Screwed
Weld
Neck
Blind
Lap
Joint
58,51
86,64
114,8
140,6
171,5
244,5
80,29
105,7
133,4
163,3
201,9
290,3
102,5
140,6
180,5
227,7
281,7
424,6
68,95
95,25
127
156,5
190,5
279
CATALOGO
14/11/05
13:35
Pgina 43
APPROXIMATE WEIGHTS IN Kg
N.B. SIZE
Inches Metric
Slip-on
and
Screwed
Socket
Weld
Weld
Neck
Blind
Lap
Joint
1,27
1,27
1,36
0,91
1,27
125
APPROXIMATE WEIGHTS IN Kg
Slip-on
and
Screwed
Socket
Weld
Weld
Neck
Blind
Lap
Joint
28,58
30,84
30,84
28,58
1/2
15
3/4
20
1,36
1,36
1,59
1,36
1,36
150
36,29
36,74
39,01
36,29
25
1,59
1,59
1,81
1,81
1,59
200
44
50,8
63,05
44
1 /4
32
2,04
2,04
2,27
2,72
2,04
10
250
80,29
88,45
108,9
88,45
11/2
40
2,95
2,95
3,63
3,63
2,95
12
300
97,52
102,5
133,8
108,8
50
3,63
3,63
4,54
4,54
3,63
14
350
117,5
157,4
171,5
131,5
21/2
65
5,44
5,44
6,35
6,3
5,44
16
400
166
218,2
239
181,4
80
6,8
6,8
8,16
9,07
6,8
18
450
215,5
251,7
301,6
212,7
31/2
90
9,53
11,79
13,15
9,53
20
500
277,6
313
387,8
285,8
100
14,97
16,78
18,6
14,97
24
600
370,1
4432
533
392,8
APPROXIMATE WEIGHTS IN Kg
N.B. SIZE
Inches Metric
Slip-on
and
Screwed
Weld
Neck
Blind
Lap
Joint
APPROXIMATE WEIGHTS IN Kg
Slip-on
and
Screwed
Weld
Neck
Blind
Lap
Joint
147,9
168,7
187,3
167,8
80
14,06
14,51
14,51
14,06
12
300
100
24,04
23,13
24,49
24,04
14
350
172,4
254,9
224,1
188,2
125
37,65
39,01
39,46
37,65
16
400
208,2
310,7
280,8
210,9
150
49
49,9
51,26
49
18
450
293,5
419,1
399,2
294,8
200
78
84,82
89,36
86,18
20
500
359,3
528,0
502,1
367,4
10
250
111,1
121,6
131,5
124,7
24
600
671,3
680,4
952,1
703,1
APPROXIMATE WEIGHTS IN Kg
N.B. SIZE
Inches Metric
APPROXIMATE WEIGHTS IN Kg
Slip-on
and
Screwed
Socket
Weld
Weld
Neck
Blind
Lap
Joint
15
2,72
2,72
3,18
1,81
2,72
3/4
20
3,18
3,18
3,4
2,72
3,18
25
3,4
3,4
3,86
4,08
3,4
10
1 /4
32
4,54
4,54
4,54
4,54
4,54
12
300
302,6
11/2
40
6,35
6,35
6,35
6,35
6,35
14
350
50
9,53
9,53
10,89
11,34
9,53
16
21/2
65
16,33
16,33
16,33
15,88
16,33
18
80
21,77
21,77
21,77
21,77
20
100
33,11
31,3
33,11
33,11
24
125
59,87
59,87
64,41
59,87
1/2
Slip-on
and
Screwed
Weld
Neck
Blind
Lap
Joint
74,39
74,39
72,12
74,39
200
117
123,8
137
117
250
197,8
205,9
230
220
150
Socket
Weld
313
351,5
285,8
426,4
442,3
403,7
400
567
589,7
521,7
450
737,1
793,8
669
500
929,9
1009,3
805,2
600
1508,3
1644,4
1281,5
43
CATALOGO
14/11/05
13:35
Pgina 44
APPROXIMATE WEIGHTS IN Kg
N.B. SIZE
Inches Metric
Slip-on
and
Screwed
Weld
Neck
Blind
Lap
Joint
APPROXIMATE WEIGHTS IN Kg
Slip-on
and
Screwed
Weld
Neck
Blind
Lap
Joint
1/2
15
3,18
3,18
3,18
3,18
80
37,65
42,64
39,01
36,29
3/4
20
3,63
3,63
3,63
3,63
100
56,7
65,77
61,23
54,43
25
4,99
5,44
4,99
4,99
125
95,25
111,1
102,06
93
11/4
32
7,26
7,71
7,71
7,26
150
147,4
172,4
156,5
142,9
11/2
40
9,98
11,34
10,43
9,98
200
220
63,1
240,4
213,2
50
17,24
19,05
17,69
16,78
10
250
421,8
87,6
464,9
408,2
65
24,94
23,59
25,4
24,04
12
300
499
691,7
589,7
499
2 /2
WEIGHTS IN Kg
SIZE
WEIGHTS IN Kg
SIZE
WEIGHTS IN Kg
mm
Wt per ft
Wt per M
mm
Wt per ft
Wt per M
mm
Wt per ft
Wt per M
0,5
0,0004
0,0015
21
0,829
2,72
72
9,74
31,96
1,0
0,0018
0,0062
22
0,908
2,98
75
10,57
34,68
1,5
0,0042
0,014
23
0,994
3,26
80
12,03
39,46
0,0076
0,025
24
1,08
3,55
90
15,22
49,94
2,5
0,012
0,039
25
1,17
3,85
100
18,79
61,65
0,017
0,055
26
1,27
4,17
110
22,74
74,6
3,5
0,023
0,076
27
1,37
4,5
120
27,07
88,8
0,03
0,099
28
1,47
4,83
130
31,7
104
4,5
0,038
0,125
30
1,69
5,55
140
36,88
121
0,047
0,154
32
1,92
6,31
150
42,37
139
5,5
0,057
0,187
33
2,05
6,71
160
48,16
158
0,068
0,222
35
2,3
7,55
170
54,26
178
6,5
0,079
0,26
36
2,44
7,99
180
60,96
200
0,092
0,302
38
2,71
8,9
190
67,97
223
7,5
0,106
0,347
39
2,86
9,38
200
75,3
247
0,12
0,395
40
3,01
9,86
220
90,8
298
8,5
0,136
0,445
42
3,32
10,88
240
108
355
0,152
0,499
45
3,8
12,48
250
117
385
9,5
0,169
0,556
48
4,33
14,21
260
127
417
10
0,188
0,617
50
4,7
15,41
280
147
483
11
0,227
0,746
52
5,08
16,67
300
169
555
12
0,271
0,888
55
5,69
18,65
320
192
631
13
0,317
1,04
56
5,89
19,33
340
217
713
14
0,369
1,21
58
6,32
20,74
350
230
755
15
0,424
1,39
60
6,77
22,2
360
244
799
16
0,482
1,58
62
7,22
23,7
380
271
890
17
0,543
1,78
64
7,7
25,25
400
301
986
18
0,61
65
7,94
26,05
500
469
1540
19
0,68
2,23
68
8,69
28,51
20
0,753
2,47
70
9,21
30,21
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Pgina 45
PLATE metric
THICKNESS
5 mm
6 mm
8 mm
10 mm
12 mm
15 mm
20 mm
25 mm
30 mm
40 mm
50 mm
WT PER SQ FT
WT PER SQ M
2000
x 1000 mm
WEIGHTS IN Kg
2500
x 1250 mm
3,802
4,563
6,084
7,604
9,125
11,406
15,207
19,01
22,813
30,414
38,02
40,925
49,111
65,483
81,845
98,222
122,778
163,689
204,622
245,556
327,378
409,244
82
98
131
164
196
246
327
409
491
655
819
128
153
205
256
307
384
512
639
767
1023
1279
3000
x 1500 mm
184
221
295
368
442
553
737
921
1105
1473
1842
4000
x 2000 mm
6000
x 2000 mm
327
393
524
655
786
982
1310
1637
1964
2619
3274
491
589
786
982
1179
1473
1964
2456
2947
3929
4911
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Pgina 46
CATALOGO
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Pgina 47
MATERIALS INFORMATION
See inside for further details
TRADEMARKS
Some alloys presented in this catalogue are registered trade marks
property of the registered owner:
47
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CATALOGO
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Pgina 49
310S
310S
Alloy: AISI-310S
(Cr. Ni. alloy)
UNS-S31008
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
19
22
24
26
Mo
Co
Fe
Cu
Mn
Si
0,08
1,5
0,045
0,030
N
(x)
2. Mechanical properties:
Representative Tensile Properties
Temp
F
Ultimate
Tensile
Strength, psi
0.2% Yield
Strength, psi
Elongation
%
Temp
F
10,000 hr
Rupture
Strength, psi
70
1000
1200
1400
1600
80,000
67,800
54,100
35,100
19,100
35,000
20,800
20,700
19,300
12,200
52
47
43
46
48
1200
1400
1600
1800
14,900
3,300
1,100
280
14,400
4,500
1,500
660
3. Physical properties:
Density Ib/in3
Melting Range F
0.284
2470-2555
Temp
F
Coefficient* of
Thermal
Expansion,
in/in F x 10-6
Thermal
Conductivity
Btuft/ft2hrF
Modulus of
Elasticity
Dynamic,
psi x 106
70
1000
1200
1400
1600
1800
2000
9.5
9.8
10.05
10.15
10.3
10.6
7.6
13.6
15.2
16.8
18.4
20.0
29.0
23.0
21.8
20.5
19.2
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Pgina 50
4. Specifications:
Norm
Tubes
Seamless Welded
ASTM
A-213
A-312
A-312
Plates
Sheets
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
Wire
A-240
A-276
A-240
A-182
A-473
A-403
A-276
A-580
B.S.
EN-10095,
X8CrNi25-21
W.Nr. 1.4841
5. Characteristics, applications:
Excellent resistance to oxidation under mildly cyclic conditions through 2000F characterizes 310.
Because of its high chromium and medium nickel contents, 310 has good resistance to sulfidation and
other forms of hot corrosion.
310 is widely used in moderately carburizing atmospheres such as encountered in petrochemical
environments. The more severely carburizing atmospheres of industrial heat treating furnaces requiere 330 or 333. 310 is not suggested for the severe thermal shock of repeated liquid quenching.
310 is often used at cryogenic temperatures, because of excellent toughness to 4 K, and low magnetic permeability.
310 has a machinability rating of 42% relative to AISI B1112 steel. With high speed steel tooling
this is about 70 surface feet per minute. Forming operations should be at room temperature whenever possible.
Oxidization resistance to 2000F
Moderate strength at high temperature
Resistance to hot corrosion
Strength and toughness at cryogenic temperatures
Applications
Kilns
Fluidized bed coal combustors
Radiant tubes
Tube hangers for petroleum refining and steam boilers
Coal gasifier internal components
Thermowells
Refractory anchor bolts
Burners, combustion chambers
Retorts, muffles, annealing covers
Saggers
Food processing equipment
Cryogenic structures.
6. Welding properties:
Good weldability.
Weld with matching AWS E310-15 DC lime electrodes or ER310 bare wire.
7. Products, we supply:
x Plates, sheets
50
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x Fittings
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x Bolting
CATALOGO
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13:35
Pgina 51
316L
316L
Alloy: AISI-316L
(Cr. Ni. alloy)
UNS-S31603
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
Mo
10
14
16
18
2
3
Co
Fe
Cu
Mn
Si
0,030
0,75
0,045
0,030
0,10
2. Mechanical properties:
Mechanical properties at 20C
0,2% proof stress
N/mm2 min.
1% proof stress
N/mm2 min.
tensile strength
N/mm2
elongation after
fracture (Lo=5do)
195
235
450-700
40
100
150
200
250
300
350
400
450
500
165
150
137
127
119
113
108
103
100
1% proof stress
200
180
165
153
145
139
135
130
128
3. Physical properties:
Specific gravity at 20C ....................................
Thermal conductivity at 20C .............................
Specific heat at 20C .......................................
Modulus of elasticity at 20C .............................
Thermal expansion in 10-6 m/m C ....................
7,95 g/cm2
15 W/mK
500 J/kgK
200000 N/mm2
20 to 100C 16,5
20 to 200C 17,5
20 to 300C 17,5
20 to 400C 18,5
20 to 500C 18,5
4. Specifications:
Norm
ASTM
Tubes
Seamless Welded
A-213
A-312
A-249
A-312
A-554
Plates
Sheets
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
Wire
A-240
A-276
A-240
A-182
A-472
A-479
A-403
A-276
A-580
B.S.
W. Nr. 1.4404
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5. Characteristics, applications:
Material is austenitic, stainless and acid resisting nickel, chromium, molybdenum steels with a very
low carbon content (ELC type).
Material features improved strength due to its nitrogen addition, which is of particular importance
for the 0,2% proof stress to be used as design basis.
Applications
Material 316L and Material No. 1.4435 are mainly used for parts and equipment in urea plant subjected to high pressures and temperatures, and to severe corrosion (steam separator, condenser, reactor, stripper, scrubber). Both grades are also suitable for applications involving the attack of a variety
of chemicals in dyemills, in the textile, paper and leather industries, as well as the chemical, pharmaceutical and plastics industries.
The steels are not magnetic.
Corrosion resistance. Intergranular corrosion
Owing to their alloying elements and to the melting technique employed. Material 316 L and 1.4435
feature very good resistance to intergranular corrosion when tested according to DIN 50914. Their corrosion resistance is also found to be excellent when subjected to a Huey test according to ASTM A
252 Practice C - a maximum corrosion rate of 0.247 g/m_hr 316L and 0.54 g/m_hr (1.4435) obtained as an average of 5 bolling periods of 48 hours each can be guaranteed.
Stress corrosion cracking and pitting
The alloying elements of Material No. 1.4466 give this grade improved resistance to stress corrosion
cracking and pitting in high-chloride media (e.g. sea water) compared to that of conventional 18/8 steels.
Due to the increased Nickel content, Material No. 1.4465 has a considerably higher range of resistance to stress corrosion cracking than e.g. X2CrNiMo 1812 (TP 316 L).
Due to the Molybdenum content and the increased Chromium content there is a good corrosion resistance to flowing waters containing Chlorides.
Forming properties
Both grades can conveniently be cold formed, hot formed and machined.
Huey-test
Apart from the testing for resistance to grain disintegration the Huey-test also serves for investigating whether there are any further inhomogeneities such as precipitations within the grain, sigma phase and inclusions of Ferrite. For this reason the Huey-test represents a very strict testing method,
which includes a great number of parameters.
5,91 g/m2 24h=0.27 mm/year at the Huey-test. This extraordinarily low value can only be guaranteed by special provisions at the production of the steel and by extensive quality control during the various of production.
6. Welding properties:
Welding presents no difficulties. With an approved welding technique for fully austenitic filler metals
sound weld joints can be achieved up to a plate thickness of 80 mm. Welding should be carried out with
a short arc and mean amperage taking care to prevent weave beads exeeding two times the electrode diameter. Thick layers are to be avoided. Its is recommended to chip out the end craters. Interpass
temperature should not exceed 150. Quite on general, no postheat-treatment is required.
7. Products, we supply:
x Plates, sheets
52
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CATALOGO
14/11/05
13:35
Pgina 53
317L
317L
Alloy: AISI-317L
(Cr. Ni. Mo. alloy)
UNS-S31703
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
Mo
11
15
18
20
3
4
Co
Fe
Cu
Mn
Si
0,35
0,75
0,040
0,030
0,10
2. Mechanical properties:
Tensile strength, mini: 515 MPa
Yield strength, mini: 205 MPa
3. Physical properties:
Physical Data
Density (lb/cu. in.) ............................... 0.29 or 8,00 Kg/dm3
Specific Gravity .............................................................. 7.9
Specific Heat ............................................................... 0.12
(Btu/lb/Deg F - [32-212 Deg F])
Electrical Resistivity ....................................................... 444
(microhm-cm (at 68 Deg F))
Melting Point (Deg F) ................................................... 2550
Modulus of Elasticity Tension ............................................. 28
4. Specifications:
Norm
ASTM
Tubes
Seamless Welded
A-213
A-312
A-249
A-312
A-813-4
Plates
Sheets
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
Wire
A-240
A-276
A-582
A-240
A-182
A-472
A-479
A-403
A-774
A-778
A-276
A-580
B.S.
W.Nr. 1. 4438
X2 Cr Ni Mo 18164
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Pgina 54
5. Characteristics, applications:
Principal Desing Features
317L is a low carbon version of 317 stainless. It possesses the same high strength and corrosion
resistance and will produce stronger welds due to its low carbon content. Many users are shifting over
to this alloy in lieu of 304 and 316.
Corrosion Resistance
Resistant to a wide variety of marine environments, salts, dilute nitric, acetic and sulfuric acids. Significantly higher resistance to pitting and crevice corrosion at ambient temperatures than 316 or 316L
stainless.
Hot Working
All common hot working processes are possible with this alloy. Heat to 2100-2300F (1149-1260C).
Avoid working this material below 1700F (927C). For optimum corrosion resistance, a post-work annealing is recommended.
Cold Working
Shearing, stamping, heading and drawing can be successfully performed. To remove internal stresses, a post-work annealing is recommended.
Annealing
1850-2050F (1010-1121C), followed by rapid cooling.
Hardening
This alloy does not respond to heat treatment. Cold work will cause an increase in both hardness
and strength.
Machinability
Low speeds and constant feeds will minimize this alloys tendency to work harden. Tougher than 304
stainless with a long stringy chip, the use of chip breakers is recommended.
Applications
Chemical and petrochemical process equipment, pulp and paper manufacturing and condensers in
fossil and nuclear fueled power generation stations.
6. Welding properties:
All common fusion and resistance methods except oxyacetylene welding have proven successful. Use
AWS E/ER 317L filler metal for best results.
7. Products, we supply:
x Plates, sheets
54
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x Forgings
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CATALOGO
14/11/05
13:35
Pgina 55
317LMN
317LMN
Alloy: AISI-317LMN
(Cr. Ni. Mo. alloy)
UNS-S31703
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
Mo
13,5
17,5
17
20
4
5
Co
Fe
Cu
Mn
Si
0,030
0,75
0,045
0,030
0,10
0,20
2. Mechanical properties:
Tensile strength, mini: 550 MPa
Yield strength, mini: 240 MPa
3. Physical properties:
Physical Data
Density (lb/cu. in.) .................................... 0.29 or 8 Kg/dm3
Specific Heat ............................................................... 0.12
(Btu/lb/Deg F - [32-212 Deg F])
Melting Point (Deg F) ................................................... 2600
Thermal conductivity ....................................................... 9.4
Modulus of Elasticity Tension ............................................. 28
4. Specifications:
Norm
Tubes
Seamless Welded
Plates
Sheets
ASTM
A-312
A-240
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
Wire
B.S.
W.Nr. 1. 4439 (X2 Cr Ni Mo N 17135)
SEN - 400
5. Characteristics, applications:
Cold bending
Heat treatment is in most cases not necessary after cold bending to normal bending radio. At a higher
degree of forming and at operational conditions which could cause stress corrosion in austenitic
steels, a stress-relieving annealing is reconmmended.
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Pgina 56
Corrosion Resistance
The addition of nitrogen provides a good austenitic stability for Material 317LMN giving it a superior
corrosion resistance to that of 1.4435. Even after heat treatment e.g. welding, a good corrosion resistance is maintained as there is no possibility of the formation of harmful phases e.g. the sigma phase. The increased molybdenum content affords a high corrosion resistance in chlorine-ion-containing
media. Pitting corrosion resistance is particularly improved.
Material 317LMN is characterized by good resistance in
Mixed acids
sulphuric acid / nitric acid, Hydrofluoric acid / nitric acid
sodium chlorite, sodium-hypochlorite
Bleaching solutions
Sea and brackish water
sodium chloride
Applications
Positive experiences with Material 317 LMN can be expected amongst others in the following
applications:
6. Welding properties:
Electrode rod welding as well as the WIG (TIG)-method is suitable for welding tubes into tube plates.
The use of additives of the same type is recommended in order to obtain a weld free of ferrites and with
the favourable properties of the basic material. Welding should be carried out with as little heat as possible. There is usually no need for further heat treatment.
Weldable by all common methods. Because of the carbon restriction in 317LMN, carbide precipitation along the weld boundaries will be minimized. Filler metal should be either 317L, LM or LMN, although Alloy 625 (Inconel tm) has been successfully employed.
7. Products, we supply:
x Plates, sheets
56
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x Fittings
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x Bolting
CATALOGO
14/11/05
13:35
Pgina 57
321
321
Alloy: AISI-321
(Cr. Ni. alloy)
UNS-S32100
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
9
12
17
19
Mo
Co
Fe
Cu
Mn
Si
0,08
0,75
0,045
0,030
0,10
TI
(x)
2. Mechanical properties:
Tensile strength, mini: 515 MPa
Yield strength, mini: 205 MPa
Temp
F
Ultimate
Tensile
Strength, psi
0,2%
Yield
Strength, psi
Temp
F
10,000 hrs
400
600
800
62,000
62,000
62,000
20,500
18,000
17,000
1100
1200
1300
30,000
19,000
11,200
23,500
12,900
7,200
3. Physical properties:
Density: 8 Kg/dm3
Density Ib/in3
Melting Range F
0.286
2550-2600
Temp
F
Coefficient* of
Thermal
Expansion,
in/in F x 10-6
Thermal
Conductivity
Btuft/ft2hrF
Modulus of
Elasticity
Dynamic,
psi x 106
200
400
800
1000
9.3
9.4
10.0
10.3
8.8
9.7
11.4
12.1
28.0
26.5
23.8
22.5
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Pgina 58
4. Specifications:
Norm
Tubes
Seamless Welded
ASTM
A-213
A-312
A-376
A-249
A-312
A-554
Plates
Sheets
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
Wire
A-240
A-276
A-582
A-167
A-240
A-182
A-473
A-479
A-403
A-276
A-580
B.S.
W.Nr. 1.4541
5. Characteristics, applications:
High carbon steels prone more to intercrystalline attack in weld zones and slower cooling sections.
These steel avoids such attacks through its stabilization with Ti. The corrosion behaviour of this alloy
in natural environments is very similar to the TP 304/304L alloys. Architecturally, it may not be adequate for near-industrial or onshore locations in Europe. Satisfactory in many low-chloride waters, it is
prone to pitting or crevice corrosion in seawater. Water treatment, galvanic protection and deaeration
can influence the performance.
Features
Oxidation resistant to 1600F
Stabilized against weld heat affected zone (HAZ) intergranular corrosion
Resists polythionic acid stress corrosion cracking
Application
321 stainless is a titanium stabilized grade commonly used for service in the 1000-1600F temperature range. For service temperatures up to about 1600F, a stabilizing treatment at 1550-1650F, a stabilizing treatment at 1550-1650F, air cool, may be used to provide optimum resistance to intergranular corrosion and to polythionic acid stress corrosion cracking.
6. Welding properties:
321 is readily welded by all common methods including submerged arc. Appropriate weld fillers are AWS
ER347 bare wire and E347 covered electrodes.
7. Products, we supply:
x Plates, sheets
58
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x Fittings
x Bars
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x Bolting
CATALOGO
14/11/05
13:35
Pgina 59
321H
321H
Alloy: AISI-321H
(Cr. Ni. alloy)
UNS-S32109
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
9
12
17
19
Mo
Co
Fe
Cu
Mn
Si
TI
0,04
0,10
0,75
0,045
0,030
0,10
(x)
2. Mechanical properties:
Tensile strength, mini: 515 MPa
Yield strength, mini: 205 MPa
at
Density
Value
Unit
Property
at
Value
Unit
8,027
Kg/m
Melting Range
1400-1430
Specific Heat
500
J/kg. C
1.02
Electrical Conductivity
25C
1.25
% IACS
Electrical Resistivity
25C
0.72
Micro ohm. m
Coefficient of Expansion
0-100C
16.6
/ C
Modulus of Elasticity
20C
193
GPa
0-315C
17.2
/ C
Shear Modulus
20C
77
GPa
0-540C
18.6
/ C
Poissons Ratio
20C
0.30
100C
16.1
W / m. C
Thermal Conductivity
4. Specifications:
Norm
ASTM
Tubes
Seamless Welded
A-213
A-312
A-376
A-249
A-312
Plates
Sheets
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
Wire
A-240
A-276
A-582
A-240
A-182
A-473
A-479
A-403
A-276
A-580
B.S.
W.Nr. 1.4878
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13:35
Pgina 60
5. Characteristics, applications:
This is the high carbon version of TP 321 which ensures greater creep resistance. Behaves much
the same as TP 321 in oxidation resistance.
This grade is version of the most common stainless steel, grade 304. They contain carbide forming
or stabilising elements such as titanium, niobium and tantalum, which form carbides in preference to
chromium carbide, and so prevent sensitisation. The grades were more common before the development of steelmaking equipment for reliable and economical manufacture of 304L grade, which is now
used in most applications.
Grade 321 is stabilised with titanium, 347 with niobium (columbium, Cb, in USA practice), and 348
with niobium plus tantalum, with a controlled cobalt content. Grade 348 is mainly used in nuclear applications. Each grade has an H version, with guaranteed high carbon (~0.07%), which can be used in
pressure vessels to higher temperatures.
The grades are used:
where the steel will be used at temperatures in the carbide precipitation range, 425 to 900C,
and subsequently exposed to corrosive environments.
where heavy parts (> 5 mm thickness) are fabricated by welding, and will not be subsequently solution annealed.
In practice, grade 304L is most often used nowadays, except for components for feat treatment
equipment and furnaces which are used intermittently, and may face corrosive conditions while cool.
The grades have similar corrosion resistance to grade 304 which has not been sensitised. They are
not suitable for decorative applications, as the stabilising additions produce inclusions which impair surface quality. They are not available in BA finish, and are usually used as heavy sections in 2D or No 1
finish.
Applications
Heat exchangers, furnaces, boilers in chemical and petrochemical plant.
Welded construction and parts heated in the carbide precipitation range, subsequently requiring the
corrosion resistance of grade 304: boilers, exhaust manifolds, fasteners, fire walls, furnace heating
elements, jet engine parts, mufflers for stationary engines, stack liners.
6. Welding properties:
Good weldability.
7. Products, we supply:
x Plates, sheets
60
x Tubes
x Fittings
x Bars
x Forgings
x Bolting
CATALOGO
14/11/05
13:35
Pgina 61
347
347
Alloy: AISI-347
(Cr. Ni. alloy)
UNS-S34700
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
9
13
17
19
Mo
Co
Fe
Cu
Mn
Si
Cb
(x)
0,08
0,75
0,045
0,030
3. Physical properties:
at
Property
Density
Value
Unit
Property
at
Value
Unit
8,027
Kg/m
Melting Range
1400-1430
Specific Heat
500
J/kg. C
1.02
Electrical Conductivity
25C
1.25
% IACS
Electrical Resistivity
25C
0.72
Micro ohm. m
Coefficient of Expansion
0-100C
16.6
/ C
Modulus of Elasticity
20C
193
GPa
0-315C
17.2
/ C
Shear Modulus
20C
77
GPa
0-540C
18.6
/ C
Poissons Ratio
20C
0.30
100C
16.1
W / m. C
Thermal Conductivity
4. Specifications:
Norm
ASTM
Tubes
Seamless Welded
A-213
A-312
A-376
A-249
A-312
A-554
Plates
Sheets
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
Wire
A-240
A-276
A-582
A-240
A-182
A-473
A-479
A-403
A-276
A-580
B.S.
W.Nr. 1.4550
61
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5. Characteristics, applications:
General Description:
Stainless steels are iron based alloys containing at least 10.5% Chromium. They achieve their stainless characteristics through the formation of an invisible and adherent Chromium rich oxide film. Alloy
347 is a general purpose austenitic stainless steel with a face centered cubic structure. It is essentially
non-magnetic in the annealed condition and can only be hardened by cold working.
Niobium has been added to suppress grain boundary Chromium Carbide precipitation.
Finishes
No 1 (hot rolled, annealed and pickled), 2D (cold rolled).
Heat Treatment
Solution annealing is performed at 1000-1120C, followed by rapid cooling. The grades cannot be hardened by heat treatment. Stress relieving is rarely required due to their high ductility and frequent use at
high temperatures.
Typical Applications
Welded construction and parts heated in the carbide precipitation range, subsequently requiring the corrosion resistance of grade 304: boilers, exhaust manifolds, fasteners, fire walls, furnace heating elements,
jet engine parts, mufflers for stationary engines, stack liners.
6. Welding properties:
These grades are readily weldable by most fusion techniques (GTAW/TIG, GMAW/MIG/MAG,
MMAW/stick, SAW), with no preheat, postheat or control of interpass temperature needed. Grade
347 welding consumables are used for 321 and 347 grades, and are prequalified in AS1554.6:1994
for welding to most other austenitic grades. Pickling and passivation is not usually required for use at
elevated temperatures.
7. Products, we supply:
x Plates, sheets
62
x Tubes
x Fittings
x Bars
x Forgings
x Bolting
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410
Alloy: AISI-410
(Cr. alloy)
UNS-S41000
410
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
0,75
11,5
13,5
Mo
Co
Fe
Cu
Mn
Si
0,08
0,15
0,040
0,030
2. Mechanical properties:
Tensile strength, mini: 450 MPa
Yield strength, mini: 205 MPa
Heat Treated Condition. 1 (25mm) round bar, oil quenched from 1800F (982C)
Tempering
Tensile
0.2% yield
Elongation
Reduction
Temp
Strength
Strength
in 2
of Area, %
As
quenched
psi
MPa
psi
MPa
(50mm), %
193,450
1334
149,750
1032
17.0
Hardness
Brinell
RC
56.8
388
42
300
149
188,525
1300
148,575
1024
17.3
59.7
388
42
500
260
181,550
1252
143,550
990
16.8
60.7
388
42
700
371
181,425
1251
144,650
997
16.0
61.6
361
39
1050
566
124,050
855
110,330
761
20.8
67.2
255
25
1150
621
117,530
810
103,745
715
21.3
66.1
235
22
1200
649
113,020
779
99,125
683
22,0
66,5
229
20
75,610
521
43,590
301
34.5
74.5
143
Annealed
(1500/816)
3. Physical properties:
Density 0.276 lb/in3 (7650 kg/m3); 8 kg/dm3).
Melting Point (approx.) 2223F (1495C)
Magnetic Permeability In the annealed condition 410 will have a maximum permeability value of
900 Oersteds.
Modulus of Elasticity 29 x 106 psi (200 GPa).
Mean Specific Heat 32-212F (0-100C) 0.11 Btu/lb.F (460 J/kg.K)
Temper.
Coeficient* of
Thermal Expansion
Electrical Resistivity
Thermal
Conductivity
Temperature
212 100
5.5
9.9
14.4
25.1
932 500
6.2
11.2
16.6
28.9
68
212
392
752
20
100
200
400
ohm.circularmil/ft
microhm.m
343
385
433
529
0.57
0.64
0.72
0.88
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4. Specifications:
Norm
Tubes
Seamless Welded
ASTM
A-268
A-511
A-268
Plates
Sheets
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
Wire
A-240
A-276
A-240
A-473
A-182
A-479
A-403
A-580
A-276
5. Characteristics, applications:
Type 410 is a corrosion and heat resistant 12% chromium steel. It is the most widely used of the
hardenable stainless steels. Heat treated 410 has mechanical properties comparable to the engineering alloy steel AISI 4130, coupled with the additional benefit of good corrosion resistance.
Hardenable stainless which may be tempered as high as 1350F (732C) to produce high impact
toughness. Oxidation resistant through 1500F (816C) intermittently, 1200F (649C) continuously.
Corrosion Resistance
410 stainless is highly resistant to atmospheric corrosion. Maximum corrosion resistance is obtained by
hardening and polishing. Mild atmospheres, soft water (verify water analysis). Oxidizing saline solutions free
of chlorides, fluorides, iodides, bromides Cold diluted nitric solutions. Certain cold diluted organic acids:
picric, tannic, lactic Non-corrosive products such as: alcohol, benzol, petroleum, oil, soap
Metallurgy
The microstructure of annealed 410 consists of ferrite and carbides. Austenite forms in increasing
amounts as the steel is heated above approximately 1450F (790C). Rapid cooling from above 1450F
(790C) produces a partially or completely martensitic structure, depending upon the austenitizing temperature and the analysis. A fully martensitic structure, or very nearly so, may be developed by oil quench from
1800F (982C), or by air cooling if the section is light.
Chromium near the upper specified limit will reduce maximum hardness and will usually produce
small amounts of ferrite in with the hardened martensite. Heats of 410 with higher carbon will have
slightly greater hardness in the annealed condition, and greater hardness in the hardened condition.
Heat Treatment
Annealing: Heat uniformly to 1200-1400F (650-760C), remove from furnace and air cool. This should
result in Brinell hardness about 187.
For maximum softness, heat to 1500-1650F (816-900C), furnace cool slowly to 1100F (593C),
after which air cooling is permissible. Brinell hardness should be approximately 155.
Hardening: Heat to 1750-1850F (954-1010C), soak at heat, and quench in oil. Light sections will also harden by air cooling. 410 will harden to some degree when heated 1500F (816C) and over unless
slowly cooled to below the critical temperature.
Tempering: Soak at heat at least one hour, longer for large sections, and air cool. Tempering 410 in the
range 750-1050F (400-570C) results in decreased impact toughness and somewhat reduced corrosion
resistance.
Applications
Press plates. Petrochemical equipment. Gate valves. Mining machinery. Distillation trays.
6. Welding properties:
Because 410 is an air hardening steel, it must be given a high preheat, at least 350-400F (180200C) before welding, and immediately given a full anneal before the weldment cools. Otherwise the
metal will harden, and cracking is likely. This nickel alloy is comparatively low strength, and therefore accommodates some of the strain which may otherwise contribute to cracking in the 410 weldment.
7. Products, we supply:
x Plates, sheets
64
x Tubes
x Fittings
x Bars
x Forgings
x Bolting
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431
Alloy: AISI-431
(Cr. Ni. alloy)
UNS-S43100
431
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
1,25
2,5
15
17
Mo
Co
Fe
Cu
Mn
Si
0,2
0,04
0,03
2. Mechanical properties:
Yield strength 0.2: 200 GPa
3. Physical properties:
7,85 Kg/dm3
Density
4. Specifications:
Norms
Material
Chemical
composit
Pipes-Tubes
Seamless
Plates
Welded. Sheets
Rounds,
Strips
Wires
Forgings
Bars
DIN
F-44
BS
ASTM
AISI
A-511
A-276
A-276 A-580
A-473
ISO
AFNOR
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Tempering
Temper for desired properties. Temperatures between 700-1050F (371-565C) will adversely affect impact strength and corrosion properties.
Hardening
1800-1950 F (982-1066C), oil quench or ail cool for maximum properties.
Applications
431 has been successfully used in a variety of aircraft and general industrial applications. These include fasteners, bolts, valve components an chemical equipment.
6. Corrosion data:
Sulphuric acid: 3
Hydrocloric acid: 3
Hydrofluoric acid: 3
Phosphoric acid: 3
Sea water: 2
Salts: 3
Alkalis: 3
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Weldability:
Most electric welding procedures have proven successful with 431 stainless. Filler metal should be
AWS E/ER410. To avoid cracking, pre-heat the workpiece to 400-600F (204-316C). After air cooling, treat at 1200F (649C) to reattain maximum properties.
8. Products, we supply:
x Plate-strip
66
x Pipes-tubes
x Accessories
x Bars
x Forgings
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UNS S31254
Alloy: UNS S31254
(Cr, Ni, Mo)
UNS: S31254
UNS S31254
1. Chemical composition in %:
Ni
Cr
Mo
18
20
6,2
Co
Fe
Cu
Mn
Si
Rem
0,7
0,020
0,5
0,4
Mini
Max
0,20
2. Mechanical properties:
Yield strength
Tensile strength
Elongation
Hardness
Impact value
Rp0.2
Rp1.0
Rm
A5
HB
KCV
N/mm2
N/mm2
N/mm2
%
J/cm2
min
min
min
min
max
min
Characteristic temperatures
20C
300
340
650
35
210
120
Temp.C
Solidification range
Scaling temperature in air
Hot forming
Quench annealing
Pressure vessel application
*
N/mm min
N/mm2 min
N/mm2 min
270
305
635
1400-1325
1000
1200-1000
1170 water*)
(60)400
235
270
615
195
225
560
175
205
525
160
190
510
3. Physical properties:
20C
Density
Modulus of elasticity
Linear expansion 20 100C
Thermal conduction
Heat capacity
Electric resistivity
g/cm3
kN/mm2
x 106/C
W/mC
J/kgC
nWm
8.0
200
16.5
13.5
500
850
4. Specifications:
Forgings: F-44
5. Characteristics and applications:
The high levels of chromium, particulary of molybdenum, endow S31254 with an extremely good resistance to pitting and crevice corrosion. The addition of copper provides improved resistance in certain acids. Furthermore, due to its relatively high nickel content in combination with the high levels of
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chromium and molybdenum, S31254 possesses a good resistance against corrosion. Numerous field
tests, as well as practical experience, show that S31254 is resistant to crevice corrosion in sea water, even at increased temperatures.
S31254 is delivered in an annealed condition (1150-1200C, rapid cooling) and has an austenitic
structure. In certain cases there may be traces of intermetallic phases (chi-and sigma phase) in the
centre of the material. Normally, however, this has no influence on the impact strength or on the corrosion resistance. When exposed to a temperature range of between 600-1000C, these phases can
precipitate at the grain boundaries. If the given recommendations for hot forming, welding and heat
treatment are followed, there will be no precipitation affecting the corrosion resistance.
CORROSION
RESISTANCE
General corrosion
In a solution containing halides such as chloride, bromide or fluoride ions conventional stainless steels can readily be attacked by localized corrosion in the form of pitting, crevice corrosion or stress corrosion cracking. In certain cases, however, the presence of halides can accelerate the general (uniform) corrosion. This applies especially to cases where halides occur in nonoxidizing acids.
Pitting corrosion
In a solution with a chloride concentration exceeding that of sea water, S31254 possesses a very
good resistance up to high temperatures.
Intergranular corrosion
S31254 has a very low carbon content. Therefore, as far as the connection with the heat input is
concerned, there is little risk of carbide precipitation. Due to the low carbon content and the general
chemical composition, this steel passes the Strauss test (ASTM A 262 Practice E) even after one hour
of sensitizing at 600-1000C.
However, due to the high alloying element content of the steel, intermetallic phases can precipitate at
the grain boundaries as in the above mentioned temperature range. These precipitations do not involve a
risk of intergranular corrosion in the corrosive media where this steel is used. Thus, welding can be carried out without any risk of intergranular corrosion. However, in a hot concentrated nitric acid, these phases can cause risk to intergranular corrosion in the heat-affected zone.
Crevice corrosion
The weak point of the conventional stainless steel grades is their limited resistance to crevice corrosion. In sea water, for example, there is a considerable larger risk of crevice corrosion under gaskets,
deposits or fouling than of pitting on the free surfaces.
S31254 is completely free from attacks, even after exposure to sea water at 60C. Conventional
stainless steel grades, on the other hand, are attacked already at low temperatures by crevice corrosion.
Stress corrosion cracking
Under favourable conditions, stress corrosion cracking can occur in all stainless steels, with the exception of those ferritic grades which are not alloyed with nickel or copper.
For austenitic steels, the resistance to stress corrosion cracking increases with the rise of the nickel and molybdenum contents.
S31254 possesses a very good resistance to stress corrosion cracking. However, this steel grade
does not pass the SCC test in a 45% boiling magnesium chloride test solution, which is the severest
test procedure to detect stress corrosion cracking. The same happens with ferritic steels, alloyed with
nickel or copper and ferritic-austenitic steels.
PROCESSING
Hot working
Hot working should be carried out in the temperature range of between 1150-1000C. Higher temperatures will reduce the workability. Fairly heavy scaling occurs at temperatures exceeding 1150C.
To ensure dissolution of possible precipitations of secondary phases from the hot forming, the subse68
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quent heat treatment shall take place at min. 1150C, followed by the quickest possible cooling. If a cooling rate is too low, it can cause a reduced corrosion resistance.
Cold working
S31254 possesses very good cold formability. Bending, pressing and other forming operations can
be carried out without any difficulty. Thus, practical experience obtained from the pressing of elbows,
tees, reducers, etc. has been very favourable. The steel workhardens rapidly.
MACHINING
Like other austenitic steels, S31254 is tough. The relatively high hardness and the tendency towards work-hardening must be taken into account when this grade is machined.
Fully satisfactory machining results can be obtained when selecting the right choice of tools and machining data.
Applications
Up to the present S31254 has been supplied for the following applications:
Use of equipment in contact with sea water such as heat exchangers, cooling water pipes and
even in cases where stagnant conditions can occur. Desalation plants.
Equipment at pulp bleaching plants, such as drums, vats and press rolls for filter washers, and
pipelines for pulp and filtrate.
Components in gas cleaning systems, e.g. in pulp and metallurgical industries, and in power stations.
Tanks and pipelines for different chemicals with high halide levels.
Equipment used for the destillation of tall oil.
6. Welding properties:
S31254 possesses good weldability and can be welded using conventional welding methods for
stainless steel.
Sheets and plates in grade S31254 have a homogeneous composition. Remelting of the parent metal, such as during welding without filler metal, may cause microscale variations in composition for elements such as chromium, nickel and, particularly, molybdenum. This phenomenon occurs in all highly
alloyed stainless steels. These variations may reduce the pitting resistance of the weld.
The following welding instructions should be observed:
1. The material may not be subjected to abrasive contact with copper/brass items. Penetration of
Cu/Zn into the grain boundaries can give rise to crack formation.
2. P 12 welding consumables should be used for all welding methods. TIG- and plasma -arc- welding
without filler wire should be avoided in cases where post-weld annealing is impossible.
3. Ignite the electrode in the joint since ignition burns beside the weld can give rise to corrosion
attacks.
4. Weld with low heat input, the run energy should not exceed 1.5 KJ/mm. Weaving should be avoided in horizontal position. Do not use unnecessarily high ampearages or thicker electrodes than
necessary.
7. Products, we supply:
x Plate-strip
x Pipes-tubes
x Accessories
x Bars
x Forgings
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AL-6XN
Alloy: AL6XN
(Cr. Ni. Mo alloy)
UNS-N08367
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
Mo
23,5
25,5
20
22
6
7
Co
AL-6XN
Fe
Cu
Mn
Si
0,75
0,3
0,04
0,03
0,18
0,25
2. Mechanical properties:
Maximum Allowable Design Stress Values in tension, ksi (Mpa)
DIMENSIONALLY STABLE Under Cited conditions
For Metal
<3/16 inch thick sheet, >3/16 inch thick plate,
Temperature not
strip, seamless
bar, forgings
exceeeding
45YS
100TS
(310)
(717)
45YS
100TS
(310)
(717)
45YS
100TS
(310)
(717)
45YS
100TS
(310)
(717)
100
38
28.6
(197)
27.1
(187)
24.3
(167)
23.1
(159)
200
93
26.2
(181)
26.2
(181)
22.2
(153)
22.2
(153)
300
149
23.8
(164)
23.8
(164)
20.2
(139)
20.2
(139)
400
204
21.0
(151)
21.0
(151)
18.7
(129)
18.7
(129)
500
260
20.5
(141)
20.5
(141)
17.4
(120)
17.4
(120)
600
316
19.4
(134)
19.4
(134)
16.5
(114)
16.5
(114)
650
343
19.0
(131)
19.0
(131)
16.1
(111)
16.1
(111)
700
371
18.6
(128)
18.6
(128)
15.8
(109)
15.8
(109)
750
399
18.3
(126)
18.3
(126)
15.5
(107)
15.5
(107)
800
427
18.0
(124)
18.0
(124)
15.3
(105)
15.3
(105)
3. Physical properties:
Density 8 Kg/dm3
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4. Specifications:
Norm
Tubes
Seamless Welded
ASTM
B-690
B-829
A-312
B-675
A-249
A-270
A-269
Plates
Sheets
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
Wire
A-240
B-688
B-691
B-472
B-240
B-688
A-462
B-564
B-462
B-366
B-691
B.S.
5. Characteristics, applications:
AL-6XN alloy is a nickel molybdenum alloy with excellent resistance to chloride pitting and crevice
corrosion. AL-6XN has been used for seawater heat exchangers, chemical process tanks and pipelines, offshore oil and gas seawater heat exchangers.
Corrosion Resistance
AL-6XN alloy has proven to be resistant to a broad range of very corrosive processing environments. Exceptional corrosion resistance is obtained to chloride-induced corrosion in the forms of pitting, crevice and
stress corrosion cracking. AL-6XN alloy also has excellent general corrosion resistance to various acids and
salt solutions. This is achieved due to the higher levels of:
Nitrogen which retards the formation of chi phase during manufacturing and field welding
Chromium provides good resistance to oxidizing environments
Molybdenum improves resistance to chlorides.
Cost Comparison
Al-6XN alloy initially is more expensive than 300 series stainless steels. However, life-cycle costs for
systems utilizing the alloy can be far less than the comparable costs of the initial installation, maintenance, and subsequent replacement of lesser alloys used in aggressive environments. In addition to
material replacement, labor costs, and production downtime caused by system failures of 300 series
stainless steels used in very corrosive environments, consideration must also be given to the associated costs of product contamination caused by corrosion related failures. Studies have shown the initial cost comparison of Al-6XN raw material to other alloys as follows:
304L stainless steel = factor of 1 (base)
316L stainless steel = 1.15 (x) 304L stainless steel
AL-6XN Alloy = 3 (x) 304L stainless steel
C-276 / C-22 = 5 (x) 304L stainless steel
When selecting materials for process systems, guidelines should be followed giving consideration to
the service environment. The inclusion of corrosion control and the correct material selection is the
most efficient and economical means for controlling corrosion and adding life to a piping system.
Fabrication
The toughness and ductility of the AL-6XN alloy provides for relative ease of fabrication in the shop
or field environments. Satisfactory machining may be achieved by the selection of the correct tools and
machine set-ups.
General or Uniform Corrosion
General corrosion is rather predictable. The uniform attack of an entire area exposed to a corrosive media usually is expressed as an average loss-of-metal-thickness over a given period of time and
is expressed in units such as mils (0.001 inch) per year, or mpy. Table 1 compares the immersion
corrosion resistance, conducted in accordance with ASTM G-31, of five alloys in eight different boiling acid and alkali solutions. These data illustrate the performance of the alloys in a variety of envi72
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ronments and do not necessarily simulate a particular process or industry environment. Note that
the AL-6XN alloy has a much lower general corrosion rate than the 300 series stainless steels in
these aggressive environments.
Table 1: Corrosion Resistance in Boiling Solutions
Rate ASTM G-31
Test Solution (Boiling)
Type 316L
Alloy 276
0.12 (0.003)
0.48 (0.01)
0.59 (0.02)
0.12 (0.003)
0.48 (0.01)
23.41 (0.60)
18.37 (0.47)
7.68 (0.20)
2.40 (0.06)
2.76 (0.07)
44.90 (1.23)
48.03 (1.14)
27.13 (0.69)
7.32 (0.19)
11.24 (0.28)
0.60 (0.02)
0.72 (0.02)
0.47 (0.01)
0.24 (0.006)
0.36 (0.009)
71.57 (1.82)
55.75 (1.42)
8.88 (0.23)
4.56 (0.12)
2.64 (0.07)
77.69 (1.92)
32.78 (0.83)
9.61 (0.24)
11.4 (0.29)
17.77 (0.45)
124.3 (3.16)
93.26 (2.39)
9.13 (0.23)
9.36 (0.24)
2.64 (0.067)
645.7 (16.15)
298.3 (7.58)
100.8 (2.53)
71.9 (1.83)
13.93 (0.35)
Pitting Corrosion
Probably the most important characteristic of a stainless steel alloy exposed to chloride containing solutions is its resistance to pitting and crevice attack. The pitting resistance of an austenitic
stainless steel may be correlated to alloy composition in terms of the Pitting Resistance Equivalent
Number. PREN = %Cr + 3.3 (%Mo) + 16 (%N); where chromium, molybdenum and nitrogen are in
weight percent. Increasing the molybdenum in the alloy produces greater resistance to pitting. Therefore high molybdenum-high chromium alloys generally provides the best pitting resistance.
Another important consideration is the chloride pitting potential of stainless steel. This is an indication of the susceptibility of the alloy to localized corrosion. If the potential is more positive, the
chances of pitting are reduced.
The Critical Pitting Temperature (CPT) is the minimum solution temperature at which pitting is
first observed. When compared to the other alloys in these tests, the AL-6XN alloy demonstrated
a significantly greater resistance to pitting.
Critical Pitting Temperatures
CCCT1
CPT2
CPT3
Product
304
316
317
904L
AL-6XN
<27.5
27.5
35
68
110
<-2.5
2.5
1.7
20
43
59
66
104
177
15
18.9
40
80.5
77
113
172
25
45
78
Increasing the acidity (decreasing the pH), of a solution beyond a certain value may result in a
dramatic increase in the general corrosion rate. This value is referred to as the depassivation pH,
above which the rate is low and below which the rate is high. Corrosion rates in an acidified 3.5%
sodium chloride solution at room temperature for austenitic stainless steel, ferritic stainless steel,
and AL-6XN stainless show that AL-6XN alloy is the most resistant of the austenitic stainless alloys.
The AL-6XN alloy corrosion rate does not appreciably increase until the solution pH falls below 0.3.
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Crevice Corrosion
Crevice corrosion is another form of localized corrosion that occurs when the corroding metal is in
close contact with anything that makes a tight crevice. Metal degradation at the mating surface of a
sanitary clamp fitting and gasket is usually the result of crevice corrosion. Crevice corrosion is usually
the first to occur and is predictable as to when and where it will take place. Like pitting, the presence
of chlorides makes the reaction proceed at a fast rate. There is a critical crevice corrosion temperature (CCCT) below which corrosion will not occur. The greater the difference between the CCCT and
the operating temperature, the greater the probability that crevice corrosion will occur.
Intergranular Corrosion
The most common example of intergranular corrosion is the formation of chromium carbide in
the heat-affected zone (HAZ) of higher carbon stainless steel duringwelding. These carbides form
along the grain boundaries. Because the carbides require more chromium than is locally available,
the carbon depletes chromium from the area around the carbon. The grain boundary zone is left low
in chromium and creates a new, low chromium alloy in that region. A mismatch in galvanic potential between the base metal and the grain boundary results, so galvanic corrosion begins. As the
grain boundaries corrode, the grain and the chromium carbides drop out like particles of rusty sand.
The surface of the metal develops a sugary appearance.
Intergranular corrosion also can occur whenever intermetallic compounds such as chi or sigma
phase form. These compounds usually form when some type of heating occurs, such as welding, heat treatment, or metal fabrication. Understanding how they form makes it relatively easy to control
their formation. Since AL-6XN stainless has low carbon, chromium carbide formation usually is not
a problem. However, chi phase may be a problem as it forms when the weld metal cools after welding, especially in the heat affected zone, or if heat treatment is improperly performed, or if the alloy
is held for a short time in the 1200-1800F (650-1000C) range.
Stress Corrosion Cracking
Because the AL-6XN alloy has increased resistance to SCC it has been used successfully in applications such as chemical process equipment, brewery equipment, feed-water heaters, and flue gas
reheaters. AL-6XN alloy is very resistant to SCC at temperatures less than 121C. The threshold
temperature for initiating SCC decreases with increasing chloride content.
Applications
AL-6XN alloy is currently in use in the following industries:
Food Processing
Pharmaceutical
Biopharmaceutical
Brewery
Desalination
Semi-conductor
Aerospace
Pulp & paper
Sports drinks
Ketchup
Soy sauce
Barbecue sauce
Salsa
Fine chemicals
Cosmetics
Pharmaceuticals
6. Welding properties:
Good weldability.
The low carbon and high nitrogen contents minimize the precipitation of carbides and secondary
phases that can occur during welding. Field welding can be easily achieved provided that a suitable overmatched filler ring is used and the material has been properly cleaned and prepared for welding. Welding procedures are similar to those used with other austenitic stainless steels.
7. Products, we supply:
x Plates, sheets
74
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x Bolting
CATALOGO
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Pgina 75
904L
Alloy: 904L
(Cr. Ni. Mo alloy)
UNS-N8904
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
Mo
23
28
19
23
4
5
Co
Fe
Cu
1
2
0,02
Mn
Si
0,045
0,035
904L
2. Mechanical properties:
Tensile strength, mini: 490 MPa
Yield strength, mini: 215 MPa
3. Physical properties:
Density (lb / cu. in.) .......................................... 0.285 and 8 Kg/dm3
Specific Gravity ........................................................................... 7.9
Specific Heat (Btu/lb/Deg F - [32-212 Deg F]) ............................. 0.12
Electrical Resistivity (microhm-cm [at 68 Deg F]) ............................ 480
Modulus of Elasticity Tension ...................................................... 28.4
4. Specifications:
Norm
ASTM
Tubes
Seamless Welded
Plates
Sheets
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
Wire
B-674
B-625
B-649
B-625
A-182
B-649
B-366
B-649
B-673
B-674
B.S.
AF-NOR-ZIN CDU 25,20
DIN-1.4539
5. Characteristics, applications:
Principal Design Features
904L is an austenitic stainless steel designed for moderate to high corrosion resistance. Its low carbon
content improves cleanliness and weld strength.
Corrosion Resistance
High leves of chromium, nickel, molybdenum and copper give 904L good resistance to stress corrosion
cracking, chloride pitting and to reducing media such as hot phosphoric acid and dilute sulfuric acid. In these areas it is superior to 316 and 317.
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This austenitic speciality with its high molybdenum and a reduced carbon contets offers excellent resistance to:
Special characteristic:
Extraordinary resistance to pit corrosion, stress corrosion and intergranular corrosion.
Structure after heat treatment, austenitic.
With application up to 400C and an operation up to 100000 h, grade 904L is resistant to intercrystalline corrosion acc. to DIN 50914.
Machinability
Slow speeds and positive feeds will minimize this alloys tendency to work harden and glaze. Use chip breakers where possible to overcome problems with long draggy chips.
Hot Working
Hot work should proceed after uniform heating to 2000-2200 F. Do not work the material at less than
1800F. Full annealing should follow any hot work to retain maximum ductility and corrosion resistance.
Cold Working
Although higher forces are required, 904L will respond in a similar fashion to other austenitic stainless
steels like 304, 316 or 317. Most common operations can be successfully performed.
Annealing
1920-1990F (1050-1090C), rapid cooling.
Hardening
This alloy does not respond to heat treatment. It may only be hardened by cold reduction.
Applications
Utility scrubber assemblies, acid and fertilizer production equipment. Desalation plants.
For highly critical corrosion problems in the chemical and petrochemical industry, pulp and paper industry
as well as for flue gas desulphurization plants.
6. Welding properties:
Most common fusion and resistance methods may be employed. For maximum corrosion resistance, it is recommended to use filler metals of equal or higher alloy content.
7. Products, we supply:
x Plates, sheets
76
x Tubes
x Fittings
x Bars
x Forgings
x Bolting
CATALOGO
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13:35
Pgina 77
UNS S31803
Alloy: UNS S31803
(Cr. Ni. alloy)
UNS: S31803
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
Mo
4,5
6,5
21
23
2,5
3,5
Co
Fe
Cu
Mn
0,03
Si
1
P
0,03
0,02
0,08
0,20
UNS S31803
2. Mechanical properties:
At room temperature
heat-treated
condition
0.2 yield
point
min.
N/mm2
psi
480
69600
450
65250
quenched
flat products
profile products
tensile
strength
elongation
(L 5 d)
% min.
N/mm2
psi
680-880
98600-127600
680-880
98600-126600
long
30
long.
transv.
72
53
140
103
At higher temperatures:
50
122
100
212
150
302
200
392
250
482
280
536
410
59150
360
52200
335
48575
310
44950
295
42775
285
41325
C
F
0.2% yield point min.
N/mm2
psi
3. Physical properties:
Characteristic temperatures
Specific gravity
g/cm3
7.8
Specific heat
J/kg K
0.377
Thermal conductivity
W/m K
16
expansion 20-100C
106/K
12
Electrical resistivity
microohm cm
80
Coefficient of linear
Modulus of elasticity
at 20C
kN/mm2
200
Solidification range
Scaling temperature in air
Sigma phase formation
Carbide precipitation
475 embrittlement
Hot forming
Quench annealing
Stress relief annealing
Range for pressure vessel application
Temp. C
1445-1385
1000
700-900
450-800
350-525
1150-950
1020-1070
1020-1070
(10) 280
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Pgina 78
4. Specifications:
Norms
Material
Pipes-Tubes
Seamless Welded.
DIN
1.4462
Plates
Rounds,
Strips
Wires
Forgings
Sheets
Bars
Flanges
1.4462
1.4462
F-51
A240
A276
A182
Fittings
BS
ASTM
A479-A182
A789
A790
A815
ISO
AFNOR
Z3CND22.05AZ
CATALOGO
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Pgina 79
262, Practice B), these specimens did not undergo intergranular corrosion and after a 180 bending
no cracks have been observed.
CORROSION
RESISTANCE
General corrosion is characterized by an uniform attack of the steel surface when it comes into contact with a corrosive medium. The resistance is normally considered good if the corrosion rate is less
than 0.1 mm/year, due to its high chromium and molybdenum content.
Duplex has a better resistance than type 316 and 317 in most mediums.
Intergranular corrosion
Thanks to the Duplex structure and the low carbon content, Duplex has a very high resistance to
intergranular corrosion. In general, when welding ferritic-austenitic steels, a narrow heat-affected zone, close to the fusion line is obtained, where the structure may become fully ferritic. Chromium carbides precipitate rapidly in such a zone; thus, producing a risk of intergranular corrosion. However, Duplex has a balanced composition which ensures a sufficient amount of austenite in the heat affected
zone to minimize the risk of undesirable carbide precipitation.
Sulphide strees corrosion cracking
The presence of hydrogen sulphide in chloride solutions entails the risk of stress cracking also at
lower temperatures. The resistance of Duplex stainless steels varies with the chemical composition and
the microstructure. One example of the types of environments where sulphide stress corrosion cracking may occur is in sour oil and gas wells. Duplex has proved to be very resistant in such environments. Contrary to chloride induced stress corrosion cracking, sulphide stress corrosion cracking also
attacks the ferritic phase. Laboratory tests have shown that Duplex has a high resistance to sulphide
stress corrosion cracking.
Pitting and crevice corrosion
The resistance to these types of corrosion is increased by an addition of chromium, molybdenum
and nitrogen.
Stress corrosion cracking
Conventional austenitic stainless steels may be attacked by stress corrosion cracking in chloride environments at elevated temperatures. Duplex stainless steels with a continuous ferrite phase, are much
less prone to this type of corrosion.
Corrosion fatigue
The high mechanical strength combined with the very good corrosion resistance gives Duplex a high
corrosion fatigue strength.
PROCESSING
Hot forming should be carried out in the temperature range of 1200-900C/2200-1650F. After
this a final heat treatment is required.
However, it should be borne in mind that the mechanical stength of the material is low at high temperatures.
At temperatures below 950C embrittling can take place on account of the combination of strain
and exposure in the sigma phase field.
At room temperature cold working can be done without any problems. Cold working >10% entails also a final heat treatment. Work hardening is higher than that of austenitic stainless steels, necessitates,
however, accordingly higher forces of deformation and tools with higher maintenance of cutting power.
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MACHINING
With high speed tools the same cutting data can be applied as with type 316. However, when cemented carbide tools are used the cutting speeds have to be reduced by 20%.
HEAT
TREATMENT
All forms of supply are normally delivered in the solution-annealed condition. The temperature of
solution annealing ranges between 1040 and 1100C/1900-2000F. Up to 2 mm/0.078 in. quenching can be carried out in air, for thicknesses greater than 2 mm/0.078 in. water quenching will
be necessary.
Hot working
C
F
1200-900
2200-1650
cooling medium
air
heat-treatment
C
F
1040-1100
1900-2000
time min.
cooling medium
just soaking
Structure after heat treatment: ferriteaustenite. Stress relief treatments can in special cases be performed at 550-600C
6. Welding properties:
Duplex is easily weldable by all welding processes.
Duplex steels require somewhat more careful attention when being welded than normal austenitic
steels. The following precautions should be observed:
The material should be welded without preheating.
Welding should be performed using a low heat input. The material should be allowed to cool, preferably below 150C between passes. Do not use higher amperage than necessary. Increased
electrode diameter means higher heat input, if not compensated by higher welding speed.
Duplex can be welded using the following methods:
Manual metal arc with covered electrodes
Gas shielded arc welding such as TIG, plasma and MIG
Submerged arc welding
Post weld heat treatment is normally not necessary. In cases where heat treatment is considered,
for example for stress relieving, this should be carried out at the temperature range of between 10201070C.
7. Products, we supply:
x Plate-strip
80
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
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13:35
Pgina 81
FERRALIUM-255
Alloy: Ferralium-255 (SD 40)
(Cr. Ni. Mo. alloy)
UNS-S32550
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
4,5
6,5
24
27
Mo
Co
Fe
Cu
3,5
Mn
0,03
Si
N
0,08
0,20
FERRALIUM-255
The composition above is that shown for UNS S3250 in ASTM A240. The composition of Ferralium
alloy 255[SD40] falls within this range but the exact proprietary compositional range is confidential and
is not released. The standard requirements for Pitting Resistance Equivalent (PRE.N) are met, where
PRE.N = %Cr + 3.3%Mo + 16%N > 40.0.
2. Mechanical properties:
At room temperature
Typical Properties
tons f/in2
N/mm2
tons f/in2
N/mm2
Solution
Treated &
Stress Relieved
Solution
Treated
& Aged
31.7
490
47.9
740
25
44
60
220-270
36.9
570
53.7
830
23
37
50
250-330
780 N/mm2
540 N/mm2
28%
>100 Joules
800 N/mm2
400 N/mm2
1020 degrees
Ferralium alloy 255 is normally supplied in the solution-treated and stress relieved condition. The excellent mechanical properties obtained in this condition can be raised further by ageing and if required
shoud be stated at the order stage.
ELEVATED
The recommended maximum continuous operating temperature for Ferralium alloy 255-3SF is
275C. The alloy can be used for occasional short periods at slightly higher temperatures but care
should be exercised.
The lowest temperture for which Ferralium alloy 255-3SF can be considered is around minus 50C. The
V-notch impact at minus 18C is typically 80-100 Joules.
FATIGUE
CHARACTERISTICS
Ferralium alloy 255-3SF has excellent resistance to fatigue and corrosion fatigue, making it particularly
suitable for items such as shafts in seawater environments.
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3. Physical properties:
Density at 20C kg/m3
g/cc
lb./in3
Mean Coefficient of Thermal Expansion, K-1
7806
7.81
0.282
11.1 x 10-6
11.5 x 10-6
12.0 x 10-6
12.4 x 10-6
12.9 x 10-6
13.6
14.2
14.7
15.2
15.8
16.3
18.4
0.80
80
31
33
29 x 106
199 x 103
11 x 106
75 x 103
0.32
20-100C
20-200C
20-300C
20-400C
20-500C
0C
20C
40C
60C
80C
100C
200C
microhm-m
microhm-cm
microhm-in
Magnetic Permeability
Youngs Modulus
Ib.f/in2
N/mm2
Ib.f/in2
N/mm2
Torsional Modulus
Poissons Ratio
4. Specifications:
Norm
ASTM
Tubes
Seamless Welded
A-789
A-790
A-789
A-790
Plates
Sheets
A-240
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
A-240
A-182
A-473/9
A-815
Wire
5. Characteristics, applications:
Description
Ferralium alloy 255-3SF is a high strength, high alloy duplex stainless steel made under the same Patent
which covers the standard Ferralium alloy 255. It has an even more closely controlled composition and heat treatment so as to achieve the optimum corrosion resistance from the alloy system but can be machined and welded as readily as the alloy 255.
This wrought alloy which complements the advanced cast Ferralium alloy 255-3SC has been developed especially for the more critical applications in oil and gas production both offshore and onshore, and in naval ships in fact wherever a high degree of resistance to pitting and crevice attack
in addition to general corrosion resistance is important. Its resistance to acids, notably to sulphuric acid up to about 65% concentration, is also significantly improved so that it is very useful for
handling all kinds of contaminated waters.
Compared with other commercially available duplex alloys such as W.NR 1.4462 (often designated
2205) it has higher strength but retains good ductility and its corrosion resistance is of a significantly hig82
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Pgina 83
her order in both sea water and acids. Against the conventional high alloy austenitic alloys characterised
by UNS NO8904 it has both higher strength and much better resistance to selective attack, approaching
that of the so-called 6Mo alloys although the PRE (pitting resistance equivalent) values of the latter are
slightly higher. However it must be appreciated that PRE is not an absolute measure and is merely a broad
method of grading by calculation from the Cr, Mo and N contents of the alloy. The PREN value for Ferralium
alloy 255-3SF exceeds 37. As with Ferralium alloy 255, a significant copper content in Ferralium alloy 2553SF enhances the basic corrosion resistance of the high alloy duplex structure (approximately 50:50) controlled by the chromium, molybdenum, nickel and nitrogen contents. In particular, the copper tends to retard pitting and crevice attack and benefits resistance to sulphuric acid.
Ferralium alloy 255-3SF is relatively noble in a galvanic table, comparing with titanium, and has a rest
potential of +0.04 volts (S.C.E.) in 3% Na Cl.
The good resistance to erosion provided by Ferralium alloy 255 is equalled by the alloy 255-3SF, especially in the age-hardened condition.
In the solution-treated condition the hardness of alloy 255-3SF is within the limit set by NACE MR-0175 and Ferralium alloy 255 in the wrought form is now included by name in this Material Recommendation.
The UNS number for Ferralium alloy 255-3SF is S32550.
CORROSION RESISTANCE
Crevice Corrosion
The 300 series austenitic stainless steels are particularly susceptible to a breakdown of their passive film
under crevice conditions in sea water and other corrosive waters. Some highly alloyed ferritic stainless steels resist crevice corrosion attack much more successfully, as can ferritic/austenitic alloys.
Ferralium alloy 255-3SF is even better than wrought Ferralium alloy 255 which already led the field in
resisting this form of attack. For comparison and grading of materials it is widespread practice to use accelerated tests in FeCl3. The table below shows comparisons between Ferralium alloy 255-3SF, some other
wrought duplex alloys and austenitic alloys. The critical crevice temperatures were determined on specimens having a bold (uncovered) to crevice area ratio of approximately 20:1; significant changes in the above ratio may alter the critical crevice temperature.
Critical Crevice Corrosion Temperatures in 10% FeCl36H20 (pH1)
CCTC
Ferralium alloy 255-3SF
Ferralium alloy 255
2205 (1.4462)
30
20
17.5
CCTC
CN7M modified (4.5 Mo) (cast)
DP3 (25Cr/7Ni/3Mo + W)
316 stainless steel
0 to 12.5
10
2.5
Pitting Corrosion
The pitting resistance of most duplex stainless steels is superior to that of the standard austenitic alloys
such as types 316 and 317 even in low carbon grades.
Ferralium alloy 255-3SF offers a further advance in pitting resistance compared with Ferralium alloy
255, already outstanding in this respect. The critical pitting temperature of alloy 255-3SF in 3% NaCl solution is compared with some other wrought alloys below.
The results presented in the table may be less than claimed elsewhere for the alloys other than the Ferralium alloys. This can be due to the difference in detail between the precise test methods employed. All
the figures were established by an identical procedure used in the same test equipment so that they represent a true comparison.
Critical Pitting Temperatures in 3% NaCl (deaerated)
CCTC
Ferralium alloy 255-3SF
Ferralium alloy 255
2205 (1.4462)
40
30
20
CCTC
CN7M modified (4.5 Mo) (cast)
316 stainless steel
20
0
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Pgina 84
The presence of copper in Ferralium alloy 255-3SF, as in alloy 255, is particularly benefical in aiding the
resistance to initiation and particularly to propagation of pitting attack. A minimum of 1% copper is essential to ensure the optimum resistance to pitting.
Stress Corrosion
The stress corrosion cracking resistance in chloride environments of Ferralium alloy 255-3SF is, in common with standard alloy 255, greatly superior to that of the standard austenitic stainless steels. A considerable amount of test data and service experience with Ferralium alloy 255 has demonstrated the alloys
excellent performance in resisting this form of attack. Alloy 255-3SF is identical in performance to the standard alloy and data can be provided if required.
One factor in handling sea water is that in many situations it may be polluted. For example, harbour water and oil field water may contain considerable amounts of dissolved hydrogen sulphide. This can destroy
the passivation of stainless steels, leading to accelerated pitting, increased propensity to crevice attack and
potentially most damagingly to stress corrosion cracking. The beneficial effect of copper in stabilising the
passive film helps Ferralium alloy 255-3SF to combat these forms of attack and the modified chemistry of
the alloy further improves resistance to the stress corrosion hazard created by the presence of H2S. Where Ferralium alloy 255 is required to meet the requirements of NACE MR-01-75, in which it appears by name, this is satisfied by supplying the alloy in the solution treated and stress-relieved condition.
Acids
Ferralium alloy 255-3SF possesses far superior resistance to sulphuric acid compared with conventional austenitic stainless steels such as type 316. For many years alloy 255 has been used very successfully
in the lower and higher concentrations of sulphuric acid.
The selection chart is based on tests on material machined and later tested rather than on freshly abraded samples. Freshly abraded samples or activated samples may exhibit different rates of corrosion. This
is of particular significance in aggressive non-oxidising acid conditions.
The application of Ferralium alloy 255-3SF in sulphuric acid can be further extended in strongly aerated solutions and in the presence of oxidising substances but it is essential to carry out tests to establish suitability.
The outstanding resistance of Ferralium alloy 255-3SF to commercial phosphoric acid containing impurities such as hydrofluoric acid, chlorides and sulphuric acid combined with its excellent resistance to wear
and erosion renders the alloy of special interest for critical components on pumps, valves and fluid handling equipment generally in the production of fertilizer grade phosphoric acid where hot abrasive slurries are
involved. Ferralium alloy 255-3SF and the cast alloy 255-3SC can often replace more expensive highly alloyed stainless steels and nickel based alloys.
Ferralium alloy 255-3SF will successfully resist a wide range of acid mixtures such as sulphuric/nitric,
phosphoric/nitric and nitric/adipic and is highly resistant to acetic, formic and other organic acids where
halide contamination may be present.
PITTING
AND
CREVICE CORROSION
IN
CHLORIDE ENVIRONMENTS
Ferralium 255 & Ferralium SD40 possess outstanding resistance to pitting and crevice corrosion in marine and seawater environments. They match the resistance of any other superduplex stainless steel and
are far superior to the so-called marine grades of stainless steel, such as AISI 316 and 317, and the standard type duplexes such as Alloy 2205. The carefully controlled composition of Ferralium SD40, which is
specifically designed as an offshore grade of superduplex and which has a substantial content of nitrogen
and molybdenum, gives a Pitting Resistance Equivalent (PREN) > 40.0, where PREN = %Cr + 3.3%Mo +
16%N.
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Conc.
w/w
alloy
CF-8M (316)
CN-7M
255-3SF
0-50%
Boiling
Hot
Acetic Anhydride
to Boiling
(urea production)
to 120
Ammonium Chloride
All
75
Ammonium Hidroxide
Citric Acid
All
to Boiling
to Boiling
Acetic Acid
Ammonium Carbamate
20
2%
100
Formic Acid
Hydrochloric Acid
Nitric Acid
0-60%
Nitric Acid
Boiling
70%
Boiling
Phosphoric Acid
All
Phosphoric Acid
0-60%
Phosphoric Acid
Phosphoric Acid
Wet Process
to 100
Boiling
60%-70%
120
88%
Boiling
80
80-90
to Boiling
25%-35%
P2O5
45%-55%
fertilisers
Potassium Chloride
Phosphoric Acid in
production of phosphate
P2O5
0-30%
Sea Water
to Boiling
Sodium Hydroxide
All
20
Sodium Hydroxide
All
Boiling
0-98%
40
Sulphuric Acid
5%-30%
80
Sulphuric Acid
30%-50%
60
Sulphuric Acid
98%
100
Sulphuric Acid
98%
150
Sodium Chloride
Sulphuric Acid
to 80
100
Sulphuric Acid/Nitric
Acid Misture 43% H2SO4,
25% HNO3, 32% H2O
Notes:
1. Ferralium alloy 255 more resistant to pitting in the presence of chlorides.
2. Ferralium alloy 255 more resistant to pitting and selective attack under crevice and stagnant conditions.
3. Plant tests recommended.
4. Plants tests recommended.
5. Data relates to CF-8C (347).
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EROSION
Pgina 86
AND WEAR
The resistance of Ferralium alloy 255-3SF to erosion, cavitation and wear is extremely good, being the
same as that of the standard alloy 255. Many established applications utilise this property to advantage
most notably in pumps and valves.
MACHINING
FERRALIUM alloy 255-3SF can be readily machined and although considerably harder than the austenitic stainless steels, the same techniques can generally be used. High speed tools can be used but speeds
can be substantially increased by the use of carbide tipped tools.
In common with many stainless steels and high strength materials, heavy machining on Ferralium alloy
255-3SF can sometimes result in slight movement during subsequent operations. This may be accetuated
by surface work hardening if blunt tools are used.
Whilst this movement is not significant in most cases, components requiring specially close tolerances
should be given a stress relief.
STRESS CORROSION CRACKING
The stress corrosion cracking resistance in chloride environments is far superior to any of the standard
austenitic grades. Ferralium 255 & Ferralium SD40 have been successfully tested to 100% of yield
strength in boiling seawater and the tests have shown that the alloys are not susceptible to stress corrosion cracking, even under these extreme conditions.
CORROSION
The corrosion resistance of Ferralium 255, which is designed specifically as a chemical grade superduplex, is generally superior to that of the standard austenitic types in sulphuric, phosphoric, nitric and many other acids and salts. Ferralium 255 is highly resistant to acetic acid, formic acid and
other organic compounds. They are particulary suitable for the higher concentrations and temperatures where pitting and preferential corrosion are common causes of failure with standard austenitics in the presence of chloride and other impurities.
Ferralium 255 & Ferralium SD40 are proprietary super duplex stainless steels, containing approximately 26% chromium, 6% nickel, 1.6% copper, 3.3% molybdenum and 0.24% nitrogen. The materials are the latest refinement of the Ferralium series of superduplex stainless steels and Ferralium
SD40 was specifically introduced to comply with those specifications calling for a Pitting Resistance
Equivalent (PREN) > 40.0.
The main features of Ferralium 255 & Ferralium SD40 are:
Excellent corrosion resistance in a wide variety of corrosive chemicals including sulphuric, phosphoric and nitric acids.
Outstanding resistance to pitting and crevice corrosion in seawater and other chloride containing
environments, Pitting Resistance Equivalent (PREN) exceeds 40.0.
High strengh compared to austenitic and 22% chrome duplex stainless steels.
Excellent ductility and impact strength at both ambient and sub-zero temperatures.
High resistance to abrasion, erosion and cavitation erosion.
Excellent resistance to stress corrosion cracking in chloride containing environments compared
to standard austenitics.
Since the original Ferralium grade was invented at Langley Alloys in the 1960s, the Ferralium alloy
series have been providing excellent service in a wide variety of corrosive environments. Some of the
existing industries and applications where the alloys have been successfully used are listed below.
Chemical Process Industry. Sulphuric Acid Production, Nitric Acid Processes, Polypropylene Production, PVC Production, Titanium Dioxide Production, Caustic Evaporators, Equipment Handling
Organic and Fatty Acids.
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Marine Industry and Shipbuilding. Propellers and Shafts, Rudders, Shaft Seals, Pumps, Bolts
and Fasteners, Valves, Instrumentation, Oil and Chemical Tankers.
Oil and Gas Industry. Pumps, Valves, Pipe, Vessels, Welllhead Equipment, Subsea Equipment.
Pollution Control. Fans and pumps, Wet Scrubbers, Incinerators.
Copper Semlting. ID Fans, Tuyeres bars, Wet Scrubbers, Leaching Area Precipitators.
Pulp and Paper Industry. Black liquor heater tubes, Digester Blow Valves, Rotary Feed Valves,
I.D. Fans, Brownstock Washers, Precipitators, Bleaching Components.
Food Industry. Sugar Cane Centrifuges, Corn and Vegetable processing plant.
Agrochemicals. Fertiliser Production (Wet phosphoric acid).
Civil Engineering. Statue of Liberty supporting structure, Swimming Pools, Sewage Treatment.
HEAT
TREATMENT
The standard solution heat-treatment for Ferralium alloy 255-3SF is carried out at 1060C followed by
rapid quench, preferably in water. Uniformity of temperature within a range of 10C is essential and adequate time should be allowed so as to ensure that the material is fully soaked throughout at the temperature. Quenching should be carried out immediately on removal from the furnace, with the minimum of cooling in air during transfer to the quenche tank.
Stress Relief
This should be carried out by heating to 350C and holding for two hours at temperature followed by air
cool. Depending upon the nature of the component, the extent of machining and the tolerances required,
this treatment may be carried out at one or more stages of the machining cycle.
Ageing
We recommend that ageing heat-treatment is carried out only by the manufacturer, as it requires a very
careful control.
6. Welding properties:
There is very extensive experience in the welding of the standard wrought Ferralium alloy 255 and
Ferralium alloy 255-3SF can be welded equally readily.
It is recommended that only Ferralium alloy 255 HB flux coated electrodes be used to weld Ferralium
alloy 255-3SF. These electrodes have been specially developed to ensure sound welds and satisfactory
properties in the deposited metal. The use of any other electrodes will be most unlikely to result in
welds with both acceptable ductility and the corrosion resistance of the parent metal.
Pre-heat before weldings is not required and maximum interpass temperature is 300C. Heat input should be as low as possible consistent with achieving sound welds.
Ferralium alloy 255-3SF is normally supplied in the solution-treated (and stress relieved) condition,
which is the ideal for welding of the alloy.
Welds in light sections and minor repair welds do not generally require post-weld heat-treatment but
heavy section welds should preferably be given a solution treatment after welding so as to ensure maximum corrosion resistance and ductility.
Carbon steel and standard austenitic stainless steels can be welded to Ferralium alloy 255-3SF using
either Ferralium alloy 255 HB electrodes or one of the specialised electrodes developed for welding of
dissimilar materials.
7. Products, we supply:
x Plates, sheets
x Tubes
x Fittings
x Bars
x Forgings
x Bolting
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SD-F55
UNS S32760
Alloy: UNS-S32760 (Super Duplex) F-55
(Cr. Ni. Mo. alloy)
UNS-S32760
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
Mo
6
8
24
26
3
4
Co
Fe
Cu
Mn
Si
0,5
1
0,03
0,03
0,01
0,2
0,3
0,5
1
X
SD-F55
UNS S32760
Room temperature
WROUGHT
(UNS S32760)
YIELD SRENGTH
(0.2% offset)
TENSILE STRENGTH
ELONGATION IN 50 mm
HARDNESS
550 MPa
(80 Ksi)
750 MPa
(109 Ksi)
25%
28 HRC MAX
PRODUCT
FORM
FORGINGS
BAR
PLATES
(up to 30mm)
TEMP
(C)
(F)
20
50
100
150
200
250
300
68
122
212
302
392
482
572
PRODUCT
FORM
PLATES
(31 TO 70mm)
TEMP
(C)
(F)
20
50
100
150
200
250
300
68
122
212
302
392
482
572
YIELD
STRENGTH
0.2% OFFSET
(MPa)
(ksi)
550
500
470
450
430
400
385
80
73
68
65
62
58
56
YIELD
STRENGTH
0.2% OFFSET
(MPa)
(ksi)
550
470
430
400
380
370
360
80
68
62
58
55
54
52
TENSILE
STRENGTH
(MPa)
(ksi)
750
725
700
680
670
650
635
109
105
102
99
97
94
92
TENSILE
STRENGTH
(MPa)
(ksi)
750
700
670
620
610
600
590
109
102
97
90
88
87
86
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The above properties for forgings are typical values for section thicknesses up to 300 mm solid or
250 mm in an annulus with a minimum bore of 100 mm. As the properties from forgings are very dependent upon the product route and the actual forging ratio then properties and design are by agreement for other than standard items.
It is not recommended for uses which involve extended exposure to temperatures greater than
300C (572F) as there is a substantial reduction in toughness.
Impact Strength
It has good impact strength. There is no true ductile brittle transition, just a gradual decrease in impact energy as the temperature is lowered. The impact energy varies according to product type and
production route. The impact strength is slightly less than that of parent metal.
3. Physical properties:
Density
The density is 7.84 g/cm3(7840 kg/m3 or 489 lb/ft3) at 20C (68F)
Specific Heat
Thermal Conductivity
Typical values
TEMP
(C)
SP. HT.
(J KG-1 K-1)
TEMP
(C)
THERMAL COND
(Wm-1 K-1)
20
100
150
200
250
300
482
500
513
523
535
547
20
100
150
200
250
300
12.9
14.4
15.4
16.3
17.3
18.2
Thermal Expansion
Resistivity
20-100
12.8
11.5
20-200
13.3
12.2
20-300
13.8
12.9
16.8
17.2
17.6
TEMP
(C)
20
100
150
200
250
300
WROUGHT
ZERON 100
0.851
0.897
0.927
0.956
0.985
1.014
Magnetic Permeability
At room temperature the peak relative magnetic permeability is typically 29.
Youngs Modulus
The modulus is a function of austenite/ferrite ratio and production route. Variations of 5% are
found with both wrought and cast products. The typical value at room temperature is 190 GPa
(27600 ksi).
Poissons Ratio
The typical value at room temperature is 0.32.
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4. Specifications:
Norm
Tubes
Seamless Welded
ASTM
A-790
A-789
A-790
A-789
A-928
B.S.
DIN
Plates
Sheets
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
A-240
A-276
A-479
A-240
A-182
A-988
A-473
A-988
A-815
EN10028-7
EN1088-2
EN10088-3
EN10273
Wire
1.4541
Fasteners ASTM-A-320.
5. Characteristics and applications:
This is a highly alloyed duplex stainless steel for use in aggresive environments. Its properties include:
The combination of the above properties makes the optimum choice in a range of industries. Oil and
gas industry applications include process, seawater, firewater, and subsea pipework systems, with associated risers, manifolds, pressure vessels, valves and heat exchangers. Applications in other industries
include pipework systems and associated engineering equipment for pollution control, pulp and paper, power generation, flue gas desulphurisation, chemical, pharmaceutical, desalination, mining, metallurgical
and marine industries.
CORROSION RESISTANCE
It is highly resistant to corrosion in a wide range of organic and inorganic acids. The copper content gives excellent resistance to corrosion in many non-oxidising acids. Commercial acid applications often contain chlorides and other impurities which can cause corrosion of some stainless steels. It offers much improved corrosion performance in these environments.
It is also highly resistant to strong alkalis. The production of caustic soda results in hot, strong solutions
and even in 60 wt% caustic soda, SD-F55 has very low corrosion rates (<0.1 mm/y). Caustic soda is often
found with chlorides in extraction processes and even with 10g/l chloride, SD-F55 has excellent corrosion
resistance. Three years service experience of fabricated pipework in 2M caustic soda with chlorides at
230C has been excellent.
Pitting Corrosion
Exposure to 6% FeCl3 for 24 hours in accordance with ASTM G48 method A to determine the maximum
temperature at which no pitting occurs (the critical pitting temperature, CPT) has given the following results:
Solution annealed wrought: 70-80C (158-176F) depending on product form and manufacturing route.
These values are for single exposure testing; testing a single specimen at a series of increasing temperatures gives a higher CPT value.
Crevice Corrosion
The resistance to localised corrosion is often assessed by use of the PREN number (%Cr + 3.3%Mo +
16%N). It is made to a minimum PREN of 40, ensuring a guaranteed and high resistance to pitting and cre91
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vice corrosion. Has been in service in sea water since 1986 as castings, and since 1989 as wrought pipes and fittings giving satisfactory performance.
At sea water temperatures above ambient (20C) the risk of crevice corrosion increases. Resists crevice corrosion up to 55C but is limited by the pitting resistance of the welds to about 40C. With the application of post weld treatments sea-water temperatures up to 65C have been handled successfully. Short
term elevated temperature upsets are not uncommon in cooling water circuits. Laboratory tests have
shown that does not suffer crevice corrosion easily during short upsets to 70C, and when corrosion does
initiate, repassivation occurs rapidly on cooling, from 42C.
Stress Corrosion Cracking
SD-F55 has excellent resistance to stress corrosion cracking (SCC) in both chloride environments, and
process environments containing H2S and CO2.
In brines with lower chloride contents can tolerate much higher pressures of H2S. As the pH, at temperature and pressure, increases, so does the resistance to sulphide SCC.
Hydrogen Embrittlement
In common with all high strength steels, duplex and super duplex stainless steels can be susceptible to
hydrogen embrittlement if stressed above the specified minimum yield strength in the presence of hydrogen.
Hydrogen embrittlement therefore becomes an area for consideration when these steels are used subsea with conventional cathodic protection.
However, the proper application of normal design stress criteria and coating technology has allowed
many subsea projects to utilize duplex and super duplex stainless steels successfully for a number of years.
MANUFACTURING
Heat Treatment
Should be solution annealed in the temperature range 1100-1140C (2012-2084F) followed by water
quenching.
Hot Forming
Hot forming should be carried out in the temperature range 1100C TO 1280C (2012-2336F). It is
recommended that this is followed by solution annealing and water quenching. Components should subsequently be pickled or fully machined.
Cold Forming
It can be adequately cold formed by various processes but the high mechanical properties should be taken into account. It is recommended that any cold work in excess of 10%-15% is removed by solution annealing and water quenching. It should be noted that cold working above these limits can result in hardness
levels above standard.
6. Welding properties:
Good weldability.
Where a solution anneal and quench as a post-weld heat treatment is to be carried out, is usually
welded with matching composition consumables. With overalloyed consumables, no post-weld heat treatment is necessary. Corrosion and mechanical properties similar to the parent metal can be obtained folowing recommended procedures.
7. Product, we supply:
x Plates
92
x Tubes
x Fittings
x Bars
x Forgings
x Bolting
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UNS S32750
Alloy: UNS-S32750
(Cr. Ni. alloy)
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
Mo
6
8
24
26
3
5
Co
Fe
Cu
Mn
Si
0,5
0,03
1,20
0,80
0,035
0,020
0,24
0,32
2. Mechanical properties:
Tensile strength, mini: 700 MPa
Yield strength, mini: 450 MPa
UNS S32750
3. Physical properties:
Density Kg/dm-3
Thermal conductivity
W m-1 K-1 at 20C
Specific heat capacity J kg-1 K-1
Coefficient of thermal
expansion 10-6 K-1
Electrical resistivity
m ohm m
7.8
12.90
460-500
13
0.916
4. Specifications:
Norm
ASTM
Tubes
Seamless Welded
A-790
A-789
Plates
Sheets
Shapes,
Bars
Strips
Flanges
Forgings
Fittings
A-240
A-276
A-479
A-240
A-182
A-988
A-473
A-988
A-815
EN10028-7
EN1088-2
EN10088-3
EN10273
A-790
A-789
A-928
B.S.
Wire
DIN 14410
Fasteners ASTM-A-320.
5. Characteristics, applications:
Super-Duplex Stainless Steels
The first-generation Duplex stainless steels were developed more than 70 years ago in Sweden for
use in the sulfite paper industry. Duplex alloy were originally created to combat corrosion problems caused by chloride-bearing cooling waters and other aggressive chemical process fluids.
Called Duplex because of its mixed microstructure with about equal proportions of ferrite and austenite, Duplex stainless steels are a family of grades, which range in corrosion performance depending on their
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alloy content. The term Super-Duplex was first used in the 1980s to denote highly alloyed, high-performance Duplex steel with a pitting resistance equivalent of >40 (based on Cr% + 3.3 Mo% + 16N%).
With its high level of chromium, Super-Duplex steel provides outstanding resistance to acids, acid chlorides, caustic solutions and other environments in the chemical / petrochemical, pulp and paper industries,
often replacing 300 series stainless steel, high nickel superaustenitic steels and nickel-based alloys.
The chemical composition based on high contents of chromium, nickel and molybdenum improves
intergranular and pitting corrosion resistance. Additions of nitrogen promote structural hardening by
interstitial solid solution mechanism, which raises the yield strength and ultimate strength values without impairing toughness. Moreover, the two-phase microstructure guarantees higher resistance to pitting and stress corrosion cracking in comparison with conventional stainless steels.
From the introduction of its first-generation, Duplex steel has seen a steady increase in popularity.
Recently, the production of highstrength, corrosion resistant super-duplex coil has been implemented
in the marine and chemical industries, architecture and mast riggings, wire lines, lifting and pulley
equipment and well service strands. In fact, development of wire processing techniques has enabled
the production of steel wires down to 1 mm in diameter.
The various Alloys
Super-Duplex falls under the Duplex stainless steel grouping. Duplex stainless steels are graded for
their corrosion performance depending on their alloy content. Today, modern Duplex stainless steel can
be divided into four groups:
Lean Duplex such as 2304, which contains no deliberate Mo addition;
2205, the work-horse grade accounting for more than 80% of duplex usage;
25Cr duplex such as Alloy 255 and DP-3;
Benefits
High strength.
High resistance pitting, crevice corrosion resistance.
High resistance stress corrosion cracking, corrosion fatigue and erosion.
Excellent resistance to chloride stress-corrosion cracking.
High thermal conductivity.
Low coefficient of thermal expansion.
Good sulfide stress corrosion resistance.
Low thermal expansion and higher heat conductivity than austenitic steels.
Good workability and weldability.
High energy absorption.
Applications
Heat exchangers, tubes and pipes for production and handling of gas and oil.
Heat exchangers and pipes in desalination plants.
Mechanical and structural components
Power industry FGD systems.
Pipes in process industries handling solutions containing chlorides.
Utility and industrial systems, rotors, fans, shafts and press rolls where the high corrosion fatigue strength can be utilized.
Cargo tank, vessels, piping and welding consumables for chemical tankers.
High-strength, highly resistant wiring.
6. Welding properties:
Good weldability.
7. Products, we supply:
x Plates, sheets
94
x Tubes
x Fittings
x Bars
x Forgings
x Bolting
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17-4PH
Alloy: 17-4PH
(Cr. Ni. Cu. alloy)
UNS-S17400
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
3
5
15
17
Mo
Co
Fe
Cu
Mn
Si
3
5
0,07
0,04
0,03
Nb
(x)
2. Mechanical properties:
Tensile strength, mini: 930 MPa
Yield strength, mini: 274 MPa
17-4PH
psi
Mpa
135,000
931
105,000
724
16
Property
UTS
ksi
0.2% YS
ksi
Elong.
% in 2
or 4XD
Red. of
Area %
H 900**
H 925
H 1025
H 1075
H 1100
H 1150
H 1150-M
200
190
170
165
150
145
125
185
175
165
150
135
125
85
14
14
15
16
17
19
22
50
54
56
58
58
60
68
Hardness
Brinell
Rockwell
420
409
352
341
332
311
277
C 44
C 42
C 38
C 36
C 35
C 33
C 27
Impact,
Charpy V-Notch
ft.lbs.
15
25
35
40
25
30
100
** For applications requiring greater impact toughness, aging for 4 hours develops typical properties UTS 196 ksi, 0.2% YS 181 ksi, Elong. In 2 14%, Reduction of Area
52%, Hardness Rockwell C43, and Charpy V-notch impact 20 foot-pounds.
3. Physical properties:
Melting Range 2560-2625F (1404-1440C)
For condition H 900:
Density, lb/in3 ................................... 0.282
Electrical resistivity, ohm circular mil/ft . 463
Magnetic Permeability, at
H = 100 Oersted .................................... 90
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ft/ft2
hr
4. Specifications:
AFNOR = 27 CNU 17.04
ASTM
W. Nr
Bar
Billet
Forgins
A564-Type 630
1.4562
A564-Type 630
1.4562
A564-Type 630
1.4562
5. Characteristics, applications:
Alloy 17-4 PH is a martensitic, precipitation-hardening, chromium-nickel-copper stainless steel. It
provides an excellent combination of high strength an hardness, short time, low temperature heat treatment and good mechanical properties at temperatures up to 316C (600F). In addition, it offers corrosion resistance comparable to that of Type 304 in most applications. This grade may be used in either the solution heat treated condition (Condition A) or in one of a variety of precipitation-hardened
conditions, depending on the particular properties desired.
17-4 PH is an age-hardening martensitic alloy combining high strength with the corrosion resistance of stainless steel. Hardening is achieved by a short-time, simple low-temperature treatment. Unlike
conventional martensitic stainless steels, such as type 410, 17-4 PH is quite weldable. The strength,
corrosion resistance and simplified fabrication can make 17-4 PH a cost-effective replacement for high
strength carbon steels as well as other stainless grades.
Features
High tensile strength and hardness to 600F
(316C).
Corrosion resistant.
Excellent oxidation resistance to about 1100F
(593C).
Fabricable.
Simple low-temperature heat treatment.
Creep-rupture strength to 900F (482C).
Applications
Gate valves.
Aircraft structures, accessories, engine parts.
Chemical processing machinery.
Food processing machinery.
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Heat Treatment
At the solution treating temperature, 1900F (1040C), the metal is austenitic but undergoes transformation to a low-carbon martensitic structure on cooling to room temperature. This transformation
is not complete until the temperature drops to 90F (32C). Subsequent heating to temperatures of
900 to 1150F (480 to 620C) for one to four hours precipitation strengthens the alloy. This hardening treatment also tempers the martensitic structure, increasing ductility and toughness.
Solution annealing should be performed in air, argon or dry hydrogen. Cracked ammonia and endothermic atmospheres are likely to contaminate the metal. Remove machining oils and forming lubricants
before solution annealing. Plasma cut surfaces should be ground or machined off before heat treatment to avoid possible cracking.
Heat Treatment for 17-4 PH and Their Designation
Designation .............. Processing
Condition A* ............. Heated at 1900F 25F for 1/2 hour, air (Solution treated) cooled or oil
quenched to below 90F. Normally performed at mill.
H 900 ..................... Condition A material heated at 900F 15F for 1 hour and air cooled. Maximum hardness but low toughness. Sensitive to stress corrosion cracking. Heating 4 hours improves toughness with about 4 ksi reduction in tensile and
yield.
H 925, H 1025, ...... Condition A material heated 4 hours at specified temperature, and air cooled.
H 1075, H 1100
H 1150,H 1150-M ... Condition A material heated at 1400 25F for 2 hours, air cooled, then heated at 1150 15F for 4 hours and air cooled. This heat treatment used for
maximum toughness, and for cryogenic applications to -320F.
*
For most applications 17-4 PH should not be used in Condition A. This is true even though the desired tensile strength may be
provided by that condition. While the alloy is relatively soft in Condition A, the structure is untempered martensite that has low
fracture toughness and ductility, with poor resistance to stress-corrosion cracking. Superior service performance is assured
by using 17-4 HP in the heat-treated condition.
Temp
Condition
H 1100
100
200
300
400
500
600
40.0
40.0
40.0
38.9
38.1
37.5
H 1150
38.6
38.6
38.6
37.5
37.6
36.2
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6. Welding properties:
Sections up to 1 thick are normally welded in the annealed (A) condition. Highly restrained joints or
heavier sections are best welded in conditiones H1100 or H1150. Welding of 17-4 PH in conditions
H900 through H1075 is not recommended.
No preheat is usually necessary for sections up to 4 thick. For restrained welds a 200-300F (100150C) preheat is beneficial.
Matching composition ER630 wire or E630 covered electrodes (AMS 5803, 5825 or 5827) are
normally used. Joints to carbon or low alloy steel may be made with ERNiCr-3 wire or ENiCrFe-3 covered electrodes. For GMAW, 75%Ar 25%He shielding gas is suggested.
Postweld heat treatment is required. For single pass welds on condition A base metal, simply aging
to codition H 900 through H 1150 usually suffices (H 900 condition has very low notch toughness).
For multipass welds the structure should be solution annealed after welding, followed by an aging treatment 900-1150F.
Notches must be avoided and partial penetration welds with their built-in notches are quite undesirable. For improved notch toughness in the weld bead, consider making the root pass only with ERNiCr3 (alloy 82) wire to maximize ductility.
7. Products, we supply:
x Plates, sheets
98
x Tubes
x Fittings
x Bars
x Forgings
x Bolting
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20CB3
Alloy: Carpenter: 20 Cb 3
(Ni. Cr. alloy)
UNS-N08020
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
Mo
32
38
19
21
2
3
Co
Fe
Cu
3
4
Mn
Si
Nb
(x)
0,07
0,045
0,035
(*) = Nb + Ta = 8 x C -1
2. Mechanical properties:
Tensile strength, mini: 591 MPa
Yield strength, 0.2: 241 MPa
Elongation: 30%
HRB: 95
20CB3
3. Physical properties:
Density: 8,03 Kg/dm3
4. Specifications:
Norms
Material
Chemical
composit
Pipes-Tubes
Plates
Rounds,
Seamless
Welded.
Sheets
Bars
B-729
B-474
B-464
B-463
B-473
Strips
B-463
B-473
BS
ASTM
B-462
B-366
Sea water: 2
Salts: 2
Alkalis: 2
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
x Pipes-tubes
x Accessories
x Bars
x Forgings
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B3
Alloy: Hastelloy B-3
(Cr, Ni, Mo, alloy)
UNS-N10675
1. Chemical composition in %:
Ni
Mini
Max
Balance
Cr
Mo
Co
Fe
1
3
27
32
0,01
1
3
Cu
Mn
Si
0,03
0,10
0,03
0,015
W
3
2. Mechanical proparties*:
Test
Temperature
C
Room
200
400
600
800
1000
1200
*
Room
95
205
315
425
540
650
Ultimate Tensile
Strenght
Ksi
MPa
125,0
120,7
110,0
104,4
102,0
97,8
103,5
860
830
760
720
705
675
715
Yield Strength
at 0,2% Offset
Ksi
Mpa
60,6
55,3
47,0
43,5
42,4
39,0
45,6
420
380
325
300
290
270
315
Elongation
in 2 in (51 mm)
%
B3
53,4
56,9
59,7
63,4
62,0
59,0
55,8
3. Physical properties:
Physical Property
Density
Melting Temperature
Electrical Resistivity
130 microhm-cm
Mean Coefficient of
Thermal Expansion
Temp., F
Room
2500-2585
Room
200
400
600
800
1000
1200
1400
78-200
78-400
78-600
78-800
78-100
78-1200
78-1400
British Units
0,333 Ib/in 3
53,8 microhm-in
53,9 microhm-in
54,1 microhm-in
54,3 microhm-in
54,4 microhm-in
55,4 microhm-in
57,5 microhm-in
54,7 microhm-in
5,7 microhm-in.-F
6,1 microhm-in.-F
6,3 microches/in.-F
6,5 microches/in.-F
6,6 microches/in.-F
6,5 microches/in.-F
7,1 microches/in.-F
Temp., C
Room
1370-1418
Room
100
200
300
400
500
600
700
25-100
25-200
25-300
25-400
25-500
25-600
25-700
Metric Units
9,22 g/cm3
137 microhm-cm
137 microhm-cm
137 microhm-cm
138 microhm-cm
138 microhm-cm
140 microhm-cm
143 microhm-cm
142 microhm-cm
10,6 x 10-6 m/m-C
11,1 x 10-6 m/m-C
11,4 x 10-6 m/m-C
11,6 x 10-6 m/m-C
11,6 x 10-6 m/m-C
11,8 x 10-6 m/m-C
12,2 x 10-6 m/m-C
101
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Pgina 102
Physical Property
Density
Melting Temperature
Thermal Diffusivity
Physical Property
Thermal Conductivity
Specific Heat
Temp., F
Room
2500-2585
Room
200
400
600
800
1000
1200
1400
Temp., F
Room
200
400
600
800
1000
1200
1400
Room
200
400
600
800
1000
1200
1400
British Units
0,333 Ib/in 3
4,6 x 10-3 in2/sec.
4,9 x 10-3 in2/sec.
5,4 x 10-3 in2/sec.
5,8 x 10-3 in2/sec.
6,3 x 10-3 in2/sec.
6,6 x 10-3 in2/sec.
7,3 x 10-3 in2/sec.
7,5 x 10-3 in2/sec.
British Units
78 Btu-in./ft.2 hr.-F
83 Btu-in./ft.2 hr.-F
93 Btu-in./ft.2 hr.-F
104 Btu-in./ft.2 hr.-F
116 Btu-in./ft.2 hr.-F
129 Btu-in./ft.2 hr.-F
142 Btu-in./ft.2 hr.-F
156 Btu-in./ft.2 hr.-F
0,089 Btu/Ib.-F
0,092 Btu/Ib.-F
0,098 Btu/Ib.-F
0,102 Btu/Ib.-F
0,104 Btu/Ib.-F
0,104 Btu/Ib.-F
0,112 Btu/Ib.-F
0,143 Btu/Ib.-F
Temp., C
Room
1370-1418
Room
100
200
300
400
500
600
700
Temp., C
Room
100
200
300
400
500
600
700
Room
100
200
300
400
500
600
700
Metric Units
9,22 g/cm3
3,0 x 10-3 cm2/sec.
3,2 x 10-3 cm2/sec.
3,4 x 10-3 cm2/sec.
3,7 x 10-3 cm2/sec.
4,0 x 10-3 cm2/sec.
4,4 x 10-3 cm2/sec.
4,5 x 10-3 cm2/sec.
4,9 x 10-3 cm2/sec.
Metric Units
11,2 W/m-K
12,1 W/m-K
13,4 W/m-K
14,6 W/m-K
16,3 W/m-K
17,9 W/m-K
19,6 W/m-K
21,4 W/m-K
373 J/kg-K
382 J/kg-K
409 J/kg-K
421 J/kg-K
431 J/kg-K
436 J/kg-K
434 J/kg-K
595 J/kg-K
4. Specifications:
DIN ..............................
Werkstoff-Nr. .................
VdTV-Werkst.-BI. ..........
DIN ..............................
ASTM ...........................
ASME ...........................
NiMo29Cr
2.4600
517
17744, 17750, 17751, 17752, 17753
B-333, B-335, B-564, B-619, B-622
SB-333, SB-335, SB-619, SB-622, SB-626
The alloy is also covered by ASTM specifications B-333 (plate, sheet and strip), B-335 (bar), B-366
(welded fittings), B-564 (forgings), B-619 (welded pipe), B-622 (seamiess pipe and tube and B-626
(welded tube).
5. Applications, characteristics:
B-3 alloy is an additional member of the nickel-molybdenum family of alloys with excellent resistance to
hydrochloric acid at all concentrations and temperatures. It also withstands sulfuric, acetic, fomic and
phosphoric acids, and other nonoxidizing medis. B-3 alloy has a special chemistry designed to achieve a level of thermal stability greatly superior to that of its predecessore, e.g. HASTELOY B-2 alloy. B-3 alloy has
excellent resistance to pitting corrosion cracking and to knife-line and heat-affected zone attack.
Fabrication
The improved thermal stability of B-3 alloy minimizes the problems associaled with fabrication of
B-2 alloy components. This is due to the reduced tendency to precipitate deleterious intermetalic
102
CATALOGO
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Pgina 103
phases in B-3 alloy, thereby, affording it greater ductility than B-2 alloy during and following various
thermal cycling conditions.
B-3 alloy has good overall forming. It may be forget or otherwise hotworked, providing that it is held
at 2250F (1230C) for a time sufficient to bring the entire piece to temperature. Since it is low carbon alloy, the use of lower hot finishing temperatures may be necesary to achieve grain size control.
B-3 alloy may also be formed by cold working. Although it does work-harden somewhat rapidly, B-3
alloy components can be made using all common cold forming techniques.
Limited tests in boiling 20 percent hydrochloric acid indicate that the uniform corrosion resistance
of B-3 alloy is not affected by cold reductions up to 50 percent as compared to that of the alloy in the
solution heat-treated condition.
B-3 alloy can be welded by all common welding techniques, although oxyacetylene and submerged
arc welding processes are not recommended when the fabricated item is to be used in corrosive service. Special precautions should be taken to avoid excessive heat input.
Heat Treatment
All wrought forms of B-3 alloy are furnished in the solution heatreated condition unless otherwise
specified, B-3 alloy is solution heat- treated al 1950F (1065C) and rapid quenched, except for bright
annealed sheet or heat-treated at 2100F (1150C) and cooled in hydrogen.
Applications
B-3 alloy is suitable for use in all applications previously requiring the use of B-2 alloy. Like B-2 alloy,
B-3 is not recommended for use in the presence of ferric or cupric salts as these salts may cause rapid corrosion fallure. Ferric or cupric salts may develop when hydrochloric acid comes in contact with
iron or copper.
AQUEOUS CORROSION RESISTANCE
Average Unform Corrosion Resistance in Boiling Acids*
Acid Madium
Acetic Acid
Formic Acid
Hydrochloric Acid
(As-welded)
(50 ppm Fe*)
Concentration
Weight Percent
10
30
50
70
99 (Glacial)
10
20
30
40
60
89
1
2
5
10
15
20
20
20
Aveage
Corrosion Rate Per Year
Mils
mm
0,005
0,2
0,2
0,005
0,2
0,005
0,2
0,005
0,7
0,017
0,4
0,010
0,6
0,015
0,6
0,015
0,5
0,013
0,3
0,008
0,2
0,005
0,3
0,005
1,2
0,03
3,8
0,10
5,5
0,14
6,6
0,22
0,31
12,1
13,6
0,35
60,0
2,0
103
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Pgina 104
Acid Madium
Phosphoric Acid
(chemically pure)
Sulfuric Acid
(As-welded)
(Aged 48 Hrs @ 1000F (540C)
Aveage
Corrosion Rate Per Year
Mils
mm
2,4
0,06
2,0
0,05
3,0
0,08
2,9
0,07
0,4
0,010
0,7
0,018
0,8
0,020
1,2
0,03
1,2
0,03
18,8
0,48
1,2
0,03
1,7
0,04
2,4
0,06
2,0
0,05
2,3
0,06
6,6
0,17
Concentration
Weight Percent
10
30
50
85
2
5
10
20
30
30
40
50
50
50
60
70
Data from three production heats, for material in the solution heat-treated condition, unless noted. Test values were determined from an average of four 24 hour exposures.
Acid Medium
MONIEL 400
alloy
Type
316L
B-2
alloy
0,2
(0,005)
0,4
(0,010)
0,2
(0,005)
0,5
(0,013)
0,7
(0,018)
41
(1,041)
2,1
(0,053)
30,
(0,076)
(0,152)
18
(0,457)
4,5
(0,114)
1,7
(0,043)
1,2
(0,030)
>20,000
(>500)
185
(4,699)
12
(0,305)
15
(0,381)
>20,000
(>500)
1587
(40,310)
125F (52C)
Mils
mm
175F (79C)
Mils
mm
8,6
8,7
9,0
10,0
11,8
13,4
31,6
11,1
12,7
13,7
15,9
22,8
35,0
0,22
0,22
0,23
0,25
0,30
0,34
0,80
Data from three production heats, for material in the solution heat-treated condition.
104
0,28
0,32
0,35
0,41
0,58
0,89
CATALOGO
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Pgina 105
6. Welding properties:
Those in the welding industry, however, should be aware of the potencial hazards associated with
welding fumes, gases, radiation, electric shock, heat, eye injuries, bums, etc.
Nickel-, cobalt-, and iron-base alloy products may contain, in varying concentration, the following elemental constituents: aluminum, cobalt, chromium, copper, iron, manganese, molybdenum, nickel and
tungsten. For specific concentretions of these and other elements present, refer to the Material Safety
Data Sheets (MSDS) available from Haynes International, Inc.
Inhalation of metal dust or fumes may cause adverse health affects. Exposure to dust or fumes
which may be generated in working these alloy may also cause eye irritation, skin rash and effect on other organ systems.
7. Products, we supply:
x Plates, sheets
x Tubes
x Fittings
x Bars
x Forgings
x Bolting
105
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Pgina 106
CATALOGO
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Pgina 107
C22
Alloy: Hastelloy-C22
(Ni. Cr. Mo. alloy)
UNS-06022
1. Chemical composition in %:
Ni
Mini
Max
Balance
Cr
Mo
20
22,5
12,5
14,5
Co
Fe
2,5
2
6
Cu
Mn
0,015
Si
0,5
0,08
0,02
S
0,02
0,35
2,5
3,5
2. Mechanical properties:
Tensile strength, mini: 690 MPa
Yield strength, mini: 310 MPa
3. Physical properties:
Density: 8,69 kg/dm3.
Melting point: 2550 F
Specific heat: 0,1 (Btu/Ib/Deg F-[32-212 Deg F])
Expansion coefficient: 619
Thermal conductivity: 70
C22
4. Specifications:
Norms
Material
Chemical
Pipes-Tubes
composit
Seamless
B-622
B-622
Plates
Welded. Sheets
Rounds,
Strips
Wires
Forgings
B-575
B-462
B-574
B-462
Bars
2.4611
DIN
BS
ASTM
B-619
B-575
B-574
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
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Pgina 108
CATALOGO
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Pgina 109
C276
Alloy: Hastelloy-C276
(Ni. Cr. Mo. alloy)
UNS-N10276
1. Chemical composition in %:
Ni
Mini
Max
Balance
Cr
Mo
14,5
16,5
15
17
Co
Fe
2,5
4
7
Cu
Mn
0,010
Si
0,08
P
0,04
S
0,03
0,35
3
4,5
2. Mechanical properties:
Tensile strength, mini: 690 MPa
Yield strength, mini: 293 MPa
Dureza HB < 240
3. Physical properties:
Density: 8,89 kg/dm3.
Melting range: 1325 a 1370 C
Specific heat: 427 J/Kg. K
Expansion coefficient: 11,7x10-6/K at 100C
Thermal conductivity: 10,6 W/mK
C276
4. Specifications:
Norms
DIN
Material
2.4819
Chemical
Pipes-Tubes
composit
Seamless
17744
17751
Welded.
Plates
Rounds,
Strips
Sheets
Bars
17750
17752
17750
B-575
B-574
B-575
B-574
B-564
6208
9723
6208
9724
9725
BS
ASTM
ISO
B-622
NiMo16Cr15Fe6W4
9722
6207
B-619
B-626
B-366
109
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Pgina 110
Applications
Alloy C-276 finds wide application in the chemical and petrochemical industries.
Typical applications include:
Alloy C-276 is the improved version of alloy C and is resistant to numerous media including strongly oxidizing chemicals (for example iron and cupric chloride) warm polluted acids, solvents, chloride and media
contaminated by chloride (organic and inorganic), dry chloride, formic and acetic acid, acetic anhydride,
sea water and saline solutions. Furthemore, alloy C-276 is resistant when exposed to damp chlorine gas,
hypochlorite and chlorodioxide solutions. Alloy C-276 combines this excellent corrosion resistance with immensely improved machineability. This alloy does not separate grain boundaries in the zone influenced by
welding so that it is suited for most chemical applications even without heat-tratament.
Alloy C-276 is a nickel-chromium alloy with high molybdenum and tungsten but low iron and silicon
contents, which provides superior corrosion resistance to a wide variety of environments. The composition is specially formulated to maintain corrosion resistance, even in the weld heat-affected zone, thus
making Alloy 276 suitable even in the as-welded condition. The alloy has excellent resistance to general pitting and stress-corrosion cracking and resists oxidation up to approximately 1038C (1900F).
The alloy has shown remarkable corrosion resistance in the especially corrosive areas of flue gas desulphurisation systems, such as outlet ducting leading to the stack. It has also been used to solve corrosive problem areas in sewage treatment plants.
Alloy C-276 is used extensively in severe operating enviroments, including those encountered in chemical processing, pulp and paper, air pollution control, waste treatment and other disposal, and other
applications.
C-276 exhibits excellent resistance to ferric and cupric chlorides, hot contaminated organics and
inorganics, chlorine, firmic acid, acetic acid, acetic anhydride, sea water and brine. It is one of the few
alloys that is resistant to wet chlorine gas, hypochlorite, and chlorine dioxide.
Chemical Process Equipment heat exchangers, reactors and vessels, evaporators, pumps, valves and piping for procesing sulfuric acid, pesticides, phenol, styrene, vinyl chloride, chlorine and
other chemicals.
Pulp and Paper bleaching, head boxes, and wastegas scrubbers.
Ore Processing uranium and aluminium sulfate.
Waste Treatment and Disposal sewage sludge incinerators, industrial and municipal incinerators, chemical and toxic waste incinerators.
Air Pollution Control power plant scrubbers and related equipment, electrostatic precipitators,
reheaters, wastehert recovery systems, industrial boiler scrubbers, marine inert-gas scrubbers.
6. Welding properties:
Good weldability.
7. Products, we supply:
x Plate-strip
110
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
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Pgina 111
C4
Alloy: Hastelloy-C4
(Ni. Cr. Mo alloy)
UNS-N6455
1. Chemical composition in %:
Ni
Mini
Max
Balance
Cr
Mo
Co
Fe
14
18
14
17
Cu
Mn
Si
Ti
0,015
0,08
0,04
0,03
0,7
2. Mechanical properties:
Tensile strength, mini: 690 MPa
Yield strength, mini: 310 MPa
3. Physical properties:
Density: 8,64 kg/dm3.
Specific heat: 0.102 (Btu/lb/DegF-[32-212 DegF]
4. Specifications:
Norms
Material
Chemical
composit
DIN
ASTM
2.4610
Pipes-Tubes
Seamless
Welded.
Plates
Rounds,
Sheets
Bars
1.7744
B-574-85
Strips
2.4610
2.4610
B-622
B-619
B-626
B-575
B-574
B-575
B-366
CATALOGO
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Pgina 112
recommended when the fabricated item is intended for use in corrosion service. Special precautions
should be taken to avoid excesive heat input.
Wrought forms of C-4 alloy are furnished in the solution heat-treated condition unless other wise specified. C-4 alloy is a solution heat-treated at 1950F (1066C) and rapid quenched.
6. Welding properties:
Good weldability.
7. Products, we supply:
x Plate-strip
112
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
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13:35
Pgina 113
ALLOY-028
Alloy: Incoloy-028
(Ni. Cr. Mo. alloy)
UNS-N08028
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
Mo
29,5
32,5
36
28
3
4
Co
Fe
Cu
Mn
Si
0,6
1,4
0,030
2,5
0,030
0,030
2. Mechanical properties:
(Annealed)
(Cold Worked)
Tensile Strength,
ksi ...................... 73
MPa .................. 500
Yield Stregth (0,2% Offset), ... ksi ..... 31
MPa .................. 214
Elongation, %
........................... 40
Hardness (HRB) ....................... 80-90
Tensile Strength,
Yield Stregth (0,2%
Elongation, %
Hardness (HRB)
3. Physical properties:
Density, Ib/in3 ..........................................
g/cm3 .........................................
Specific Heat (32-212F), Btu Ib F
(microm/m C) .........................................
(0-100C), J/Kg C .......................
Coefficient of Expansion, 10-6 in/in F
(microm/m C)
70-200F (21-93C) ......................
70-500F (21-260C) ....................
70-800F (21-427C) ....................
A
0,29
8,0
0,105
450
8,3 (15,0)
8,8 (15,9)
9,3 (16,8)
Thermal ConducitivityA,
Btu in/ft2 h F ................
W/m C ........
Electrical ResistivityA,
ohm circ mil/ft ................
micro ohm m ..
Youngs ModulusA, 103 ksi .
GPa ...............
ALLOY-028
66
11,4
594
0,99
29,0
200
4. Specifications:
Norms
DIN
Material
Pipes-Tubes
composit
Seamless
B-668
B-709
B-668
Welded.
Plates
Rounds,
Sheets
Bars
Strips
1.4563
ASTM
ISO
Chemical
B-709
B-709
FeNi31Cr27
Mo3,5CuI
AFNOR
ZNINCDU31,27
113
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Pgina 114
Sea water: 2
Salts: case dependent
Alkalis: case dependent
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
114
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
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13:35
Pgina 115
330
Alloy: Incoloy-330
(Ni. Cr. Mo. alloy)
UNS-N08330
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
34
37
17
20
Mo
Co
Fe
Cu
1
Mn
Si
0,75
1,5
0,03
0,03
0,08
Pb
Sn
0,005 0,025
2. Mechanical properties:
At Room Temperature
Tensile
Strength,
psi
0.2% Yield
Strength, psi
Elongation
%
Hardness
Rb
Temp
F
10,000 hr
Rupture
Strength, psi
85,000
39,000
47
70-85
1400
1600
1800
2000
3600
2100
500
4300
1700
630
(280)
3. Physical properties:
3
Density Ib/in
Melting Range F
0.287
2450-2540
330
Temp
F
Coefficient* of
Thermal
Expansion,
in/in F x 10-6
Thermal
Conductivity
Btuft/ft2hrF
Modulus of
Elasticity
Dynamic,
psi x 106
70
1400
1600
1800
9,7
9,8
10,0
7,2
13,7
14,2
14,7
28,5
21,0
19,5
18,0
4. Specifications:
Norms
Material
DIN
1.4333
1.4886
ASTM
B-511-2
B-535-6
Chemical
Pipes-Tubes
Plates
Rounds,
composit
Seamless
Welded.
Sheets
Bars
B-546
B-710
B-535
B-546
B-715
B-536
B-512
B-511
Strips
B-536
B-511
B-366
B-512
115
CATALOGO
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Pgina 116
Applications
6. Welding properties:
Good weldability.
A-330 may be readily welded using A-330-04 weld fillers of matching composition. Do not use AWS
ER330. Keep interpass temperatures low, do not preheat, do use reinforced stringer beads.
7. Products, we supply:
x Plate-strip
116
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
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13:35
Pgina 117
800
Alloy: Incoloy-800
(Ni. Cr. alloy)
UNS-N08800
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
Mo
30
35
19
23
Co
Fe
Cu
Mn
Si
0,75
0,10
1,50
Al
Ti
0,015
0,15
0,60
0,15
0,60
39,5
2. Mechanical properties:
Tensile strength, mini: 520 MPa
Yield strength, mini: 205 MPa
3. Physical properties:
Density: 8,02 kg/dm3.
Specific heat: 502 J/Kg. K
4. Specifications:
Norms
Material
Chemical
composit
DIN
1.4876
BS
NA15
ASTM
B-408
B-409
Pipes-Tubes
Seamless
Welded.
3074
B-514
B-515
B-407
B-163
B-514
B-515
Plates
Rounds,
Strips
Sheets
Bars
3072
3076
3073
3076
B-409
B-408
B-564
B-409
B-408
B-564
B-366
Sea water: 2
Salts: 2
Alkalis: 2
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
x Pipes-tubes
x Accessories
x Bars
x Forgings
800
CATALOGO
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Pgina 118
CATALOGO
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Pgina 119
800H
Alloy: Incoloy-800H
(Ni. Cr. alloy)
UNS-N08810
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
30
35
19
23
Mo
Co
Fe
Cu
Mn
Si
0,75
0,05
0,10
1,50
39,5
Al
Ti
0,015
0,15
0,60
0,15
0,60
2. Mechanical properties:
Tensile strength, mini: 450 MPa
Yield strength, mini: 170 MPa
3. Physical properties:
Density: 8 kg/dm3.
Melting range: 1350 to 1400 F
Specific heat: 500 J/Kg. K
Expansion coefficient: 15,8 x 10-6/K (20-300C)
4. Specifications:
Norms
Material
DIN
1.4958
BS
NA15(H)
ASTM
ISO
Chemical
Pipes-Tubes
composit
Seamless
17459/460
17459
Welded.
Plates
Rounds,
Sheets
Bars
17460
17460
3074
3072
3076
3073
B-407
B-163
B-515
B-514
B-409
B-408
B-564
Strips
17460
B-409
B-564
B-366
MC-FeNi32
Cr21APTi
AFNOR
5. Characteristics and applications:
Alloy 800H is an austenitic heat resistant alloy mean for high temperature structural applications.
The strength of 800H is achieved by controlled levels of carbon, aluminum and titanium alone with a
2100F (1149C) minimum anneal to achieve grain size ASTM5 or coarser.
Alloy 800H is essentially the same as Alloy 800, except that the carbon content is maintained at the
upper portion of the carbon range of the alloy.
This, combined with an annealing treatment that produces a coarser grain size, provides an alloy
of higher creep and rupture strength.
These features, in addition to the alloys good high-temperature corrosion resistance, produce an
alloy that is most useful for application requiring long-time operation at elevated temperatures and/or
in corrosive atmospheres.
Features
High desing stresses for ASME Section VIII aplication to 1650F (899C)
Seamless pipe and tube 5 O.D. and under to 1800F (982C), Section VIII
119
800H
CATALOGO
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Pgina 120
6. Corrosion data:
Sulphuric acid: 2
Hydrocloric acid:
Nitric acid: 1
Phosphoric acid: 2
Sea water: 2
Salts: 2
Alkalis: 2
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
800H is commonly joined by 82 (ERNiCr-3) bare wire for applications under 1450F (788C). 33004 (N08334) bare wire and 330-04-15 (W88334) covered electrodes offer a close match of thermal
expansion coefficients. For applications 1600F (871C) and higher 333 (N06333) bare wire and 33307-16 covered electrodes offer greater strenght.
To avoid possible stress relaxation grain boundary cracking of N08811 in applications above 1000F
(538C) the welded fabrication may be heated 1650F (899C) for about one hour per inch (25mm) of
thickness, 30 minutes minimum, air cooled.
8. Products, we supply:
x Plate-strip
120
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
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Pgina 121
800HT
Alloy: Incoloy-800HT
(Ni. Cr. alloy)
UNS-N08811
1. Chemical composition in %:
Mini
Max
Balance
Ni
Cr
30
35
19
23
Mo
Co
Fe
Cu
Mn
Si
0,75
0,06
0,10
1,50
39,5
Al
Ti
0,15
0,015 0,60
0,15
0,60
(x)
2. Mechanical properties:
Tensile strength, mini: 450 MPa
Yield strength, mini: 170 MPa
3. Physical properties:
Density: 8 kg/dm3.
Melting point: 1350 to 1380 C
Specific heat: 455 J/Kg. K
Expansion coefficient: 15,8 x 10-6/K (20-300C)
4. Specifications:
Norms
Material
Chemical
composit
DIN
1.4959
BS
NA15HT
ASTM
Pipes-Tubes
Seamless
Welded.
17459/60
Plates
Rounds,
Sheets
Bars
17460
B-407
B-163
B-515
B-409
B-408
Strips
17460
17460
B-409
B-564
B-366
ISO
AFNOR
800HT
CATALOGO
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13:35
Pgina 122
pigtails, headers/collectors/manifolds, transfer piping, catalyst tubes (in low pressure processes) and
quench-system piping.
Typical applications include:
ethylene pyrolysis tubing in convection and radiant sections resistance to carburisation and good mechanical properties.
ethylene dichloride cracking tubes resistance to carburisation and to dry hydrogen chloride and
chlorine
cracking tubes used in the production of acetic anhydride and ketenehigh strength, resistance to
carburisation and the formation of sigma phase
components, e.g. heat exchangers, piping systems etc, in coal conversion plants
steam generator tubing in helium cooled, high temperature reactor systems high strength, resistance to helium and to steam
6. Corrosion data:
Sulphuric acid: 2
Hydrocloric acid: 3
Hydrofluoric acid:
Phosphoric acid: 2
Sea water: 2
Salts: 2
Alkalis: 2
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
122
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
14/11/05
13:35
Pgina 123
825
Alloy: Incoloy 825
(Cr, Ni, Mo alloy)
UNS-N08825
1. Chemical composition in %:
Ni
Cr
Mo
Mini
38
19,5
2,5
Max
46
23,5
3,5
Co
Fe
Cu
22
1,5
3
Mn
Si
Al
Ti
0,6
0,05
0,5
0,03
0,2
1,2
Balance
INCOLOY alloy 825 has good mechanical properties from cryogenic temperatures to moderately
high temperatures. Exposure to temperatures above about 1000 F (540 C) can result in microstructural changes (phase formation) that significantly lower ductility and impact strength. For that reason,
the alloy is not normally used at temperatures where creep-rupture properties are desing factors.
High-temperature tensile properties are shown. The tests were conducted on cold-drawn rod of
0,75-in. (19-mm) diameter annealed at 1725 F (940 C)/1 h.
825
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Pgina 124
3. Physical properties:
Some physical constants for INCOLOY alloy 825 are listed in Table 1. Values for thermal expansion,
thermal conductivity, and electrical resistivity at various temperatures are in Table 2. Modulus of elasticity and Poissons ratio over a range of temperatures are given in Table 3. Modulus values, which were determined dynamically, were used to compute Possons ratio.
Thermal Properties. Table 2.
Temperature
F
250
200
100
0
78
100
200
400
600
800
1000
1200
1400
1600
1800
2000
F
150
100
0
25
100
200
300
400
500
600
700
800
900
1000
a
Coefficient
of Expansiona
10-6in/in-F
Thermal
Conductivity
Electrical
Resistivity
7,8
8,3
8,5
8,7
8,8
9,1
9,5
9,7
55
59
66
72,6
76,8
78,4
85,0
97,5
109,6
119,7
130,9
141,8
154,9
171,8
192,0
678
680
687
710
728
751
761
762
765
775
782
793
mm/mC
W/mC
mWm
7,8
8,2
8,5
8,6
8,8
8,9
9,3
9,6
7,9
8,9
10,7
11,1
12,3
13,8
15,4
16,9
18,2
19,6
21,2
23,1
25,5
1,13
1,14
1,18
1,21
1,24
1,26
1,27
1,27
1,28
1,29
1,30
124
Ib/in3
0,294
MG/m3
8,14
Melting Range,
F
2500-2550
C
1370-1400
Specific Heat,
Btu/Ib-F
0,105
J/kg-C
440
Curie Temperature,
F
<-320
C
<-196
Permeability at 200 oersted (15,9 kA/m)
1.005
Density,
Youngs
Modulus
Shear
Modulus
Poissons
106psi
106psi
Ratio
73
200
400
600
800
1000
1200
1400
1600
1800
2000
29,8
29,2
28,2
27,2
26,1
25,0
23,8
22,5
20,9
19,0
16,8
10,51
10,28
9,87
9,48
9,04
8,60
8,13
7,64
7,12
6,48
5,58
0,42
0,42
0,43
0,43
0,44
0,45
0,46
0,47
0,47
0,47
0,51
GPa
GPa
Poissons
Ratio
23
100
200
300
400
500
600
700
800
900
1000
206
201
195
188
181
175
168
160
151
141
128
72,5
70,7
68,2
65,6
63,2
60,3
57,5
54,5
51,4
48,0
43,7
0,42
0,42
0,43
0,43
0,43
0,45
0,46
0,47
0,47
0,47
0,46
CATALOGO
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Pgina 125
4. Specifications
DIN-2.4858
Seamless Pipes/Tubes:
Welded Pipes/Tubes:
Plates/sheets:
Bars:
Fittings:
Flanges:
- Code NiCr21Mo
ASTM-B-423
ASTM-B-704/705
ASTM-B-424
ASTM-B-425
ASTM-B-366
ASTM-B-564
5. Applications, characteristics:
Alloy 825 is a thermally stabilized alloy which is resistant to both inorganic and organic acids. It has
excellent resistance to oxidizing and nonoxidizing hot acid conditions and at temperatures up the boiling
point it is resistant to many acids and alkaline solutions.
INCOLOY alloy 825 is a nickel-iron-chromium alloy with additions of molybdenum, copper, and titanium. The alloys chemical composition, is designed to provide exceptional resistance to many corrosive environments. The nickel content is sufficient for resistance to chloride-ion stress.
Corrosion cracking. The nickel, in conjunction with the molybdenum and copper, also gives outstanding resistance to reducing environments such as those containing sulfuric and phosphoric acids. The
molydbenum also aids resistance to pitting and crevice corrosion. The alloys chromium content confers resistance to a variety of oxidizing substances such as nitric acid, nitrates, and oxidizing salts. The
titanium addition serves, with an appropriate heat treatment, to stabilize the alloy against sensitization
to intergranular corrosion.
The resistance of INCOLOY alloy 825 to general and localized corrosion under diverse conditions gives the alloy broad usefulness. Applications include chemical processing, polution control, oil and gas
recovery, acid production, pickling operations nuclear fuel reprocessing, and handling of radioactive
wastes.
Corrosion Resistance
INCOLOY alloy 825 is well known for resistance to sulfide corrosion and chloride-ion stress-corrosion
cracking, acid attack, and hydrogen embrittlement cracking. Because it combines corrosion resistance and strength, INCOLOY alloy 825 makes an excellent choice for long-term use with sour crudes and
gases.
Hydrogen Sulfide
INCOLOY alloy 825 is used to resist the corrosive conditions in sour gas and oil wells. The environments include hydrogen sulfide and carbon dioxide in sour crude and gas at high temperatures and
pressures. Table 4 shows the performance of the alloy in a test (NACE test) used to evaluate alloys for
such service. The test consists of exposure of stressed, steel-coupled C-rings to a room-temperature
solution of 5% sodium chloride whith 0,5% acetic acid and saturated with hydrogen sulfide. The specimens of INCOLOY alloy 825 were stressed at 100% of yield strength (0,2% offset). No failure occurred
in the test period of 48 or 50 days.
The result of similar, but more severe tests are given in Table 5. Stressed C-rings were exposed to
the test solutions at high temperatures in pressurized autoclaves. The overpressure gas contained hydrogen sulfide or hydrogen sulfide and carbon dioxide. No cracking of INCOLOY alloy 825 occured in
these tests with specimens stressed at 90% of yield strenght.
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Pgina 126
1000psi
MPa
Results
105,0
724
111,9
114,2
772
787
127,4
147,1
133,4
878
1014
920
133,5
920
Tests Environment
25% sodium chloride,
0,5% acetic acid,
1 g/L sulfur
saturated with
hydrogen sulfide,
150psi (1,0 MPa)
overpressure of
hydrogen sulfide,
350 F (177 C)
15% sodium chloride,
saturated with
hydrogen sulfide,
1000 psi (6,9 MPa)
overpressure of
nitrogen
with 1% hydrogen
sulfide and 20% carbon
dioxide,
400 F (204 C)
Material Condition
Yield Strength
(0,2% Offset)
Test Stress
1000psi
MPa 1000psi MPa
Results
111,9
772
101,0
696
114,2
787
103,0
710
105,0
724
94,5
652
111,9
147,1
772
1014
100,0
132,4
690
913
Stress-Corrosion Cracking
An important property of INCOLOY alloy 825 is its relative freedom from stress-corrosion cracking.
The resistance of austenitic alloys to chloride-ion stress-corrosion cracking depends on nickel content.
INCOLOY alloy 825 contains sufficient nickel (42%) for a high degree of resistance to cracking in chloride environments. Table 6 shows the performance of the alloy in boiling 45% magnesium chloride. The
test were performed on stressed U-bend specimens.
Sea water
INCOLOY alloy 825 has good resistance to general corrosion, pitting, and crevice corrosion in sea
water, although it is subject to biological fouling in continuous immersion. The alloy is also highly resistant to chloride-ion stress-corrosion cracking even in hot sea water.
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Pgina 127
Condition
Test Results
Annealed
Annealed plus
welded
Annealed
No cracking in 720 h
No cracking in 720 h
Cracking in 24 h
Intergranular Corrosion
Like other nickel-iron-chromium alloys, INCOLOY alloy 825 can be sensitized to intergranular corrosion in some aggressive oxidizing media. However, INCOLOY alloy 825 contains an addition of titanium,
which, during an appropriate heat treatment, stabilizes the alloy against such sensitization. The mechanisms of sensitization and stabilization for the alloy have been reported. Sensitization of unstabilized material can result from exposure to temperatures of 1200 to 1400 F (650 to 760 C) during welding
or service.
Susceptibility to intergranular attack is commonly measured by the Huey Test. It consists of exposure to boiling 65% nitric acid for five consecutive 48-h periods. An average corrosion rate of less than
3 mils per month (36 mpy) (0,91 mm/y) for the five periods is considered to be satisfactory performance. Substantially higher rates indicate sensitization of the material.
FABRICATION
Hot and cold forming
The hot-working range for INCOLOY alloy 825 is 1600 to 2150 F (870 C to 1180 C). For optimum corrosion resistance, final hot working should be done at temperatures between 1600 and 1800
F (870 and 980 C)
Cooling after hot working should be air cool or faster. Heavy sections may become sensitized during
cooling from the hot-working temperature, and therefore be subject to intergranular corrosion in certain media. A stabilizing anneal (see above) restores resistance to corrosion. If material is to be welded
or subjected to further thermal treatment and sudsequently exposed to an environment that may cause intergranular corrosion, the stabilizing anneal should be performed regardless of cooling rate from
the hot-working
Cold-forming properties and practices are essentially the same for INCOLOY alloy 825 as for INCONEL alloy 600. Although workhardening rate is somewhat less than for the common grades of austenitic stainless steels, it is still relatively high. Forming equipment should be well powered and strongly
built to compensate for the increase in yield strength with plastic deformation.
Annealing
Work-hardened material can be softened completely by annealing. The treatment requires exposure to
a sufficient temperature for a time long enough to cause full recrystallization of the workhardened grain struture. That removes all of the stresses, softens the material, and decreases mechanical strength.
Recrystallization is a function of time, temperature and amount of cold work as well as alloy composition.
Grain growth occurs when material is heated at higher temperatures or for longer times than those required for recrystallization. Although that results in further softening, a coarse grain structure is
unsuitable for some cold-forming operations and many service conditions (for example, a fine grain is
usually required for good fatigue strength).
A coarse grain cannot be refined in the high-nickel alloys by thermal treatment alone. It can be removed only by cold working to a degree that will result in recrystallization to a finer grain during subsequent annealing. If coarse grain is desired, or if maximum softness is required and coarse grain is not
harmful to the application, the material can be given a solution anneal. Solution annealing, or solution
treating, is performed by heating at temperatures in the upper part of the annealing range. The treatment is also used to dissolve the hardening elements in precipitation-hardenable alloys prior to aging.
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Pgina 128
Annealing temperatures are critical in maintaining the high degree of corrosion resistance for wich
INCOLOY alloy 825 was designed. For this reason, material leaving the mill has been carefully processed to provide maximum corrosion resistance. Therefore, during subsequent working, interstage and
final anneals should be limited to the 1700 to 1800 F (930 to 980 C) range, consistent with selected time and prior cold work. The optimum temperature for stabilization in considered to be 1725 F
(940 C) whereas 1800 F (980 C) provides the optimum combination of softness and fine grain
structure without sacrificing corrosion resistance. Quenching is usually not necessary for parts of thin
cross section such as those from sheet, strip and wire, but rapid cooling may be desired to avoid sensitization in heavier sections.
Prior to any heat treatment, normal precautions should be taken to remove all lubricants, shop soil,
and markings which could induce intergranular attack and embrittlement.
APPLICATIONS
Alloy 825 is employed for phosphoric acid evaporators, pickiling vats, plants for chemical processing, propeller shafts, transportation means for corrosive media, polution control, oil and gas recovery,
acid production and handling of radioactive wastes.
6. Welding properties:
Welding methods: Arc welding, TIG, MIG, plasma, autogenous welding.
Note: Take care that the surface is cleaned before welding.
7. Products, we supply:
x Plates, sheets
128
x Tubes
x Fittings
x Bars
x Forgings
x Bolting
CATALOGO
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13:35
Pgina 129
286
Allloy: Incoloy-286
(Ni. Cr. alloy)
UNS-S66286
1. Chemical composition in %:
Ni
Cr
Mo
Min.
24
13,5
Max.
27
16
1,5
Co
Fe
Cu
Balance
Mn
0,08
Si
0,040
Al
0,030
0,35
Ti
Bo
1,9
0,10
0,0010
2,325
0,50
0,010
2. Mechanical properties:
Representative Tensile Properties
1800F/1325F heat treat
Temp
F
Ultimate
Tensile
Str, psi
0,2% Yield
Strength,
psi
RT*
RT
400
800
1000
1200
1400
95,000*
145,000
143,000
138,000
131,000
103,000
64,000
50,000*
95,000
93,000
93,000
87,000
88,000
62,000
43
53
35
31
14
23
59
51
45
35
Temp
F
1000
1100
1200
99,000
81,000
61,000
88,000
71,000
46,000
annealed
3. Physical properties:
Density Ib/in3
Melting Range F
2500-2600
Temp
F
Coefficient of
Thermal
Expansiona,
in/in F x 10-6
Thermal
Conductivity
Btuft/ft2hrF
Modulus of
Elasticity
Dynamic,
psi x 106
200
800
1000
1200
1400
9,2
9,6
9,8
9,9
10,3
8,0
9,8
13,0
14,1
-
23,7
21,9
20,1
286
129
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Pgina 130
4. Specifications:
Norms
Material
Chemical
composit
DIN
Pipes-Tubes
Seamless
Welded.
Plates
Rounds,
Sheets
Bars
Strips
1.4980
BS
A-638
ASTM
A-453 Gr660
A-638 Gr660
A-638
ISO
AFNOR
Sulphuric acid: 3
Hydrocloric acid: 3
Hydrofluoric acid: 3
Phosphoric acid: 3
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
130
Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
14/11/05
13:35
Pgina 131
DS
Alloy: Incoloy-DS
(Ni, Cr alloy)
UNS-N08330
1. Chemical composition in %:
Min.
Max.
Balance
Ni
Cr
34
37
17
22
Mo
Co
Fe
Cu
Mn
Si
0,08
0,75
1,50
0,03
0,03
Ti
Pb
Su
2. Mechanical properties:
Tensile strength, mini: 483 MPa
Yield strength, mini: 207 MPa
3. Physical properties:
Density: 8 kg/dm3.
Melting range: 1330 a 1400 C
Specific heat: 452 J/Kg. K
Expansion coefficient: 15,9 x 10-6/K
Thermal conductivity: 11,4 W/mK
4. Specifications:
Norms
Material
Chemical
composit
DIN
1.4862
BS
NA17
ASTM
Pipes-Tubes
Seamless
Welded.
3074
B-535
B-546
Plates
Rounds,
Strips
Sheets
Bars
3072
3073
3076
3073
B-536
B-512
B-536
B-512
B-366
ISO
DS
AFNOR Z12NCS35.16
131
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Pgina 132
Applications
Alloy DS finds wide application in high-temperature processes:
fans operating at high temperatures in carburising furnaces resisting carburisation
boxes and baskets used in carburising resisting carburisation and showing weight savings when
compared with cast boxes.
hangers, hooks and conveyor chains used to carry vitreous-enamelled components during firing resisting oxide spalling so that oxide does not fall on the enamel
combustion tubes resisting oxidation and carburisation and alternating oxidising and carburising
conditions
jigs and fixtures used in furnace brazing and wire mesh belts to carry components in heat-treatment processes
thermocouple sheaths resisting carburisation and nitriding
flare-stack tips resisting alternating conditions
components handling cracked ammonia
6. Corrosion data:
Sulphuric acid: 2
Hydrocloric acid: 3
Hydrofluoric acid: case dependent
Phosphoric acid: 2
Nitric acid: 1
Sea water: 2
Alkalis: 2
Organic acids: 1
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
132
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
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13:35
Pgina 133
600
Alloy: Inconel-600
(Ni. Cr. alloy)
UNS-N06600
1. Chemical composition in %:
Min.
Max.
Balance
Ni
Cr
72
14
17
Mo
Co
Fe
Cu
Mn
Si
6
10
0,5
0,15
0,5
Ti
0,015
2. Mechanical properties:
Tensile strength, mini: 550 MPa
Yield strength, mini: 240 MPa
3. Physical properties:
Density: 8,42 kg/dm3.
Melting range: 1370 to 1425 C
Specific heat: 455 J/Kg. K
Expansion coefficient: 14,4 x 10-6/K (20 a 300C)
Thermal conductivity: 14,8 W/mK
4. Specifications:
Norms
Material
DIN
2,4816
BS
NA14
ASTM
ISO
AFNOR
Chemical
Pipes-Tubes
Welded.
Plates
Rounds,
Sheets
Bars
Strips
composit
Seamless
17742
17752
17750
17752
17750 17753
17754
3074
3072
3076
3073
3075
3076
B-168
B-166
B-564
B-168
B-166
B-564
B-167
B-163
B-516
B-517
B-366
NiCr15Fe8
NC15Fe
600
5. Characteristics and applications:
Alloy 600 is a nickel-base alloy with excellent carburization, and good oxidation resistance at elevated temperatures. The alloy has long been used in the heat treating industry for many of the same application as 330.
Alloy 600 has useful resistance to dry Cl2 and HCl gases at moderately elevated temperatures. Alloy
600 is not suggested for use at red heat when sulfur is present.
Grades 200 and 201 nickel are normally preferred for handling concentrated, high temperature
caustic. However, when sulfur compounds are present as well, or for ammonium hydroxide service,
600 is suggested. Alloy 600 is subject to stress corrosion cracking in hot, concentrated caustic alkalies. To avoid stress corrosion cracking, the 600 fabrication should be fully stress relieved prior to use.
A minium treatment of 1650F 1 hour is sugested, 1800-1850F 1 hour preferred.
Alloy 600 shows moderate resistance to mineral acid and good resistance to acetic, formic, stearic and other organic acids.
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Pgina 134
Excellent resistance is shown in high purity water, as used in the primary and secondary circuits of
some nuclear reactors.
Alloy 600 is particularly resistant to attack by dry chlorine or hydrogen chloride, even at temperatures up to 650C (1200F).
At high temperatures in air the annealed and solution treated alloys show good resistance to oxide
scaling and have high strength.
The alloy also resists ammonia bearing atmospheres, as well as nitrogen and carburising gases. Under alternating oxidising and reducing conditions this alloy may suffer from selective oxidation (green
rot).
Applications
Typical applications include:
thermocouple sheathing in aggressive atmospheres
vinychloride monomer production; resistance to chlorine, hydrogen chloride, oxidation and carburisation
conversion of uranium oxide to hexafluoride; resistance to attack by hydrogen fluoride
production and use of caustic alkalis, particularly in the presence of sulphur compounds
production of organic and inorganic chlorinated and fluorinated compounds, resistance to attack
by chlorine and fluorine
nuclear reactor components
heat treatment furnace retorts and components, particularly with carburising or nitriding atmospheres
catalyst regenerators in petrochemical production
production of titanium dioxide by the chlorine route.
6. Corrosion data:
Sulphuric acid: 2
Nitric acid: 3
Hydrofluoric acid: 2
Phosphoric acid: 2
Sea water: 2
Salts: 1
Alkalis: 1
Chlorydric acid: 2
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
134
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
14/11/05
13:35
Pgina 135
601
Alloy: Inconel-601
(Ni. Cr. alloy)
UNS-N06601
1. Chemical composition in %:
Min.
Max.
Balance
Ni
Cr
58
63
21
25
Mo
Co
Fe
Cu
1
C
0,10
Mn
1,5
Si
0,5
Al
0,015
1
1,7
2. Mechanical properties:
Tensile strength, mini: 559 MPa
Yield strength, mini: 205 MPa
3. Physical properties:
Density: 8,1 kg/dm3.
Specific heat: 461 J/Kg. K
Expansion coefficient: 14,9 x 10-6/K (20 to 300C)
Thermal conductivity: 11,3 W/mK
4. Specifications:
Norms
DIN
Material
2.4851
Chemical
Pipes-Tubes
Welded.
Plates
Rounds,
Sheets
Bars
Strips
composit
Seamless
17742
17751
17750
17752
17750
B-167
B-163
B-168
B-564
B-166
6207
6208
9723
6208
BS
ASTM
ISO
AFNOR
B-366
NiCr23Fe15Al
NC23FeA
9722
9724
9725
601
CATALOGO
14/11/05
13:35
Pgina 136
Resistance to carburisation is good. Alloy 601 has also shown good resistance to carbonitriding
conditions.
Due to its high chromium and aluminium content, Alloy 601 shows good resistance to oxidising sulphur-bearing atmospheres at elevated temperatures.
Applications
Alloy 601 has found a wide variety of applications in industries as diverse as thermal and chemical
processing, pollution control and power generation.
trays, baskets and fixtures for heat treatment plant
refractory anchors, strand-annealing and radiant tubes, high velocity gas burners, wire mesh
belts in industrial furnaces
insulating cans in ammonia reformers and catalyst support grids in nitric acid production
components in exhaust gas systems
combustion chambers in solid waste incinerators
tube supports and ash-handling components
components of waste-gas detoxification systems
oxygen preheaters
6. Corrosion data:
Sulphuric acid: 2
Hydrocloric acid: 2
Hydrofluoric acid: 2
Phosphoric acid: 2
Sea water: 2
Salts: 1
Alkalis: 1
Chloryhidric acid: 3
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
136
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
14/11/05
13:35
Pgina 137
625
Alloy: Inconel-625
(Ni. Cr. Mo alloy)
UNS-N6625
1. Chemical composition in %:
Min.
Ni
Cr
Mo
58
20
23
10
Max.
Co
Fe
Cu
Mn
Si
Ti
Al
2. Mechanical properties:
Tensile strength, mini: 827 MPa
Yield strength, mini: 414 MPa
3. Physical properties:
Density: 8,5 kg/dm3.
Specific heat: 415 J/Kg. K
Density Ib/in3
Melting Range F
0.305
2350-2460
a
Coefficient of Thermal
Expansion, in/in F x 10-6
7.3
7.4
7.6
7.8
8.2
8.5
8.8
Temp
F
70
400
600
800
1000
1200
1400
1600
Thermal Conductivity
Btuft/ft2hrF
5.7
7.2
8.2
9.1
10.1
11.0
12.0
13.2
Modulus of Elasticity
Dynamic, psi x 106
29.8
28.4
27.5
26.6
25.6
24.4
23.1
4. Specifications:
Norms
Material
DIN
BS
ASTM
2,4856
NA21
ISO
AFNOR
NiCr22Mo9Nb
NC22DNb
Chemical
Pipes-Tubes
composit
Seamless
17744
17751
B-444
Welded.
B-704
B-705
Plates
Rounds,
Sheets
Bars
17750
3072
B-443
17752
3076
B-446
B-564
Strips
17750
3072
B-443
17752
B-564
625
B-366
CATALOGO
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13:35
Pgina 138
High resistance to corrosive attack by mineral acids, such as nitric phosphoric, sulphuric and hydrochloric acids, as well as to alkalis and organic acids in both oxidising and reducing conditions.
Alloy 625 is used both for its high strength and outstanding aqueous corrosion resistance. The strength
of 625 is primarily a solid solution effect from molybdenum and columbium. Alloy 625 has excellent weldability, and is frequently used to weld AL-6XN. Matching filler metals are also used to join dissimilar metals.
Alloy-625 is a low-carbon nickel-chromium-molybdenum-niobium alloy which shows excellent resistance to a variety of corrosive media.
Due to its low carbon content and stabilising heat treatment, Alloy 625 shows little tendency to sensitisation even after 50 hours at temperatures in the range 650-900 C (1200-1650 F).
The alloy is supplied in the soft-annealed condition for applications involving wet corrosion, and is approved by TUV for pressure vessels in the temperature range 196 to 450C (321 to 840 F).
The mechanical properties of Alloy 625 can be increased by age-hardening.
This alloy is characterised by:
outstanding resistance to pitting, crevice corrosion, impingement corrosion and intergranular attack.
almost complete freedom from chloride-induced stress-corrosion cracking.
good resistance to mineral acids, such as nitric, phosphoric, sulphuric and hydrochloric acids.
good resistance to alkalis and organic acids.
good mechanical properties.
in special high-temperature applications where very high strength and creep values are required,
the high-carbon, solution treated version (Alloy 625, grade 2) should be used.
virtual immunity to chloride-induced stress-corrosion cracking.
practically no corrosive attack in marine and industrial atmospheres. High resistance to seawater and brackish water, even at high temperatures.
no sensitisation during welding.
good resistance to carburisation and to oxidation under static and cyclic conditions, and to chlorine containing gases.
Applications
The soft annealed, low carbon Alloy 625 is widely used in chemical process technology, as its good
corrosion resistance and high strength permit the use of thin structural parts. Alloy 625 is used for
structures in contact with seawater and subject to high mechanical stresses.
For high-temperature applications, up to about 1000 C (1830 F), the solution-annealed, high carbon version (Alloy 625, grade 2) is recommended, due to its excellent creep properties.
6. Corrosion data:
Sulphuric acid: 1
Hydrocloric acid: 1
Hydrofluoric acid: 1
Phosphoric acid: 1
Sea water: 1
Salts: 1
Alkalis: 1
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
138
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
14/11/05
13:35
Pgina 139
718
Alloy: Inconel-718
(Ni. Cr. alloy)
UNS-N07718
1. Chemical composition in %:
Ni
Cr
Mo
Co
Min.
50
17
2,80 4,75
Max.
55
21
3,30 5,50
Fe
Cu
Mn
Si
Ti
Al
Co
0,65 0,20
0,30
Bo
(X)
0,006
X
(X) Cb + Ta=4,75 to 5,5
2. Mechanical properties:
Tensile strength, mini: 1241 MPa
Yield strength, mini: 1034 MPa
3. Physical properties:
Density: 8,2 kg/dm3.
Melting range: 1260 to 1340 C
Specific heat: 432 J/Kg. K
Expansion coefficient: 12,6 x 10-6/K
Thermal conductivity: 11,1 W/mK
4. Specifications:
Norms
Material
Chemical
composit
DIN
2,4668
ASTM
B-637
ISO
AFNOR
Pipes-Tubes
Seamless
Welded.
Plates
Rounds,
Sheets
Bars
B-670
B-637
AIR9165
AIR9165
Strips
B-670
B-637
NiCr19NbMo
B-637
NiCr19Nb5-Mo3
NC19FeNb
AIR9165
718
CATALOGO
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13:35
Pgina 140
The major applications of Alloy 718 in the oil field industry are Gate Valves, Choke Stems, Fasteners,
Tubing Hangers and Fire Safe Valves.
Alloy 718 i also used for hotworking shear blades, extrusion-dies and liners where conventional tool steels do not have sufficient strength at the high extrusion temperatures required.
Features
Good mechanical properties tensile, fatigue and creep-rupture
Oxidation resistant throughout its useful temperature range
Resistant to aqueous corrosion and chloride ion stress corrosion cracking
Heat Treatment
718 alloy is strengthened by a precipitation hardening reaction involving columbium, titanium, aluminum and nickel, with a degree of solid solution strengthening by molybdenum. Two commonly used heat treatments are:
Anneal 1700-1850 F air cool or faster. Age 1325 F 8 hr, furnace cool to 1150 F, hold at 1150
F for a total aging time of 18 hr, air cool.
Size change in hardening annealed 718 will show a contraction of 0.0008 inch/inch after precipitation hardening.
Anneal 1900-1950 F, air cool or faster. Age 1400 F 10 hr, furnace cool to 1200 F, hold at
1200 F for a total aging time of 18 hr, air cool.
The 1700-1850 F treatment is optimum for rupture and notch rupture strength, and rupture ductility. This treatment develops the highest room temperature tensile and yield strengths, but with somewhat reduced transverse ductility. Because of a fine grain size this anneal is used for high cycle fatigue strength.
The 1900-1950 F treatment improves transverse tensile ductility, impact strength and low-temperature notch tensile strength. The disadvantages of this treatment are notch brittleness in stress
rupture and, because the higher temperature anneal develops a coarser grain size, reduced fatigue
strength.
Applications:
Gas turbine engine parts. Liquid fuel rocket motor components, springs, fasteners, cryogenic tanks.
6. Corrosion data:
Sulphuric acid: 2
Hydrocloric acid: 2
Hydrofluoric acid:
Phosphoric acid: 2
Sea water: 1
Salts: 1
Alkalis: 1
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Weldability:
Excellent welding characteristics, resistant to postweld age cracking.
8. Products, we supply:
x Plate-strip
140
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
14/11/05
13:35
Pgina 141
X-750
Alloy: Inconel X-750
(Ni. Cr. alloy)
UNS-N07750
1. Chemical composition in %:
Min.
Ni
Cr
Mo
70
14
0,7
17
1,20
Max.
Co
Fe
Cu
Mn
Si
5
1
0,50
0,08
0,50
0,01
Al
Ti
0,4
2,25
2,75
(x)
2. Mechanical properties:
Tensile strength, mini: see ASTM-B-637
Yield strength, mini: see ASTM-B-637
3. Physical properties:
Density: 8,3 kg/dm3.
Melting range: 1395 to 1430 C
Specific heat: 430 J/Kg. K
Expansion coefficient: 12,9 x 10-6/K (20 to 100C)
Thermal conductivity: 12 W/mK
4. Specifications:
Norms
Material
Chemical
composit
DIN
Pipes-Tubes
Seamless
Welded.
Plates
Rounds,
Sheets
Bars
Strips
2,4669
ASTM
B-637
ISO
NiCr15Fe5Ti
2Al
AFNOR
NC15TNbA
B-366
X-750
CATALOGO
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13:35
Pgina 142
requirements and are achieved after an extensive 47 hour heat treatment operation. Other applications
are heatreating fixtures, forming tools, extrusion dies, and test machine grips. For springs and fasteners, Alloy X-750 is used from sub-zero to 648 C, (1200 F).
6. Corrosion data:
Sulphuric acid: 2
Hydrocloric acid: 2
Hydrofluoric acid:
Phosphoric acid: 2
Sea water: 2
Salts: 1
Alkalis: 1
Nitric acid: 3
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
142
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
14/11/05
13:35
Pgina 143
400
Alloy: Monel-400
(Ni. Cu. alloy)
UNS-N04400
1. Chemical composition in %:
Ni
Min.
Cr
Mo
Co
Fe
Cu
63
Mn
Si
0,30
0,5
Al
Ti
28
Max.
2,5
34
0,024
2. Mechanical properties:
Tensile strength, mini: 485 MPa
Elongation A5 = 35 % min.
3. Physical properties:
Density: 8,85 Kg/dm3.
Specific heat: 430 J/Kg.K
Expansion coefficient: 15,8 x 10-6/K
Thermal conductivity: 26 W/mK
4. Specifications:
Norms
Material
DIN
2.4360
BS
NA13
Chemical
AFNOR
NICU30
Rounds,
Sheets
Bars
Strips
Seamless
17743
17751
17750
17752
3074
3072
3076
3073
9722
Welded.
Plates
composit
ASTM
ISO
Pipes-Tubes
3075
B-163
B-165
B-725
B-730
B-127
B-164
B-564
6207
6208
9723
6208
9724
B-366
9725
NU30
Corrosion Resistance
Alloy 400 has outstanding resistance to neutral and alkaline salts. It has been a standard material
for salt plants for many years.
143
400
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Pgina 144
This alloy is one of the few metallic materials which can be used in contact with fluorine, hydrofluoric acid, hydrogen fluoride or their derivatives.
Alloy 400 shows very high resistance to caustic alkalies. Behaviour in seawater is also excellent,
with improved resistance to cavitation corrosion compared with copper-base alloys. It can be used in
contact with dilute solutions of mineral acids such as sulphuric and hydrochloric acids, particularly if
they are air-free. However, as the alloy contains no chromium, corrosion rates may be increased significantly in oxidising conditions.
Whilst Alloy 400 can be considered immune to chloride-ion stress cracking, it can stress crack in
the presence of mercury or in most aerated HF vapours. A stress relieving heat treatment is applied in
such cases.
Applications
6. Corrosion data:
Sulphuric acid: 1
Hydrocloric acid: 1
Hydrofluoric acid: 1
Phosphoric acid: 1
Sea water: 1
Salts: 1
Alkalis: 1
Nitric acid: 3
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
144
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
14/11/05
13:35
Pgina 145
K500
Alloy: Monel K-500
(Ni. Cu. alloy)
UNS-N05500
1. Chemical composition in %:
Ni
Min.
Cr
Mo
Co
Fe
Cu
Mn
Si
27
63
Max.
33
0,18
1,5
0,50
0,010
Al
Ti
2,3
0,35
3,15 0,85
2. Mechanical properties:
Tensile strength, mini: 965 MPa
Elongation A5 = 20 % min
3. Physical properties:
Density: 8,9 Kg/dm3.
Specific heat: 456 J/Kg.K
Expansion coefficient: 14,9 x 10-6/K
Thermal conductivity: 17,4 W/mK
4. Specifications:
Norms
Material
DIN
2.4375
BS
NA18
Chemical
Pipes-Tubes
composit
Seamless
Welded.
17743
17743
17743
3074
ASTM
ISO
AFNOR
Plates
Rounds,
Sheets
Bars
Strips
17752
3072
3076
B-865
17754
3073
3075
B-865 B-865
NICU30Al3Ti
NU30AT
K500
Corrosion Resistance
In general the corrosion resistance of Alloy K-500 is similar to that of Alloy 400.
145
CATALOGO
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Pgina 146
Excellent resistance is shown to a wide range of media from pure water to mineral acids, salts and
alkalis. Alloy K-500 is virtually immune to chloride-ion stress corrosion cracking. In the aged condition,
the alloy may be susceptible to stress-corrosion cracking in moist, aerated hydrofluoric acid vapour at
stresses near the yield strength.
In high velocity seawater and in marine atmospheres, good resistance is shown but, in slow moving or
stagnant seawater, pitting may occur. Alloy K-500 also shows good resistance in sour-gas environments.
Applications
Alloy K-500 finds wide application in the marine, chemical, petrochemical and shipbuilding industries.
valve seals, pump sleeves and wear rings in marine environments high strength and resistance
to seawater
pump shafts for fire-fighting pumps high strength (resulting in smaller diameter shafts) and resistance to flowing seawater
propeller shafts high strength (resulting in smaller diameter shafts and thus smaller bearings)
and resistance to seawater
fasteners e.g. bolts, used in marine atmospheres and tidal waters resistance to chloride containing environments
doctor blades and scrapers
towing cable armouring high strength, non-magnetic properties and resistance to seawater
springs resistance to a variety of corrosive media
oil well drilling equipment such as non-magnetic drill collars, valves and instrumentation sleeves
resistance to chloride-containing media and sour gas environments
aviation instrument components non-magnetic properties
6. Corrosion data:
Sulphuric acid: 1
Hydrocloric acid: 1
Hydrofluoric acid:
Phosphoric acid: 1
Sea water: 1
Salts: 1
Alkalis: 1
Nitric acid: 3
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
146
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
14/11/05
13:35
Pgina 147
NICKEL-200
Alloy: Nickel-200
(Ni alloy)
UNS-N02200
1. Chemical composition in %:
Ni
Min.
Cr
Mo
Co
Fe
Cu
0,40
0,25
Mn
Si
99
Max.
0,15 0,35
0,35
0,010
2. Mechanical properties:
Tensile strength, mini: 380 MPa
Elongation A5 = 40 % mini
3. Physical properties:
Density: 8,9 Kg/dm3.
Expansion coefficient: 14,3 x 10-6/K (20 to 300C)
4. Specifications:
Norms
Material
DIN
2.4066
BS
NA11/12
Pipes-Tubes
Plates
Rounds,
Strips
composit
Seamless
Welded.
Sheets
Bars
17740
17751
17751
17750
17752
3072
3076
3073
3075
B162
B160
B564
B162
B160
3074
B161
B163
ASTM
ISO
Chemical
B725
B730
B564
B366
Ni99.0
147
NICKEL-200
CATALOGO
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Pgina 148
6. Corrosion data:
Sulphuric acid: 2
Hydrocloric acid: 2
Hydrofluoric acid: 1
Phosphoric acid: 2
Sea water: 1
Salts: 1
Alkalis: 1
Nitric acid: 3
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
148
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
14/11/05
13:35
Pgina 149
NICKEL-201
Alloy: Nickel-201
(Ni alloy)
UNS-N02201
1. Chemical composition in %:
Ni
Min.
Cr
Mo
Co
Fe
Cu
0,40
0,25
Mn
Si
99
Max.
0,02 0,35
0,35
0,01
2. Mechanical properties:
Tensile strength, mini: 380 MPa
Elongation = 40 % mini
3. Physical properties:
Density: 9,89 Kg/dm3.
Specific heat: 440 J/Kg.K
Thermal conductivity: 76 W/mK
4. Specifications:
Norms
Material
DIN
2.4068
BS
NA12
ASTM
ISO
Chemical
Pipes-Tubes
Rounds,
Sheets
Bars
Strips
composit
Seamless
17740
17751
17750
17752
3074
3072
3076
3073
B-162
B-160
B-564
B-162
B-161
B-163
Welded.
Plates
B-725
B-730
3075
B-564
B-366
LcNi.99
NICKEL-201
149
CATALOGO
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Pgina 150
6. Corrosion data:
Sulphuric acid: 2
Hydrocloric acid: 2
Hydrofluoric acid: 1
Phosphoric acid: 2
Sea water: 1
Salts: 1
Alkalis: 1
Nitric acid: 3
Symbols:
1. Good to excellent
2. Acceptable
3. Inadequate
7. Welding properties:
Good weldability.
8. Products, we supply:
x Plate-strip
150
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
14/11/05
13:35
Pgina 151
TANTALUM
Metal: TANTALUM
It is a industrialy pure metal.
Chemical composition:
Average composition in mg/g:
Ta
Ta+Nb Ag
99,85 99,90
Cd
Co
Cr
Cu
Fe
Mg
Mn
Mo
Na
Nb
<5
15
<10
<10
<10
<10
50
<1
<5
<5
<5
50
<5
150
Fe
Mg
Mn
Mo
Na
Nb
Ni
Pb
Ti
Zn
Zr
30
20
<10
<5
<15
200
<5
<5
Ta+Nb Ag
Cd
Co
Cr
Cu
Ti
Zn
Zr
As previous
O
Pb
200
Grades = ASTM-B-364 and 365.
Introduction:
The tantalum has been accepted as a preferred material for a wide variety of applications.
Tantalum is not a new material. Its first commercial use at the turn of the century was as filaments
in light bulbs. Later, when it became apparent that tantalum was practically inert to attack by most
acids, applications in the laboratory and in the chemical and medical industries were developed. The
rise of the electronics industry accelerated the development of many new applications.
Much of this growth can be attributed to a broader range of tantalum powders and mill products
available from the producers and increasing utilization of tantalum's unique properties high melting
point, ability to form a dielectric oxide film and chemical inertness. Encouraging these applications, new
reduction, melting, and fabrication techniques have led to higher purities, higher reliabilities and improved yields to finished products.
Physical Properties:
Pure tantalum has a body centered cubic crystal lattice. There is no allotropic transformation to the
melting point which means that unalloyed tantalum cannot be hardened by heat treatment. Additions of
oxygen, carbon or nitrogen above normal levels, either purposefully or accidentally, are considered as
alloying additions no matter what the concentration.
TANTALUM
151
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Pgina 152
180.9
16,6 gm/cc, 0.601 Ib/in3
Density
Melting Point
2996 C, 5432 F
9.525 x 10-11 mmHg
Thermal Conductivity
20 C
100 C
1430 C
1630 C
1830 C
Specific Heat
100 C
0.130 cal/cm-sec C
0.131 cal/cm-sec C
0.174 cal/cm-sec C
0.186 cal/cm-sec C
0.198 cal/cm-sec C
0.03364 cal/gm
Electrical Conductivity
13.9 % IACS
Electrical Resistivity
-73C
75C
127C
1000C
1500C
2000C
9.0 micro-ohm/cm
12.4 micro-ohm/cm
18.0 micro-ohm/cm
54.0 micro-ohm/cm
71.0 micro-ohm/cm
87.0 micro-ohm/cm
Mechanical properties:
The room temperature mechanical properties of tantalum are dependent on chemical purity,
amount of reduction in cross-sectional area and temperature of final annealing. Annealing time does
not appear to be critical. Close control over the many parameters which affect mechanical properties
are mandatory to insure reproducible mechanical behavior.
TABLE II Typical Mechanical Properties Annealed Tantalum Sheet
Thickness
0.005 Deep Draw
0.005 Regular
0.010 Regular
0.030 Regular
0.060 Regular
.2% Yield
Strength PSI
Ultimate
Tensile
Strength PSI
Elongation %
29,000
44,000
40,000
35,000
35,000
41,000
55,000
52,000
45,000
45,000
22
18
32
40
42
Hardness
Rockwell
15 T
B
75
75
48
Tantalum can be strengthened only by cold work with resulting loss in ductility. As certain residual impurities have pronounced effects on ductility levels and metallurgical behaviour, the purpose of most consolidation techniques is to make the material as pure as possible. Cold working methods are used almost
without exception to preclude the possibility of embrittlement by exposure to oxygen, carbon, nitrogen and
hydrogen at even moderate temperatures. Temperatures in excess of 800F should be avoided.
152
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Pgina 153
METALLURGICAL CONDITION ... There are basically three structures which can be ordered: (1)
unannealed, (2) stress-relieved, and (3) annealed.
Unannealed ... In the unannealed condition, the structure will be typically wrought fibrous. Yield and
tensile strength will be increased with corresponding decreases in elongation as shown in Table III. The
amount of work-hardening will be dependent on the amount of cold reduction since the last anneal. The
rate of work-hardening is rapid for the first 30% of reduction. The rate then diminishes so that there
will be no appreciable strengthening until reductions of over 90% are taken. There is actually no limit
to the amount of cold work which the metal can take; there are only equipment limitations or mechanical limitations, such as, poor shape control in rolling or excessive thinning when forming which dictate periodic heat treatment in vacuum to soften the metal.
Unannealed tantalum may be preferred for machinability although our providers machinists indicate
no preference. Corrosion behavior is not affected nor is the susceptibility to interstitial contamination
changed. Unannealed sheet .030" thick and under can make a 1 x thickness bend, but the annealed
condition is preferred when bending since the metal is not as stiff or as springy.
TABLE III Typical Mechanical Properties. Tantalum Sheet with Increasing Cold Work
Percent
Cold Work
.2% Yield
Strength PSI
Ultimate
Tensile
Strength PSI
30
50
80
90
95
98
70,600
82,200
100,500
117,800
127,000
74,200
86,000
109,200
123,400
135,500
135,500
Elongation %
Hardness
VHN
18
9
4
2
1
1
189
192
235
239
265
280
Stress-Relieved ... Stress-relieving at 1850 F in vacuum reduces yield and tensile strengths and raises elongation levels. These properties will be intermediate between annealed and unannealed. Stressrelieving has been used more as a matter of expediency than design. Fabricators need some ductility
to allow them to roll tubes into tube sheets. Until recently, the only tubular heat treating vacuum furnaces were limited to 1850 F maximum. This equipment limitation dictated the use of stress-relieving.
As newer furnaces allowing full annealing in vacuum are now on stream, stress-relieving may gradually
fall into disuse.
Annealed ... Tantalum specified in the annealed condition is in its softest, most ductile condition. The
usual objective of the procedure is to choose an annealing temperature which will result in compIete
recrystallization but avoid excessive grain growth. This temperature will be about 2150 F 75 F. The
temperature for recrystallization is, however, considerably affected by the purity and amount of cold
work prior to annealing.
When the amount of reduction is limited, complete recrystallization is very difficult unless the annealing
temperature is substantially increased. Purity is at the core of this problem. Unless sufficient work (about
75% reduction) is put into the material, tantalum does not have the impurities present to act as nucleation sites for grain growth unless an inordinate amount of energy in the form of annealing heat is added.
This will result in recrystallization, but to a very large grain size. The larger the cross-section, the more severe is this problem. Recrystallization to a finer grain size becomes more readily obtainable. The tensile
test is normally used to determine the state of anneal. ASTM specifications for annealed tantalum are
shown in Table IV.
This test is backed by hardness tests, Olsen cups, and grain size determinations to insure product
quality. The Olsen test is particularly effective for thin sheet as tensile test elongations decrease as a
function of material thickness. The Olsen cup has the added advantage of detecting any strong directionality tendencies or to show orange peel indicating a coarse grain. (See Table V).
153
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Tantalum sheet develops directionality if a producer does not choose his rolling and annealing schedules with care. Directionality is a term used to describe non-uniform sheet properties in the rolling direction and transverse to the rolling direction. Sheet with directionality has reduced elongations in the
transverse direction which may affect performance in spinning and deep drawing operations. When
these metal working functions are to be performed, it is helpful for the user to so specify when ordering the material.
TABLE IV ASTM Specification Limits for Tensile Properties. Test Procedure ASTM E8-61T
Ultimate PSI
Maximun
Minimum
Yield PSI
Maximun
Elongated
Minimum %
Hardness
Maximum
Cold Worked
75,000
Stress-Relieved
any section exceeding .021"
any section less than .021"
55,000
55,000
10
7,5
55,000
55,000
45,000
45,000
25
15
Annealed
any section exceeding .021
any section less tahn .021" to
.005 minimum
80
15T
.030 Regular
.020 Regular
.010 Regular
.005 Deep Draw
.005 Regular
Typical
Depth
Specification
Minimum
Force (Ibs.)
Typical
.450
.425
.350
.380
.250
.320
.320
3920
3200
1540
820
504
FORMING ... Tantalum in the annealed condition is an extremely ductile material. Unusually high reductions without annealing are possible because of its low rate of work hardening characteristics. Tubing 11/16" diameter with a 1/8" wall by 16" long has been drawn from circular blanks without annealing in a series of seven draws. It is nevertheless recommended that the producer be advised when
spinning or drawing is planned.
Spinning ... Successful tantalum spinning can be accomplished using conventional spinning techniques. The slow work hardening rate permits repeated drafts without in process anneals, unless unusually severe formations are to be attempted. Spinning thinner material such as .010" or .020" thick
may have to be annealed more often.
Mandrels should be made of steel or aluminum bronze. Hardwood and composition mandrels are
usually too soft to permit sufficient ironing for good surface finish. If steel mandrels are used, bottoms
should be faced with aluminium bronze to prevent galling of the blank. Steel roller wheels or yellow
brass tools are used with generous amounts of yellow soap. A commercial compound, Warren's Spinning Compound #1, has been found to offer good lubricating characteristics for tantalum.
Deep Drawing ... Although tantalum is a soft, ductile metal, certain precautions are suggested for
optimum results. Conventional reductions are possible provided due allowance is made for tantalum's
galling characteristics. The metal will have more of a tendency to seize on the punch and/or draw ring.
This friction may result in premature failure unless lubrication is generous. Aluminum bronze is recommended for the draw ring when justified.
154
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The metal can be stretched and ironing is feasible with aluminum bronze dies. As in any deep drawing operation, some experimentation with holddown, punch and draw ring radii and clearance may be
necessary to prevent wrinkling. Initial reductions of 50% are possible. Drawing may be continued although gradually decreasing the amount of reduction per draw is recommended.
Niobium and tantalum can be clad onto other metals such as steel, aluminum and copper to produce cost effective composites.
Niobium and tantalum can be machined using standard equipment and cutting tools. Water soluble
oil is used as a cutting fluid for turning, drilling, milling and sawing. Chlorothane is used as an assist for
tapping.
Niobium and tantalum can be welded to themselves and to several other metals by resistance welding, tungsten-inert gas, plasma welding and electron beam welding. Formation of brittle intermetallic
phases is likely with many metals and must be avoided. Surfaces to be heated above 300 C should
be protected by and inert gas (argon or helium) to prevent embrittlement.
Corrosion resistance:
Selecting any material for corrosive service can be fraught with hazards. Operating conditions can
be substantially different from the conditions used in the laboratory to establish base line data. Whenever possible, a welded sample should be exposed to the expected operating environment. The following
comments are based on laboratory data which should be used only as a guide for preliminary screening
when material selection problems exist.
Tantalum is extremely resistant to corrosion by most acids. Like glass, one of the few exceptions to
its general acid resistance is hydrofluoric acid which will attack tantalum readily. Any solution containing
the fluoride ion should be avoided. Concentrated sulfuric acid and to a lesser degree, hot 85% phosphoric acid will attack tantalum. Hydrochloric, nitric and 80% phosphoric acid provided fluorine is kept
below 5 ppm, chromic, oxalic and organic acids should not be detrimental.
Tantalum is less resistant to alkaline solutions. Boiling solutions of strong alkalies will rapidly attack
the metal. This attack is somewhat temperature and concentration dependent, but in general, service
in strong alkalies above room temperature should be avoided.
The material is not usually attacked by salt solutions except those which contain or will hydrolyze to
strong alkalies or by fluorides. Chlorides and bromides such as ferric chloride, mercuric and stannous
chloride up to 350 F should be satisfactory.
Great care should be exercised to prevent hydrogen embrittlement by electrolytic action in practically
all electrolytes particularly at elevated temperature. Embrittlement may result from either galvanic coupling or because of stray electric currents. To prevent this embrittlement from occurring, tantalum
should be insulated from other metals in the equipment and any stray currents should be located and
eliminated.
At temperatures not exceeding 300 F and in the absence of fluorine, free SO3 or strong alkalies,
most organic and inorganic liquids will not effect tantalum. The same is true of nearly all corrosive gases including either wet or dry chlorine or bromine. Temperatures in excess of 300 F could lead to longer term embrittlement problems unless there is protection from interstitial contamination. Tantalum
has shown excellent resistance to attack by such liquid metals as sodium, lithium, magnsium, potassium and mercury in temperatures to 2000 F.
Corrosion rates for tantalum, miobium, titanium and 304 stainless steel are listed for comparison
in table VI.
155
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TABLE VI Comparison of corrosion rates for Tantalum, Niobium, Titanium, 304 Stainless Steel and
Platinum
Medium
Acetic Acid
AlCl3 (10% soln)
NH4Cl(10% soln)
HCl, 20%
, conc.
HNO3, 20%
, 70%
, 65%
H3PO4, 85%
H2SO4, 10%
, 40%
, 98%
, 98%
, 99%
, 98%
, 98%
H2SO4, fuming (15% So3)
Aqua regia
Chlorine, wet
H2O, Cl2 sat
, sea
Oxalic acid
NaOH, 5%
, 10%
, 40%
HF, 40 %
(a) indicates no data
(b) embrittled
156
Temp.
Ta
100
100
100
21
100
21
100
100
100
170
25
100
25
25
25
50
100
200
250
23
70
25
75
25
25
21
96
21
100
100
80
25
212
212
212
70
212
70
212
212
212
338
76
212
76
76
76
122
212
392
482
73
158
78
167
76
76
70
205
70
212
212
176
76
nil
nil
nil
nil
nil
nil
nil
nil
nil
<1
nil
nil
nil
nil
nil
nil
nil
3
rapid
0.5
rapid
nil
nil
nil
nil
nil
0.1
nil
0.7
<1
rapid
rapid
Nb
Ti
(a)
nil
nil
nil
<0.5
0.04
175
0.1
4(b)
rapid
nil
nil
nil
nil
<5
<1
8
3(b)
40
nil
7
0.1
60
0.2
0.8 (b)
115(b)
high
rapid
rapid
(assume rapid)
nil
35
nil
nil
nil
5
nil
nil
0.6(b)
1.1
rapid
5
rapid
rapid
s.s.
304
Pt
20
20
>20
high
rapid
7
> 50
> 50
> 50
>> 50
> 50
50
<1
<1
5
nil
nil
nil
nil
1
nil
nil
nil
nil
nil
nil
nil
800
0.1
nil
nil
nil
nil
nil
nil
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CATALOGO
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Atomic Weight
Density
Melting Point
Boiling Point
Coefficient of Thermal Expansion (RT)
Electrical Resistivity
Electrical Conductivity
Specifie Heat
Thermal Conductivity
Crystal Structure
Thermal Neutron Cross Section
Niobium
Tantalum
92.9064
8.66g/cc
2468 C
4927 C
7,1 x 10-6/C
15 /cm
13.2% IACS
.126 J/g
.523 J
bcc
1.1 b
180.95
16.6g/cc
2996 C
5431 C
6.5 x 10-6/C
13.5 /cm
13.9% IACS
.140 J/g
.544 J
bcc
21.3 b
Niobium:
195 M Pa(28 ksi)
105 M Pa(15 ksi)
30 % +
80 % +
Tantalum:
285 M Pa(41 ksi)
170 M Pa(25 ksi)
30 % +
80 % +
Cold Worked:
Hardness:
Annealed
Cold Worked
60 HV
150 HV
90 HV
210 HV
Poisson's Ratio
.38
.35
.24
Elastic Modulus
.24
6
Tension
Shear
<147 K
<75 K
800-1100 C
900-1200 C
(Significantly affected
by increasing interstitial contents.)
Recrystallization Temperature
Concentration
Temp.
Nb
Ta
Ti
Zr
50%
Dry
Wet
50 %
5%
30 %
65 %
10 %
40 %
98 %
Boiling
200 F
220 F
Boiling
200 F
200 F
Boiling
Room
Boiling
Boiling
Nil
Nil
Nil
1mpy
1mpy
5mpy
<2mpy
(1)
20mpy
attacked
Nil
Nil
Nil
Nil
Nil
Nil
<2mpy
(1)
Nil
<2mpy
Nil
attacked
Nil
5mpy
>100mpy
rapid
<2mpy
Nil
rapid
rapid
Nil
Nil
10mpy
5mpy
Nil
Nil
<2mpy
Nil
3mpy
<200
158
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Both niobium and tantalum are more expensive than other specialty engineering materials. However,
when the metal costs are incorporated into finished equipment costs, the cost differences are not nearly as great as one might expect. The cost premium associated with niobium and tantalum chemical
process equipment can be justified in many applications requiring long life and low maintainance costs.
Niobium and tantalum applications:
The most common application for niobium is as an alloy addition to steels and superalloys for elevated temperature service, particularly in aerospace applications. Niobium itself is used in many applications, including heat exchangers for chromeplating solutions, cathodic protection systems, electronic
components and nuclear applications.
Niobium's combination of strength, melting point, resistance to chemical attack and low neutron absorption cross-section promotes its use in the nuclear industry. Tantalum does not have a low neutron
absorption cross-section and is used for radiation shielding. Niobium has been identified as the preferred construction material for the first reactors in the space power systems programs.
Although the electronics industry consumes the majority of tantalum produced (approximately 60%)
for capacitors, other industries concerned with corrosion, especially the chemical processing industry,
are accounting for an increasingly large percentage of the market.
Superconductivity may be the most exciting future application for niobium. Niobium itself becomes superconductive at temperatures less than 9.1K, but the niobium 48% titanium alloy is the
most widely used superconducting material. Magnetic fields of up to 10 tesla have been achieved
using the Nb-48Ti alloy at temperatures below 18K. These magnets can be used in medical diagnostic equipment, nuclear fusion power systems, high energy physics research, energy storage
systems, magnetic separation of minerals and scrap, superconducting motors and generators and
many other applications.
Tantalum and niobium mill products are used in the fabrication of corrosion resistant process equipment, including reaction vessels, columns, bayonet heaters, shell and tube heat exchangers, U-tubes,
thermowells, spargers, rupture diaphragms and orifices.
Three basic types of construction are used to fabricate tantalum or Niobium into vessels and other
components for the chemical process industry: loose-lined, integrally-clad and solid.
In loose-lined construction, the tantalum or niobium liners are fabricated and formed into the shell
without bonding. This "loose-lined" construction is the most economical and most widely used method of fabrication. Although economical, this type of construction has some disadvantages such as
unsuitability for use in vacuum service and poor heat transfer qualities due to air space between the
liner and shell.
Because of niobium's chemical inertness, strength, and heat transfer capability, a compact and
maintenance free unit can replace the teflon unit without the need for a steam desuperheating system at a significantly lower cost. Again, tantalum's corrosion resistance, strength and heat transfer
capability combine to make the tantalum unit a very cost effective replacement for the graphite heat
exchanger.
Welding properties:
Good weldability.
Performed as standard but it must be protected with and inert gas such as Argon/Helium or an
industrial mixture, during thewhole process. If the weld becomes contaminated it will be fragile.
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159
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Pgina 160
CATALOGO
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Pgina 161
NIOBIUM
General:
Niobium [or columbium] metal is more resistant to corrosion than most common materials, but is
considerably poorer than tantalum. Niobium has the advantages of lower density and a low thermal
neutron cross section.
Corrosion Resistance of Niobium (Columbium):
At room tempe rature niobium metal is inert to almost all salt solutions and to the mineral acids. As
with tantalum, the exceptions are hydrofluoric acid, fuming sulfuric acid and strong alkalis. As the temperature is raised, niobium's corrosion resistance falls rapidly. At 100 C noticeable corrosion of the metal
occurs in acid media, with the exception of nitric acid to which it remains inert. Acids will often cause hydrogen embrittlement at moderate temperatures, although the corrosion rate may still be quite low. The
list of materials to which niobium is resistant at 100C, is shown in Table 1. Niobium is very corrosion
resistant when compared to most metals. Data on the corrosion rate of niobium are given in Table 2; the
tendency toward hydrogen embrittlement is noted. Even dilute alkalis attack niobium. 5% caustic attacks
niobium at 20C more rapidly than it does tantalum at 100 C. (Compare data in Table 2)
Oxidation of niobium at high temperatures by air, oxygen and nitrogen is about the same as for tantalum. Little data are available for other gases.
TABLE 1. Materials to which Niobium is completely inert up to 100 C (212 F)
Air
Chlorine gas, wet
Hydrochloric acid, dilute
NIOBIUM
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Pgina 162
In the manufacture of high purity chemicals and pharmaceuticals, tantalum insures that no impurities
are introduced from the container or reactor.
Niobium lies between titanium and tantalum in price, density and corrosion resistance. Thus far, its
main use has been in the nuclear reactor field. It has the great advantage of a low nuclear cross section. That, combined with its good corrosion resistance to hot aqueous systems and capability of handling molten metals, has made it an important material of construction in the nuclear field.
TABLE 2 Comparison of corrosion rates for Tantalum, Niobium, Titanium, 304 Steel and Platinum
Medium
Temp.
Acetic Acid
AlCl3 (10% soln)
NH4Cl(10% soln)
HCl, 20%
,conc.
HNO3, 20%
, 70%
, 65%
H3PO4, 85%
H2SO4, 10%
, 40%
, 98%
, 98%
, 99%
, 98%
, 98%
H2SO4, fuming (15% So3)
Aqua regia
Chlorine, wet
H2O, Cl2 sat
, sea
Oxalic acid
NaOH, 5%
, 10%
, 40%
HF, 40 %
Ta
Nb
100
100
100
21
100
21
100
100
100
170
25
100
25
25
25
50
100
200
250
23
70
25
75
25
25
21
96
21
100
100
80
25
212
212
212
70
212
70
212
212
212
338
76
212
76
76
76
122
212
392
482
73
158
78
167
76
76
70
205
70
212
212
176
76
nil
nil
nil
nil
nil
nil
nil
nil
nil
<1
nil
nil
nil
nil
nil
nil
nil
3
rapid
0.5
rapid
nil
nil
nil
nil
nil
0.1
nil
0.7
<1
rapid
rapid
Ti
(a)
nil
nil
nil
<0.5
0.04
175
0.1
4(b)
rapid
nil
nil
nil
nil
<5
<1
8
3(b)
40
nil
7
0.1
60
0.2
0.8 (b)
115(b)
high
rapid
rapid
(assume rapid)
nil
35
nil
nil
nil
5
nil
nil
0.6(b)
1.1
rapid
5
rapid
rapid
304
Pt
20
20
>20
high
rapid
7
> 50
> 50
> 50
>> 50
> 50
50
<1
<1
5
nil
nil
nil
nil
1
nil
nil
nil
nil
nil
nil
nil
800
0.1
nil
nil
nil
nil
nil
nil
Welding properties:
Good weldability.
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Pgina 163
TITANIUM
Metal = Titanium
1. General
Titanium as an industrially pure metal has a great resistance to aggresive environments due to a
self-healing coating that naturally forms, together with its workability and machinability make it a very interesting metal for many situations.
2. Physical properties:
Density: see table 1
Specific heat: 520 J/Kg.xK
3. Chemical composition in %:
Grado
1
ASTM
Ti
Fe
Others
DIN
B-381GrF1
0,08
0,0125
0,05
0,10
balance
0,20
17864
0,08
0,0125
0,06
025
balance
0,25
17864
0,10
0,013
0,06
.025
balance
0,30
17864
0.10
0,013
0,06
0,25
balance
0,30
17864
0,08
0,0125
0,05
<
balance
0,30
B-348Gr1
2
B-348Gr2
B-381GrF2
B-348Gr3
B-381GrF3
B-348Gr4
B-38GrF4
B-384Gr5
B-381GrF5
0,20
Al
17864
5,5 a 6,5
V3,5 a 4,5
B-265
0,08
0,0125
0,03
0,25
balance
0,30
12
B-265
0,08
0,0125
0,03
0,25
balance
0,30
4. Specifications:
Tubes: ASTM B337/B338
CATALOGO
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Pgina 164
resistance can be improved through the introduction of an oxidation agent into the environment or through thickening of the existing oxide coating. Alternatively, an alloy with Mo or Pd can be considered.
Current applications
Aero Engines
Components operating up to 600 C, discs, blades, spacer rings, structural parts, auxiliary equipment, etc.
Air Frames
Fastenings, struts and ties, skins, main structural components in airframes, landing gear, hydraulic equipment, airducting, firewalling, floors,
etc.
Performance Engineering
Chemical and
Petrochemical Engineering
Vessels, plate and tubular heat exchangers, mixers, stirrers filter bodies,
driers, conveyors, pumps and valves. Thermowells, probes, level controls, analyser, etc. especially for crude oil handling and processing and
plant for production of urea, ammonium nitrate and ammonia, fibre and
fertilizer products, chlorine and synthetic resins.
Heat Exchangers and
Titanium will provide protection against environmental pollution and cross
Surface Condensers
pollution form process streams as well as metal ion loss in cooling waters.
(Especially for Power
Titanium tubes are currently available in several extended surface configuGeneration and Desalination) rations, including fine integral fin, roped and clad high fin. Design for corrosion resistance and optimum heat transfer with all liquid systems, liquid/air
systems, condensing and evaporating is therefore possible.
Brewing, Dairy, Food and
The inert nature of titanium aids product purity, provides ease of cleaning
Pharmaceuticals Manufacture and sterilisation, etc.
Metal Finishing Industry
Jigs and fixtures for anodizing of aluminium and electroplating anode baskets for containing nickel and copper chips and residues, hooks for nickel anodes, heating and cooling coils for plating tanks, baskets and jigs
for pickling and descaling, supports and hangers for articles for hot dip
galvanizing.
Pollution Control
and Waste Processing
Specialised
Applications
Surgical implants for the human body, including hip prostheses, bone plates and screws, denture posts. Precision instrument manufacture, pressure sensitive transducers, transistors etc. Artistic and architectural applications, personal jewellery, plaques, dart shafts, etc.
Gr.2 N/mm
-40 + 20
50
75
100
150
200
250
173
173
167
153
126
102
85
164
Even at 20 C, titanium's creep properties must taken into consideration in the calculation of design strength values. The following values are
based on creep-rupture ratings for 100,000 hours.
From a strength perspective the maximum temperature for the usage
of unalloyed titanium grades is approximately 350 C. For components not
subject to stress oxidation sets a limit at aproximately 500 C.
CATALOGO
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Pgina 165
Density
Kg/m3
Melting Point
C
Thermal
Expansion
Coefficient
Thermal
Conductivity
W/(m.K)
Electrical
Resistance
Ohm x m
Elasticity
Modulus
MPa
Titanium
4505
1688
8.4 x 10-6
17
55 x 10-8
106.4 x 103
Iron
7900
1530
12 x 10-6
63
9.7 x 10-8
206.0 x 103
Aluminum
2700
660
23 x 10-6
205
2.7 x 10-8
69.2 x 103
Nickel
8900
1453
15 x 10-6
92
9.5 x 10-8
206.0 x 103
Copper
8900
1083
17 x 10-6
385
1.7 x 10-8
107.9 x 103
7900
1410
17 x 10-6
16
72 x 10-8
200.1 x 103
Brass
8400
970
18.5 x 10-6
100
7.5 x 10-8
107.9 x 103
Monel
8800
1325
14 x 10-6
26
48 x 10-8
179.5 x 103
ASTM
DIN
Ref. N.
Aerospace Specifications
British
Standard
American
American
A.M.S.
MILT
TA
Ti35A/115
Ti50A/125
1
2
3.7025 1
3.7035 2,3,4,5
9046
Ti65A/130
Ti75A/160
3
4
3.7055
3.7065 6,7,8,9
4902, 4941
4942, 4951
4900
4901
Ti0.2% Pd
Ti-Code 12
7.11
12
Ti-6Al-4V/318
Ti-4Al-4Mo-2.5Sn
(550)
Ti-6Al-2Sn4Zr-2Mo
Ti-6Al-2Sn4Zr-6Mo
45-51
and 57
4975, 5976
Remarks
4981
1A
1C
1B
3C
3G
9047
Comp
1.2
Comp
3.6
Comp
11
Comp
14
Commercially
Pure Titanium
Industrial Alloys
with superior
corrosion resitance
Aerospace/Engineering
Alloys having high
strength developed
by heat treatment
165
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Pgina 166
Ultimate Tensile
Strength
Elongation
Youngs
Modulus
Density
Weldability
Rating
tons/sq.in
kg/mm2
tons/in2
kg/mm2
tons/in2
kg/mm2
Ib/in3
gm/cc
Ti35A/115
13 min
20 min
26 max
41 max
25 min
6,650
10,500
.163
4.51
Excellent
Ti50A/125
18 min
28 min
25-35
39-55
20 min
6,650
10,500
.163
4.51
Excellent
Ti65A/130
22 min
34 min
30-40
46-62
20 min
6,650
10,500
.163
4.51
Excellent
Ti75A/160
25 min
39 min
35-45
55-71
18 min
6,650
10,500
.163
4.51
Excellent
Ti0.2% Pd (Gr. 7)
13 min
20 min
25-35
39-55
20 min
6,650
10,500
.163
4.51
Excellent
Ti Code 12
22 min
35 min
27 min
34 min
20 min
6,800
10,700
.163
4.51
Excellent
Ti-6Al-4V/318
54 min
85 min
58 min
92 min
10 min
7,360
11,600
.161
4.45
Good
Ti-4Al-4Mo-2.5 Sn
56 min
88 min
68 min
107 min
10 min
7,500
11,800
.167
4.60
Poor
Ti-6Al-2Sn-4Zr-2Mo
54 min
85 min
58 min
92 min
10 min
7,370
11,600
.164
4.54
Good
Ti-6Al-2Sn-4Zr-6Mo
58 min
92 min
67 min
106 min
10 min
7,370
11,600
.168
4.65
Fair
Salts
Alkalies
Organic Acids
Nitric Acid
ASTM-B Norms
Brinell Hardness
Elongation %
Yield S.
02,%MPA
Tensile S.MPA
Mechanical
properties aprox.
Sea Water
Chlorhydric Acid
5
Phosforic Acid
Sulphuric Acid
3
Fluorhydric Acid
Strenght Stability
4
Carburization
Oxidation
Corrosion resistance
Titanio Grade
CATALOGO
240
170
24
70
265-337-338-348-363-367
345
275
20
80
265-337-338-348-363-367
450
380
18
90
265-337-338-348-363-367
550
485
15
100
265-337-338-348-363-367
895
830
10
265-348; W.3.7165
345
275
20
80
265-338-348-W.3.7235
For comparison of corrosion rates for Tantalum, Niobium, Titanium, 304 stainless steel and Platinum see Niobium (table 2).
10. Welding properties:
Good weldability. Performed as standard but it must be protected with an inert gas such as
Argon/Helium or an industrial mixture, during the whole process. If the weld becomes contaminated
it will be fragile.
11. Products, we supply:
x Plate-strip
166
x Pipes-tubes
x Accessories
x Bars
x Forgings
CATALOGO
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13:35
Pgina 167
ZIRCONIUM
Metal: ZIRCONIUM
1. General
It is a very reactive metal that reacts naturally with the atmospheric oxygen forming a protecting coat that adheres to the metal as a self-healing layer.
2. Machining:
Good machinability, but shavings must be kept in water.
3. Chemical composition:
There are 4 grades (2 pures and 2 alloyed).
Grade/composition
ASTM
Zr+Hf mini
Hf max.
Fe+Cr max.
H. max.
N. max.
C. max.
NbO max.
Grade 702
Grade 704
Grade 705
Grade 706
R60702
90,2
4,5
0,20
0,0005
0,025
0,05
0,16
R60704
97,5
4,5
0,2 a 0,4
0,005
0,025
0,05
0,18
R60705
95,5
4,5
0,2
0,005
0,025
0,05
2a3
0,18
R60706
95,5
4,5
0,2
0,005
0,025
0,05
2a3
0,16
Grade 702
Grade 704
Grade 705
Grade 706
379
207
16
6,51
413
241
14
6,57
552
379
16
6,64
510
345
20
6,64
4. Mechanical properties:
Tensile S. MPa
Yield S. MPa
Elongation %
Density Kg/dm3
mini
mini
mini
5. Specifications:
Plates B551
Bar B550
Forgings B493 wires
CATALOGO
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13:35
Pgina 168
Acetic acid
Urea
Formic acid
Sulphuric acid
Citric acid
Methyl methacrylate
Nitric Acid
7. Welding properties:
Good weldability. Performed as standard but it must be protected with an inert gas such as
Argon/Helium or an industrial mixture, during the whole process. If the weld becomes contaminated
it will be fragile.
8. Products, we supply:
x Plate-strip
168
x Pipes-tubes
x Accessories
x Bars
Forgings
CATALOGO
14/11/05
13:35
Pgina 169
DISCLAIMER:
TECNOCOMMERZ EUROPA, S.L. makes no warranty of any
kind with respect to the subject matter or accuracy of the
information contained herein. Specifically disclaims all
warranties, expressed, implied or otherwise, including
without limitation, all warranties of merchantability and
fitness for a particular purpose.
In no event shall be liable for any special, incidental, indirect
or consequential damages of any kind or any damages
whatsoever resulting from loss of use, data, profits, whether
or not advised of the possibility of damage, and on any
theory of liability, arising out of or in connection with the use
of the information contained herein.
This publication may include technical inaccuracies or
typographical errors. Changes may be periodically made to
the information herein.
CATALOGO
14/11/05
13:35
Pgina 170