Documente Academic
Documente Profesional
Documente Cultură
Lecture 17
Cathodic Protection Influencing Factors and Monitoring
Keywords: Coated Surfaces, Protection Criterion, Anode Materials, Pipeline Protection.
For large structures such as underground pipe lines, impressed current cathodic
protection is used, while for smaller structures such as house-hold water tanks, ships
hull etc, sacrificial anodes can be effectively used. Painting of steel pipe lines and
tubes can significantly reduce protection current requirements and thus save cost.
Approximate current requirements for cathodic protection of steel pipes are given
below:
Uncoated in flowing sea water
10-15 mA/ft2
Well-coated in water
0.01-0.003 mA/ft2
As can be seen above, good surface coating significantly reduces protection current
requirements.
Electrochemical basis for protection criterion can be assessed:
Protection of steel is taken as example:
Fe = Fe++ + 2e
E0 = - 0.44 V
When polarized to half cell potential of above reaction, corrosion rate reduces to 0.
Rate of forward and reverse reaction are same when net reaction rate is zero.
Eh = - 0.44 +
log [Fe++]
1
Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
-0.85 to -0.95 V
Lead
-0.6 V
-0.5 to -0.66 V
Aluminium
-0.95 to -1.2 V
2
Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
Material
Cast Iron
Average
consumption rate
kg/A-year
57
Steel scrap
5-8
Aluminium
45
Graphite
0.6 1.0
Lead
-----
Platinum
-----
Magnesium, zinc and aluminium and their alloys can be used as sacrificial anodes.
Design considerations for both impressed current and sacrificial anode systems have
some common steps.
a) Area to be protected
Exposed areas of the structure in coated system, exposed area at breaks and
deteriorated coatings.
b) Polarised potential Current density based on area need be estimated.
c) Current demand Current density demands depend on the environment and
nature of surface coating.
d) Anode consumption Required number and weights of anode materials
determined from known consumption rates for the desired current demand.
Anode number and distribution for the protected structure can be thus
estimated.
Anode resistance and design output current can then be estimated.
3
Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
4
Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
5
Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore
Electrochemical
Impedance
spectroscopy
Electrochemical noise
Harmonic synthesis
Polarization curves
Polarization
resistance
Physical
Electrical resistance
Radiography
Ultrasonic
Weight loss determination
Use of
6
Course Title: Advances in Corrosion Engineering
Course Co-ordinator: Prof. K. A. Natarajan, IISc Bangalore