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Component
Carbon Dioxide
Methane
Ethane
Propane
Iso-butane
Normal-butane
Iso-pentane
Normal-pentane
Hexanes +
TOTAL
MW
xMW
0.0011
0.0214
0.3897
0.3648
0.0294
0.0877
0.0171
0.0182
0.0706
44.01
16.043
30.07
44.097
58.123
58.123
72.15
72.15
87.436
0.048411
0.3433202
11.718279
16.0865856
1.7088162
5.0973871
1.233765
1.31313
6.1729816
43.7226757
page 23-9
lbm
gal
0.0011072287
0.007852223
0.2680137666
0.3679231736
0.0390830655
0.1165845186
0.0282179665
0.0300331574
0.1411849001
913.79582
6480.43965
221191.762
303646.995
32255.254
96217.2032
23288.2878
24786.3648
116519.898
6.8199
2.5
2.9696
4.2268
4.6927
4.8691
5.2058
5.2614
5.591
133.989622
2592.17586
74485.3723
71838.5055
6873.49585
19760.7778
4473.52718
4710.98278
20840.6185
0.00065135
0.01260115
0.36209019
0.34922317
0.03341361
0.0960616
0.02174682
0.02290115
0.10131095
825300
205709.445
1.5
0.6666666667
MW
44.1
200
100
10.73
Z-factor
0.9359706775
page 23-11
Pure Component Properties
ft3/lbm
lbm/ft3
F
psia
(psia ft3)/(R lbmol)
SRK91 equation
Calculation of Pseudo-critical Te
FIG. 23-2
Component
CH4
C2H6
C3H8
iC4H10
nC4H10
iC5H12
nC5H12
nC6H14
TOTAL
Mole
Fraction,
yi
Component
Critical
Temperature,
Tci, F
0.8319
0.0848
0.0437
0.0076
0.0168
0.0057
0.0032
0.0063
-116.66
89.92
205.92
274.41
305.55
369
385.8
453.8
page 23-11
Calculation of Pseudo-critical Temperature and Pressure for a Natural Gas Mixture
FIG. 23-2
Component
Critical
Temperature,
Tci, R
Pseudocritical
Temperature,
Tpc, R
Component
Critical
Pressure,
Pci, psia
Pseudocritical
Pressure,
Ppc, psia
342.01
548.59
664.59
733.08
764.22
827.67
844.47
912.47
284.518119
46.520432
29.042583
5.571408
12.838896
4.717719
2.702304
5.748561
666.4
706.5
616
527.9
550.6
490.4
488.6
436.9
554.37816
59.9112
26.9192
4.01204
9.25008
2.79528
1.56352
2.75247
Tpc =
Ppc=
391.660022
661.58195
FIG. 23-2
Component
Molecular
Weight,
MW
Mixture
Molecular
Weight,
yi MW
16.043
30.07
44.097
58.123
58.123
72.15
72.15
86.177
13.3461717
2.549936
1.9270389
0.4417348
0.9764664
0.411255
0.23088
0.5429151
MWm=
20.4263979
page 23-17
Component
H2S
CO2
Mole
Fraction,
yi
0.2
0.07
T
P
100
1000
F
psia.
Tc
Pc
433.9
826.9
R
psia
age 23-17
Tc'
29.8
404.1
F
R
Pc'
761.738467 psia
Tr'
Pr'
1.38497897
1.31278653
0.831
Fig. 23-4
Fig. 23-8
page 23-36
Calculation of Viscosity of a Gas Mixture
FIG. 23-2
FIG. 23-2
Mole
Fraction,
yi
Component
Molecular
Weight,
MW
Component
Molecular
Weight,
MW
Component
Critical
Pressure,
Pci, psia
CH4
0.8
16.043
12.8344
667
N2
0.15
28.013
4.20195
492.8
CO2
0.05
44.01
2.2005
1069.5
Component
19.23685
e 23-36
FIG. 23-2
FIG. 23-2
Component
Critical
Temperature,
Tci, F
Component
Critical
Temperature,
Tci, R
Component
Critical
Temperature,
Tci, R
Vci
ft3/lb
Vci
ft /lb mole
Vci
ft /lb mole
-116.66
342.01
273.608
0.0988
1.5850484
1.26803872
-232.53
226.14
33.921
0.051
1.428663
0.21429945
87.76
546.43
27.3215
0.0342
1.505142
0.0752571
334.8505
1.55759527
Zci
ft3/lb
Zci
ft3/lb
0.2880911 0.2304728766
0.29015054 0.0435225814
0.27455162 0.0137275809
0.2877230389
page 23-24
FIG. 23-2
Component
Mole
Fraction,
yi
Methane
Carbon Dioxide
Ethane
Propane
n-Butane
n-Pentane
n-Hexane
n-Heptane
n-Octane
n-Decane
n-Tetradecane
0.20896
0.3973
0.01886
0.02387
0.03586
0.02447
0.01844
0.02983
0.02995
0.18208
0.03038
TOTAL
FIG. 23-2
Component
Molecular
Weight, lb
Weight,
MW
16.043
44.01
30.07
44.097
58.123
72.15
86.177
100.204
114.231
142.285
198.394
3.35234528
17.485173
0.5671202
1.05259539
2.08429078
1.7655105
1.58910388
2.98908532
3.42121845
25.9072528
6.02720972
Relative density
of liquid 60F
0.82203
0.50738
0.58408
0.63113
0.66404
0.68819
0.70698
0.73406
age 23-24
References
Density (60F)
lb/cu ft
51.2289096
31.6199216
36.3998656
39.3320216
41.3829728
42.8880008
44.0589936
45.7466192
47.815
Volume
cu ft
0
895.746347
0
33.2829837
75.8679043
69.4410971
65.7618426
128.195894
150.735442
1185.16923
288.191033
0.22827
0.2724
288.7055
425.18
0.2863
0.58396492
36.4394107
K
K
g/mL
lb/cu ft
page 24-10
Example Enthalpy Calculation
Component
Methane
Carbon Dioxide
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexane
TOTAL
FIG. 23-2
FIG. 23-2
Mole
Fraction,
yi
Component
Molecular
Weight,
MW
Component
Critical
Temperature,
Tci, F
Component
Critical
Temperature,
Tci, R
0.901
0.0106
0.0499
0.0187
0.0065
0.0045
0.0017
0.0019
0.0052
16.043
44.01
30.07
44.097
58.123
58.123
72.15
72.15
86.177
-116.66
87.9
89.92
205.92
274.41
305.55
369
385.8
453.8
342.01
546.57
548.59
664.59
733.08
764.22
827.67
844.47
912.47
MWm=
2055.64
ge 24-10
e Enthalpy Calculation
FIG. 23-2
FIG. 23-2
Pseudocritical
Temperature,
Tpc, R
Component
Critical
Pressure,
Pci, psia
Pseudocritical
Pressure,
Ppc, psia
Acentric
Factor
Ideal Gas
Enthalpy
Btu/lb
308.15101
5.793642
27.374641
12.427833
4.76502
3.43899
1.407039
1.604493
4.744844
667
1069.5
706.5
616
527.9
550.6
490.4
488.6
436.9
600.967
11.3367
35.25435
11.5192
3.43135
2.4777
0.83368
0.92834
2.27188
0.0108
0.2667
0.0972
0.1515
0.1852
0.1981
0.2286
0.251
0.299
292
100
189
162
151
162
151
158
139
Tpc =
369.707512
Ppc=
669.0202