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Chapter 6: Gases
Dr. Chris Kozak
Memorial University of Newfoundland, Canada
Slide 1
www.chem.mun.ca/homes/cmkhome/CMKTeaching
Slide 2
Force (N)
Area (m2)
Liquid Pressure
P = g h d
g = 9.81 m/s2, h = height of column, d = density of liquid
General Chemistry: Chapter 6
Slide 3
Barometric Pressure
Standard
Atmospheric
Pressure
1 00 atm
1.00
760 mm Hg, 760 torr
101 325 kPa
101.325
kP
1.01325 bar
1013.25 mbar
Slide 4
Manometers
Slide 5
STP
Gas properties depend on conditions.
Define standard conditions of
temperature and pressure (STP).
P = 1 atm = 760 mm Hg
T = 0C
= 273.15 K
Slide 6
A Manometer Question
A liquid with d = 0.854 g mL-1 was used in an open-end
manometer to measure a gas pressure that was slightly greater
than atmospheric pressure, which was 745 mm Hg. In the
manometer, the liquid level was 17.5 mm higher in the open
arm than in the arm nearest the gas sample. What was the gas
pressure in torr?
Slide 7
V 1/P
VT
Vn
nT
P
PV = nRT
RT
General Chemistry: Chapter 6
Slide 8
PV = nRT
PV
R=
nT
= 0.082057
0 082057 L atm mol-1 K-1
= 8.3145 m3 Pa mol-1 K-1
= 8.3145 J mol-1 K-1
General Chemistry: Chapter 6
Slide 9
P1
T1
P2
T2
Slide 10
PV = nRT
and
PV =
m
RT
M
M=
m RT
PV
n=
m
M
Slide 11
Example 6-10
Determining a Molar Mass with the Ideal Gas Equation.
Propylene is an important commercial chemical
chemical. It is used
in the synthesis of other organic chemicals and in plastics
production. A glass vessel weighs 40.1305 g when clean,
dry and evacuated; it weighs 138.2410 g when filled with
water at 25C (=0.9970 g cm-3) and 40.2959 g when filled
with p
propylene
py
g
gas at 740.3 mm Hg
g and 24.0C. What is
the molar mass of propylene?
Strategy:
gy
Determine Vflask. Determine mgas. Use the Gas Equation.
General Chemistry: Chapter 6
Slide 12
Example 6-10
Determine
Vflask:
Vflask = mH2O dH2O = (138.2410 g 40.1305 g) (0.9970 g cm-3)
= 98.41
98 41 cm3 = 0.09841
0 09841 L
Determine mgas:
mgas = mfilled - mempty = (40.2959 g 40.1305 g)
= 0.1654 g
Slide 13
Example 5-6
6-10
Use the Gas
Equation:
PV = nRT
M=
PV =
m
RT
M
M=
m RT
PV
CH3
Slide 14
Gas Densities
PV = nRT
and
PV =
m
m
,
n
=
d=
M
V
m
RT
M
m
MP
=d=
V
RT
Slide 15
Slide 16
Example 6-12
Using the Ideal gas Equation in Reaction Stoichiometry
Calculations.
The decomposition of sodium azide, NaN3, at high
temperatures produces N2(g). Together with the necessary
devices to initiate the reaction and trap the sodium metal
formed, this reaction is used in air-bag safety systems.
What volume of N2(g), measured at 735 mm Hg
g and 26C,,
is produced when 70.0 g NaN3 is decomposed?
2 NaN3(s) 2 Na(l) + 3 N2(g)
Slide 17
Example 6-10
Determine moles of N2:
nN2 = 70 g NaN3
1 mol NaN3
65.01 g NaN3
3 mol N2
2 mol NaN3
= 1.62 mol N2
nRT
P
1.00 atm
760 mm H
Hg
= 41.1 L
General Chemistry: Chapter 6
Slide 18
Slide 19
Slide 20
Partial Pressure
Ptot = Pa + Pb +
Va = naRT/Ptot
and
Vtot = Va + Vb+
n
n RT/Ptot
Va
= a
= a
ntotRT/Ptot
ntot
Vtot
t t
t t
n
n RT/Vtot
Pa
= a
= a
ntotRT/Vtot
ntot
Ptot
Th Mole
M l Fraction
F ti
= a The
Slide 21
Partial Pressure
Partial pressure is the pressure of a component of
gas that contributes to the overall pressure.
Partial volume is the volume that a gas would occupy
at the total pressure in the chamber.
Ratio of partial volume to total volume
volume, or of partial
pressure to total pressure is the MOLE FRACTION.
Slide 22
Pneumatic Trough
Total pressure of wet gas (Pgas + PH2O) is equal to
atmospheric pressure (Pbar) if the water level is the same
inside and outside
Slide 23
Slide 24
Slide 25
ek =
1
mu 2
2
N
V
Frequency of collisions,
v =u
Impulse or momentum
transfer
transfer,
I = mu
Pressure p
proportional
p
to
impulse times frequency
N
mu 2
V
Slide 26
1N
m u2
3V
urms =
u2
Slide 27
Pressure
Assume one mole:
PV =
1
NAm u 2
3
PV = RT so:
3RT = N A m u 2
NAm = M:
3RT = M u 2
Rearrange:
u rms =
3RT
M
Slide 28
u rms =
3RT
M
Slide 29
Temperature
Modify:
PV =
1
2
1
NAm u 2 = N A ( m u 2 )
3
3
2
PV=RT
PV
RT so:
RT =
ek =
2
N A ek
3
3 R
(T)
2 NA
Slide 30
Slide 31
Slide 32
Effusion
Eff i
A related phenomenon.
Slide 33
Grahams Law
rate of effusion of A (u rms ) A
3RT/M A
MB
=
=
=
rate of effusion of B (u rms ) B
3RT/MB
MA
Slide 34
Slide 35
Real Gases
At low Pressure, these gases
behave ideally
As pressure increases, the
molecules deviate from ideal
behaviour.
The heavier the gas, the more
weird it behaves
At a critical P and T, some
gases begin to behave like
liquids, but they are NOT
liquids but Supercritical Fluids!
General Chemistry: Chapter 6
Slide 36
P+
n2a
V2
V nb
= nRT
Slide 37