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INDIGO WORKSHOP
There are about ten different plants from around the world which have enough Indigo coloring matter in
them to be practical for harvesting and producing dye for the color blue. In the gardens in Lauris, we find
True Indigo or African or Indian Indigo (Indigofera tintoria), Japanese or Chinese Indigo (Polygonum
tinctorum), Chinese Indigo (Strobilanthes cusia), and European Woad (Isatis tinctoria). Michel will
demonstrate quick organic reduction methods to kick start the fermentation process using the latter two in
Indigo Workshop.
Introduction
Hammering Leaves:
Extracting Indigo Pigment from a Chinese Indigo Plant
Indigo is a substantive dye; it requires no mordant or fixative to remain permanent in the fabric. This is
due to the fact indigo is insoluble in water. To be dissolved, it must undergo a chemical change called
reduction which converts indigo into "white indigo" (leuco-indigo). When a submerged fabric is removed
from the dyebath, the white indigo quickly combines with oxygen in the air and reverts to the insoluble,
the stable color blue which is the indigo blue. The process is called reduction and oxidation and also the
dyeing process is termed mechanical bonding versus chemical bonding the dyeing process in other
dyes such as acid dye, fiber reactive dye, direct dye, etc. Mechanical bonded colors on cloth tends to be
weak against friction, thus fading and whiting of blue jeans along the seams, knees, bottoms - the areas
which receives more wear and tear.
The unique characteristics of indigo dye is demonstrated by using leaves from Chinese Indigo
(Strobilanthes Cusia), which when hammered between two layers of cotton fabric, release their colorant
into the fabric. The color appears green, but with washing and oxidization, the chlorophyll is removed
from the fabric and indican (a coloring matter, colorless, water soluble, derivative of the amino acid
tryptophan) in the fabric binds with oxygen and turns into stable color blue.
Pick fresh leaves from an Indigo Plant. The leaves must be very fresh and used immediately after
picking
Place in a large beaker.
Fill the beaker with boiling water to make an infusion and extract the sap from the leaves.
Set aside (WAIT 15 MINUTES or Longer).
Fill a second large beaker 3/4 full with room temperature water.
Add 1-2 cups finely ground lime (calcium hydroxide)
Stir the beaker very well.
Note: Michel uses oyster shells he collects from local restaurants which he bakes until
the shells will fall apart like ash, usually about 1 hour at 1000 degrees C.
The oyster shells are a natural form of lime and ideally suited for the process.
4. Wait until the lime settles to the bottom of the beaker in order to obtain an aqueous solution that can
be separated from the lime sediment at the bottom.
Step Three: Remove Liquid from Woad Leaves
1. After 15 minutes or more, the liquid is ready. It is a dark amber (yellowish) color.
2. Pour the liquid into a third new beaker, straining off the leaves. Discard or recycle leaves in garden.
3. Oxygenate the liquid by adding air. Pour the liquid back and forth 10-20 times in order to oxygenate
it. If you have a lot of liquid, use an air pump to add air to the liquid.
4. Add the lime water. Michel refers to using a small amount, which is a ratio of 1 part Lime Water to
3-4 parts woad juice liquid.
5. Immediately you should notice the color shifting from amber to a greenish color.
6. Continue oxygenating the liquid until the foam at the surface turns a bit bluish.
Note: The green liquid is a combination of yellow coloring matter (Flavonoids) from the
plant, and Indigo. Indigo is not soluble in water, it appears in the solution as microparticulate matter. So there is both Flavonoids and Indigo in the solution, together.
Because the Indigo is not soluble in water, it will either settle to the bottom, or it can be
removed using a filtration process afterwards.
7. Continue oxygenating until the color is a dark color, and then wait for several minutes until the foam
at the surface appear blue.
x1
x2
x3
Note: There is no right or wrong concentration for your Vat. Michel is familiar
with the dilution of a 10 Gram Vat in a liter of water, the amount of time it takes
to dye the fabric, and the color blue that will result. It is a matter of preference
how much Indigo you use, with the understanding of less Indigo for a lighter
shade, and more indigo for a darker shade, always retaining the ratio of 1-2-3
for the vat to work consistently.
Step Two: Crush your Indigo and Lime to render them soluble in water.
Note: The Indigo is crushed in a plastic jar with marbles and water, hydrating it,
so it will form a suspension in the dye vat solution. If you do not hydrate the
Indigo, you will waste about 90% of your pigment.
The shellfish lime is crushed in a brass mortar until it is a consistent, very fine
powder.
Fruit sugar is very soluble in water and will easily dissolve; there is no
preparation required.
possibility of oxygen entering and spoiling the vat. Therefore a tall/narrow pot is ideal
for the process.
2.Add hot water to the pot.
Note: Michel does not work with exact concentrations in this demonstration, but
appears to be adding enough hot water to fill the empty vat
initially full. He later decides to top it off because of the quantity of fabric
samples he wishes to dye (see #6 notes below).
3.Add the crushed and very well hydrated indigo to the water in the vat. In order not to waste, rinse
the marbles afterwards and add the remaining indigo hydration to the vat.
4.Add the sugar, stirring gently in order to dissolve it.
5.Add the finely crushed Lime powder to the vat, thereby achieving the vat.
6.Stir the liquid with a long spoon in the middle only, to make sure the lime is not at the bottom of
the pot. Stirring in the middle creates movement at the bottom of the vat, but not so much at the
top. This will mix the lime into the liquid but reduce the amount of oxygen added at the surface.
WAIT ABOUT 10 MINUTES before improving the vat.
Note: Michel decides to top off the vat with water, not to change the recipe, but instead
to make the vat larger in volume for the next section where he will dip samples. He
emphasizes that the ratio is always the same, 1-2-3, and the amount of water you use is
a function of the shade of blue you wish to achieve, as well as the amount of fabric you
wish to dye.
7.Stir again from the middle gently. Observe the Vat.
Three things must be present before we proceed to use the vat:
The surface must be shiny with a copper-like coating.
Dark bubbles, metallic and a bit reddish, will have appeared at the surface.
A small sampling with a spoon will show the liquid is a dark green or golden brown.
8.Wait about 15 minutes to improve the vat before proceeding.
Note: Michel waits a minimum of 15 minutes in order to use the Indigo Vat for the
purposes of the demonstration. In fact the vat may sit for several days improving over
time.
3.Remove the fabric from the vat. It should appear as a greenish shade, which is the
intermediate stage between reduced/colorless indigo, and oxygenated indigo
which is blue. The fabric gradually changes from greenish yellow to blue.
4.To improve the process, rinse it in a bowl of clean cold water to help it oxidize
more quickly. The fabric is now turning a bright green, and gradually more and
more blue.
5.To achieve a deeper blue shade, wait until the fabric is fully oxidized, dip the fabric
again, and repeat the rinsing process.
Rough Wool
Silk Fabric
Viscose Velvet
Linen
Greasy Wool
Brownish Wool
Pale Blue
Jade Green
Teal Green
Pale Blue
Faded Green
Darker Brown
Deep Blue
Very Saturated Blue
Very Saturated Deep Blue
Deep Blue
Deep Blue
Even Darker Brown/Blue
Comments:
The greasy wool is taking much more colorant in the 3-day Vat than the raw wool, which performed
better in the Fresh Vat.
Viscose velvet which did not produce a nice shade of blue in a Fresh Dye Vat is now producing a
deep blue color, not because of the fiber type, but because of the structure of the fabric. Velvet
fabric will take on substantially more colorant and benefit from the mature Vat.
The same dye Vat will produce a variety of results depending on the type fiber, the structure of the fiber/
fabric, and other elements such as the pH of the Vat which will be explained later.
Indigo Vat 1-2-3! with Henna - A Concentrated 30g Vat -- Step by Step
As with Fructose in the earlier demonstration, Henna, a small flowering tree, is a readily available
product which can be used for the Vat 1-2-3! Henna has some excellent antioxidant values like Fructose,
and can be used to prepare an Indigo Dye Vat as well.
Michel chooses to prepare a very concentrated Vat, and will triple the portions of each ingredient.
For Preparing the Indigo (Dye) Vat 1-2-3! with Henna, you just need three things:
One Part Dried Natural Indigo Pigment or the Paste Produced in the Previous Section
Shellfish Lime (Calcium Hydroxide) as an interesting, natural base
An Anti-oxidant which will remove the oxygen from the vat, in this case, Henna
Step One: Measure your Materials and Place in the Vat.
In the following ratio for a 30 Gram Concentrated Indigo Pigment Vat with Henna:
1 Part Indigo
2 Parts Lime
3 Parts Henna
+ Hot Water, close to boiling
x1
x2
x3
Sequence: First add the henna, then the indigo, and last the lime directions according to p. 5
Step Two: Crush your Indigo and Lime to render them soluble in water.
The Indigo is crushed in a plastic jar with marbles and water as before.
The shellfish lime is crushed in a brass mortar until it is a consistent, very fine powder, as
before.
Henna is very soluble in water and will easily dissolve; there is no preparation required.
Step Three: Preparing the Indigo Vat
The vat is stirred from the middle as before, and allowed to sit for 15 minutes before observing
the results.
Step Four: Observe and Test the Vat
The Vat is ready. It has a coppery/oily surface and bubbles are appearing. Michel tests the Vat by dyeing
some viscose fabric in the Vat as previously described. He stresses that the Vat will be exceptional if
allowed to sit for 2-3 days, but that some good results will appear at this time as well.
The Results Observed:
The fabric when rinsed shifts from green to a very very dark blue in a matter of minutes. The
concentrated Vat achieves strong results with one dyeing cycle only.
The Concentrated Vat can be used as a kind of mother vat -- it can be diluted in various ratios and
concentrations later on and for very very dark shades.
The Concentrated Vat is ideally suited for pressed or tied fabrics such as tie dyed and clamped
fabrics, Shibori fabrics and resist fabrics such as batik.Indigo with Resist:
DISC ONE: INDIGO WORKSHOP
CHAPTER NOTES copy right (c)2011 Michel Garcia & Yoshiko Iwamoto Wada
For other volumes, use the ratio above according to the amount of water you are using.
For example for 200ml of water:
20 Grams of Magnesium salt,
40 Grams Arabic Gum
60 Grams of Herbal Ghassoul Clay
How it works: The Magnesium Salt gives a chemical effect, preventing the Indigo
from bonding with the fabric fibers. The Arabic Gum gives a physical resist, acting
much like a glue, preventing the indigo from bonding as well. And finally, the Clay
provides a mechanical coating to the fabric fibers, providing even further resist against
the Indigo on the fabric.
Step One: Crush the Arabic Gum
Arabic Gum comes from the Acacia Tree, and it may come ground or it may be in
chunks. It must be crushed to a fine powder.
Step Two: Crush the Ghassoul Clay
The Clay needs to be reduced to a fine powder, and Michel prefers a Mortar for a
demonstration on grinding it down to a powder.
The Magnesium Salt does not require preparation, it is soluble and already ground.
Step Three: Combine Ingredients to Prepare the Resist
DISC ONE: INDIGO WORKSHOP
CHAPTER NOTES copy right (c)2011 Michel Garcia & Yoshiko Iwamoto Wada
1.Dissolve the 10 Grams of Magnesium Salt in the 100ml of water first. Allow it to dissolve for
several minutes.
2.Transfer the Magnesium Salt-Water solution to a magnetic mixer if one is available.
3.Add the 20 Grams of Arabic Gum and dissolve using a magnetic mixer if one is available because
it will take some time and effort. Otherwise stir constantly while adding the gum and give it
plenty of time to dissolve - even overnight if necessary. Allow the Arabic Gum to fully dissolve
before adding the Clay, about 5-10 minutes using the magnetic mixer. The solution should be
milky at this time.
4.Add the Clay to the mixture. The clay will expand in the solution, and will thicken it considerably.
The right point is when the texture is syrupy and smooth. A mortar and pestle is useful after you
add the clay
Step Four: Apply the Clay Paste Resist and Dye the Fabric
1.Using a brush (or other applicator), apply the Clay Paste to the white cotton fabric liberally.
2.Dry the paste pattern on the fabric completely.
3.Carefully add the fabric to the Indigo Vat to dye it.
Michel says for the effect I am after, 1 minute in the Indigo Vat is sufficient dye time.
4.Remove the fabric from the Vat, squeezing out excess dye into the Vat.
5.Transfer the fabric to a bowl of clean water to oxidize the Indigo and to dissolve the Clay Paste.
Allow the fabric to soak for several minutes or until the clay paste is dissolved.
6.Remove the fabric for inspection.
A pale blue shade pattern appears against a blue background.
7.Dry the fabric completely before continuing.
Step Five: Repeat the Process (Step Four) to achieve more shades of blue and a more complex
pattern on the cloth.
By applying the resist Paste to some paler areas and overlapping the solid blue areas, it
is possible to get now two (2) shades of blue from the next dip in the Indigo Vat -- a
deeper shade on the paler area where held with resist, and an additional shade on the
solid blue background.
To achieve a stronger and more noticeable effect, leave the dyed fabric in the Indigo Vat
2-4 Minutes on this second dipping, to allow the fabric to absorb more dye. Oxygenate
and rinse as before, again spending a bit more time in the water, maybe 2-4 minutes.
Observe the interesting results, a combination of Clay Resist Paste and Indigo Dye.
The paste can be preserved for several days. Cover it to prevent evaporation.