Documente Academic
Documente Profesional
Documente Cultură
com
CHEMISTRY – 1998
RAJASTHAN P.E.T.
m
co
2. Which of the following is amphoteric :
g.
(1) GeO2 (2) CO2
(3) PbO2 (4) All same
ng
3. CH3COOC5H11 is obtained by :
(1) C5H11OH + CH3COOH
ye
.m
(2) C5H11CH2OH = HCOOH
w
4. 5 amp. current is passes through a dry cell for 2 hours. The value of produced electric
by
current will be :
(1) 36 x 108 C (2) 3.6 x 108 C
d
4
(3) 36 x 10 C (4) 3.6 x 104 C
e
er
6. Orthouitropnenol is a A;
(1) Lewis base (2) Lewis acid
(3) 1 and 2 (4) nither 1 nor 2
Powered by www.myengg.com
8. Glycine works in a reaction as : Powered by www.myengg.com
(1) Acid (2) Base (3) both 1 and 2 (4) none of these
11. O-F bond in OF2 compound is formed by the overlapping of following orbitals :
(1) sp2-2p (2) sp3-2p (3) sp3-2s (4) sp-2p
m
13. The no. of structural isomers of heptane is :
co
(1) equal to pentane (2) less than hexane
(3) more than pentane (4) less than pentane
g.
ng
14. Which of the following hydroxide is soluble in NH4OH :
(1) Sb(OH)3 (2) Bi(OH)3 (3) Fe(OH)3 (4) none of above
ye
.m
15. Which of the following differs from others :
(1) Pd (2) CO (3) Ni (4) Rb
w
w
(1) (CH3)2C(OH)C13
(2) (CH3)2C=CHCOCH=C(CH3)2
by
(3) (CH3)2C=CHCOCH3
(4) none of above
e d
er
(2) H2O
Po
(3) CH3COOH
(4) HI
19. For which of the following elements the quantum nos are 3, 2, 0, + ½ :
(1) K (2) CO (3) Ne (4) C1
20. The coordination nos. of Na+ and C1- in NaCI are respectively :
Powered by www.myengg.com
(1) 6, 6 (2) 4, 6 (3) 6, 8 (4) 8, 8
Powered by www.myengg.com
m
(1) equal to cyclopean
co
(2) equal to each other
(3) all are different
g.
(4) none of these
ng
25. CF2C12 is used as :
(1) Anaesthic (2) Polymer (3) Refrigerant
ye
(4) Antipyretic
.m
26. The weight of carbon atom is :
w
(1) 1.9 x 10-23 (2) 12 gm (3) 6 gm (4) 6.02 gm. X 1023 gm.
w
w
30. The mole fraction of acetone in a solution of 2.8 mole acetone and 8.2 mole of CHC13 will be :
(1) 0.540 (2) 0.241 (3) 0.254 (4) 0.524
Powered by www.myengg.com
33. The dry ice is : Powered by www.myengg.com
(1) Solid H2O (2) Solid CO2 (3) Solid & Dry H2O (4) none of above
→
←
34. For the reaction 2A C + D the value of equilibrium constant is 1 x 10-3 . If [C] = 1.2 x 10-3 M,
[D] = 3.8 x 10-6 M the value of [A] will be :
(1) 5.2 x 10-6 M (2) 3.6 x 10-9 M
-3
(3) 2.1 x 10 M (4) 4.8 x 10-12 M
35. Which of the following does not obey the octet rule :
(1) PCI3 (2) SF6 (3) SO2 (4) OF2
m
38. Which of the following has highest melting point :
co
(1) C4H10 (2) C3H8 (3) C2H6 (4) CH4
g.
39. Which of the following is not a metal :
ng
(1) Au (2) Hg (3) Ag (4) none of these
41. The shape and size of 2p, 3p, 4p and 5p orbital are :
w
(3) different
(4) equal
e d
43. If the ionization constant of CH3COOH is 1.8 x 105, the degree of ionization of 0.01 M
Po
CH3COOh will be :
(1) 1.8 x 10-7 (2) 1.8 (3) 4.2 x 10-2 (4) 42.4 x 10-5
44. If the price of Nac1 sugar are 2 and 14 rupees per kg. then the price of 1 mole NaC1 and 1
mole sugar will be :
(1) 7 Rs. (2) different (3) equal (4) 28 Rs.
46. In which of the following central atom uses sp2 hybrid orbitals :
(1) SbH3 (2) NH3 (3) PH3 (4) +CH3
Powered by www.myengg.com
47. Which of the following is paramagnetic :Powered by www.myengg.com
(1) C (2) CN- (3) O2- (4) NO+
49. C3H8 on combustion gives CO2 and H2O. The required volume of O2 will be :
(1) 5 times of C3H8 (2) three times (3) 2 times (4) 2.5 times
m
co
53. The most light weight inert gas is :
(1) Ar (2) Ne (3) He (4) Kr
g.
ng
54. Which of the following element forms cation easily :
(1) Sr (2) Ne (3) Li (4) Mg
ye
.m
55. Which of the following is the strongest ionic compound :
(1) LiC1 (2) HC1 (3) CsC1 (4) CH3C1
w
w
57. CO is isoelectronic of :
(1) N2+ (2) O2+ (3) CN- (4) O2-
e d
er
(3) n = 0
Po
59. The dipole moment of BF3 is zero. Which of the following 6 bond orbitals are used by B :
(1) sp2 (2) sp (3) sp3 (4) none of these
Powered by www.myengg.com
63. The molecule which has linear structure Powered
is : by www.myengg.com
(1) NO2 (2) SO2 (3) CO2 (4) OCl2
1 2
65. N=C-C-CH2 in this compound bond
H
Between C(1) and C(2) is formed by hybrid orbitals of :
(1) sp & sp2 (2) sp & sp3 (3) sp & sp (4) sp2-sp2
66. The dipole moment of CCl4 is zero, because of :
(1) equal electron affinity of C, and Cl
(2) equal size of C and Cl
(3) regular size of C and Cl
(4) planar structure
m
67. The number of moles of H2 at 500 cm.3 volume, 700 mm. pressure and 3000 K temperature
co
will be:
(1) 0.203x10-2 moles
g.
(2) 20.x10-3 moles
ng
(3) 20.3x10-2 moles
(4) 2.03 x 10-7 moles
ye
68.Which of the following has electronic configuration as 4f1-145s25p65d16s2 :
.m
(1) Representative elements
w
(3) Lanthanides
w
(4) Actinides
by
69. The wave number of hydrogen atom in Lymen series is 82, 200 cm.-1. The electron
goes from :
e d
(1) III orbit to II (2) II orbit to I (3) IV orbit to III (4) none of these
er
(1) PVC (2) Tetrafluro ethane (3) Tetra fluro ethane (4) C2H4
Po
Powered by www.myengg.com
74. The first inert gas compound invented was :
Powered by www.myengg.com
(1) KrF6 (2) XeF6 (3) XeF2 (4) XePtF6
m
79. In which of the following nos. of primary carbon atoms are maximum :
co
(1) is pentane (2) iso-octane (3) neopentane (4) all of these
g.
80. Na2 S2O3 is used in photography because :
ng
(1) It is a compound of sulphur
(2) It reacts with Ag Br to form sodium silver thisulphate
(3) It is an antichlor reagent
ye
.m
(4) none of these
w
Powered by www.myengg.com
(2) F.C.R. Powered by www.myengg.com
(3) Wurtz reaction
(4) Markownikoff’s rule
89. H2O2 is :
(1) strong oxidizing agent and weak reducing agent
(2) neigther oxidizing agent nor reducing agent
(3) only reducing agent
(4) only oxidizing agent
m
co
91. Carborundum is :
(1) SiB (2) SiC (3) SiO2 (4) CO2
g.
ng
92. Stainless steel is :
(1) Fe, Ni, CO, C (2) Fe, Mg, Ni, C
(3) Fe, Cr, Ni, C (4) Fe, Mn, Cr, Ni
ye
.m
93. fluorine is formed by electrolysis of the fused mixture of K and HF because :
w
95. The colour of the solution of alkali metal in liquid ammonia appears to blue due to :
e
er
96. The solubility product of calcium oxalate is 2.5 x 10-3 mole2/liter-2 . The required
minimum concentration of calcium ion to precipitate it will be :
(1) >5x10-2 (2) 5x10-2 (3) <5x10-2 (4) none of these
Powered by www.myengg.com
(4) Bauxite Powered by www.myengg.com
99. Which of the following gives rod colour precipitate with sodium cupritartaarate :
(1) CH3COOH (2) CH3COCH (3) CH3COC2H5 (4) CH3CHO
m
co
g.
ng
ANSWER SHEET
1.(3)
12.(4)
2.(1)
13.(3)
3.(1)
14.(3)
4.(4)
15.(4)
ye
5.(3) 6.(1) 7.(3)
16.(2) 17.(4) 18.(2)
8.(3)
19.(1)
9.(4)
20.(1)
10.(4)
21.(1)
11.(2)
22.(2)
.m
23.(3) 24.(3) 25.(3) 26.(1) 27.(1) 28.(2) 29.(1) 30.(3) 31.(1) 32.(3) 33.(2)
34.(3) 35.(2) 36.(3) 37.(1) 38.(1) 39.(4) 40.(3) 41.(3) 42.(1) 43.(3) 44.(2)
w
45.(4) 46.(4) 47.(3) 48.(3) 49.(1) 50.(3) 51.(4) 52.(1) 53.(3) 54.(1) 55.(3)
w
56.(1) 57.(3) 58.(2) 59.(1) 60.(2) 61.(3) 62.(2) 63.(3) 64.(4) 65.(1) 66.(3)
w
67.(4) 68.(3) 69.(2) 70.(3) 71.(4) 72.(1) 73.(4) 74.(4) 75.(1) 76.(1) 77.(1)
by
78.(3) 79.(2) 80.(2) 81.(3) 82.(4) 83.(3) 84.(4) 85.(2) 86.(2) 87.(3) 88.(2)
89.(1) 90.(4) 91.(2) 92.(3) 93.(3) 94.(1) 95.(2) 96.(1) 97.(2) 98.(1) 99.(4)
d
100.(2)
e
er
w
Po
Powered by www.myengg.com